CN103393552B - 胶原蛋白洗发香波 - Google Patents
胶原蛋白洗发香波 Download PDFInfo
- Publication number
- CN103393552B CN103393552B CN201310307232.7A CN201310307232A CN103393552B CN 103393552 B CN103393552 B CN 103393552B CN 201310307232 A CN201310307232 A CN 201310307232A CN 103393552 B CN103393552 B CN 103393552B
- Authority
- CN
- China
- Prior art keywords
- shampoo
- collagen
- antiseptic
- propylene glycol
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 37
- 102000008186 Collagen Human genes 0.000 title claims abstract description 30
- 108010035532 Collagen Proteins 0.000 title claims abstract description 30
- 229920001436 collagen Polymers 0.000 title claims abstract description 30
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 27
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 230000002421 anti-septic effect Effects 0.000 claims description 17
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- DNKGZSOYWMQDTK-UHFFFAOYSA-N 3-iodoprop-1-ynyl N-butylcarbamate Chemical compound CCCCNC(=O)OC#CCI DNKGZSOYWMQDTK-UHFFFAOYSA-N 0.000 claims description 10
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 claims description 10
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 10
- 235000013824 polyphenols Nutrition 0.000 claims description 10
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 9
- 239000004330 calcium propionate Substances 0.000 claims description 9
- 235000010331 calcium propionate Nutrition 0.000 claims description 9
- 239000004302 potassium sorbate Substances 0.000 claims description 9
- 235000010241 potassium sorbate Nutrition 0.000 claims description 9
- 229940069338 potassium sorbate Drugs 0.000 claims description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 8
- 230000003301 hydrolyzing effect Effects 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims description 8
- 241001122767 Theaceae Species 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 210000004209 hair Anatomy 0.000 abstract description 8
- 239000003755 preservative agent Substances 0.000 abstract description 6
- 230000002335 preservative effect Effects 0.000 abstract description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- GOJYXPWOUJYXJC-UHFFFAOYSA-M sodium;2-[1-(2-hydroxyethyl)-2-undecyl-4,5-dihydroimidazol-1-ium-1-yl]acetate;hydroxide Chemical compound [OH-].[Na+].CCCCCCCCCCCC1=NCC[N+]1(CCO)CC([O-])=O GOJYXPWOUJYXJC-UHFFFAOYSA-M 0.000 abstract 1
- 238000004383 yellowing Methods 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000000813 microbial effect Effects 0.000 description 3
- 210000004761 scalp Anatomy 0.000 description 3
- 208000001840 Dandruff Diseases 0.000 description 2
- 201000004624 Dermatitis Diseases 0.000 description 2
- OPVLOHUACNWTQT-UHFFFAOYSA-N azane;2-dodecoxyethyl hydrogen sulfate Chemical compound N.CCCCCCCCCCCCOCCOS(O)(=O)=O OPVLOHUACNWTQT-UHFFFAOYSA-N 0.000 description 2
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 description 2
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical compound O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000003648 hair appearance Effects 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- GYCKQBWUSACYIF-UHFFFAOYSA-N o-hydroxybenzoic acid ethyl ester Natural products CCOC(=O)C1=CC=CC=C1O GYCKQBWUSACYIF-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-STWYSWDKSA-M potassium sorbate Chemical compound [K+].C\C=C\C=C\C([O-])=O CHHHXKFHOYLYRE-STWYSWDKSA-M 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
本发明公开了一种胶原蛋白洗发香波，由下述组分按重量百分比组成：月桂基聚氧乙烯醚硫酸铵8-12%，月桂酰两性基乙酸钠2-4%，丙二醇2-6%，水解胶原0.4-0.6%，防腐剂0.1-0.3%，余量为水。本发明的胶原蛋白洗发香波，泡沫丰富，能够修护头发软弱干脆、开叉、枯黄及其他受损发质。
Description
技术领域
本发明涉及一种洗发香波，具体涉及一种胶原蛋白洗发香波。
背景技术
洗发香波是人们日常生活中不可缺少的必需品，使用时能从头发及头皮中去除表面的油污和皮屑，而对头发、头皮和人身健康无不良影响。洗发香波种类繁多，按剂型和功能分主要有透明洗发香波、膏状洗发香波、珠光洗发香波、调理洗发香波、去屑洗发香波、专用洗发香波等。
近年来，由于人们生活品质的提高，洗发次数的增多，对洗发香波也提出了越来越多的要求。既需要洗发香波具有较好的去污去屑效果，又需要其具有较好的气味，同时还需要保持发质的光泽，具有较长的保质期。
为了延长洗发香波的保质期，使其在开封使用后长期放置仍不变质，通常会在洗发香波中加入一定量的防腐剂，但是目前市面上的洗发香波常用的高效防腐剂有对羟基苯甲酸甲酯(即尼泊金甲酯)、对羟基苯甲酸乙酯(即尼泊金乙酯)、苯甲酸钠、异噻唑啉酮等，它们对皮肤和眼睛都有一定的刺激性，在与眼睛接触后，需要立即用大量清水冲洗；甚至会引起部分人群皮肤过敏、发生皮炎等症状，因此其在洗发香波中的用量也受到严格的控制。
另外，咪唑烷基脲和已内酰脲作为防腐剂的原理均是作为甲醛供体，通过释放甲醛达到杀灭微生物的作用，当释放甲醛超标时也会对人体皮肤造成损害，在很多国家都是严格限制其含量甚至禁止使用的。
发明内容
针对现有技术中存在的上述不足，本发明所要解决的技术问题之一提供一种胶原蛋白洗发香波。
本发明目的是通过如下技术方案实现的：
一种胶原蛋白洗发香波，由下述组分按重量百分比组成：月桂基聚氧乙烯醚硫酸铵8-12％，月桂酰两性基乙酸钠2-4％，丙二醇2-6％，水解胶原0.4-0.6％，防腐剂0.1-0.2％，余量为水。
优选地，
所述防腐剂由下述组分按重量份组成：茶多酚10-15份，山梨酸钾10-15份，丙酸钙10-15份，丁基氨基甲酸碘代丙炔酯5-10份。
本发明中，
月桂基聚氧乙烯醚硫酸铵，英文名:Ammonium lauryl ether sulfate，CAS号：32612-48-9。
月桂酰两性基乙酸钠，CAS号：156028-14-7。
丙二醇，CAS号：26264-14-2。
水解胶原，CAS登录号：92113-31-0。
茶多酚，Tea Polyphenols，CAS号:84650-60-2。
山梨酸钾，CAS：24634-61-5。
丙酸钙，CAS号：4075-81-4。
丁基氨基甲酸碘代丙炔酯，CAS号：55406-53-6。
本发明的胶原蛋白洗发香波，泡沫丰富，能够修护头发软弱干脆、开叉、枯黄及其他受损发质。本发明的胶原蛋白洗发香波，选用茶多酚、山梨酸钾、丙酸钙和丁基氨基甲酸碘代丙炔酯的配伍制成的防腐剂，具有很好的协同增效的抑杀效果和安全性能。
具体实施方式
下面实施例是对本发明的进一步说明，而不是限制本发明的范围。在本发明中，如无特别说明，各原料均以有效物含量为100％计。
实施例1
一种胶原蛋白洗发香波，由下述组分按重量百分比组成：月桂基聚氧乙烯醚硫酸铵10％，月桂酰两性基乙酸钠3％，丙二醇4％，水解胶原0.5％，防腐剂0.2％，余量为水。
上述防腐剂，由下述组分按重量份组成：茶多酚10份、山梨酸钾10份、丙酸钙10份、丁基氨基甲酸碘代丙炔酯10份。将茶多酚、山梨酸钾、丙酸钙和丁基氨基甲酸碘代丙炔酯搅拌混合均匀，即可制成混合防腐剂。
取适量的水，加热至80-90℃，在搅拌过程中，按所述比例加入月桂基聚氧乙烯醚硫酸铵和月桂酰两性基乙酸钠，搅拌均匀后，降低温度至50-60℃，加入丙二醇、水解胶原和混合防腐剂，搅拌1.5小时后，冷却至室温，得到胶原蛋白洗发香波。
实施例2
一种胶原蛋白洗发香波，由下述组分按重量百分比组成：月桂基聚氧乙烯醚硫酸铵10％，月桂酰两性基乙酸钠3％，丙二醇4％，水解胶原0.5％，防腐剂0.2％，余量为水。
上述防腐剂，由下述组分按重量份组成：山梨酸钾20份、丙酸钙10份、丁基氨基甲酸碘代丙炔酯10份。
按实施例1的方法进行制备，得到胶原蛋白洗发香波。
实施例3
一种胶原蛋白洗发香波，由下述组分按重量百分比组成：月桂基聚氧乙烯醚硫酸铵10％，月桂酰两性基乙酸钠3％，丙二醇4％，水解胶原0.5％，防腐剂0.2％，余量为水。
上述防腐剂，由下述组分按重量份组成：茶多酚10份、丙酸钙20份、丁基氨基甲酸碘代丙炔酯10份。
按实施例1的方法进行制备，得到胶原蛋白洗发香波。
实施例4
一种胶原蛋白洗发香波，由下述组分按重量百分比组成：月桂基聚氧乙烯醚硫酸铵10％，月桂酰两性基乙酸钠3％，丙二醇4％，水解胶原0.5％，防腐剂0.2％，余量为水。
上述防腐剂，由下述组分按重量份组成：茶多酚20份、山梨酸钾10份、丁基氨基甲酸碘代丙炔酯10份。
按实施例1的方法进行制备，得到胶原蛋白洗发香波。
测试例
将实施例1-4的胶原蛋白洗发香波放入保温箱(40℃，95％湿度)，放置28天进行微生物挑战试验，选择胡梅，陈逸君的《复配化妆品防腐剂的增效作用》(《日用化学品科学》第29卷第12期,2006年12月)第4页表6的测试菌株，参照该文献2.3.2.3的评价标准，微生物挑战试验0天时，混合细菌和混合霉菌的初始菌株浓度均为5×105cfu/g(ml)。
表1：微生物挑战试验结果(cfu/g(ml))
由表1结果可见，实施例1的胶原蛋白洗发香波在试验28天后，使得混合细菌的菌株浓度都降至10cfu/g(ml)以下，证明其对细菌具有较强的抑杀作用。防腐效果明显优于实施例2-4。
因此选用了茶多酚、山梨酸钾、丙酸钙和丁基氨基甲酸碘代丙炔酯的配伍制成的防腐剂，具有很好的协同增效的抑杀效果，本发明选用此防腐剂制成的胶原蛋白洗发香波同时具有较好的防腐性和安全性能。
Claims (1)
1.一种胶原蛋白洗发香波，其特征在于，由下述组分按重量百分比组成：月桂基聚氧乙烯醚硫酸铵8-12％，月桂酰两性基乙酸钠2-4％，丙二醇2-6％，水解胶原0.4-0.6％，防腐剂0.1-0.2％，余量为水；
所述防腐剂由下述组分按重量份组成：茶多酚10-15份，山梨酸钾10-15份，丙酸钙10-15份，丁基氨基甲酸碘代丙炔酯5-10份。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310307232.7A CN103393552B (zh) | 2013-07-20 | 2013-07-20 | 胶原蛋白洗发香波 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310307232.7A CN103393552B (zh) | 2013-07-20 | 2013-07-20 | 胶原蛋白洗发香波 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103393552A CN103393552A (zh) | 2013-11-20 |
| CN103393552B true CN103393552B (zh) | 2015-03-25 |
Family
ID=49557422
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310307232.7A Expired - Fee Related CN103393552B (zh) | 2013-07-20 | 2013-07-20 | 胶原蛋白洗发香波 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103393552B (zh) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102895130A (zh) * | 2012-09-29 | 2013-01-30 | 南通东泰新能源设备有限公司 | 胶原蛋白洗发香波 |
-
2013
- 2013-07-20 CN CN201310307232.7A patent/CN103393552B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN103393552A (zh) | 2013-11-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106038330B (zh) | 一种洁面乳及其制备方法 | |
| CN106580762B (zh) | 具有抚纹抗皱功效的护肤品组合物、眼霜及其制备方法 | |
| CN105748376A (zh) | 一种控油防脱洗发水 | |
| CN110327282A (zh) | 一种可改善头皮表皮微生物菌群的去屑洗发水及制备工艺 | |
| CN104546522A (zh) | 具有高效广谱抑菌能力的组合物及其在化妆品中的应用 | |
| CN106511160A (zh) | 一种保湿霜及其制备方法 | |
| CN105997642B (zh) | 一种肌肤闺蜜霜及其制备方法 | |
| CN104622743A (zh) | 一种具有深层温和保湿功效的芦荟凝胶及其制备方法 | |
| KR101917774B1 (ko) | 블랙커민씨드 추출물을 유효성분으로 포함하는 화장품 보존용 조성물 | |
| CN113332191A (zh) | 一种洗发水及其制备方法 | |
| CN106109259B (zh) | 一种预防汗味的香波沐浴露 | |
| CN104027294B (zh) | 含岩藻多糖和石榴提取物的眼霜及其制备方法 | |
| CN103356401B (zh) | 小麦蛋白洗发香波 | |
| CN107308043A (zh) | 一种祛痘控油洗面奶及其制备方法 | |
| CN109199987A (zh) | 一种含椰子活性物的修护面膜液及其制备方法 | |
| KR101781466B1 (ko) | 연꽃 추출물 및 오매 추출물을 유효성분으로 함유하는 항산화 활성을 가지는 피부 외용제 조성물 | |
| JP2022176251A (ja) | 第四級アミン配合物及びその使用 | |
| CN105326696A (zh) | 一种天然植物抗氧化精华乳及其制备方法 | |
| CN103393565B (zh) | 月桂酰赖氨酸丝滑洗发香波 | |
| CN102657592B (zh) | 一种抗衰老的精华液组合物及其制备方法 | |
| CN109350572A (zh) | 一种祛红血丝的化妆品组合物及其制备方法和应用 | |
| CN103393564B (zh) | 芦荟柔顺洗发香波 | |
| CN103393551B (zh) | 洗发香波 | |
| CN103040671A (zh) | 一种美肤化妆品 | |
| CN103393566B (zh) | 橄榄光泽洗发香波 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Sun Yukuan Inventor after: Zhong Ni Inventor before: Chen Longdi |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: CHEN LONGDI TO: SUN YUKUAN ZHONG NI |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: FOSHAN DIEBEISI BIO-TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANGHAI YANZI CHEMICAL TECHNOLOGY CO., LTD. Effective date: 20150512 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 201111 MINHANG, SHANGHAI TO: 528244 FOSHAN, GUANGDONG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20150512 Address after: 528244, No. 1, No. two, Riverside Industrial Park, Lishui Town, Nanhai District, Guangdong, Foshan Patentee after: FOSHAN DEEPERSEA BIOTECHNOLOGY CO.,LTD. Address before: 201111 Shanghai city Minhang District Yuanjiang Road No. 5500 building first room E2128 Patentee before: SHANGHAI YANZI CHEMICAL TECHNOLOGY Co.,Ltd. |
|
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Chen Jianliang Inventor before: Sun Yukuan Inventor before: Zhong Ni |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: SUN YUKUAN ZHONG NI TO: CHEN JIANLIANG |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160812 Address after: 528200, No. 1, Riverside Industrial Park, Lishui Town, Nanhai District, Guangdong, Foshan, China Patentee after: FOSHAN NANHAI QINGXIU COSMETICS Co.,Ltd. Address before: 528244, No. 1, No. two, Riverside Industrial Park, Lishui Town, Nanhai District, Guangdong, Foshan Patentee before: FOSHAN DEEPERSEA BIOTECHNOLOGY CO.,LTD. |
|
| CP01 | Change in the name or title of a patent holder |
Address after: 528200, No. 1, Riverside Industrial Park, Lishui Town, Nanhai District, Guangdong, Foshan, China Patentee after: FOSHAN FUXIN TECHNOLOGY INDUSTRY Co.,Ltd. Address before: 528200, No. 1, Riverside Industrial Park, Lishui Town, Nanhai District, Guangdong, Foshan, China Patentee before: FOSHAN NANHAI QINGXIU COSMETICS Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150325 Termination date: 20210720 |