CN103342919A - Gravure aqueous suede printing ink - Google Patents
Gravure aqueous suede printing ink Download PDFInfo
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- CN103342919A CN103342919A CN2013102789224A CN201310278922A CN103342919A CN 103342919 A CN103342919 A CN 103342919A CN 2013102789224 A CN2013102789224 A CN 2013102789224A CN 201310278922 A CN201310278922 A CN 201310278922A CN 103342919 A CN103342919 A CN 103342919A
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- printing ink
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- organic silicon
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- suede
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Abstract
The invention relates to printing ink, and in particular relates to gravure aqueous suede printing ink. The printing ink is characterized by comprising the following components in percentage by weight: 78-82% of an aqueous polyurethane elastomer, 5-9% of hydrophilic aliphatic polyisocyanate, 0.5-4.5% of propylene glycol monomethyl ether, 0.3-0.7% of an aqueous organic silicon flatting agent, 0.1-0.5% of an aqueous organic silicon defoamer, 0.5-4.5% of gas phase carbon dioxide, 1-5% of organic extinction powder and 3-7% of water. The printing ink provided by the invention is the gravure aqueous suede printing ink which can simulate lint effect and is dual-component aqueous printing ink. The printing ink after film formation is not only flexible in suede texture and excellent in decorativeness, but also has the advantages of good flexibility, environment-friendliness, smoothness, wear resistance and the like.
Description
Technical field
The present invention relates to a kind of printing ink, be specially a kind of gravure waterborne suede printing ink.
Background technology
At the cigarette-brand print field, gravure printing mainly is for the specially printing of Se Semo, and the printing effect that some are special all is that mode by silk screen printing realizes as imitative metal etch, frost flower, woven design etc.Along with country is more and more higher to the requirement of the cigarette package feature of environmental protection, the residual requirement that has been difficult to satisfy the product feature of environmental protection of the volatile organic compounds of silk-screen printing-ink, therefore, develop a kind of gravure ink with special-effect, particularly gravure water color ink and become an important means that improves enterprise self competitive power.
Summary of the invention
At problems of the prior art, the object of the present invention is to provide a kind of technical scheme of gravure waterborne suede printing ink.
Described a kind of gravure waterborne suede printing ink, it is characterized in that: the weight percent of each component that printing ink comprises is: aqueous polyurethane elastic body 78%～82%, hydrophilic aliphatic polymeric isocyanate 5%～9%, propylene glycol monomethyl ether 0.5%～4.5%, waterborne organic silicon flow agent 0.3%～0.7%, waterborne organic silicon defoamer 0.1%～0.5%, aerosil 0.5%～4.5%, organic quenching powder 1%～5%, water 3%～7%.
Described a kind of gravure waterborne suede printing ink, the weight percent that it is characterized in that each component that described printing ink comprises is: aqueous polyurethane elastic body 79%～81%, hydrophilic aliphatic polymeric isocyanate 6%～8%, propylene glycol monomethyl ether 1%～3%, waterborne organic silicon flow agent 0.4%～0.6%, waterborne organic silicon defoamer 0.2%～0.4%, aerosil 1%～3%, organic quenching powder 1.7%～3.4%, water 4%～6.2%.
Described a kind of gravure waterborne suede printing ink, the weight percent that it is characterized in that each component that described printing ink comprises is: aqueous polyurethane elastic body 80%, hydrophilic aliphatic polymeric isocyanate 7.2%, propylene glycol monomethyl ether 2%, waterborne organic silicon flow agent 0.5%, waterborne organic silicon defoamer 0.3%, aerosil 2%, organic quenching powder 3%, water 5%.
Described a kind of gravure waterborne suede printing ink, it is characterized in that described ink formulation flow process is as follows: proportionally be equipped with raw material, earlier with the aqueous polyurethane elastic precursor emulsion, propylene glycol monomethyl ether mixes, stir, then itself and waterborne organic silicon flow agent and waterborne organic silicon defoamer are mixed in proportion, the use high speed dispersor stirs with 800-1000 rev/min rotating speed, mix, add aerosil afterwards again, the organic quenching powder stirs, and adds water afterwards again, hydrophilic aliphatic polymeric isocyanate, stir, filter with 120 purpose screen cloths, then check, packing namely makes this gravure waterborne suede printing ink.
The present invention is a kind of gravure water-based printing ink that can imitate out the flannelette effect, it is the water color ink of a kind of pair of component, not only have the soft texture of matte after the film forming, ornamental splendid, but also have good flexible, the feature of environmental protection, smooth degree, rub resistance etc.
Printing ink of the present invention has feel and the texture of flannelette concurrently, satisfied the imagination that design field all the time wants to embody at the cigarette-brand printing flannelette effect, simulated the texture of the soft frosted of flannelette in the papery packing by printing means; And because what use is the aqueous polyurethane elastic precursor emulsion in this printing ink, reduced the internal stress when solidifying, made to have high snappiness after the ink setting film forming, and can well embody visual impression and the feel of flannelette; And the adding of hydrophilic aliphatic polymeric isocyanate has remedied China ink layer after one-component system (aqueous polyurethane elastic precursor emulsion) the printing ink film forming not damage resistant, the deficiency of printability such as anti-xanthochromia not, make printing ink of the present invention namely have the feature of environmental protection of water color ink, snappiness, have the rub resistance of UV printing ink, the advantage of anti-xanthochromia again, make this printing ink be fit to large-scale production and application.The more craft feature of product and cultural connotation are given in the use of printing ink of the present invention.
Embodiment
The weight percent of each component that printing ink of the present invention comprises is: aqueous polyurethane elastic body 78%～82%, hydrophilic aliphatic polymeric isocyanate 5%～9%, propylene glycol monomethyl ether 0.5%～4.5%, waterborne organic silicon flow agent 0.3%～0.7%, waterborne organic silicon defoamer 0.1%～0.5%, aerosil 0.5%～4.5%, organic quenching powder 1%～5%, water 3%～7%.
As preferably, the weight percent of each component that printing ink of the present invention comprises is: aqueous polyurethane elastic body 79%～81%, hydrophilic aliphatic polymeric isocyanate 6%～8%, propylene glycol monomethyl ether 1%～3%, waterborne organic silicon flow agent 0.4%～0.6%, waterborne organic silicon defoamer 0.2%～0.4%, aerosil 1%～3%, organic quenching powder 1.7%～3.4%, water 4%～6.2%.
As preferably, the weight percent of each component that printing ink of the present invention comprises is: aqueous polyurethane elastic body 80%, hydrophilic aliphatic polymeric isocyanate 7.2%, propylene glycol monomethyl ether 2%, waterborne organic silicon flow agent 0.5%, waterborne organic silicon defoamer 0.3%, aerosil 2%, organic quenching powder 3%, water 5%.
In the above-mentioned printing ink, aqueous polyurethane elastic body (mixture, BAYHYDROL UV XP 2649) as the aqueous high molecular emulsion in the printing ink composition, be very crucial composition material, not only have the function of low-melting ink vehicle, also can make the shrinking percentage of printing ink when drying low, thereby at stock good adhesive is arranged, and have fabulous snappiness after the ink setting film forming, best matte feel and vision texture have cigarette package concurrently to the performance of aspects such as China ink layer rub resistance, smooth degree; This resin can be buied in market, and manufacturer is Bayer Material Science (China) company limited.
Hydrophilic aliphatic polymeric isocyanate (BAYHYDUR 305) is the solidifying agent during printing ink is formed, it can react at a certain temperature with the aqueous polyurethane elastic precursor emulsion, thereby increased the cross-linking density of high-polymer molecular chain, make polyurethane film also have fine wear resistance having an excellent flexible while, thereby the main purpose of adding hydrophilic aliphatic polymeric isocyanate is to guarantee the China ink flexible while of layer, further strengthen the rub resistance of China ink layer, bright degree, relevant printability such as yellowing resistance, make the performance of this aqueous double-component printing ink between water color ink and UV printing ink, this resin can be buied in market, and manufacturer is Bayer Material Science (China) company limited.
Film coalescence aid during propylene glycol monomethyl ether (molecular formula CH3CHOHCH2OCH3) is formed as printing ink, main effect is plastic flow and the recoverable deformation that promotes the aqueous polyurethane elastic precursor emulsion, improve coalescent performance, can be in wider temperature range film forming, vapor away voluntarily after the film forming, can not influence the performance of China ink layer, and environmental-protecting performance is superior, can directly buy on market, manufacturer is Sanmu Group Co., Ltd., Jiangsu.
Waterborne organic silicon flow agent (Bayer DC51) can reduce frictional coefficient, anti as a kind of auxiliary agent, improve wear resistance, extraordinary feel is provided, do not influence coating film gloss and transparency, can directly buy on market, manufacturer is Dow corning company.
Waterborne organic silicon defoamer (DOW CORNING DC65) also is a kind of auxiliary agent, mainly plays froth breaking, can also strengthen levelling property, wettability, the wear-resisting and sliding property of printing ink, and and printing ink in each component compatibility good.Can on market, directly buy.Manufacturer is Dow corning company.
Flatting silica during aerosil (TS100) is formed as printing ink, main effect is that extinction effect is fabulous, and is little to the transparency influence of printing ink, also can increase flowability and the storage endurance of printing ink.Can on market, directly buy.Manufacturer is Degussa.
Another flatting silica during organic quenching powder (PERGOPAK M5) is formed as printing ink, it mainly acts on is the flatting efficiency height, has good weathering resistance, rheology impact to printing ink is little, and can improve damage resistant, and improve sticking power and elasticity, increase matte feel and the texture of printing ink.Can on market, directly buy.Sky, manufacturer Beijing perseverance is built development in science and technology company limited.
Solvent during water is formed as printing ink mainly plays the effect of dilution.
Above-mentioned printing ink can adopt following method to make: proportionally be equipped with raw material; earlier with the aqueous polyurethane elastic precursor emulsion; propylene glycol monomethyl ether mixes; stir; then itself and waterborne organic silicon flow agent and waterborne organic silicon defoamer are mixed in proportion; use high speed dispersor (Shanghai chemical industry one factory; unit type F-250) middling speed stirs (rotating speed 800-1000 rev/min); mix; add aerosil afterwards again; the organic quenching powder; stir; add water again afterwards; hydrophilic aliphatic polymeric isocyanate; stir (20 minutes time); filter with screen cloth (120 order), then check; packing namely makes this gravure waterborne suede printing ink.
Embodiment 1
Be equipped with following raw material earlier: aqueous polyurethane elastic body 800g, hydrophilic aliphatic polymeric isocyanate 72g, propylene glycol monomethyl ether 20g, waterborne organic silicon flow agent 5g, waterborne organic silicon defoamer 3g, aerosil 20g, organic quenching powder 30g, water 50g;
Preparation process: earlier aqueous polyurethane elastic precursor emulsion, propylene glycol monomethyl ether are mixed, stir; Then itself and waterborne organic silicon flow agent and waterborne organic silicon defoamer are mixed in proportion, use high speed dispersor (Shanghai chemical industry one factory, unit type F-250) middling speed stirs (rotating speed 800-1000 rev/min), mix, add aerosil, organic quenching powder afterwards again, stir, add water again afterwards, hydrophilic aliphatic polymeric isocyanate, stir (20 minutes time), filter with screen cloth (120 order), check then, pack, namely make 1000 these gravure waterborne suede printing ink of gram;
Be equipped with printing ink according to aforementioned proportion during batch process.
Embodiment 2
Be equipped with following raw material earlier: aqueous polyurethane elastic body 780g, hydrophilic aliphatic polymeric isocyanate 90g, propylene glycol monomethyl ether 30g, waterborne organic silicon flow agent 7g, waterborne organic silicon defoamer 1g, aerosil 45g, organic quenching powder 17g, water 30g;
Preparation process such as embodiment 1 are equipped with printing ink according to aforementioned proportion during batch process.
Embodiment 3
Be equipped with following raw material earlier: aqueous polyurethane elastic body 820g, hydrophilic aliphatic polymeric isocyanate 50g, propylene glycol monomethyl ether 5g, waterborne organic silicon flow agent 3g, waterborne organic silicon defoamer 5g, aerosil 5g, organic quenching powder 50g, water 62g;
Preparation process such as embodiment 1 are equipped with printing ink according to aforementioned proportion during batch process.
Embodiment 4
Be equipped with following raw material earlier: aqueous polyurethane elastic body 790g, hydrophilic aliphatic polymeric isocyanate 80g, propylene glycol monomethyl ether 10g, waterborne organic silicon flow agent 4g, waterborne organic silicon defoamer 2g, aerosil 10g, organic quenching powder 34g, water 70g;
Preparation process such as embodiment 1 are equipped with printing ink according to aforementioned proportion during batch process.
Embodiment 5
Be equipped with following raw material earlier: aqueous polyurethane elastic body 805g, hydrophilic aliphatic polymeric isocyanate 60g, propylene glycol monomethyl ether 45g, waterborne organic silicon flow agent 6g, waterborne organic silicon defoamer 4g, aerosil 30g, organic quenching powder 10g, water 40g;
Preparation process such as embodiment 1 are equipped with printing ink according to aforementioned proportion during batch process.
Embodiment 6
Be equipped with following raw material earlier: aqueous polyurethane elastic body 810g, hydrophilic aliphatic polymeric isocyanate 70g, propylene glycol monomethyl ether 15g, waterborne organic silicon flow agent 5.3g, waterborne organic silicon defoamer 2.6g, aerosil 17g, organic quenching powder 20g, water 60.1g;
Preparation process such as embodiment 1 are equipped with printing ink according to aforementioned proportion during batch process.
Claims (4)
1. gravure waterborne suede printing ink, it is characterized in that: the weight percent of each component that printing ink comprises is: aqueous polyurethane elastic body 78%～82%, hydrophilic aliphatic polymeric isocyanate 5%～9%, propylene glycol monomethyl ether 0.5%～4.5%, waterborne organic silicon flow agent 0.3%～0.7%, waterborne organic silicon defoamer 0.1%～0.5%, aerosil 0.5%～4.5%, organic quenching powder 1%～5%, water 3%～7%.
2. a kind of gravure waterborne suede printing ink according to claim 1, the weight percent that it is characterized in that each component that described printing ink comprises is: aqueous polyurethane elastic body 79%～81%, hydrophilic aliphatic polymeric isocyanate 6%～8%, propylene glycol monomethyl ether 1%～3%, waterborne organic silicon flow agent 0.4%～0.6%, waterborne organic silicon defoamer 0.2%～0.4%, aerosil 1%～3%, organic quenching powder 1.7%～3.4%, water 4%～6.2%.
3. a kind of gravure waterborne suede printing ink according to claim 1, the weight percent that it is characterized in that each component that described printing ink comprises is: aqueous polyurethane elastic body 80%, hydrophilic aliphatic polymeric isocyanate 7.2%, propylene glycol monomethyl ether 2%, waterborne organic silicon flow agent 0.5%, waterborne organic silicon defoamer 0.3%, aerosil 2%, organic quenching powder 3%, water 5%.
4. according to claim 1 or 2 or 3 described a kind of gravure waterborne suede printing ink, it is characterized in that described ink formulation flow process is as follows: proportionally be equipped with raw material, earlier with the aqueous polyurethane elastic precursor emulsion, propylene glycol monomethyl ether mixes, stir, then itself and waterborne organic silicon flow agent and waterborne organic silicon defoamer are mixed in proportion, the use high speed dispersor stirs with 800-1000 rev/min rotating speed, mix, add aerosil afterwards again, the organic quenching powder, stir, add water again afterwards, hydrophilic aliphatic polymeric isocyanate, stir, filter with 120 purpose screen cloths, then check, packing namely makes this gravure waterborne suede printing ink.
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| CN201310278922.4A CN103342919B (en) | 2013-07-04 | 2013-07-04 | Gravure aqueous suede printing ink |
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| CN201310278922.4A CN103342919B (en) | 2013-07-04 | 2013-07-04 | Gravure aqueous suede printing ink |
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| CN103342919A true CN103342919A (en) | 2013-10-09 |
| CN103342919B CN103342919B (en) | 2014-10-08 |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614002A (en) * | 2013-12-05 | 2014-03-05 | 湖南互力达涂料科技有限公司 | Waterborne UV (ultraviolet) gravure ink |
| CN103818130A (en) * | 2014-02-13 | 2014-05-28 | 上海烟草包装印刷有限公司 | Method and device for making matte of paper packaging box |
| CN103911043A (en) * | 2014-04-25 | 2014-07-09 | 湖北中信京华彩印股份有限公司 | Water-borne silk-screen suede printing ink and preparation method thereof |
| CN104497703A (en) * | 2015-01-16 | 2015-04-08 | 烟台市红星彩印有限公司 | Water-based ink printing method |
| CN109233430A (en) * | 2018-10-24 | 2019-01-18 | 安徽金泽包装材料有限公司 | The preparation method of low gloss printing ink for cardboard |
| CN109371761A (en) * | 2018-10-17 | 2019-02-22 | 江苏大亚新型包装材料有限公司 | A kind of production technology of the wrapping paper with soft sense of touch |
| CN110370772A (en) * | 2019-07-12 | 2019-10-25 | 嘉兴市豪能科技股份有限公司 | A kind of antiskid type sense of touch film packing box and its processing technology |
| CN111040509A (en) * | 2020-01-06 | 2020-04-21 | 丁玉玲 | LDP leather-like ink |
| CN112980306A (en) * | 2019-12-16 | 2021-06-18 | 江苏泰格油墨有限公司 | Water-based gravure touch gloss oil and preparation process thereof |
| CN115075027A (en) * | 2017-05-31 | 2022-09-20 | 耐克创新有限合伙公司 | Sublimation printing |
| CN115197605A (en) * | 2022-06-17 | 2022-10-18 | 佛山市儒林化工有限公司 | Printing ink with wrinkle texture effect and preparation method thereof |
| CN115710442A (en) * | 2022-11-07 | 2023-02-24 | 上海烟草集团有限责任公司 | Suede effect printing ink and suede effect finishing process for offset printing on-line of paper packaging box |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614002A (en) * | 2013-12-05 | 2014-03-05 | 湖南互力达涂料科技有限公司 | Waterborne UV (ultraviolet) gravure ink |
| CN103818130A (en) * | 2014-02-13 | 2014-05-28 | 上海烟草包装印刷有限公司 | Method and device for making matte of paper packaging box |
| CN103818130B (en) * | 2014-02-13 | 2018-07-27 | 上海烟草包装印刷有限公司 | A kind of production method and its device of paper package box matte |
| CN103911043A (en) * | 2014-04-25 | 2014-07-09 | 湖北中信京华彩印股份有限公司 | Water-borne silk-screen suede printing ink and preparation method thereof |
| CN103911043B (en) * | 2014-04-25 | 2016-07-06 | 湖北京华彩印有限公司 | A kind of water-soluble silk screen matte ink and preparation technology thereof |
| CN104497703A (en) * | 2015-01-16 | 2015-04-08 | 烟台市红星彩印有限公司 | Water-based ink printing method |
| CN115075027A (en) * | 2017-05-31 | 2022-09-20 | 耐克创新有限合伙公司 | Sublimation printing |
| CN109371761A (en) * | 2018-10-17 | 2019-02-22 | 江苏大亚新型包装材料有限公司 | A kind of production technology of the wrapping paper with soft sense of touch |
| CN109233430A (en) * | 2018-10-24 | 2019-01-18 | 安徽金泽包装材料有限公司 | The preparation method of low gloss printing ink for cardboard |
| CN110370772B (en) * | 2019-07-12 | 2022-03-29 | 嘉兴市豪能科技股份有限公司 | Anti-skid touch film packaging box and processing technology thereof |
| CN110370772A (en) * | 2019-07-12 | 2019-10-25 | 嘉兴市豪能科技股份有限公司 | A kind of antiskid type sense of touch film packing box and its processing technology |
| CN112980306A (en) * | 2019-12-16 | 2021-06-18 | 江苏泰格油墨有限公司 | Water-based gravure touch gloss oil and preparation process thereof |
| CN111040509A (en) * | 2020-01-06 | 2020-04-21 | 丁玉玲 | LDP leather-like ink |
| CN115197605A (en) * | 2022-06-17 | 2022-10-18 | 佛山市儒林化工有限公司 | Printing ink with wrinkle texture effect and preparation method thereof |
| CN115710442A (en) * | 2022-11-07 | 2023-02-24 | 上海烟草集团有限责任公司 | Suede effect printing ink and suede effect finishing process for offset printing on-line of paper packaging box |
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Effective date of registration: 20210225 Address after: 310030 No.6, xiyuansan Road, Sandun Town, Xihu District, Hangzhou City, Zhejiang Province Patentee after: ZHEJIANG MINONG CENTURY GROUP Co.,Ltd. Patentee after: ZHEJIANG MINONG MATERIAL TECHNOLOGY Co.,Ltd. Address before: 310030 No.6, xiyuansan Road, Sandun Town, Xihu District, Hangzhou City, Zhejiang Province Patentee before: ZHEJIANG MINONG CENTURY GROUP Co.,Ltd. |