CN103351679A - Heat retaining thermal insulation type exterior wall coating and preparation method thereof - Google Patents
Heat retaining thermal insulation type exterior wall coating and preparation method thereof Download PDFInfo
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- CN103351679A CN103351679A CN2013102466726A CN201310246672A CN103351679A CN 103351679 A CN103351679 A CN 103351679A CN 2013102466726 A CN2013102466726 A CN 2013102466726A CN 201310246672 A CN201310246672 A CN 201310246672A CN 103351679 A CN103351679 A CN 103351679A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 28
- 238000000576 coating method Methods 0.000 title claims abstract description 28
- 238000009413 insulation Methods 0.000 title claims description 16
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 7
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000919 ceramic Substances 0.000 claims abstract description 4
- 239000000835 fiber Substances 0.000 claims abstract description 4
- 239000011521 glass Substances 0.000 claims abstract description 4
- -1 polyoxypropylene glycerol Polymers 0.000 claims abstract description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 13
- 238000004581 coalescence Methods 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 229920004890 Triton X-100 Polymers 0.000 claims description 6
- 239000013504 Triton X-100 Substances 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- OGSPWJRAVKPPFI-UHFFFAOYSA-N Alendronic Acid Chemical compound NCCCC(O)(P(O)(O)=O)P(O)(O)=O OGSPWJRAVKPPFI-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004113 Sepiolite Substances 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- 229940062527 alendronate Drugs 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- 229910052624 sepiolite Inorganic materials 0.000 claims description 3
- 235000019355 sepiolite Nutrition 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 238000005336 cracking Methods 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 239000000378 calcium silicate Substances 0.000 abstract 1
- 229910052918 calcium silicate Inorganic materials 0.000 abstract 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 abstract 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 239000004005 microsphere Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 238000005201 scrubbing Methods 0.000 abstract 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 5
- 238000005034 decoration Methods 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to an exterior wall coating, which is composed of the following raw materials in parts by weight: 76-86 parts of water-based acrylic emulsion, 12-20 parts of styrene-acrylic emulsion, 15-50 parts of ceramic fibers, 1-2 parts of calcium silicate, 3-4 parts of hollow glass microspheres, 0.6-1 part of aluminium oxide, 0.8-1 part of N-(beta-aminoethyl)-gamma-aminopropyltrimethoxysilane, 0.7-1 part of hydroxyethyl cellulose, 2-4 parts of ethyl acrylate, 0.4-0.6 part of polyethylene glycol octylphenol ether, 0.1-0.2 part of polyoxypropylene glycerol ether, 0.2-0.3 part of dibenzoyl peroxide, 3-5 parts of coalescing agent and 10-30 parts of deionized water. The coating provided by the invention has low raw material loss, low gel production, simple process, hard coating film, good glossiness, strong impact resistance, low cracking rate, soft texture, high decorative property, high weather resistance, excellent scrubbing resistance, strong adhesion, long service life, no special smell, no heavy metals such as mercury and lead, and no formaldehyde volatile matter; and therefore, the exterior wall coating meets the technical requirements of an environment-friendly coating.
Description
Technical field
The present invention relates generally to a kind of coating, relates in particular to a kind of thermal-insulation exterior coating and preparation method thereof.
Background technology
In recent years; along with the raising of living standards of the people and the development of society; people are to the selection pay attention to day by day of building decoration coating, and are more simple better to the construction requirement of coating, for particularly in exterior coating; not only rest in the most basic protection to ground; decorative effect to coating is had higher requirement, and exterior coating requires to have water repelling property, requires to have from washing property; it is hard and smooth, dirty once rushing that paint film is wanted.
But the acrylic coating of throwing on the domestic market exists, and gloss is low, poor adhesive force, winter hardiness are poor, not water-fast, water vapour, soda acid, salts solution and organic polar solvent, poor flexibility under the room temperature, the shortcoming such as wear no resistance, and high temperature easily returns sticking, fragile under low temperature splitting, cause coating to ftracture easily, peel off, rainwater etc. infiltrate metope, corrosion body of wall easily, and this not only affects the beautiful decoration of buildings, and will reduce the work-ing life of buildings.
Summary of the invention
The object of the invention is exactly in order to remedy the defective of prior art, exterior coating that a kind of paint film is stable, glossiness is good, tolerance is strong and preparation method thereof to be provided.
The present invention is achieved by the following technical solutions:
A kind of thermal-insulation exterior coating, it is comprised of the raw material of following weight parts:
Aqueous acrylic emulsion 76-86, benzene emulsion 12-20, ceramic fiber 15-50, Calucium Silicate powder 1-2, hollow glass micropearl 3-4, aluminum oxide 0.6-1, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane 0.8-1, Natvosol 0.7-1, ethyl propenoate 2-4, Triton X-100 0.4-0.6, polypropylene glycerol aether 0.1-0.2, dibenzoyl peroxide 0.2-0.3, film coalescence aid 3-5, deionized water 10-30;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 30-40, polyvinyl alcohol 4-6, vinyltriethoxysilane 6-10, alkylphenol Polyoxyalkylene ethers 0.8-1, benzene emulsion 3-4, nano-sized carbon 1-2;
Polyvinyl alcohol is joined in the 4-5 times of water, be steam heated to 95-100 ℃, stirring and dissolving adds benzene emulsion, and reducing temperature is 60-70 ℃, constant temperature stirred 3-4 minute, add each raw material of residue, low speed 300-400 rev/min was disperseed 2-3 minute, and 100-120 ℃ of insulation left standstill 1-2 hour, be cooled to normal temperature, namely get described film coalescence aid.
A kind of preparation method of thermal-insulation exterior coating may further comprise the steps:
Above-mentioned weight part is heated to 72-80 ℃ as protection under the gas at nitrogen with above-mentioned Triton X-100, add ethyl propenoate, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, fully stir, continue the rising temperature to 85-90 ℃, add dibenzoyl peroxide, stirred rear insulation reaction 30-40 minute, add benzene emulsion, be cooled to normal temperature, 500-600 rev/min was stirred 6-8 minute; Add aqueous acrylic emulsion, deionized water, 900-1000 rev/min was stirred 8-10 minute; Add again nanometer sepiolite powder, ethylenediamine tetramethylene fork Alendronate, stirred 15-20 minute at 700-800 rev/min; Add each raw material of residue, under 600-700 rev/min speed, fully stir, add acetic acid or sodium acetate, adjusting PH is 8-9, stirs to be described exterior coating.
Advantage of the present invention is:
The coating raw material loss that the present invention produces is few, gel generates few, technique is simple, paint film is hard, glossiness is good, anti-impact force is strong, be not easy cracking, texture is soft, ornamental strong, high weather resisteant is arranged, brushing resistance, strong adhesion, long service life, without special odor, not mercurous, the plumbous heavy metal that waits, formaldehydeless volatile matter, meet the technical requirements of environmental protection coating material, the film coalescence aid of adding has very high stability, efficient binding property, film-forming properties has increased the density of coated membrane, improved quality of forming film, so that rete has strong adhesion, without the cavity, split sunken, the fine and close advantage such as even.
Embodiment
Embodiment 1
A kind of thermal-insulation exterior coating, it is comprised of the raw material of following weight parts (kilogram):
Aqueous acrylic emulsion 86, benzene emulsion 20, ceramic fiber 50, Calucium Silicate powder 1, hollow glass micropearl 4, aluminum oxide 0.6, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane 0.8, Natvosol 0.7, ethyl propenoate 2, Triton X-100 0.6, polypropylene glycerol aether 0.2, dibenzoyl peroxide 0.3, film coalescence aid 5, deionized water 30;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 40, polyvinyl alcohol 6, vinyltriethoxysilane 10, alkylphenol Polyoxyalkylene ethers 0.8, benzene emulsion 4, nano-sized carbon 2;
Polyvinyl alcohol is joined in 4 times of water, be steam heated to 100 ℃, stirring and dissolving adds benzene emulsion, reducing temperature is 70 ℃, and constant temperature stirred 4 minutes, adds each raw material of residue, 400 rev/mins of dispersions of low speed 2 minutes, 120 ℃ of insulations were left standstill 2 hours, were cooled to normal temperature, namely got described film coalescence aid.
A kind of preparation method of thermal-insulation exterior coating may further comprise the steps:
Above-mentioned weight part is heated to 80 ℃ as protection under the gas at nitrogen with above-mentioned Triton X-100, add ethyl propenoate, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, fully stir, continue rising temperature to 90 ℃, add dibenzoyl peroxide, insulation reaction is 40 minutes after stirring, and adds benzene emulsion, be cooled to normal temperature, 600 rev/mins were stirred 8 minutes; Add aqueous acrylic emulsion, deionized water, 1000 rev/mins were stirred 10 minutes; Add again nanometer sepiolite powder, ethylenediamine tetramethylene fork Alendronate, stirred 20 minutes at 800 rev/mins; Add each raw material of residue, under 700 rev/mins speed, fully stir, add acetic acid or sodium acetate, regulating PH is 9, and stirring is described exterior coating.
Performance test:
Paint film appearance is full, smooth, good without lump, glossiness;
The thermal-insulation test: pass through for 10000 times, paint film is without breakage;
The artificial ageing resistance test: 2000 hours non-foaming, do not peel off, flawless;
Temperature-change resistance (5 circulations): without unusual;
Alkali resistance: 200 hours without unusual.
Claims (2)
1. thermal-insulation exterior coating is characterized in that what it was comprised of the raw material of following weight parts:
Aqueous acrylic emulsion 76-86, benzene emulsion 12-20, ceramic fiber 15-50, Calucium Silicate powder 1-2, hollow glass micropearl 3-4, aluminum oxide 0.6-1, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane 0.8-1, Natvosol 0.7-1, ethyl propenoate 2-4, Triton X-100 0.4-0.6, polypropylene glycerol aether 0.1-0.2, dibenzoyl peroxide 0.2-0.3, film coalescence aid 3-5, deionized water 10-30;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 30-40, polyvinyl alcohol 4-6, vinyltriethoxysilane 6-10, alkylphenol Polyoxyalkylene ethers 0.8-1, benzene emulsion 3-4, nano-sized carbon 1-2;
Polyvinyl alcohol is joined in the 4-5 times of water, be steam heated to 95-100 ℃, stirring and dissolving adds benzene emulsion, and reducing temperature is 60-70 ℃, constant temperature stirred 3-4 minute, add each raw material of residue, low speed 300-400 rev/min was disperseed 2-3 minute, and 100-120 ℃ of insulation left standstill 1-2 hour, be cooled to normal temperature, namely get described film coalescence aid.
2. the preparation method of a thermal-insulation exterior coating as claimed in claim 1 is characterized in that may further comprise the steps:
Above-mentioned weight part is heated to 72-80 ℃ as protection under the gas at nitrogen with above-mentioned Triton X-100, add ethyl propenoate, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, fully stir, continue the rising temperature to 85-90 ℃, add dibenzoyl peroxide, stirred rear insulation reaction 30-40 minute, add benzene emulsion, be cooled to normal temperature, 500-600 rev/min was stirred 6-8 minute; Add aqueous acrylic emulsion, deionized water, 900-1000 rev/min was stirred 8-10 minute; Add again nanometer sepiolite powder, ethylenediamine tetramethylene fork Alendronate, stirred 15-20 minute at 700-800 rev/min; Add each raw material of residue, under 600-700 rev/min speed, fully stir, add acetic acid or sodium acetate, adjusting PH is 8-9, stirs to be described exterior coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310246672.6A CN103351679B (en) | 2013-06-20 | 2013-06-20 | A kind of thermal-insulation exterior coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310246672.6A CN103351679B (en) | 2013-06-20 | 2013-06-20 | A kind of thermal-insulation exterior coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103351679A true CN103351679A (en) | 2013-10-16 |
| CN103351679B CN103351679B (en) | 2016-02-03 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310246672.6A Active CN103351679B (en) | 2013-06-20 | 2013-06-20 | A kind of thermal-insulation exterior coating and preparation method thereof |
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| Country | Link |
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| CN (1) | CN103351679B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046144A (en) * | 2014-05-23 | 2014-09-17 | 李世跃 | Odorless latex paint |
| CN104086089A (en) * | 2014-06-16 | 2014-10-08 | 北京市建筑工程研究院有限责任公司 | Glazed hollow bead hydrophobic agent, preparation method of hydrophobic agent, modified glazed hollow bead and preparation method of modified glazed hollow bead |
| CN104312335A (en) * | 2014-11-04 | 2015-01-28 | 侨健新能源科技（苏州）有限公司 | Thermal insulation coating with high adhesive force and impact resistance |
| CN107189596A (en) * | 2017-08-02 | 2017-09-22 | 合肥广民建材有限公司 | A kind of heat-preservation building paint containing nanoparticle and preparation method thereof |
| CN109054521A (en) * | 2018-06-25 | 2018-12-21 | 滁州麦斯特新型建材有限公司 | A kind of exterior coating and preparation method thereof with moisture-proof role |
| CZ308497B6 (en) * | 2019-07-07 | 2020-09-23 | First Point a.s. | Mixture for thermal insulation plaster |
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2013
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046144A (en) * | 2014-05-23 | 2014-09-17 | 李世跃 | Odorless latex paint |
| CN104046144B (en) * | 2014-05-23 | 2016-06-15 | 李世跃 | A kind of clean taste emulsion paint |
| CN104086089A (en) * | 2014-06-16 | 2014-10-08 | 北京市建筑工程研究院有限责任公司 | Glazed hollow bead hydrophobic agent, preparation method of hydrophobic agent, modified glazed hollow bead and preparation method of modified glazed hollow bead |
| CN104312335A (en) * | 2014-11-04 | 2015-01-28 | 侨健新能源科技（苏州）有限公司 | Thermal insulation coating with high adhesive force and impact resistance |
| CN107189596A (en) * | 2017-08-02 | 2017-09-22 | 合肥广民建材有限公司 | A kind of heat-preservation building paint containing nanoparticle and preparation method thereof |
| CN109054521A (en) * | 2018-06-25 | 2018-12-21 | 滁州麦斯特新型建材有限公司 | A kind of exterior coating and preparation method thereof with moisture-proof role |
| CZ308497B6 (en) * | 2019-07-07 | 2020-09-23 | First Point a.s. | Mixture for thermal insulation plaster |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103351679B (en) | 2016-02-03 |
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Denomination of invention: A thermal insulation type exterior wall coating and its preparation method Effective date of registration: 20231026 Granted publication date: 20160203 Pledgee: Lai An county Jinan financing Company limited by guarantee Pledgor: CHUZHOU BEST NEW BUILDING MATERIAL CO.,LTD. Registration number: Y2023980062875 |