CN103351925A - Cutting fluid composition - Google Patents
Cutting fluid composition Download PDFInfo
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- CN103351925A CN103351925A CN2013102453069A CN201310245306A CN103351925A CN 103351925 A CN103351925 A CN 103351925A CN 2013102453069 A CN2013102453069 A CN 2013102453069A CN 201310245306 A CN201310245306 A CN 201310245306A CN 103351925 A CN103351925 A CN 103351925A
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Abstract
The invention discloses a cutting fluid composition. The cutting fluid composition comprises, by weight, 20-30 parts of mineral oil, 1-10 parts of alkyl sodium sulfonate, 1-5 parts of fatty alcohol-polyoxyethylene ether, 2-8 parts of fluorocarbon surfactants, 2-10 parts of organic boric acid ester, 2-15 parts of antirust additives, 0.5-5 parts of anticorrosion bactericides, 0.1-0.6 parts of organosilicon antifoaming agents and 5-60 parts of water. The cutting fluid composition is advantaged by good permeability, antirust performance and bacteriostasis anticorrosion performance, storage stabilization and moderate viscosity.
Description
Technical field
The present invention relates to the cutting fluid technical field, relate in particular to a kind of cutting fluid composite.
Background technology
Cutting fluid is that a kind of metal that is used in is cut, cuts, grinds in the course of processing, be used for the industrial type fluid of Cooling and Lubricator cutter and workpiece, cutting fluid is formed through compound compatibility by multiple super strong functional auxiliary agent, possesses simultaneously good cooling performance, lubricity, rustless property, oil removing cleaning function, anti-corrosion function, easily dilutable characteristics.
Cutting fluid is divided into water-insoluble (oil base) liquid and water-soluble (water base) liquid two large classes by the oil product chemical constitution.The lubricity of oil base cutting fluid is better, and cooling performance is relatively poor.It is relative relatively poor that water-base cutting fluid and oil base cutting fluid are compared lubricity, and cooling performance is better.Cutting requires the oilness of cutting fluid to be eager to excel at a slow speed, in general, uses machining oil when cutting speed is lower than 30m/min.
Cutting fluid comprises the oil base cutting fluid that contains mineral oil and additive, contains polyoxyethylene glycol or polypropylene glycol as the glycol-based cutting fluid of main ingredient, and the water-based cutting fluid of water phase surfactant mixture form.Yet these cutting fluids have shortcoming.The oil base cutting fluid is poor at the cooling performance of cutting point.The oil base cutting fluid can be polluted workpiece or instrument, need to further clean with organic solvent, and is unfriendly to environment.Glycol-based cutting fluid and water-based cutting fluid in cutting operation viscosity stability and the dispersion stabilization of abrasive material aspect performance relatively poor.
The advantage of chemosynthesis cutting fluid is economy, rapid heat dissipation, the strong and fabulous workpiece visibility of cleaning, is easy to the controlled working size, and its stability and anti-corrupt energy force rate emulsion are strong.Oilness is not good enough, and this will cause adhesion and the wearing and tearing of lathe movable part, and the thick residue that chemosynthesis stays can affect the motion of machine parts, also can make the faying surface of these parts produce corrosion.
In recent ten years, because the improving constantly of cutting technology, the continuing to bring out of advanced cutting machine, the development of cutter and workpiece material has promoted the development of cutting fluid technology.Along with the deep development of advanced manufacturing technology and the reinforcement of people's environmental protection consciousness, the cutting fluid technology has been proposed Secretary, it will promote the cutting fluid technology and develop to higher field.
CN101768502A discloses a kind of micro-emulsion cutting fluid composition and method of making the same, said composition comprises the raw material of following by weight percentage ratio meter: the mineral oil of 22-32%, the anion surfactant of 2-10%, the nonionogenic tenside of 1-5%, the emulsion stabilizer of 1-3%, the oiliness improver of 5-10%, the extreme-pressure additive of 5-10%, the rust-inhibiting additive of 5-15%, the anticorrosion and bactericidal agent of 0.5-3%, the anti-foam additive of 0.1-0.3%, surplus are water.Micro-emulsion cutting fluid preparation method of composition of the present invention is easy, and the cutting fluid S50 composition that provides is ecological stable form product, and oilness and cooling are good, can improve the working accuracy of workpiece; And has very strong bacteriostasis, long service life; The pH value stabilization is good, for workpiece provides good rust-preventing characteristic.
At present, the performance of various water-base cutting fluids is different and different with prescription with result of use, compare with emulsion, though have little, the advantages such as cost is lower, less pollution of power consumption, but still there is some deficiency, for example: what have still has certain pollution, some scent ofs, and the water quality requirement to preparation that has is stricter.
Summary of the invention
In order to solve the problem of prior art, the present invention proposes the cutting fluid composite of a kind of pollution-free, good antirust property, low bubble, hypertonicity.
A kind of cutting fluid composite that the present invention proposes comprises following component by weight:
In technique scheme, fatty alcohol-polyoxyethylene ether is as emulsifying agent, play the effect that promotes oil phase and water to form emulsion, described fatty alcohol-polyoxyethylene ether be among AEO-3, AEO-5, AEO-7, the AEO-9 any one, perhaps be AEO-7/AEO-3, AEO-5/AEO-9, AEO-5/AEO-9/AEO-7, AEO-9/AEO-3 etc.
In technique scheme, described rust-inhibiting additive can form protective membrane with the metallic surface or passive film plays rust inhibition, and rust-inhibiting additive is the composition of any one and benzotriazole in boric acid amine salt, boric acid acid amides and the boric acid ester.
In technique scheme, anticorrosion and bactericidal agent act as the growth that prevents with anti-bacteria, described anticorrosion and bactericidal agent is isothiazolinone.
In technique scheme, described silicone antifoam agent is selected from the combination of any one or at least two kinds in dimethylsilane, polysiloxane defoamers, the polyether-modified defoamer, for example, dimethylsilane/polysiloxane defoamers, polyether-modified defoamer/dimethylsilane/polysiloxane defoamers etc.
In technique scheme, organic boric acid ester is as anti-extreme pressure agent, and described organic boric acid ester contains element S and element P, is preferably NPBS.
In technique scheme, add fluorocarbon surfactant in the cutting fluid take mineral oil as base oil, make cutting fluid disclosed in this invention have the good surface-active while, also satisfied good low bubble, has simultaneously very low surface tension, have good perviousness, said fluorocarbon surfactant is siliceous fluorocarbon surfactant.
In optimal technical scheme, a kind of cutting fluid composite of the present invention comprises following component by weight:
Compared with prior art, the present invention has following beneficial effect:
Cutting fluid provided by the invention is added with fluorocarbon surfactant, cooperate mineral oil as base oil, fatty alcohol-polyoxyethylene ether is as emulsifying agent, obtained the emulsion cutting fluid of outward appearance homogeneous, storage-stable, modest viscosity, in addition with the compatibility of silicone antifoam agent, the gained cutting fluid has advantages of low bubble, ground surface activity, has good perviousness.Cutting fluid provided by the invention is added with rust-preventive agent and anticorrosion and bactericidal agent, gives the cutting product good rustless property and antibacterial antiseptic property.In sum, cutting fluid provided by the invention has good perviousness, rustless property, antibacterial antiseptic property, storage-stable, modest viscosity.
Embodiment
Embodiment 1
In this enforcement, a kind of cutting fluid composite comprises following component by weight:
Embodiment 2
In this enforcement, plant cutting fluid composite, comprise by weight following component:
Embodiment 3
In this enforcement, a kind of cutting fluid composite comprises following component by weight:
Comparative Examples
Embodiment 1 is as Comparative Examples in the CN101768502A, and concrete steps are as follows:
Described raw material is the percentage ratio meter by weight, 22.0 parts in mineral oil, be warming up to 40 ℃, add successively 2.0 parts of emulsifying agent petroleum sodium sulfonates, 5.0 parts of fatty alcohol-polyoxyethylene ether, 8.0 parts of oiliness improver oleic acid, 10.0 parts of extreme-pressure additive clorafins, 3.0 parts of emulsion stabilizer diethylene glycol monobutyl ethers, stir, at ambient temperature, add again 4.0 parts in boric acid amine salt, 6.0 parts of boric acid acid amides, 0.2 part of rust-preventive agent benzotriazole, 38.7 parts in water, 1.0 parts of anticorrosion and bactericidal agent hexahydrotriazines, 0.1 part of kilfoam silicone emulsion.After stirring, make the S50 cutting fluid stoste of microemulsified, this stoste can be diluted 10～40 times of uses as the case may be.
Simultaneous test
Stability in storage, spumescence, the surface tension of embodiment 1-3 and Comparative Examples are compared test, and its performance test results is as follows:
As can be seen from Table 1, the surface tension of cutting fluid provided by the invention is low, has good perviousness, and foam is low, has guaranteed the working accuracy in later stage, and simultaneously, stability in storage and rustless property are also very good.
The above; only be the better embodiment of the present invention; but protection scope of the present invention is not limited to this; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to replacement or change according to technical scheme of the present invention and inventive concept thereof, all should be encompassed within protection scope of the present invention.
Claims (8)
1. a cutting fluid composite is characterized in that, comprises by weight following component:
2. cutting fluid composite as claimed in claim 1 is characterized in that, described fatty alcohol-polyoxyethylene ether is the combination of any one or at least two kinds among AEO-3, AEO-5, AEO-7, the AEO-9.
3. cutting fluid composite as claimed in claim 1 or 2 is characterized in that, described rust-inhibiting additive is the composition of any one and benzotriazole in boric acid amine salt, boric acid acid amides and the boric acid ester.
4. such as each described cutting fluid composite among the claim 1-3, it is characterized in that, described anticorrosion and bactericidal agent is isothiazolinone.
5. such as each described cutting fluid composite among the claim 1-4, it is characterized in that, described silicone antifoam agent is selected from the combination of any one or at least two kinds in dimethylsilane, polysiloxane defoamers, the polyether-modified defoamer.
6. such as each described cutting fluid composite among the claim 1-5, it is characterized in that, described organic boric acid ester contains element S and element P.
7. such as each described cutting fluid composite among the claim 1-6, it is characterized in that, said fluorocarbon surfactant is siliceous fluorocarbon surfactant.
8. each described cutting fluid composite is characterized in that according to claim 1-7, comprises by weight following component:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310245306.9A CN103351925B (en) | 2013-06-19 | 2013-06-19 | Cutting fluid composition |
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| CN201310245306.9A CN103351925B (en) | 2013-06-19 | 2013-06-19 | Cutting fluid composition |
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| CN103351925A true CN103351925A (en) | 2013-10-16 |
| CN103351925B CN103351925B (en) | 2015-07-01 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104120003A (en) * | 2014-06-25 | 2014-10-29 | 安徽豪鼎金属制品有限公司 | Microemulsion cutting fluid for metals and preparation method thereof |
| US10287477B2 (en) | 2017-02-03 | 2019-05-14 | Saudi Arabian Oil Company | Dispersant in cement formulations for oil and gas wells |
| CN112276141A (en) * | 2020-09-04 | 2021-01-29 | 广州锻造一厂股份有限公司 | Deep hole machining method for large-sized forged part |
| CN115161093A (en) * | 2022-07-12 | 2022-10-11 | 深圳市爱康泉水处理服务有限公司 | Composition for cutting fluid conditioner, cutting fluid conditioner and application of cutting fluid conditioner |
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| GB814864A (en) * | 1956-08-13 | 1959-06-10 | Bataafsche Petroleum | Metal-working lubricants |
| CN102002424A (en) * | 2010-12-14 | 2011-04-06 | 上海德润宝特种润滑剂有限公司 | Micro emulsion cutting fluid composition and preparation method thereof |
| CN102021070A (en) * | 2010-12-14 | 2011-04-20 | 南通宏申化工有限公司 | Cutting fluid for water-soluble monocrystalline silicon wafers or polycrystalline silicon wafers |
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2013
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| GB814864A (en) * | 1956-08-13 | 1959-06-10 | Bataafsche Petroleum | Metal-working lubricants |
| CN102002424A (en) * | 2010-12-14 | 2011-04-06 | 上海德润宝特种润滑剂有限公司 | Micro emulsion cutting fluid composition and preparation method thereof |
| CN102021070A (en) * | 2010-12-14 | 2011-04-20 | 南通宏申化工有限公司 | Cutting fluid for water-soluble monocrystalline silicon wafers or polycrystalline silicon wafers |
Cited By (32)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104120003A (en) * | 2014-06-25 | 2014-10-29 | 安徽豪鼎金属制品有限公司 | Microemulsion cutting fluid for metals and preparation method thereof |
| CN104120003B (en) * | 2014-06-25 | 2016-06-29 | 安徽豪鼎金属制品有限公司 | A kind of micro-emulsion cutting fluid suitable in metal and preparation method thereof |
| US10683447B2 (en) | 2017-02-03 | 2020-06-16 | Saudi Arabian Oil Company | Invert emulsion based drilling fluid and methods of using same |
| US10377939B2 (en) | 2017-02-03 | 2019-08-13 | Saudi Arabian Oil Company | Development of anti-bit balling fluids |
| US10703957B2 (en) | 2017-02-03 | 2020-07-07 | Saudi Arabian Oil Company | Development of retarded acid system |
| US10392550B2 (en) | 2017-02-03 | 2019-08-27 | Saudi Arabian Oil Company | Spacer fluid compositions, methods, and systems for aqueous based drilling mud removal |
| US10487254B2 (en) | 2017-02-03 | 2019-11-26 | Saudi Arabian Oil Company | Enhanced filtration control packages, wellbore servicing fluids utilizing the same, and methods of maintaining the structure of a wellbore |
| US10494560B2 (en) | 2017-02-03 | 2019-12-03 | Saudi Arabian Oil Company | Development of anti-bit balling fluids |
| US10494559B2 (en) | 2017-02-03 | 2019-12-03 | Saudi Arabian Oil Company | Cement slurries, cured cement and methods of making and use thereof |
| US10526520B2 (en) | 2017-02-03 | 2020-01-07 | Saudi Arabian Oil Company | Anti-bit balling drilling fluids, and methods of making and use thereof |
| US10538692B2 (en) | 2017-02-03 | 2020-01-21 | Saudi Arabian Oil Company | Development of anti-bit balling fluids |
| US10563110B2 (en) | 2017-02-03 | 2020-02-18 | Saudi Arabian Oil Company | Methods of using drilling fluid compositions with enhanced rheology |
| US10570324B2 (en) | 2017-02-03 | 2020-02-25 | Saudi Arabian Oil Company | Emulsifier compositions for invert emulsion fluids and methods of using the same |
| US10590325B2 (en) | 2017-02-03 | 2020-03-17 | Saudi Arabian Oil Company | Spacer fluid compositions that include surfactants |
| US10640695B2 (en) | 2017-02-03 | 2020-05-05 | Saudi Arabian Oil Company | Dispersant in cement formulations for oil and gas wells |
| US10662363B2 (en) | 2017-02-03 | 2020-05-26 | Saudi Arabian Oil Company | Lubricants for water-based drilling fluids |
| US10287477B2 (en) | 2017-02-03 | 2019-05-14 | Saudi Arabian Oil Company | Dispersant in cement formulations for oil and gas wells |
| US10351750B2 (en) | 2017-02-03 | 2019-07-16 | Saudi Arabian Oil Company | Drilling fluid compositions with enhanced rheology and methods of using same |
| US10822534B2 (en) | 2017-02-03 | 2020-11-03 | Saudi Arabian Oil Company | Retarded acid systems, emulsions, and methods for using in acidizing carbonate formations |
| US10844266B2 (en) | 2017-02-03 | 2020-11-24 | Saudi Arabian Oil Company | Spacer fluids and cement slurries that include surfactants |
| US10851281B2 (en) | 2017-02-03 | 2020-12-01 | Saudi Arabian Oil Company | Development of anti-bit balling fluids |
| US10876028B2 (en) | 2017-02-03 | 2020-12-29 | Saudi Arabian Oil Company | Enhanced filtration control packages, wellbore servicing fluids utilizing the same, and methods of maintaining the structure of a wellbore |
| US11365339B2 (en) | 2017-02-03 | 2022-06-21 | Saudi Arabian Oil Company | Development of retarded acid system |
| US10961426B2 (en) | 2017-02-03 | 2021-03-30 | Saudi Arabian Oil Company | Development of anti-bit balling fluids |
| US11034875B2 (en) | 2017-02-03 | 2021-06-15 | Saudi Arabian Oil Company | Enhanced filtration control packages, wellbore servicing fluids utilizing the same, and methods of maintaining the structure of a wellbore |
| US11078397B2 (en) | 2017-02-03 | 2021-08-03 | Saudi Arabian Oil Company | Spacer fluid compositions, methods, and systems for aqueous based drilling mud removal |
| US11078396B2 (en) | 2017-02-03 | 2021-08-03 | Saudi Arabian Oil Company | Spacer fluid compositions, methods, and systems for aqueous based drilling mud removal |
| US11098231B2 (en) | 2017-02-03 | 2021-08-24 | Saudi Arabian Oil Company | Spacer fluid compositions that include surfactants |
| US11098232B2 (en) | 2017-02-03 | 2021-08-24 | Saudi Arabian Oil Company | Lubricants for water-based drilling fluids |
| US11248157B2 (en) | 2017-02-03 | 2022-02-15 | Saudi Arabian Oil Company | Emulsifier compositions for invert emulsion fluids and methods of using the same |
| CN112276141A (en) * | 2020-09-04 | 2021-01-29 | 广州锻造一厂股份有限公司 | Deep hole machining method for large-sized forged part |
| CN115161093A (en) * | 2022-07-12 | 2022-10-11 | 深圳市爱康泉水处理服务有限公司 | Composition for cutting fluid conditioner, cutting fluid conditioner and application of cutting fluid conditioner |
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| CN103351925B (en) | 2015-07-01 |
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Effective date of registration: 20191223 Address after: 246500 No.27 Xingye Road, Susong Economic Development Zone, Anqing City, Anhui Province Patentee after: ANHUI ZHONG TIAN PETROCHEMICAL CO., LTD. Address before: Dragon Tianchang 239300 Anhui city of Chuzhou province Ji Xiang Yi Dragon Street Patentee before: Tianchang Runda Metal Antirust Auxiliaries Co., Ltd. |
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