CN103410276A - Roof photovoltaic waterproof coiled material and preparation method thereof - Google Patents

Roof photovoltaic waterproof coiled material and preparation method thereof Download PDF

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Publication number
CN103410276A
CN103410276A CN2013103685294A CN201310368529A CN103410276A CN 103410276 A CN103410276 A CN 103410276A CN 2013103685294 A CN2013103685294 A CN 2013103685294A CN 201310368529 A CN201310368529 A CN 201310368529A CN 103410276 A CN103410276 A CN 103410276A
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waterproof roll
film
photovoltaic
roofing
waterproof
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CN2013103685294A
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CN103410276B (en
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李晓军
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New Dayun Waterproof Technology Tangshan Co ltd
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Yantai Sitanpu Fine Construction Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/10Photovoltaic [PV]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/542Dye sensitized solar cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

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Abstract

The invention discloses a roof photovoltaic waterproof coiled material which is of a layered structure and sequentially comprises a waterproof coiled material substrate, a flexible thin film photovoltaic cell assembly, a film layer and a coating layer from inside to outside. The invention also discloses a method for preparing the roof photovoltaic waterproof roll, which comprises the following steps: (1) preparing a waterproof coiled material substrate: cleaning one side of the surface of the waterproof coiled material substrate for later use; (2) preparing a photovoltaic cell assembly: coating a nanoscale organic silicon acrylic coating or a nanoscale fluorocarbon coating on the front surface of a flexible thin-film photovoltaic cell module of which the surface is packaged by a fluorine-containing TPT polyester film or an ethylene-tetrafluoroethylene copolymer film; (3) merging and packaging: the flexible film photovoltaic cell module, the Xika single-component high-modulus polyurethane sealing adhesive and the waterproof coiled material substrate are sequentially stacked, and the components of all layers are tightly bonded through rolling and vacuumizing treatment of a laminating machine to obtain the product. The preparation method is simple, low in cost and large in substrate selection scope, and is suitable for large-area industrial production.

Description

A kind of roofing photovoltaic waterproof roll and preparation method thereof
Technical field
The present invention relates to building energy conservation and photoelectricity building field, relate to a kind of photovoltaic building materials that are applied to the BIPV (Building Integrated PV) building, be specifically related to a kind of roofing photovoltaic waterproof roll and preparation method thereof.
Background technology
Traditional roofing is only the function of becalming and taking shelter from rain, and long-term exposing to the sun and rain causes building roof waterproof layer aging damage, and it had both reduced the use function of building, has reduced the application life of building, has wasted again a large amount of sunlight resources.How to make sunshine change into advantageous effect to the adverse effect of building, change sunshine into inexhaustible regenerative resource, meet the demand of green building to roof waterproof, prolongation building application life and the required electric power of generating power for their own use, become the important research content of photoelectricity building field.
Roofing is solar energy utilization occasion the most easily and effectively, is that photovoltaic generation is in architectural preferred location.The form that roofing photovoltaic generating at present mainly takes to install the crystal silicon photovoltaic cell panel, the crystal silicon photovoltaic cell panel is arranged on building roof two kinds of fixed forms usually: a kind of is to utilize deadweight or increase ballast, directly be placed on roofing, because load is large, on light roof and long-span roofing, can't apply, exposing also difficult application on water-proof roofing, produce normal pressure because the component of tilting ballast cell panel can expose coiled material to roofing in addition, long term can destroy roof waterproof layer; Another kind of fixed form is that fixture penetrates the rolled roofing material waterproofing course, and roof construction layer fixes, and can destroy waterproofing course like this, and infiltration hidden danger is arranged, and does not meet the basic principle of waterproof.Above two kinds of fixing meanss all exist wind the potential safety hazard such as to take off.The unfavorable factors such as crystal silicon photovoltaic cell panel installation system, except the destruction existed waterproofing course, also exists increase building bearing and high-rise wind to take off risk, and the impact building is attractive in appearance.
The photovoltaic film battery assemblies such as non-crystalline silicon belong to second generation photovoltaic cell, it has following technical characterstic: 1, light matter and thin body; But 2, the good flexing of pliability, be suitable for various special opposite sex surface; 3, the low light level, scattered light, diffused light absorptive capacity are strong; 4, mat formation simple and easy to do, can with any substrate compoiste adhering.At present existing correlation technique is on-the-spot bonding with waterproof rolls such as TPO, EPDM, EPDM rubber waterproof rolling material or thermoplastic polyolefin waterproof roll modified bitumens at water-proof roofing by flexible solar photovoltaic film battery components such as non-crystalline silicons, form photovoltaic waterproof roll roofing, but there is the execute-in-place complexity in this technique, quality is affected greatly by environment and human factor, the problems such as comprehensive cost height.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of roofing photovoltaic waterproof roll and preparation method thereof, described roofing photovoltaic waterproof roll both can be used as waterproof roll, can carry out photovoltaic generation again, the functional photovoltaic building materials component required for meeting BIPV (Building Integrated PV).
A kind of roofing photovoltaic waterproof roll, described roofing photovoltaic waterproof roll is layer structure, comprises successively from the inside to the outside waterproof roll base material, fexible film photovoltaic cell component, rete and dope layer.
Roofing photovoltaic waterproof roll of the present invention, wherein said waterproof roll base material is EPDM rubber waterproof rolling material or thermoplastic polyolefin waterproof roll.
Appropriate butyl rubber, vulcanizing agent, accelerator, softening agent and reinforcing agent etc. mix with ethylene propylene diene rubber in EPDM rubber waterproof rolling material system, process through operations such as banburying, pulling-on piece filtration, extrusion moldings.This waterproof roll has excellent against weather, resistance to ag(e)ing, and also tensile strength is high, elongation per unit length is large, flexible to basic unit or ftracture strong adaptability, lightweight, serviceability temperature wide ranges (can use for a long time in-40~+ 80 ℃ of scopes), be a kind of high-effective water-proof material.It also can coldly be constructed, easy and simple to handle, and environmental contamination reduction improves workman's condition of labor, and EPDM rubber waterproof rolling material belongs to high-grade waterproofing materials, is applicable to roofworks and exposes waterproof as individual layer, also is applicable to the roof waterproof engineering of matcoveredn.
Thermoplastic polyolefin waterproof roll, that to adopt advanced polymerization technique be base-material by the TPO synthetic resin that EP rubbers and polypropylene combine, the new type waterproof coiled material that adds antioxidant, age resistor, softening agent to make, it is done inner reinforcing material with the polyester fiber grid cloth and makes enhancement type water-proof coiled material, belongs to synthetic polymeric waterproofing material class waterproof product.But such waterproof roll has good weather-proof ability, low-temperature tenderness and welding characteristic, and this product demonstrates the rubber high resiliency at normal temperature, at high temperature again can moulding as plastics.Therefore have good processing characteristics and mechanical property, and have the high-strength soldering performance, and after in the middle of material, adding one deck dacron fabric, can strengthen its physical property, improve its breaking strength, antifatigue, anti-puncture ability.
Roofing photovoltaic waterproof roll of the present invention, wherein said waterproof roll base material is single layer structure, thickness is: 1.2mm~2.0mm.With multilayer roof waterproof systems such as asphalt water-proof coiled materials, compare, single ply waterproofing prepared roofing waterproofing system has more flexibility and extensibility, owing to having reduced the roof waterproof structure level, single-layer roof is easy to design, construction, more economizes on resources, Cost reduction and raising work efficiency.Owing to having adopted mechanical fixing means, the single ply waterproofing prepared roofing can carry out waterproof and insulation integrated construction, and these are the not available advantages of other types roofing; Secondly, the performance of leaking of preventing of single ply waterproofing prepared roofing position of joints is better than the rigid joint roofing.
Roofing photovoltaic waterproof roll of the present invention, wherein said fexible film photovoltaic cell component are non-crystalline silicon flexible solar hull cell, copper indium potassium selenium thin-film solar cells, cadmium antimonide thin-film solar cells, dye-sensitized cell or organic film battery.
Roofing photovoltaic waterproof roll of the present invention, wherein said rete are fluorine-containing TPT polyester film or ethene-TFE copolymer film (ETFE), and thickness is 250um.The distinctive self-cleaning of this encapsulating film surface makes it have high anti-soil, easy cleaning, characteristics that against weather is good, and rainwater just can be removed the major pollutants of film surface usually.
Roofing photovoltaic waterproof roll of the present invention, wherein said dope layer are nanoscale organosilicon-modified acrylic coating or nanoscale fluorocarbon coating, and thickness is 30~70um.In the building-up process of organosilicon modified crylic acid resin, use a large amount of element silicons, therefore had very strong anti-uv-ray and the durability of overlength.Described nanoscale organosilicon-modified acrylic coating had both had good surface strength, had again splendid water resistance, also had simultaneously higher self-cleaning property, the globule at coating surface just like dropping on lotus leaf landing rapidly.Smooth coating surface makes dust and spot be difficult to adhere to, but natural wind and rainwater carry out automated cleaning with regard to effects on surface.This coating has strengthened the antifouling property of fluorine-containing TPT polyester film or ethene-TFE copolymer (ETFE) encapsulating film greatly, has reduced the impact on the photovoltaic cell component power generation performance of dust and dirt.Nanoscale fluorocarbon coating water white transparency, surface tension is low, and contact angle is greater than 120 degree, has powerful hydrophobic, oil rub resistance ability, the dirt such as dust and coating surface contact area is greatly reduced, thereby have the automated cleaning characteristic be unsurpassed in excellence.This coating has strengthened the antifouling property of fluorine-containing TPT polyester film or ethene-TFE copolymer (ETFE) encapsulating film greatly, has reduced the impact of the atmosphere pollutions such as acid rain, greasy dirt, vehicle exhaust on the photovoltaic cell component power generation performance.
Roofing photovoltaic waterproof roll of the present invention, wherein said roofing photovoltaic waterproof roll also comprises tack coat, described tack coat consists of west card one pack system high modulus polyurethane sealant Sikaflex-11FC (Pro), and described waterproof roll base material and fexible film photovoltaic cell component bond.
Roofing photovoltaic waterproof roll of the present invention; wherein said flexible thin-film battery assembly is connected with the both positive and negative polarity wire; the both positive and negative polarity wire adopts closed male and female fast interface and outside electrical appliance on adjacent photovoltaic waterproof roll to cooperatively interact to be connected, and described wire brushing marine glue also arranges waterproof adhesive tape as topping.
A kind of method for preparing the roofing photovoltaic waterproof roll, comprise the steps:
(1) preparation of waterproof roll base material: clean out a side of waterproof roll substrate surface standby;
(2) preparation of photovoltaic cell component: with fexible film photovoltaic cell component front surface coated nanoscale organic silicon acrylic coating or the nanoscale fluorocarbon coating of fluorine-containing TPT polyester film or ethene-TFE copolymer film (ETFE) encapsulation, coating thickness is 30~70um on surface; Described fluorine-containing TPT polyester film or ethene-TFE copolymer film (ETFE) thickness is 250um;
(3) adopt west card one pack system high modulus polyurethane sealant by the surface of described flexible thin-film battery assembly bottom adhesive to described waterproof roll base material;
(4) merge encapsulation: the order according to fexible film photovoltaic cell component, west card one pack system high modulus polyurethane sealant, waterproof roll base material stacks gradually, and vacuumizes processing through roll-in and laminating machine, makes each layer assembly close adhesion, obtains product.
The method for preparing the roofing photovoltaic waterproof roll of the present invention, wherein said waterproof roll base material are that EPDM rubber waterproof rolling material or thermoplastic polyolefin waterproof roll thickness are: 1.2mm~2.0mm;
Described fexible film photovoltaic cell component is non-crystalline silicon flexible solar hull cell, copper indium potassium selenium thin-film solar cells, cadmium antimonide thin-film solar cells, dye-sensitized cell or organic film battery.
Roofing photovoltaic waterproof roll difference from prior art of the present invention is that the present invention has adopted the flexible thin-film solar photovoltaic cell components such as non-crystalline silicon, one of maximum difference of this assembly and traditional crystal silicon solar energy battery can utilize the substrate of the material of the light weight softnesses such as stainless steel or various polymer as solar cell exactly, but makes it to have softness, the advantage such as frivolous and flexing; Have waterproof concurrently, strengthen the multiple use functions such as cracking resistance and photovoltaic generation, be applied to the photoelectricity building of newly-built and existing building reducing energy consumption, realize simultaneously building roof waterproof and the required electric power of generating power for their own use.
Roofing photovoltaic waterproof roll of the present invention is laid immediately on water-proof roofing by the construction technology of the macromolecule waterproof rolls such as TPO, EPDM EPDM rubber waterproof rolling material or thermoplastic polyolefin waterproof roll, realizes photovoltaic building materials and roof waterproof engineering Synchronization Design, synchronous construction, synchronizes examination, synchronous maintenance maintenance; Photovoltaic waterproof roll of the present invention both can be applied to long-span roofing, light roofing, also can be applied to other roofing, both can lay by local small size, also can lay by the houseful face, the roofing area utilization is high, do not need extra support system, space-saving, integrated construction, good integrity, do not affect the outward appearance of building, reduced installation cost, the waterproofing system of architectural exterior-protecting construction combines together with regenerative resource, forms real BIPV (Building Integrated PV) (BIPV) solar energy house plane system.
Preparation method of the present invention blocks one pack system high modulus polyurethane sealant Sikaflex-11FC (Pro) fexible film photovoltaic cell component and TPO with west in factory, the contour molecular monolayer waterproof roll of EPDM EPDM rubber waterproof rolling material or thermoplastic polyolefin waterproof roll blocks one-component high modulus polyurethane fluid sealant bonding agent by west, through roll-in and laminating machine, vacuumize processing, make each layer assembly close adhesion, form a kind of flexible web component that integrates waterproof and photovoltaic generation, all kinds of problems that repeatedly occur in process of deployment at the scene to reduce waterproof roll and fexible film photovoltaic cell component, manufacture method of the present invention is relatively simple, thereby cost is lower, and the choice of substrate is large, suitable large tracts of land suitability for industrialized production, the more existing crystal silicon solar energy battery of photovoltaic output characteristics of described non-crystalline silicon flexible thin-film solar cell assembly will be got well, not only can utilize solar energy direct projection generating, can also utilize surround lighting to realize low light level generating, its surface seals to prevent that water and oxygen from entering with as thin as a wafer fluorine-containing TPT polyester film or ethene-TFE copolymer diaphragm (ETFE), and the generating life-span reached more than 20 years.
Below in conjunction with accompanying drawing, roofing photovoltaic waterproof roll of the present invention is described further.
The accompanying drawing explanation
Fig. 1 is the structural representation of roofing photovoltaic waterproof roll of the present invention;
Fig. 2 is the partial enlarged drawing at the K place of Fig. 1.
The specific embodiment
Embodiment 1
As depicted in figs. 1 and 2, a kind of roofing photovoltaic waterproof roll, be layer structure, comprises successively from the inside to the outside waterproof roll base material 1, fexible film photovoltaic cell component 3, rete 4 and dope layer 5.Described waterproof roll base material 1 is EPDM rubber waterproof rolling material; Described waterproof roll base material 1 thickness is 2.0mm; Described fexible film photovoltaic cell component 3 is non-crystalline silicon flexible solar hull cell; Described rete 4 is fluorine-containing TPT polyester film or ethene-TFE copolymer film (ETFE), and thickness is 250um; Described dope layer 5 is nanoscale organosilicon-modified acrylic coating, and thickness is 30um.
Described roofing photovoltaic waterproof roll also comprises tack coat 2, consists of west card one pack system high modulus polyurethane sealant Sikaflex-11FC (Pro), and described waterproof roll base material 1 and fexible film photovoltaic cell component 3 bond; Described fexible film photovoltaic cell component is connected with the both positive and negative polarity wire, and the both positive and negative polarity wire adopts closed male and female fast interface, and described wire outside is topping with marine glue, and adopts the fire-proof and water-proof adhesive tape to protect wire.
Described wire outside is topping with marine glue, and adopts the fire-proof and water-proof adhesive tape to protect wire; In factory, with west card one pack system high modulus polyurethane sealant Sikaflex-11FC (Pro), fexible film photovoltaic cell component 3 is bonded to EPDM rubber waterproof rolling material or thermoplastic polyolefin waterproof roll base material 1 surface, through roll-in and autoclave, process, make each layer assembly close adhesion, make the photovoltaic building materials with building roof waterproof and photovoltaic generation several functions.
Embodiment 2
A kind of roofing photovoltaic waterproof roll, described waterproof roll base material 1 is thermoplastic polyolefin waterproof roll; Described waterproof roll base material 1 is single layer structure, and thickness is 1.2mm; Described fexible film photovoltaic cell component 3 is the organic film battery; Described dope layer 5 is 70um for nanoscale fluorocarbon coating thickness, and other are with embodiment 1.
Embodiment 3
A kind of roofing photovoltaic waterproof roll, described waterproof roll base material 1 is EPDM rubber waterproof rolling material; Described waterproof roll base material 1 thickness is 1.8mm; Described fexible film photovoltaic cell component 3 is copper indium potassium selenium thin-film solar cells; Described dope layer 5 is nanoscale organosilicon-modified acrylic paint thickness 50um, and other are with embodiment 1.
Embodiment 4
A kind of roofing photovoltaic waterproof roll, described waterproof roll base material 1 is thermoplastic polyolefin waterproof roll; Described waterproof roll base material 1 is single layer structure, and thickness is 1.5mm; Described fexible film photovoltaic cell component 3 is dye-sensitized cell; Described dope layer 5 is 40um for nanoscale fluorocarbon coating thickness, and other are with embodiment 1.
Embodiment 5
A kind of method for preparing the roofing photovoltaic waterproof roll, comprise the steps:
(1) preparation of waterproof roll base material: clean out a side of waterproof roll substrate surface standby; Described waterproof roll base material is EPDM rubber waterproof rolling material or thermoplastic polyolefin waterproof roll, and thickness is: 1.2~2.0mm;
(2) preparation of photovoltaic cell component: by fexible film photovoltaic cell component front surface coated nanoscale organic silicon acrylic coating or the nanoscale fluorocarbon coating of surface with fluorine-containing TPT polyester film or the encapsulation of ethene-TFE copolymer (ETFE) film, coating thickness is 30~70um; Described fluorine-containing TPT polyester film or ethene-TFE copolymer (ETFE) film thickness are 250um; Described fexible film photovoltaic cell component is non-crystalline silicon flexible solar hull cell, copper indium potassium selenium thin-film solar cells, cadmium antimonide thin-film solar cells, dye-sensitized cell or organic film battery;
(3) adopt west card one pack system high modulus polyurethane sealant by the surface of described flexible thin-film battery assembly bottom adhesive to described waterproof roll base material;
(4) merge encapsulation: the order according to fexible film photovoltaic cell component, west card one pack system high modulus polyurethane sealant, waterproof roll base material stacks gradually, and vacuumizes processing through roll-in and laminating machine, makes each layer assembly close adhesion, obtains product.
Described fexible film photovoltaic cell component is connected with the both positive and negative polarity wire, and the both positive and negative polarity wire adopts closed male and female fast interface, and described wire outside is topping with marine glue, and adopts the fire-proof and water-proof adhesive tape to protect wire.
Photovoltaic waterproof roll mounting method is: the photovoltaic waterproof roll is layed in to roofing by the job practices of single ply waterproofing coiled material.Solar film battery on every volume photovoltaic waterproof roll has independently positive and negative level electric current to draw wire and closed male and female fast interface.Electric lead, fast interface and junction box are held in place in the wire slotted eye that prolongs photovoltaic waterproof roll width one side.When mounted the electric lead fast interface of every volume photovoltaic waterproof roll is carried out to circuit by junction box and connect combination (connection of serial or parallel connection circuit), then utilize metallic channel that the guiding of electric power output line is connected to inverter, change direct current into alternating current, the switchbox in being arranged on the building thing is served electrical network (grid-connected use) or is directly offered building load electricity consumption.Between closed male and female fast interface and junction box, be connected to the fluid sealant sealing-in.Whole line slot is filled sealing with weatherability, insulating properties, all good silica gel of sealing, makes it to reach the requirement of waterproof, antifreeze, anti-high temperature.
Above-described embodiment is described the preferred embodiment of the present invention; not scope of the present invention is limited; design under the prerequisite of spirit not breaking away from the present invention; various distortion and improvement that those of ordinary skills make technical scheme of the present invention, all should fall into the protection domain that the claims in the present invention book is determined.

Claims (10)

1. roofing photovoltaic waterproof roll, it is characterized in that: described roofing photovoltaic waterproof roll is layer structure, comprises successively from the inside to the outside waterproof roll base material, fexible film photovoltaic cell component, rete and dope layer.
2. roofing photovoltaic waterproof roll according to claim 1, it is characterized in that: described waterproof roll base material is EPDM rubber waterproof rolling material or thermoplastic polyolefin waterproof roll.
3. roofing photovoltaic waterproof roll according to claim 1 and 2, is characterized in that, described waterproof roll base material is single layer structure, and thickness is: 1.2~2.0mm.
4. roofing photovoltaic waterproof roll according to claim 3, it is characterized in that: described fexible film photovoltaic cell component is non-crystalline silicon flexible solar hull cell, copper indium potassium selenium thin-film solar cells, cadmium antimonide thin-film solar cells, dye-sensitized cell or organic film battery.
5. roofing photovoltaic waterproof roll according to claim 4, it is characterized in that: described rete is fluorine-containing TPT polyester film or ethene-TFE copolymer film, and thickness is 250um.
6. roofing photovoltaic waterproof roll according to claim 5, it is characterized in that: described dope layer is nanoscale organosilicon-modified acrylic coating or nanoscale fluorocarbon coating, and thickness is 30~70um.
7. roofing photovoltaic waterproof roll according to claim 6 is characterized in that: also comprise tack coat, described tack coat is west card one pack system high modulus polyurethane sealant, and described waterproof roll base material and fexible film photovoltaic cell component bond.
8. roofing photovoltaic waterproof roll according to claim 7; it is characterized in that: described flexible thin-film battery assembly is connected with the both positive and negative polarity wire; the both positive and negative polarity wire adopts closed male and female fast interface and outside electrical appliance on adjacent photovoltaic waterproof roll to cooperatively interact to be connected, and described wire brushing marine glue also arranges waterproof adhesive tape as topping.
9. a method for preparing the roofing photovoltaic waterproof roll, is characterized in that: comprise the steps:
(1) preparation of waterproof roll base material: clean out a side of waterproof roll substrate surface standby;
(2) preparation of photovoltaic cell component: by fexible film photovoltaic cell component front surface coated nanoscale organosilicon-modified acrylic coating or the nanoscale fluorocarbon coating of surface with fluorine-containing TPT polyester film or ethene-TFE copolymer film encapsulation, coating thickness is 30~70um; The thickness of described fluorine-containing TPT polyester film or ethene-TFE copolymer film is 250um;
(3) adopt west card one pack system high modulus polyurethane sealant by the surface of described flexible thin-film battery assembly bottom adhesive to described waterproof roll base material;
(4) merge encapsulation: the order according to fexible film photovoltaic cell component, west card one pack system high modulus polyurethane sealant, waterproof roll base material stacks gradually, and vacuumizes processing through roll-in and laminating machine, makes each layer assembly close adhesion, obtains product.
10. the method for preparing the roofing photovoltaic waterproof roll according to claim 9, it is characterized in that: described waterproof roll base material is EPDM rubber waterproof rolling material or thermoplastic polyolefin waterproof roll, thickness is 1.2~2.0mm;
Described fexible film photovoltaic cell component is non-crystalline silicon flexible solar hull cell, copper indium potassium selenium thin-film solar cells, cadmium antimonide thin-film solar cells, dye-sensitized cell or organic film battery.
CN201310368529.4A 2013-08-22 2013-08-22 Roof photovoltaic waterproof coiled material and preparation method thereof Active CN103410276B (en)

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CN107060222A (en) * 2017-06-12 2017-08-18 合肥欧仕嘉机电设备有限公司 A kind of roofing photovoltaic waterproof roll and preparation method
CN107225832A (en) * 2017-06-12 2017-10-03 合肥欧仕嘉机电设备有限公司 A kind of water proof roofing sheet and preparation method
CN107310207A (en) * 2017-07-27 2017-11-03 合肥威斯伏新材料有限公司 A kind of photovoltaic waterproof roll
CN108487555A (en) * 2018-03-15 2018-09-04 同济大学 Photovoltaic roof waterproof roll suitable for light energy-saving roofing
CN108610593A (en) * 2018-04-20 2018-10-02 山东冬瑞高新技术开发有限公司 A kind of polymer membranes and preparation method thereof
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CN114382233A (en) * 2022-01-18 2022-04-22 雨中情防水技术集团股份有限公司 Photovoltaic TPO waterproof coiled material and preparation method thereof
CN114775918A (en) * 2022-04-12 2022-07-22 广东安拓普聚合物科技有限公司 Roof photovoltaic waterproof coiled material and preparation method thereof
CN115056556A (en) * 2022-07-09 2022-09-16 广东安拓普聚合物科技有限公司 Durable photovoltaic waterproof roll and preparation method thereof
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CN115504739A (en) * 2022-09-27 2022-12-23 云南欣城防水科技有限公司 Graphene modified photovoltaic roof high-polymer waterproof coating

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CN104134714B (en) * 2014-07-18 2016-08-24 成都新柯力化工科技有限公司 A kind of building solar energy photoelectric conversion coating and preparation method thereof
CN104134714A (en) * 2014-07-18 2014-11-05 成都新柯力化工科技有限公司 Solar photoelectric conversion coating for building and fabrication method for solar photoelectric conversion coating
CN107060222A (en) * 2017-06-12 2017-08-18 合肥欧仕嘉机电设备有限公司 A kind of roofing photovoltaic waterproof roll and preparation method
CN107225832A (en) * 2017-06-12 2017-10-03 合肥欧仕嘉机电设备有限公司 A kind of water proof roofing sheet and preparation method
CN107310207A (en) * 2017-07-27 2017-11-03 合肥威斯伏新材料有限公司 A kind of photovoltaic waterproof roll
WO2019095826A1 (en) * 2017-11-17 2019-05-23 北京铂阳顶荣光伏科技有限公司 Self-heating rolled material
CN108487555A (en) * 2018-03-15 2018-09-04 同济大学 Photovoltaic roof waterproof roll suitable for light energy-saving roofing
CN108610593B (en) * 2018-04-20 2020-04-14 广东鼎新高新科技股份有限公司 High-molecular waterproof coiled material and preparation method thereof
CN108610593A (en) * 2018-04-20 2018-10-02 山东冬瑞高新技术开发有限公司 A kind of polymer membranes and preparation method thereof
CN111435692A (en) * 2020-04-01 2020-07-21 杭州纤纳光电科技有限公司 Roll-to-roll device and method for preparing flexible solar cell by using same
CN114382233A (en) * 2022-01-18 2022-04-22 雨中情防水技术集团股份有限公司 Photovoltaic TPO waterproof coiled material and preparation method thereof
CN114382233B (en) * 2022-01-18 2023-09-19 雨中情防水技术集团股份有限公司 Photovoltaic TPO waterproof coiled material and preparation method thereof
CN114775918A (en) * 2022-04-12 2022-07-22 广东安拓普聚合物科技有限公司 Roof photovoltaic waterproof coiled material and preparation method thereof
CN114775918B (en) * 2022-04-12 2022-10-21 广东安拓普聚合物科技有限公司 Roof photovoltaic waterproof coiled material and preparation method thereof
CN115182095A (en) * 2022-06-07 2022-10-14 常德天鼎丰非织造布有限公司 Anti-fouling polyester filament felt base fabric and preparation method thereof
CN115182095B (en) * 2022-06-07 2023-12-05 常德天鼎丰非织造布有限公司 Anti-fouling polyester filament felt base cloth and preparation method thereof
CN115056556A (en) * 2022-07-09 2022-09-16 广东安拓普聚合物科技有限公司 Durable photovoltaic waterproof roll and preparation method thereof
CN115056556B (en) * 2022-07-09 2023-09-19 广东安拓普聚合物科技有限公司 Waterproof roll for durable photovoltaic and preparation method thereof
CN115504739A (en) * 2022-09-27 2022-12-23 云南欣城防水科技有限公司 Graphene modified photovoltaic roof high-polymer waterproof coating

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