CN103371148A - Bactericide pesticide for controlling agricultural bacterial diseases and application methods - Google Patents
Bactericide pesticide for controlling agricultural bacterial diseases and application methods Download PDFInfo
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Abstract
The invention discloses a bactericide pesticide applied in agriculture for the first time and application methods. The pesticide comprises dosage forms, carriers and auxiliary agents allowed in production. The content of the effective constituent bromochloro-5,5-dimethylimidazolidine-2,4-dione is 1-80%, the auxiliary agents account for 7-20% of the total weight, and the filling materials account for 2-70% of the total weight. Missible oil, wettable powder, powder, seed-dressing agents and suspending agents allowed in production are prepared through processing, and used for controlling bacterial diseases of vegetables, fruit trees, wheat, rice, corn, cotton and potatoes. The pesticide can employ application methods of plant spraying, root pouring or seed treatment and has good control effects on bacterial diseases of 7 genera of crops.
Description
Technical field
The invention belongs to the chemical protection of plant field, relate to the Pesticidal products take BCDMH as active ingredient, and this medicament is applied to the control of agriculture bacterial disease.
Background technology
The agricultural bacterial disease is the key factor of restriction agricultural production, the generation of disease not only causes the decline of agricultural output and quality, and can cause a large amount of inputs of agricultural chemicals and the rising of expenses for prevention and control, increase production cost, the nuisanceless green production of impact agricultural exists potential environment and health risk simultaneously.Bacterial disease ubiquity on the agricultural occurs in the environment of high temperature, high humidity easily, and it is popular, wayward to get final product large-scale outbreak in the short time, and rapid, the complicated and diversified characteristics of occurrence cause of occuring are arranged.
The existing control medicament of agricultural bacterial disease is summarized as following several: such medicament of a copper agent comprises Kocide SD, copper oxychloride, copper rosinate, network ammonia copper, nitro humus acid copper, cuprous oxide, Thiodiazole-copper and tiger glue adipic acid copper; Such medicament of two antibioticses comprises Zhongshengmycin, Ningnanmycin, Astromicin, new phytomycin, chloramphenicol and agricultural streptomycin sulphate; Three other bactericide mainly are MBAMT.The long-term use of above medicament easily causes pathogen susceptibility to descend, and use and misoperation very easily produce poisoning, and is responsive to the copper agent performance of tradition control bacterial disease such as Chinese cabbage.Therefore, seek a kind of to agricultural crops safety, to prevent and treat the new type bactericide of agriculture bacterial disease efficiently imperative.
BCDMH is that biocide is used in the High-efficient Water processing that the U.S. succeeds in developing in 20 century 70s, after this at first realizes commercialization in the U.S..China has some producers in the nineties in 20th century and in succession goes into operation, such medicament is widely used in the sterilization of the domestic sanitary wares such as water for industrial use processing, cycle water, swimming sterilizing deodorization and sterilization, medical instruments, food processing and hotel afterwards, also can be used for the Antiepidemic sterilizing aspect in fruit freshness preserving, aquaculture and turnover port inspection and quarantine disinfection and epidemic-stricken area.In addition, BCDMH or a kind of special bromating agent, compare with bromating agents such as N-bromoacetamide and N-bromo-succinimides have that active bromine content is high, excellent storage stability and use economic dispatch advantage, be widely used in the bromination on pi-allyl in chemical industry and the pharmaceuticals industry and benzyl compounds and the active aromatic ring, also as sanitizer etc.
BCDMH (Bromochloro-5,5-dimethylimidazolidine-2,4-dione): 1-bromo-3-chloro-5,5-dimethyl hydantoin
C
5H
6BrCIN
2O
2, former medicine is white or rice white crystalline powder, is soluble in the organic solvents such as benzene, dichlorotoleune, chloroform, is slightly soluble in water, easily decomposes in strong acid or highly basic, and is stable when dry, easily decomposes during the moisture absorption, and slight penetrating odor is arranged.The action principle of such medicament is can constantly discharge active Br-and active Cl-by dissolving in water, form hypobromous acid and hypochlorous acid, the hypobromous acid and the hypochlorous acid that generate have strong oxidizing property, the biology enzyme oxidation in the microbial body can be reached the purpose of sterilization.
Therefore, this area in the urgent need to a kind of efficient, can delay drug-fast, the bactericide agricultural chemicals that agriculture bacterial disease is had broad spectrum activity of environmental protection more.
Summary of the invention
The present invention be intended to obtain a kind of efficient, can delay drug-fast, the bactericide of environmental protection more, this bactericide first Application is in the control of agriculture bacterial disease.
Second purpose of the present invention is to obtain the agricultural chemicals preparation method of bactericide among the present invention.
The 3rd purpose of the present invention be to obtain a kind of efficiently, application method easily.
The present invention also has an order to be to obtain the range of application of this agriculture chemicals fungicide.
In a first aspect of the present invention, provide a kind of efficient, can delay pesticide resistance, the bactericide BCDMH of environmental protection more.This bactericide is used to the control of agriculture bacterial disease, has the wide spectrum preventive effect.
Another aspect of the present invention provides the preparation method of the agricultural chemicals take BCDMH as active ingredient, may further comprise the steps:
It is BCDMH 1～80% that each material consumption accounts for percentage by weight, and auxiliary agent 6～20%, carrier 0～70%, above material are processed into and produce upper any solid dosage forms or the liquid dosage form that allows according to formulations of pesticide processing request.
Described formulation comprises missible oil, wetting powder, pulvis, seed dressing and suspending agent.
Described auxiliary agent or carrier comprise dispersant, wetting agent, emulsifier, defoamer, sticker, thickener, antifreezing agent, solvent and inert carrier.
Active ingredient
Active ingredient of the present invention is BCDMH, and it is 1～80% that its consumption in formulations of pesticide process accounts for percentage by weight.
Auxiliary agent or carrier
The present invention adopts auxiliary agent or the kind of carrier that allows in the pesticide producing, comprises dispersant, wetting agent, emulsifier, defoamer, thickener, sticker, antifreezing agent, solvent and inert carrier etc.Add auxiliary agent or the dispensable active component of carrier itself, and after the dispenser to crop safety.It is 6～20% that the consumption of auxiliary agent and carrier accounts for percentage by weight, carrier 0～70%.
Dispersant
Described dispersant is selected from one or more in the following medicament: lignosulfonates, alkylphenol polyoxyethylene, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO, polycarboxylate formaldehyde condensation products, alkyl benzene sulfonate calcium salt, alkylphenol polyoxyethylene.The preferred lignosulfonates of dispersant, alkylphenol polyoxyethylene and naphthalene sulfonic acid-formaldehyde condensation product sodium salt.Described alkyl comprises C1～C22 straight or branched alkane group.It is 5～20% that dispersant dosage accounts for percentage by weight.
Wetting agent
Described wetting agent is selected from one or more in the following medicament: lauryl sodium sulfate, alkylnaphthalene sulfonate, Nekal BX, APEO, alkyl phosphoric acid sodium, alkylphenol-polyethenoxy base sodium sulphate.Wetting agent preferably sodium dodecyl sulfate, alkylnaphthalene sulfonate and alkylphenol-polyethenoxy base sodium sulphate.It is 3～10% that the wetting agent consumption accounts for percentage by weight.
Emulsifier
Described emulsifier is selected from one or more in the following medicament: dodecyl benzene sulfonate, alkylnaphthalene sulfonate, alkylsulfonate, alkylphenol polyoxyethylene, benzylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, aliphatic amine polyoxyethylene ether.It is 3～30% that emulsifier accounts for percentage by weight.
Thickener or sticker
Described thickener is selected from one or more in the following medicament: xanthans, CMC, hydroxyethylcellulose, hydroxypropul starch, methylcellulose, aluminium-magnesium silicate and polyvinyl alcohol.
Antifreezing agent
Described antifreezing agent is selected from one or more in the following medicament: ethylene glycol, propane diols, glycerine.
Defoamer
Described defoamer is selected from one or more in the following medicament: silicone oil, silicone compound, C10-20 saturated fat acid compounds, C10-20 aliphatic alcohols compound.
Carrier
Described carrier is selected from one or more in the following medicament: kaolin, diatomite, bentonite, white carbon, attapulgite, starch, modified starch and precipitated calcium carbonate.
Solvent
Described solvent is selected from one or more in the following medicament: dimethylbenzene, toluene, purified petroleum benzin, crude benzol, heavy benzene, light diesel fuel, aryl chain hydrocarbon, turpentine oil.
The preparation method
The preparation method of bactericide agricultural chemicals of the present invention is the conventional method on producing.Such as 25% BCDMH WP, will produce the auxiliary agent such as the dispersant that allows, wetting agent or carrier in the process and be pulverized and mixed and namely obtain described bactericide agricultural chemicals.
Concrete as: it is 25% that the BCDMH consumption accounts for percentage by weight, dispersant 5%, wetting agent 1%, other carriers complement to 100 and are processed into wetting powder.
Application method
Another aspect of the present invention provides the application method of this bactericide agricultural chemicals, and in different dispensers was processed, dosage was different.
Be used for the plant spraying and process, their early stage uses, and leaf is just sprayed with blade back, and dosage is 150～225gai/hm
2
Be used for root irrigation, dosage is 45～67.5gai/hm
2
Be used for seed treatment, can process seed by seed soaking and vexed kind of dual mode.
Small-sized seed such as the seed of Chinese cabbage, radish, wild cabbage, adopts 100～2000 μ g/ml liquids seed soaking 1～2h or the vexed kind 1～6h of 50～1500 μ g/ml liquids.
Large seed such as wheat, paddy rice, muskmelon, soya seeds, adopts 200～3000 μ g/ml liquids seed soaking 1～2h or the vexed kind 2～8h of 100～2000 μ g/ml liquids.
Range of application
A further aspect of the present invention provides the application of this agriculture chemicals fungicide, is used for the control of bacterial disease on vegetables, fruit tree, wheat, paddy rice, corn, cotton and the potato.
Described agriculture bacterial disease kind comprises disease or its combination that is caused by Erwinia (Erwinina), pseudomonas (Pseudomonas), Xanthomonas (Xanthomonas), clavibacter genus (Clavibacter), Raul Bordetella (Ralstonia), Acidovorax (Acidovorax) and Agrobacterium (Agrobacterium).Concrete disease species sees Table 1.
Kind and the insecticide-applying way of table 1 BCDMH control bacterial disease
Good effect of the present invention is:
1. the bactericide take BCDMH as active ingredient is widely used in the plant protection field, clear and definite using method is used for the effective prevention and control to agriculture bacterial disease.
2. by the formulation technology, BCDMH is processed into missible oil, wetting powder, pulvis, seed dressing and suspending agent, the use that makes this medicament is wide spectrum, safety more.
3. determine that by the screening of fungicidal spectrum BCDMH is efficient to the various bacterial disease on the agricultural, control efficiency generally can reach about 90%, obviously is better than producing bactericide commonly used.
Embodiment
The inventor is through extensive and deep research, screening by the medicament disinfecting activity, obtained agriculture bacterial disease is had the bactericide BCDMH of wide spectrum preventive effect, and according to formulations of pesticide processing request, this bactericide is processed into the formulations of pesticide of producing upper permission in conjunction with other auxiliary agents or carrier, more widen the scope of application of this medicament, improved the safety of medicament.With different insecticide-applying way this bactericide agricultural chemicals is applied on the multiple kinds of crops in the invention, its control efficiency obtains concrete embodiment in example.Finished on this basis the present invention.
Enforcement of the present invention only has illustration for the present invention and without limits effect.
Embodiment 1
Described bactericide is oil-suspending agent, and the percentage by weight of component is:
The concrete procedure of processing of this suspending agent is: first auxiliary agent is mixed, shear-mixed is even in high-speed shearing machine, adds afterwards BCDMH, through sand mill sand milling 1～3h, the discharging particle diameter is reached below the 5 μ m, namely obtains the BCDMH oil-suspending agent.
Embodiment 2
Described bactericide is wetting powder, and the percentage by weight of component is:
The concrete procedure of processing of this bactericide wetting powder is: BCDMH, dispersant, wetting agent and carrier are added according to formula ratio, mix in reactor, mixture namely obtains the wetting powder of this medicament behind the airslide disintegrating mill co-grinding.
Embodiment 3
Described bactericide is pulvis, and the percentage by weight of component is:
The concrete procedure of processing of this bactericide pulvis is: BCDMH, dispersant, wetting agent and carrier are added according to formula ratio, mix in reactor, mixture namely obtains the pulvis of this medicament behind the airslide disintegrating mill co-grinding.
Embodiment 4
Described bactericide is missible oil, and the percentage by weight of component is:
BCDMH 1～80%
Emulsifier 3～30%
Solvent 3～70%
The concrete procedure of processing of this bactericide missible oil is: solvent, BCDMH and emulsifier etc. are added in the reactor according to formula ratio, mix and make its dissolving, make single-phase transparent liquid after the filtration and namely obtain missible oil.
Embodiment 5
Described bactericide is seed dressing, and the percentage by weight of component is:
The concrete procedure of processing of this fungicide seed treatment agent is: BCDMH, dispersant, wetting agent, sticker and carrier are added according to formula ratio, mix in reactor, mixture namely obtains the seed dressing of this medicament behind the airslide disintegrating mill co-grinding.
Embodiment 6
BCDMH is measured the dull and stereotyped inhibition of pathogen
1 for the examination material
1.1 the former medicine of reagent agent 95% BCDMH, the inferior light fine chemistry industry in Hebei is produced.
1.2 for trying pathogen pseudomonas (Pseudomonas): bacterial spot of tomato (Pseudomonas syringae pv.Tomota), the false unit cell fruit rot (Pseudomonas fluorescers biovar II) of tomato, tomato marrow downright bad sick (Pseudomonas corrugata Roberts et Scarlett), eggplant bacterial wilt (Pseudomonas solanacearum (Smith) Smith), eggplant bacterial brown spot (Pseudomonas cichorii (Swingle) Stapp), capsicum bacterial leaf spot (Pseudomonas syringae pv.aptata), pepper fruit bacterium black spot (P.viridiflava (Burkholder)), cucumber bacterial angular leaf spot (Pseudomonas syringae pv.lachrymans (Smith et Bryan)), corn bacterial stem rot (Pseudomonas marginalis pv.marginalis (Brown) Stevens), the bacillary dizzy epidemic disease of Kidney bean (Pseudomonas syringae pv.Phaseolicola), the false unit cell leaf blight (Pseudomonas viciae Uyede) of broad bean, pea bacterial leaf spot (Pseudomonas syringae pv.pisi (Sackett)), dish soybean bacterial epidemic disease (P.glycinea var.japonica (T) Savulescu), Kidney bean bacterial leaf spot (Pseudomonas syringae pv.syringae van Hall), paddy bacterial brown spot (Pseudomonas syringae pv.syringae), kiwi berry bacterial canker (Pseudomonas syringae pv.actinidia), wildfire (Pseudomonas syringae pv.tabaci); Acidovorax (Acidovorax): bacterial fruit blotch of watermelon (Acidovorax avenae subsp.citrulli), corn bacterial leaf blight (Acidovorax avenae subsp.avenae); Xanthomonas (Xanthomonas): bacterial leaf streak of rice (Xanthomonas oryzae pv.oryzicola), the bacillary shothole disease of peach (Xanthomonas campestris pv.pruni), strawberry bacterial leaf spot (Xanthomonas fragariae), Wheat Bacterial Stripe (Xanthomonas campestris pv.translucens), citrus bacterial canker disease (Xanthomonas Campestris pv.citri), cotton bacterial angular leaf spot (Xanthoumonas campestris pv.malvacearum), tomato shot hole (Xanthomonas vesicetoria Vauterin et al.), cabbage black rot (Xanthomonas campestris pv.campestris), cucumber bacterium circle pinta (X.cucurbitae (Bryan) Dowson), common bacterial blight of bean (Xanthomonas axonopodis pv.phaseohi Vauterin et al.), dish soybean bacterium leaf blight (Xanthomonas axonopodis pv.glycines Vauterin et al.), okra bacterium angular leaf spot (X.malvacearum (Smith) Dowson); Erwinia (Erwinia): Stewart's wilt (Erwinia stewartii), banana bacterial slimy soft rot (Erwinia chrysanthemi pv.zeae), Tomato soft rot (Erwinia carotovara subsp.carotovara (Jones) Bergey et al.), black leg of cabbage (Erwinia carotovara subsp.atroseptica), watermelon bacterium fusarium wilt (Erwinia tracheiphila (Smith) Bergey et al.); Rod shape Bacillus (Clavibacter): potato bacterial ring rot (Clavibacter michiganense subsp.Sepedonicum), canker of tomato (Clavibacter michiganense subsp.michiganensis (Smith) Davis et al.); Raul Salmonella Pseudomonas (Ralstonia): banana blight (Ralstoniasolanacearum); Agrobacterium (Agrobacterium): peach root knot (Agrobacterium tumefaciens).
2 for method for testing
Under aseptic condition, reagent agent is mixed with concentration is respectively 500 μ g/ml, 1000 μ g/ml and 3000 μ g/ml are for subsequent use.Strains tested was cultivated two days under 28 ℃ of conditions in the NA liquid nutrient medium, got the NA medium that 4.5ml is cooled to 45 ℃ and mixed in sterile petri dish with the 0.5ml bacteria suspension, and bacterium culture medium is with in preparation.Get and respectively process liquid 100 μ l evenly coating in this flat board, each processes 5 culture dishes, and each concentration repeats 28 ℃ of constant temperature culture 48h " Invest, Then Investigate " colony growth situations 3 times.
Pathogen inhibiting rate grade scale:
++ ++: bacterium normal growth, unrestraint effect;
+++: has 3/4 with interior bacterial growth, and bactericidal action is 25%;
++: have 1/2 with interior bacterial growth, bactericidal action is 50%;
+: have 1/4 with interior bacterial growth, bactericidal action is 75%;
-: bacterium does not grow, and bactericidal action is 100%
3 result of the tests
BCDMH shows that to the fungistatic effect of pathogen along with the increase of BCDMH concentration, medicament strengthens the inhibitory action of pathogen.When BCDMH concentration was 1000 μ g/ml, there was inhibitory action in medicament to 37 pathogen strain bacterium in selected 44 bacterial strains, can suppress colony growth fully.When BCDMH concentration was 2000 μ g/ml, all bacterial strains all can not be grown, and showed under 2000 μ g/ml concentration, and BCDMH can suppress all pathogen growths (seeing Table 2) fully.Contrast medicament 3% Zhongshengmycin WP only presents inhibitory action to the part pathogen when being 30 μ g/ml according to the recommendation dose concentration.
Table 2 BCDMH variable concentrations is to the fungistatic effect of pathogen
Embodiment 7
BCDMH is measured the potted plant control efficiency of the live body of bacterial disease
Seedling grows to 2～3 leaf periods and carries out live test, adopts the inoculation of bacteria suspension spray-on process, and investigation variable concentrations bactericide is to the control efficiency (seeing Table 3) of each disease.Result of the test shows that when BCDMH concentration was 1000 μ g/ml, except indivedual bacterial strains, medicament can reach more than 75% disease-controlling effect.When BCDMH concentration was 2000 μ g/ml, medicament had good preventive effect to multiple diseases, and its control efficiency is all more than 85%.When contrast medicament 3% Zhongshengmycin WP is 30 μ g/ml according to the recommendation dose concentration, generally lower or without preventive effect to the preventive effect of each bacterial disease.
During table 3 BCDMH variable concentrations to the control efficiency of bacterial disease
Embodiment 8
BCDMH is measured the control efficiency of Seedborne bacterial disease
For Seedborne bacterial disease common on the agricultural, process seed with 25% BCDMH seed dressing, detect under the BCDMH variable concentrations control efficiency (seeing Table 4) to disease.Used seed is tomato, eggplant, capsicum, cucumber, Kidney bean, watermelon, wild cabbage and the rice paddy seed after manually carrying disease germs in the test.It is 2000 μ g/ml that 25% BCDMH seed dressing is diluted to respectively concentration, and 1000 μ g/ml and 500 μ g/ml adopt the method for liquid seed soaking to process infected seed, 3 afterwards directly sowings of the seed clear water flushing after the processing, routine observation seedling incidence.Result of the test shows during 25% BCDMH seed dressing, 2000 μ g/ml seed soaking, bacterial disease to be had good control efficiency, and average preventive effect is up to more than 98%.
Table 425% BCDMH seed dressing is to the control efficiency of different seed-borne diseases
Embodiment 9
Field control effectiveness test
At random district's group arrangement is adopted in each processing of test, establishes guard row all around.On August 16th, 2011, for the first time dispenser every dispenser in 7 days once, continuous 3 times, was investigated on September 13rd, 2011.Test medicine is 25% BCDMH WP, and dosage is 150～225gai/hm
2, the contrast medicament is 3% Zhongshengmycin WP, is 675g/hm according to the recommended drug amount
2Test site is Guangyang District Bu Ying village and proving ground, Langfang.
Test is undertaken by the plant foliar spray, when 25% BCDMH WP dosage is 150gai/hm
2, spray to plant is whole in their early stage.The test bacterial strain uses therefor comprises: the eggplant bacterial wilt that is caused by the withered false pseudomonas bacillus of green grass or young crops (Pseudomonas solanacearum (Smith) Smith) in the pseudomonas (Pseudomonas), the soybean bacterial epidemic disease that Pseudomonas syringae pv.glycinea (Pseudomonas syringae pv.glycinea) causes, the bacterial fruit blotch of watermelon that is caused by oat acidovorax avenae watermelon subspecies (Acidovorax avenae subsp.citrulli) in the Acidovorax (Acidovorax), the cucumber bacterium circle pinta that is caused by the pathogenic mutation (X.cucurbitae (Bryan) Dowson) of rape Xanthomonas campestris cucumber in the Xanthomonas (Xanthomonas), the Tomato soft rot that is caused by carrot soft rot Erwinia carrot soft rot pathological form (Erwinia carotovara subsp.carotovara (Jones) Bergey et al.) in the Erwinia (Erwinia), the corn Stewart's wilt that Erwinia (Erwinia stewartii) causes of withering, the canker of tomato that the Erwinia chrysanthemi corn causes a disease and caused by canker of tomato Michigan rod bacillus (Clavibacter michiganense subsp.michiganensis (Smith) Davis et al.) in paddy bacterial base rot disease that mutation (Erwinia chrysanthemi pv.zeae) causes and the rod shape Bacillus (Clavibacter).In the field experiment of above disease, BCDMH is to the eggplant bacterial wilt, bacterial fruit blotch of watermelon, the bacillary round pinta of cucumber, Tomato soft rot, canker of tomato, the soybean bacterial epidemic disease, the control efficiency of Stewart's wilt and paddy bacterial base rot disease is respectively 60.34%, 82.05%, 78.67%, 68.61%, 85.34%, 74.63%, 78.41% and 85.94%, contrast medicament 3% Zhongshengmycin WP dosage is that the 675g/hm2 control efficiency is respectively 25.46%, 21.35%, 36.61%, 46.21%, 11.37%, 32.84%, 45.94% and 27.68%.
Field experiment result shows that the BCDMH dosage is 150～225gai/hm
2The time various bacterial disease on the agricultural had favorable effect, can effectively reduce generation and the development of disease.
Claims (7)
1. new type bactericide agricultural chemicals that is used for preventing and treating agriculture bacterial disease is characterized in that: active ingredient is BCDMH and comprises and produce upper formulation, auxiliary agent and the carrier that allows.
2. a kind of new type bactericide agricultural chemicals be used to preventing and treating agriculture bacterial disease according to claim 1, it is characterized in that: the described formulations of pesticide are to produce upper any solid or the liquid dosage form that allows, and comprise missible oil, wetting powder, pulvis, seed dressing and suspending agent.
3. a kind of new type bactericide agricultural chemicals be used to preventing and treating agriculture bacterial disease according to claim 1 and 2, it is characterized in that: the auxiliary agent or the carrier that allow in the described production comprise dispersant, wetting agent, emulsifier, sticker, thickener, antifreezing agent, defoamer, solvent and other inert carrier, described dispersant is selected from lignosulfonates, alkylphenol polyoxyethylene, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO, the polycarboxylate formaldehyde condensation products, alkyl benzene sulfonate calcium salt, in the alkylphenol polyoxyethylene one or more, lignosulfonates preferably, it is 5～20% that alkylphenol polyoxyethylene and naphthalene sulfonic acid-formaldehyde condensation product sodium salt, dispersant dosage account for percentage by weight; Described wetting agent is selected from one or more in lauryl sodium sulfate, alkylnaphthalene sulfonate, Nekal BX, APEO, alkyl phosphoric acid sodium, the alkylphenol-polyethenoxy base sodium sulphate, preferably lauryl sodium sulfate, alkylnaphthalene sulfonate and alkylphenol-polyethenoxy base sodium sulphate, it is 3～10% that addition accounts for percentage by weight.
4. a kind of new type bactericide agricultural chemicals be used to preventing and treating agriculture bacterial disease according to claim 1 and 2, it is characterized in that: to account for percentage by weight be BCDMH 1～80% to the material consumption in the formulation process, auxiliary agent 6～20%, carrier 0～70%, each formulation and material input amount are as follows:
It is BCDMH 1～80% that suspending agent material consumption accounts for percentage by weight, dispersant 5～20%, antifreezing agent 1～5%, thickener 0.1～3%, defoamer 0.1～0.8%, solvent 3～80%;
It is BCDMH 1～80% that missible oil material consumption accounts for percentage by weight, emulsifier 3～30%, solvent 3～70%;
It is BCDMH 1～80% that wetting powder material consumption accounts for percentage by weight, dispersant 3～20%, wetting agent 3～10%, carrier 2～70%;
It is BCDMH 1～80% that the powder material consumption accounts for percentage by weight, dispersant 3～20%, wetting agent 3～10%, carrier 2～70%; It is BCDMH 1～50% that seed dressing material consumption accounts for percentage by weight, dispersant 3～20%, wetting agent 1～10%, sticker 5～10%, carrier 2～60%.
5. the application process of a kind of new type bactericide agricultural chemicals be used to preventing and treating agriculture bacterial disease according to claim 1 is characterized in that: applications of pesticide method comprises the plant spraying, fills with root and seed treatment.
6. the application process of a kind of new type bactericide agricultural chemicals be used to preventing and treating agriculture bacterial disease according to claim 5 is characterized in that:
Be used for the plant spraying and process, their early stage uses, and dosage is 150～225gai/hm
2
Be used for root irrigation, dosage is 45～67.5gai/hm
2
Be used for seed treatment, such as the small-sized seed of Chinese cabbage, radish and wild cabbage etc., adopt 100～2000 μ g/ml liquids seed soaking 1～2h or the vexed kind 1～6h of 50～1500 μ g/ml liquids; Such as the large seed of wheat, paddy rice, muskmelon and soybean etc., adopt 200～3000 μ g/ml liquids seed soaking 1～2h or the vexed kind 2～8h of 100～2000 μ g/ml liquids.
7. the application process of a kind of new type bactericide agricultural chemicals be used to preventing and treating agriculture bacterial disease according to claim 1, it is characterized in that: the control Damage Types is agriculture bacterial disease, comprise the pseudomonas syringae tomato mutation (Pseudomonas syringae pv.Tomota) of pseudomonas (Pseudomonas), as: bacterial spot of tomato; Pseudomonas pseudomonas fluorescens biotype II (Pseudomonas fluorescers biovar II), as: the false unit cell fruit rot of tomato; Wrinkle pseudomonad (Pseudomonas corrugata Roberts et Scarlett), as: the tomato marrow is downright bad sick; Blue or green withered false pseudomonas bacillus (Pseudomonas solanacearum (Smith) Smith), as: eggplant bacterial wilt etc.; Pseudomonas cichorii (Pseudomonas cichorii (Swingle) Stapp), as: the eggplant bacterial brown spot; Pseudomonas syringae is fit to the mutation (Pseudomonas syringae pv.aptata) of causing a disease, as: the capsicum bacterial leaf spot; Pseudomonas viridiflava (P.viridiflava (Burkholder)), as: pepper fruit bacterium black spot etc.; The pseudomonas syringae pathogenic mutation (Pseudomonas syringae pv.lachrymans (Smith et Bryan)) of shedding tears, as: cucumber bacterial angular leaf spot, snake melon bacterial angular leaf spot etc.; The false unit cell pathological form (Pseudomonas marginalis pv.marginalis (Brown) Stevens) in pseudomonad edge, edge, as: the bacillary marginal leaf blight of cucumber; The mutation (Pseudomonas syringae pv.Phaseolicola) of causing a disease of pseudomonas syringae Kidney bean, as: the bacillary dizzy epidemic disease of Kidney bean; Broadbean leaf burns pseudomonad (Pseudomonas viciae Uyede), as: the false unit cell leaf blight of broad bean; The mutation (Pseudomonas syringae pv.pisi (Sackett)) of causing a disease of pseudomonas syringae pea, as: the pea bacterial leaf spot; Pseudomonas syringae pv.glycinea (P.glycinea var.japonica (T) Savulescu), as: dish soybean bacterial epidemic disease; The pathogenic mutation (Pseudomonas syringae pv.syringae van Hall) of the false unit cell cloves of cloves, as: Kidney bean bacterial leaf spot, corn bacterial brown spot, wheat Bacterial Leaf Blight; The pathogenic mutation (Pseudomonas syringae pv.actinidia) of the false single crisp bacillus kiwi fruit of cloves, as: kiwi berry bacterial canker; Pseudomonas syringae pv.glycinea (Pseudomonas syringae pv.glycinea), as: the soybean bacterial epidemic disease; Pseudomonas syringae pv. tabaci (Pseudomonas syringae pv.tabaci), as: wildfire; Acidovorax (Acidovorax) oat acidovorax avenae watermelon subspecies (Acidovorax avenae subsp.citrulli), as: bacterial fruit blotch of watermelon; Oat acidovorax avenae oat subspecies (Acidovorax avenae subsp.avenae), as: the corn bacterial leaf blight; Xanthomonas (Xanthomonas) blister spot Xanthomonas campestris (Xanthomonas vesicetoria Vauterin et al.), as: the tomato shot hole; The black rotten mutation (Xanthomonas campestris pv.campestris) of causing a disease of Xanthomonas campestris pv campestris, as: the bacillary black rot of wild cabbage; The mutation (X.cucurbitae (Bryan) Dowson) of causing a disease of rape Xanthomonas campestris cucumber, as: the bacillary round pinta of cucumber; The mutation (Xanthomonas axonopodis pv.phaseohi Vauterin et al.) of causing a disease of carpet Xanthomonas campestris Kidney bean, as: common bacterial blight of bean; The mutation (Xanthomonas axonopodis pv.glycines Vauterin et al.) of causing a disease of carpet Xanthomonas campestris soybean, such as: dish with the bacillary leaf blight of soybean; The mutation (X.malvacearum (Smith) Dowson) of causing a disease of rape Xanthomonas campestris high mallow, as: the okra bacterial angular leaf spot; The living Xanthomonas campestris of rice (Xanthomonas oryzae pv.oryzae), as: bacterial blight of rice; The mutation (Xanthomonas oryzae pv.oryzicola) of causing a disease of the living Xanthomonas campestris streak of rice, as: bacterial leaf streak of rice; The mutation (Xanthomonas campestris pv.pruni) of causing a disease of xanthomonas campestris peaches and plums, as: the bacillary shothole disease of peach; Xanthomonas fragariae (Xanthomonas fragariae), as: the strawberry bacterial leaf spot; The mutation (Xanthomonas campestris pv.translucens) of causing a disease of xanthomonas campestris wheat is such as the mutation (Xanthomonas campestris pv.translucens) of causing a disease of: xanthomonas campestris wheat; The mutation (Xanthomonas Campestris pv.citri) of causing a disease of carpetweed Xanthomonas campestris oranges and tangerines, as: citrus bacterial canker disease; The mutation (Xanthoumonas campestris pv.malvacearum) of causing a disease of xanthomonas campestris high mallow, as: the cotton bacterial angular leaf spot; Erwinia (Erwinia) carrot soft rot Erwinia carrot soft rot pathological form (Erwinia carotovara subsp.carotovara (Jones) Bergey et al.), as: Tomato soft rot and inducing fruit soft rot of melon; Melon wilt disease Erwinia (Erwinia tracheiphila (Smith) Bergey et al.), as: the watermelon bacterialo wilt disease; Carrot soft rot Erwinia is deceived shin subspecies (Erwinia carotovara subsp.atroseptica), as: black leg of cabbage; The corn Erwinia (Erwinia stewartii) that withers, as: Stewart's wilt; The mutation (Erwinia chrysanthemi pv.zeae) of causing a disease of Erwinia chrysanthemi corn, as: banana bacterial slimy soft rot, paddy bacterial base rot disease and corn bacterial stem rot; The rotten pathological form (Clavibacter michiganense subsp.Sepedonicum) of rod shape Bacillus (Clavibacter) Michigan rod bacillus potato ring, as: bacterial soft rot of potato; Canker of tomato Michigan rod bacillus (Clavibacter michiganense subsp.michiganensis (Smith) Davis et al.), as: canker of tomato; Agrobacterium (Agrobacterium) Agrobacterium tumefaciens (Agrobacterium tumefaciens), as: peach root knot, Li Shugen carninomatosis, Apple crown gall, bretschneider pear root carninomatosis, european grape root carninomatosis and Chinese chestnut root knot.
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| CN104160845A (en) * | 2014-07-11 | 2014-11-26 | 周利 | Method for preventing and controlling bacterial brown spot in eggplant planting process |
| CN106472220A (en) * | 2016-10-13 | 2017-03-08 | 山东省烟台市农业科学研究院 | Fructus Pruni pseudocerasi anti-root knot stock screening technique |
| CN106982829A (en) * | 2017-04-12 | 2017-07-28 | 江苏金凤凰农化有限公司 | Application and application process of the guaiacol in preventing and treating lettuce disease |
| CN107306541A (en) * | 2016-08-09 | 2017-11-03 | 中国热带农业科学院环境与植物保护研究所 | A kind of bacillary Wei Nian Bing Romania diseases stem sterilization method of cassava |
| CN109644997A (en) * | 2019-01-25 | 2019-04-19 | 龙口科达化工有限公司 | A kind of environment-friendly type slurry emulsus bromochloroin and its no three wastes clean preparation method |
| CN110178672A (en) * | 2019-05-05 | 2019-08-30 | 双鸭山东昊农业科技有限责任公司 | A kind of control method of Carrot Roots maize ear rot caused by alternaria solani sorauer or leaf spot |
| CN110352987A (en) * | 2019-07-25 | 2019-10-22 | 广东新景象生物工程有限公司 | A kind of prevention and treatment citrus bacterial canker disease new drug and preparation method |
| CN110408578A (en) * | 2019-09-25 | 2019-11-05 | 中国农业科学院农业资源与农业区划研究所 | One plant of wrinkle pseudomonad and its application |
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| CN116103334A (en) * | 2022-11-16 | 2023-05-12 | 西北农林科技大学 | Instant transformation system special for screening anti-ulcer disease gene functions of kiwi fruits |
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| CN104160845A (en) * | 2014-07-11 | 2014-11-26 | 周利 | Method for preventing and controlling bacterial brown spot in eggplant planting process |
| CN107306541A (en) * | 2016-08-09 | 2017-11-03 | 中国热带农业科学院环境与植物保护研究所 | A kind of bacillary Wei Nian Bing Romania diseases stem sterilization method of cassava |
| CN107306541B (en) * | 2016-08-09 | 2020-11-27 | 中国热带农业科学院环境与植物保护研究所 | Method for sterilizing bacterial wilt, wilting disease and fruiting stems of cassava |
| CN106472220A (en) * | 2016-10-13 | 2017-03-08 | 山东省烟台市农业科学研究院 | Fructus Pruni pseudocerasi anti-root knot stock screening technique |
| CN106982829A (en) * | 2017-04-12 | 2017-07-28 | 江苏金凤凰农化有限公司 | Application and application process of the guaiacol in preventing and treating lettuce disease |
| CN109644997A (en) * | 2019-01-25 | 2019-04-19 | 龙口科达化工有限公司 | A kind of environment-friendly type slurry emulsus bromochloroin and its no three wastes clean preparation method |
| CN110178672A (en) * | 2019-05-05 | 2019-08-30 | 双鸭山东昊农业科技有限责任公司 | A kind of control method of Carrot Roots maize ear rot caused by alternaria solani sorauer or leaf spot |
| CN110352987A (en) * | 2019-07-25 | 2019-10-22 | 广东新景象生物工程有限公司 | A kind of prevention and treatment citrus bacterial canker disease new drug and preparation method |
| CN110923178A (en) * | 2019-09-25 | 2020-03-27 | 中国农业科学院农业资源与农业区划研究所 | Plant immunity inducing antibacterial agent and application thereof |
| CN110951657A (en) * | 2019-09-25 | 2020-04-03 | 中国农业科学院农业资源与农业区划研究所 | Bacterial wilt preventing and growth promoting microbial inoculum and application thereof |
| CN110408578A (en) * | 2019-09-25 | 2019-11-05 | 中国农业科学院农业资源与农业区划研究所 | One plant of wrinkle pseudomonad and its application |
| CN110923178B (en) * | 2019-09-25 | 2021-06-18 | 中国农业科学院农业资源与农业区划研究所 | Plant immunity inducing antibacterial agent and application thereof |
| CN110951657B (en) * | 2019-09-25 | 2021-06-22 | 中国农业科学院农业资源与农业区划研究所 | Bacterial wilt preventing and growth promoting microbial inoculum and application thereof |
| CN114854627A (en) * | 2022-04-29 | 2022-08-05 | 重庆西农植物保护科技开发有限公司 | Pseudomonas fluorescens for preventing and treating bacterial wilt and application thereof |
| CN114854627B (en) * | 2022-04-29 | 2023-10-13 | 重庆西农植物保护科技开发有限公司 | Pseudomonas fluorescens for preventing and treating bacterial wilt and application thereof |
| CN116103334A (en) * | 2022-11-16 | 2023-05-12 | 西北农林科技大学 | Instant transformation system special for screening anti-ulcer disease gene functions of kiwi fruits |
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