CN103395897A - Non-phosphorus environmentally-friendly water treatment agent and preparation method thereof - Google Patents
Non-phosphorus environmentally-friendly water treatment agent and preparation method thereof Download PDFInfo
- Publication number
- CN103395897A CN103395897A CN2013103736690A CN201310373669A CN103395897A CN 103395897 A CN103395897 A CN 103395897A CN 2013103736690 A CN2013103736690 A CN 2013103736690A CN 201310373669 A CN201310373669 A CN 201310373669A CN 103395897 A CN103395897 A CN 103395897A
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- Prior art keywords
- maleic anhydride
- natural high
- high moleculer
- moleculer eompound
- water treatment
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000011574 phosphorus Substances 0.000 title abstract description 13
- 229910052698 phosphorus Inorganic materials 0.000 title abstract description 13
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 51
- 238000006243 chemical reaction Methods 0.000 claims abstract description 43
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000178 monomer Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 17
- 230000008569 process Effects 0.000 claims abstract description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 230000004048 modification Effects 0.000 claims description 26
- 238000012986 modification Methods 0.000 claims description 26
- 238000006277 sulfonation reaction Methods 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 10
- 239000003999 initiator Substances 0.000 claims description 9
- 238000010189 synthetic method Methods 0.000 claims description 9
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 8
- 239000001913 cellulose Substances 0.000 claims description 8
- 229920002678 cellulose Polymers 0.000 claims description 8
- 241001597008 Nomeidae Species 0.000 claims description 6
- 229920005610 lignin Polymers 0.000 claims description 6
- 229920002472 Starch Polymers 0.000 claims description 5
- 230000001143 conditioned effect Effects 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 5
- 239000011790 ferrous sulphate Substances 0.000 claims description 5
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 5
- 239000008234 soft water Substances 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 2
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 229920002307 Dextran Polymers 0.000 claims description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- 239000004368 Modified starch Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 230000029936 alkylation Effects 0.000 claims description 2
- 238000005804 alkylation reaction Methods 0.000 claims description 2
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical compound [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 2
- 235000019357 lignosulphonate Nutrition 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- HFDCVHDLKUZMDI-UHFFFAOYSA-N sulfuric acid titanium Chemical compound [Ti].OS(O)(=O)=O HFDCVHDLKUZMDI-UHFFFAOYSA-N 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims 3
- 230000007797 corrosion Effects 0.000 abstract description 18
- 238000005260 corrosion Methods 0.000 abstract description 18
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 12
- 229920001577 copolymer Polymers 0.000 abstract description 11
- 239000002455 scale inhibitor Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 230000005764 inhibitory process Effects 0.000 description 14
- 239000000243 solution Substances 0.000 description 8
- 230000002401 inhibitory effect Effects 0.000 description 7
- 239000000498 cooling water Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 3
- 230000000630 rising effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000348 titanium sulfate Inorganic materials 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- ZMYKITJYWFYRFJ-UHFFFAOYSA-N 4-oxo-4-(2-phenylethylamino)butanoic acid Chemical compound OC(=O)CCC(=O)NCCC1=CC=CC=C1 ZMYKITJYWFYRFJ-UHFFFAOYSA-N 0.000 description 1
- 102100035024 Carboxypeptidase B Human genes 0.000 description 1
- 241001677188 Coccus viridis Species 0.000 description 1
- 101000946524 Homo sapiens Carboxypeptidase B Proteins 0.000 description 1
- 229920000805 Polyaspartic acid Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- DCEMCPAKSGRHCN-UHFFFAOYSA-N oxirane-2,3-dicarboxylic acid Chemical compound OC(=O)C1OC1C(O)=O DCEMCPAKSGRHCN-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- 108010064470 polyaspartate Proteins 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
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- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CN201310373669.0A CN103395897B (en) | 2013-08-23 | 2013-08-23 | Non-phosphorus environmentally-friendly water treatment agent and preparation method thereof |
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CN201310373669.0A CN103395897B (en) | 2013-08-23 | 2013-08-23 | Non-phosphorus environmentally-friendly water treatment agent and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN103395897A true CN103395897A (en) | 2013-11-20 |
CN103395897B CN103395897B (en) | 2015-03-18 |
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CN201310373669.0A Expired - Fee Related CN103395897B (en) | 2013-08-23 | 2013-08-23 | Non-phosphorus environmentally-friendly water treatment agent and preparation method thereof |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103964589A (en) * | 2014-04-24 | 2014-08-06 | 宋晶冰 | Preparation method for novel non-phosphorus corrosion inhibitor applied to circulating water system |
CN106145396A (en) * | 2016-08-09 | 2016-11-23 | 丁玉琴 | A kind of preparation method of Phosphateless environmentally friendly dirt dispersion agent |
CN107244752A (en) * | 2017-06-09 | 2017-10-13 | 武汉理工大学 | A kind of efficient and environment-friendly type anti-incrustation corrosion inhibitor and its preparation |
CN107619117A (en) * | 2016-07-13 | 2018-01-23 | 中国石油化工股份有限公司 | Non-phosphate inhibitor and its preparation method and application and water treatment composition and its application |
CN107720982A (en) * | 2017-11-07 | 2018-02-23 | 安徽大学 | A kind of without phosphorus water treatment agent and preparation method thereof |
CN108439618A (en) * | 2018-03-14 | 2018-08-24 | 兖矿水煤浆气化及煤化工国家工程研究中心有限公司 | A kind of coal gasification buck scale preventative and preparation method thereof |
CN110407331A (en) * | 2019-06-12 | 2019-11-05 | 李辉 | A kind of preparation method of green sustained release antisludging agent |
CN111362429A (en) * | 2020-02-28 | 2020-07-03 | 中国石油天然气股份有限公司 | Non-phosphorus scale inhibitor and preparation method and application thereof |
CN113415908A (en) * | 2021-05-19 | 2021-09-21 | 河北津宏化工有限公司 | Modified hydrolyzed polymaleic anhydride water treatment agent and preparation method thereof |
CN117164128A (en) * | 2023-11-03 | 2023-12-05 | 烟台康恩环保科技有限公司 | Organic scale and corrosion inhibitor for high-dissolved-oxygen water quality and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4666609A (en) * | 1984-11-14 | 1987-05-19 | Kurita Water Industries Ltd. | Water treatment agent |
KR100896518B1 (en) * | 2002-12-24 | 2009-05-08 | 에스케이케미칼주식회사 | Composition for preventing corrosion anc scale of boiler and treatment method of water for boiler |
CN101565241A (en) * | 2009-06-04 | 2009-10-28 | 李秀宁 | Non-phosphorus scale and corrosion inhibitor |
CN101768244A (en) * | 2010-02-11 | 2010-07-07 | 山东省泰和水处理有限公司 | Method for synthesizing phosphorus-free corrosion-inhibition scale inhibitor for water treatment from natural products |
-
2013
- 2013-08-23 CN CN201310373669.0A patent/CN103395897B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4666609A (en) * | 1984-11-14 | 1987-05-19 | Kurita Water Industries Ltd. | Water treatment agent |
KR100896518B1 (en) * | 2002-12-24 | 2009-05-08 | 에스케이케미칼주식회사 | Composition for preventing corrosion anc scale of boiler and treatment method of water for boiler |
CN101565241A (en) * | 2009-06-04 | 2009-10-28 | 李秀宁 | Non-phosphorus scale and corrosion inhibitor |
CN101768244A (en) * | 2010-02-11 | 2010-07-07 | 山东省泰和水处理有限公司 | Method for synthesizing phosphorus-free corrosion-inhibition scale inhibitor for water treatment from natural products |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103964589B (en) * | 2014-04-24 | 2015-10-21 | 宋晶冰 | A kind of non-phosphate inhibitor preparation method being applied to circulating water system |
CN103964589A (en) * | 2014-04-24 | 2014-08-06 | 宋晶冰 | Preparation method for novel non-phosphorus corrosion inhibitor applied to circulating water system |
CN107619117B (en) * | 2016-07-13 | 2019-11-12 | 中国石油化工股份有限公司 | Non-phosphate inhibitor and its preparation method and application and water treatment composition and its application |
CN107619117A (en) * | 2016-07-13 | 2018-01-23 | 中国石油化工股份有限公司 | Non-phosphate inhibitor and its preparation method and application and water treatment composition and its application |
CN106145396A (en) * | 2016-08-09 | 2016-11-23 | 丁玉琴 | A kind of preparation method of Phosphateless environmentally friendly dirt dispersion agent |
CN107244752A (en) * | 2017-06-09 | 2017-10-13 | 武汉理工大学 | A kind of efficient and environment-friendly type anti-incrustation corrosion inhibitor and its preparation |
CN107720982A (en) * | 2017-11-07 | 2018-02-23 | 安徽大学 | A kind of without phosphorus water treatment agent and preparation method thereof |
CN108439618A (en) * | 2018-03-14 | 2018-08-24 | 兖矿水煤浆气化及煤化工国家工程研究中心有限公司 | A kind of coal gasification buck scale preventative and preparation method thereof |
CN110407331A (en) * | 2019-06-12 | 2019-11-05 | 李辉 | A kind of preparation method of green sustained release antisludging agent |
CN111362429A (en) * | 2020-02-28 | 2020-07-03 | 中国石油天然气股份有限公司 | Non-phosphorus scale inhibitor and preparation method and application thereof |
CN111362429B (en) * | 2020-02-28 | 2022-06-03 | 中国石油天然气股份有限公司 | Non-phosphorus scale inhibitor and preparation method and application thereof |
CN113415908A (en) * | 2021-05-19 | 2021-09-21 | 河北津宏化工有限公司 | Modified hydrolyzed polymaleic anhydride water treatment agent and preparation method thereof |
CN113415908B (en) * | 2021-05-19 | 2022-04-29 | 河北津宏化工有限公司 | Modified hydrolyzed polymaleic anhydride water treatment agent and preparation method thereof |
CN117164128A (en) * | 2023-11-03 | 2023-12-05 | 烟台康恩环保科技有限公司 | Organic scale and corrosion inhibitor for high-dissolved-oxygen water quality and preparation method thereof |
CN117164128B (en) * | 2023-11-03 | 2024-01-02 | 烟台康恩环保科技有限公司 | Organic scale and corrosion inhibitor for high-dissolved-oxygen water quality and preparation method thereof |
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CN103395897B (en) | 2015-03-18 |
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Address after: 300400 Tianjin City, Beichen medical and pharmaceutical equipment industry park, Chen Xing Star Valley incubator Star Valley No. 1, No. Applicant after: Tianjin Ke Wei Jin Hong Environmental Technology Co., Ltd. Address before: 300400 Tianjin city Beichen District Tianjin Industrial Park, medicine and medical equipment in Star Valley incubator, Star Valley Applicant before: Tianjin Ke Wei Jin Hong Environmental Technology Co., Ltd. |
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Effective date of registration: 20170410 Address after: 063305 Hebei province Tangshan City development road on the north side of Qingyuan Road Nanpu Development Zone East Patentee after: Hebei Jinhong Chemical Co., Ltd. Address before: 300400 Tianjin City, Beichen medical and pharmaceutical equipment industry park, Chen Xing Star Valley incubator Star Valley No. 1, No. Patentee before: Tianjin Ke Wei Jin Hong Environmental Technology Co., Ltd. |
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Denomination of invention: Non-phosphorus environmentally-friendly water treatment agent and preparation method thereof Effective date of registration: 20170424 Granted publication date: 20150318 Pledgee: Bank of Cangzhou Limited by Share Ltd Tangshan branch Pledgor: Hebei Jinhong Chemical Co., Ltd. Registration number: 2017990000336 |
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Granted publication date: 20150318 Termination date: 20170823 |