CN103396091B - A kind of composite ceramics thinner and using method thereof possessing base substrate reinforced effects - Google Patents
A kind of composite ceramics thinner and using method thereof possessing base substrate reinforced effects Download PDFInfo
- Publication number
- CN103396091B CN103396091B CN201310332474.1A CN201310332474A CN103396091B CN 103396091 B CN103396091 B CN 103396091B CN 201310332474 A CN201310332474 A CN 201310332474A CN 103396091 B CN103396091 B CN 103396091B
- Authority
- CN
- China
- Prior art keywords
- composite ceramics
- mud
- base substrate
- thinner
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The present invention discloses a kind of the composite ceramics thinner and the using method thereof that possess base substrate reinforced effects, comprise the selection to inorganic, the organic water reducer of small molecules and tensio-active agent and polycarboxylic acid polymer, and the optimization to above various material addition, above-mentioned raw materials is carried out compound according to certain proportioning, and potter's clay material will be built by ball milling and composite ceramics mixing diluents is even.Composite ceramics thinner prepared by the present invention is suitable for architectural pottery formula soil, the water content of mud can be made significantly to reduce, meet the mobility needed for Production of Ceramics, saves spray-drying tower energy consumption, improves dry powder and exports output; After powder drying compacting, can improve the intensity of base substrate, be desirable architectural pottery mud dilution and strongthener.
Description
Technical field
The invention belongs to building ceramics technical field, be specifically related to a kind of the composite ceramics thinner and the using method thereof that possess base substrate reinforced effects.
Background technology
At present, be the mud after ball milling in Structural ceramics industry, send into spray-drying tower obtain powder, then suppress, shaping, fire.Wherein, drying process with atomizing power consumption is very large, and according to statistics, enter tower mud average moisture content and be about 33-38%, powder product is about 6-7% from tower water ratio, and the energy consumption needed for it accounts for produces 60% of total energy consumption.Therefore, wish that the mud moisture content entering spray-drying tower is low, there is good mobility, and good thixotropy.Pottery thinner can be achieved the above object by electrostatic repulsion effect and sterically hindered effect.
The powder obtained after ball milling needs repressed shaping again, and the blank strength of Wall or floor tile is poor, causes dry body easily damaged, and in porcelain brick formula, non-plastic raw material is more, and blank strength is poorer.The production of extensive Wall or floor tile, base substrate breakage rate, up to 10% ~ 30%, seriously have impact on production, causes unnecessary financial loss.The way solving dry body strength has two kinds: one to be the compacting pressure improving press, but when press pressure is excessive, not only can not improves blank strength, cause forming defects (as interlayer etc.) on the contrary, add expense and the energy consumption of former simultaneously; Two is add binder or tackiness agent and usually said base substrate toughener.
The present invention is intended to announce a kind of preparation method possessing the composite ceramics thinner of base substrate reinforced effects, to improve the processing performance of ceramic mud, improves the intensity of dry body, has important practical significance to the production efficiency and save energy improving architectural pottery.
Summary of the invention
The technical problem to be solved in the present invention is to provide that a kind of technique is simple, synthesis cost is low, stable performance
Possess composite ceramics thinner and the using method thereof of base substrate reinforced effects.
For solving above technical problem, technical scheme of the present invention is: a kind of composite ceramics thinner possessing base substrate reinforced effects, it is characterized in that including following component by weight percentage:
Inorganic water reducer 30-90%
The organic water reducer 7-50% of small molecules
Polycarboxylic acid polymer 1-30%
Tensio-active agent 1-5%
Wherein:
Described inorganic water reducer is commercially available Starso, water glass, sodium carbonate, trisodium phosphate, Sodium hexametaphosphate 99, tripoly phosphate sodium STPP wherein one or more;
The organic water reducer of described small molecules is commercially available Sodium salts humic acids, sodium lignosulfonate, calcium lignin sulphonate wherein one or more;
Described tensio-active agent is one or more in anion surfactant, cats product, nonionogenic tenside, novel chelate surfactant.
Described anion surfactant is carboxylate salt, sulfonate, sulfuric acid ester salt, phosphoric acid ester salt.
The preferred dodecane sulfonate of described anion surfactant, paratoluenesulfonic acid sodium salt.
Described cats product is quaternary ammonium salt, pyridinium salt.
Described cats product preferred bromination hexadecyl alkyl pyridine, the one in dimethyl diallyl ammonium chloride, alkyldimethylbenzylammonium quaternary ammonium salt, fatty acyl aminotrialkyl quaternary ammonium salt, dodecyl guanidine hydrochloride.
One in described nonionogenic tenside preferred fat polyoxyethylenated alcohol, trolamine, tween, class of department; One in the preferred N-acyl group of described novel chelate surfactant and N-alkyl ED3A sodium salt.
The preparation method of described polycarboxylic acid polymer is: unsaturated monomer, initiator, chain switching agent, antioxidant are joined in 78 DEG C of water and carry out polyreaction 0.5 hour, then adds inorganic salt quencher termination reaction and obtain co-poly carboxylic acid; Described co-poly carboxylic acid is cooled to 40 DEG C, and add sodium hydroxide and regulate the pH value of reaction system to be 7 ~ 8, namely obtain polycarboxylic acid polymer, molecular weight is 5000-20000.
Described unsaturated monomer is one or more in vinylformic acid, methacrylic acid, butyl acrylate, maleic anhydride, methylene-succinic acid; Described initiator is the one in ammonium persulphate, Potassium Persulphate, Sodium Persulfate, vitamins C, BP, tertbutyl peroxide, hydrogen peroxide, isopropyl benzene hydroperoxide, azo two isobutyl fluorine, 2,2'-Azobis(2,4-dimethylvaleronitrile), and its consumption is the 0.1-5% of unsaturated monomer quality; Described chain-transfer agent is sodium bisulfite, Potassium hydrogen sulfite, Virahol, 3-dredge base propionic acid, Thioglycolic acid, the one of dredging in base ethanol, and its consumption is the 2-300% of unsaturated monomer quality; Described antioxidant is the one in sodium bisulfite, Potassium hydrogen sulfite, rongalite, ferrous sulfate, mercaptan, tartrate, four ethene imonium, and its consumption is the 3-15% of unsaturated monomer quality; Described inorganic salt quencher is inferior sodium phosphate or sodium polyphosphate, and its consumption is the 0.1-2% of unsaturated monomer quality.
The using method of above-mentioned composite ceramics thinner, is characterized in that comprising the steps:
The first step: inorganic water reducer, the organic water reducer of small molecules, tensio-active agent, polycarboxylic acid polymer are carried out being mixed and made into composite ceramics thinner according to proportioning;
Second step: configuration architectural pottery base substrate mud;
3rd step: by weight percentage the composite ceramics thinner of 0.4% is added in architectural pottery base substrate mud, and by ball milling by architectural pottery base substrate and composite ceramics mixing diluents evenly.
Described architectural pottery body recipe is preferably: gold sand 23%, Yujiang County's sand 26%, Deng family's stone flour 15%, little sulphur stone flour 16%, raw talcum 2%, mud 4% of recommending properly qualified persons for service, white clay 7%, good mud 7%;
Described architectural pottery body recipe is preferably: burnt pit sand 26%, planetesimal sand 18%, polishing mud 4%, Dongxiang sand 26%, magnesium soil 4%, Guangdong black mud 4%, ball clay 3%, Xinfeng white clay 6%, Ji'an white clay 9%.
Innovation of the present invention is that this composite ceramics thinner is used in architectural pottery base substrate soil, the water content of mud can be made significantly to reduce, improve blank strength, mobility simultaneously needed for sufficient Production of Ceramics, save spray-drying tower energy consumption, improve dry powder and export output, therefore there are wide market outlook.
Embodiment
Below in conjunction with embodiment, the present invention is further detailed explanation.
Embodiment 1
By vinylformic acid 50Kg, ammonium persulphate 2.5Kg, Virahol 120Kg, sodium bisulfite 2Kg, add in 78 DEG C of water and carry out polyreaction 1 hour, then add 0.6Kg inferior sodium phosphate termination reaction, be then cooled to 40 DEG C and add the sodium hydroxide 90Kg of 30wt%, obtain sodium polyac rylate polymer, molecular weight 6000.Starso, Sodium salts humic acids, sodium polyac rylate polymer, paratoluenesulfonic acid sodium salt are undertaken being mixed and made into composite ceramics thinner by quality proportioning 75:15:9:1.This composite ceramics thinner 0.4% is added into ball milling in architectural pottery body recipe soil by mass percentage, this architectural pottery formula is as follows: gold sand 23%, Yujiang County's sand 26%, Deng family's stone flour 15%, little sulphur stone flour 16%, raw talcum 2%, mud 4% of recommending properly qualified persons for service, white clay 7%, good mud 7%, obtaining flow velocity is 40 seconds, water ratio is the mud of 31%, tail over and be less than 2.4%, after mud drying, dry body strength improves 14%.
Embodiment 2
By methacrylic acid 50Kg, Sodium Persulfate 2.2Kg, Potassium hydrogen sulfite 4.2 Kg, ferrous sulfate 5 Kg, add in 78 DEG C of water and carry out polyreaction 1 hour, then add 1Kg sodium polyphosphate termination reaction, be then cooled to 40 DEG C and add the sodium hydroxide 100Kg of 30wt%, obtain methacrylate polymer, molecular weight 6000.Sodium carbonate, sodium lignosulfonate, methacrylate polymer, dimethyl diallyl ammonium chloride are undertaken being mixed and made into composite ceramics thinner by quality proportioning 80:10:7:3.This composite ceramics thinner 0.4% is added into ball milling in architectural pottery body recipe soil by mass percentage, and this architectural pottery formula is with embodiment 1, and obtaining flow velocity is 40 seconds, water ratio is the mud of 31%, tail over and be less than 2.4%, after mud drying, dry body strength improves 15%.
Embodiment 3
By butyl acrylate 50Kg, BP 2Kg, Virahol 140 Kg, four ethene imonium 5 Kg, add in 78 DEG C of water and carry out polyreaction 1 hour, then add 0.5Kg inferior sodium phosphate termination reaction, be then cooled to 40 DEG C and add the sodium hydroxide 80Kg of 30wt%, obtain butyl acrylate thing, molecular weight 6000.Sodium carbonate, sodium lignosulfonate, butyl acrylate thing, paratoluenesulfonic acid sodium salt are undertaken being mixed and made into composite ceramics thinner by quality proportioning 55:35:9:1.This composite ceramics thinner 0.4% is added into ball milling in architectural pottery body recipe soil by mass percentage, this architectural pottery formula is as follows: burnt pit sand 26%, planetesimal sand 18%, polishing mud 4%, Dongxiang sand 26%, magnesium soil 4%, Guangdong black mud 4%, ball clay 3%, Xinfeng white clay 6%, Ji'an white clay 9%, obtaining flow velocity is 40 seconds, water ratio is the mud of 31%, tail over and be less than 2.4%, after mud drying, dry body strength improves 18%.
Embodiment 4
By maleic anhydride 50Kg, tertbutyl peroxide 2Kg, 3-dredges base propionic acid 6Kg, Potassium hydrogen sulfite 6Kg, add in 78 DEG C of water and carry out polyreaction 1 hour, then add 0.8Kg inferior sodium phosphate termination reaction, be then cooled to 40 DEG C and add the sodium hydroxide 80Kg of 30wt%, obtain maleic anhydride polymer, molecular weight 6000.Trisodium phosphate, calcium lignin sulphonate, maleic anhydride polymer, trolamine are undertaken being mixed and made into composite ceramics thinner by quality proportioning 60:30:9:1.This composite ceramics thinner 0.4% is added into ball milling in architectural pottery body recipe soil by mass percentage, and this builds Tao Peifang with embodiment 3, and obtaining flow velocity is 40 seconds, and water ratio is the mud of 31%, tails over and is less than 2.4%, and after mud drying, dry body strength improves 20%.
Claims (1)
1. one kind possesses the composite ceramics thinner of base substrate reinforced effects, it is characterized in that, by butyl acrylate 50kg, BP 2kg, Virahol 140 kg, four ethene imonium 5 kg, add in 78 DEG C of water and carry out polyreaction 1 hour, then add 0.5kg inferior sodium phosphate termination reaction, be then cooled to 40 DEG C and add the sodium hydroxide 80kg of 30wt%, obtain butyl acrylate thing, molecular weight 6000; Sodium carbonate, sodium lignosulfonate, butyl acrylate thing, paratoluenesulfonic acid sodium salt are undertaken being mixed and made into composite ceramics thinner by quality proportioning 55:35:9:1; This composite ceramics thinner 0.4% is added into ball milling in architectural pottery body recipe soil by mass percentage, this architectural pottery formula is as follows: burnt pit sand 26%, planetesimal sand 18%, polishing mud 4%, Dongxiang sand 26%, magnesium soil 4%, Guangdong black mud 4%, ball clay 3%, Xinfeng white clay 6%, Ji'an white clay 9%, obtaining flow velocity is 40 seconds, water ratio is the mud of 31%, tail over and be less than 2.4%, after mud drying, dry body strength improves 18%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310332474.1A CN103396091B (en) | 2013-08-02 | 2013-08-02 | A kind of composite ceramics thinner and using method thereof possessing base substrate reinforced effects |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310332474.1A CN103396091B (en) | 2013-08-02 | 2013-08-02 | A kind of composite ceramics thinner and using method thereof possessing base substrate reinforced effects |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103396091A CN103396091A (en) | 2013-11-20 |
| CN103396091B true CN103396091B (en) | 2015-08-05 |
Family
ID=49559883
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310332474.1A Expired - Fee Related CN103396091B (en) | 2013-08-02 | 2013-08-02 | A kind of composite ceramics thinner and using method thereof possessing base substrate reinforced effects |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103396091B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103952121A (en) * | 2014-04-04 | 2014-07-30 | 湖南省美程陶瓷科技有限公司 | Steatite ceramics composite water reducer and preparation method thereof |
| CN106187082B (en) * | 2016-07-20 | 2019-06-14 | 四川金辉卫浴洁具有限公司 | A kind of preparation method of the sanitary ceramics of the reinforcing agent containing green body |
| CN107311667B (en) * | 2017-07-21 | 2021-06-22 | 广州粤阳化工有限公司 | Ceramic body reinforcing debonder and preparation method thereof |
| CN107556002A (en) * | 2017-09-04 | 2018-01-09 | 肇庆市欧陶新型材料有限公司 | The preparation method and its application method of construction sanitary ceramic mud degumming agent |
| CN109704787A (en) * | 2019-01-23 | 2019-05-03 | 佛山市山有海科技有限公司 | A kind of ceramics reinforcing agent and its application |
| CN111454066B (en) * | 2020-03-20 | 2022-02-11 | 肇庆市欧陶新型材料有限公司 | Polyamine epoxy adduct-containing polymetaphosphonate ceramic water-quality adaptive dispergator |
| CN114477956B (en) * | 2022-03-02 | 2022-12-16 | 深圳市坤鹏环保建筑废料处理有限公司 | Light construction waste regeneration brick and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101838433A (en) * | 2010-05-13 | 2010-09-22 | 中科院广州化学有限公司 | Method for preparing polycarboxylic compound ceramic water reducing agent |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331814C (en) * | 2006-03-08 | 2007-08-15 | 桂林工学院 | Method for preparing composite ceramic water reducing agent |
-
2013
- 2013-08-02 CN CN201310332474.1A patent/CN103396091B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101838433A (en) * | 2010-05-13 | 2010-09-22 | 中科院广州化学有限公司 | Method for preparing polycarboxylic compound ceramic water reducing agent |
Non-Patent Citations (1)
| Title |
|---|
| "聚丙烯酸钠陶瓷减水剂的制备及分散性能研究";蒋冰艳 等;《精细化工》;20111031;第1004-1009页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103396091A (en) | 2013-11-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103396091B (en) | A kind of composite ceramics thinner and using method thereof possessing base substrate reinforced effects | |
| CN102358763B (en) | Method for preparing additive for inhibiting side effect of clay | |
| CN109400821A (en) | A kind of agent on crack resistance of concrete bleeding inhibitor and preparation method thereof with diminishing function | |
| CN103102120B (en) | A kind of decoration mortar and preparation method thereof | |
| CN106749960B (en) | Polycarboxylic acid super-plasticizer and its preparation method and application with diesis core configuration | |
| CN104086166B (en) | A kind of shaping method preparing building ceramic tiles of granite waste material wet cast | |
| CN104692701B (en) | A kind of normal temperature synthesis type polycarboxylate high performance water-reducing agent and preparation method | |
| CN103319154A (en) | Method for preparing self-releasing glaze ceramic through gel-casting forming process | |
| CN106186781B (en) | A kind of preparation method of modified naphthalene series water-reducing agent | |
| CN105622161A (en) | Cement-based lightweight foam composite material and preparation method thereof | |
| CN107200513A (en) | A kind of preparation method of New Building Materials | |
| CN105236805B (en) | Polycarboxylic acid surface modified superfine stone powder and preparation method thereof | |
| CN105542092B (en) | The method that normal temperature synthesizes spacetabs type high-slump-retentionpolycarboxylate polycarboxylate water reducer | |
| CN107188490A (en) | A kind of air-entrained concrete building block and preparation method thereof | |
| CN109650762B (en) | Phosphate type polycarboxylate superplasticizer and preparation method thereof | |
| CN103071426A (en) | Hyperdispersant and preparation method thereof | |
| CN106749962A (en) | A kind of anti-chamotte mould polycarboxylate water-reducer high and preparation method thereof | |
| CN104761688A (en) | An early-strength type polycarboxylic acid water reducer and a preparing method thereof | |
| CN103387379B (en) | Composite ceramic diluent applicable to bentonite or construction ceramic formula soil containing bentonite and use method of composite ceramic diluent | |
| CN104291725B (en) | A kind of preparation method of modified aliphatic water reducing agent | |
| CN103396092A (en) | Composite ceramic diluent suitable for barren building ceramic formula soil, and application method thereof | |
| CN103396088B (en) | A kind of composite ceramics thinner building pottery formula soil and using method thereof being applicable to attaclay or containing attaclay | |
| CN106800621A (en) | A kind of ultra early-strength polycarboxylate water-reducer and preparation method thereof | |
| CN104591695A (en) | Manufacturing method of large-sized regenerated ceramic | |
| CN104628345A (en) | Baking-free hollow brick with mildew-proof and odor-removal effects and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150805 Termination date: 20170802 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |