CN103333422A - 一种掺有低硫膨胀石墨的阻燃型可发性聚苯乙烯颗粒及其制备方法 - Google Patents
一种掺有低硫膨胀石墨的阻燃型可发性聚苯乙烯颗粒及其制备方法 Download PDFInfo
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- CN103333422A CN103333422A CN2013100925154A CN201310092515A CN103333422A CN 103333422 A CN103333422 A CN 103333422A CN 2013100925154 A CN2013100925154 A CN 2013100925154A CN 201310092515 A CN201310092515 A CN 201310092515A CN 103333422 A CN103333422 A CN 103333422A
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- expanded graphite
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- expandable polystyrene
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 99
- 229910002804 graphite Inorganic materials 0.000 title claims abstract description 96
- 239000010439 graphite Substances 0.000 title claims abstract description 96
- 229920006248 expandable polystyrene Polymers 0.000 title claims abstract description 48
- 239000003063 flame retardant Substances 0.000 title claims abstract description 37
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 32
- 239000011593 sulfur Substances 0.000 title claims abstract description 32
- 239000002245 particle Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 22
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 22
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 20
- 150000002367 halogens Chemical class 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 18
- 230000008569 process Effects 0.000 claims abstract description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- 238000010557 suspension polymerization reaction Methods 0.000 claims abstract description 8
- 239000011324 bead Substances 0.000 claims abstract description 5
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 claims abstract description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
- 239000005864 Sulphur Substances 0.000 claims description 12
- 239000006229 carbon black Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000004793 Polystyrene Substances 0.000 claims description 7
- 229920002223 polystyrene Polymers 0.000 claims description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- -1 recover to stir Substances 0.000 claims description 3
- 239000001273 butane Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 239000003999 initiator Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000004794 expanded polystyrene Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
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- 230000000052 comparative effect Effects 0.000 description 4
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- 238000005187 foaming Methods 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 3
- 229940024545 aluminum hydroxide Drugs 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229940056729 sodium sulfate anhydrous Drugs 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 235000019731 tricalcium phosphate Nutrition 0.000 description 1
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- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
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CN201310092515.4A CN103333422B (zh) | 2013-03-22 | 2013-03-22 | 一种掺有低硫膨胀石墨的阻燃型可发性聚苯乙烯颗粒及其制备方法 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103788397A (zh) * | 2014-02-19 | 2014-05-14 | 哈尔滨工业大学 | 一种含层离石墨的阻燃可发性聚苯乙烯球粒的制备方法 |
CN104109298A (zh) * | 2014-06-05 | 2014-10-22 | 北京天利合兴保温建材有限责任公司 | 改性挤塑板及其制备方法 |
CN104403217A (zh) * | 2014-09-16 | 2015-03-11 | 北京天利合兴保温建材有限责任公司 | 改性挤塑板原料及改性挤塑板制造方法 |
CN104403218A (zh) * | 2014-09-16 | 2015-03-11 | 北京天利合兴保温建材有限责任公司 | 改性挤塑板及其制造方法 |
CN104403216A (zh) * | 2014-09-16 | 2015-03-11 | 北京天利合兴保温建材有限责任公司 | 改性挤塑板原料及改性挤塑板制造方法 |
CN105295085A (zh) * | 2015-11-26 | 2016-02-03 | 苗鹏 | 一种可发性低导热阻燃聚苯乙烯珠粒的制备方法 |
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CN1269814A (zh) * | 1997-09-29 | 2000-10-11 | 巴斯福股份公司 | 可发泡苯乙烯聚合物的制备方法 |
CN1310740A (zh) * | 1998-07-27 | 2001-08-29 | 巴斯福股份公司 | 含膨胀性石墨粒子的发泡性苯乙烯聚合物的制备工艺 |
CN1329634A (zh) * | 1998-12-09 | 2002-01-02 | 巴斯福股份公司 | 发泡性聚苯乙烯粒子的制备工艺 |
EP1514895A2 (en) * | 2003-06-11 | 2005-03-16 | Synbra Technology B.V. | Activated graphite-containing particulate, expandable polystyrene |
CN101891852A (zh) * | 2009-05-22 | 2010-11-24 | 上海碧虎节能保温材料有限公司 | 聚苯乙烯/膨胀石墨复合发泡材料的制备 |
CN102286753A (zh) * | 2011-05-30 | 2011-12-21 | 黑龙江科技学院 | 一种制备高纯低硫膨胀石墨方法 |
WO2012091381A2 (ko) * | 2010-12-30 | 2012-07-05 | 제일모직 주식회사 | 발포 폴리스티렌계 비드 및 그 제조방법 |
CN102947373A (zh) * | 2010-04-21 | 2013-02-27 | 西博拉技术有限公司 | 颗粒状可发性聚合物、该聚合物的制法及该聚合物的应用 |
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2013
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CN1269814A (zh) * | 1997-09-29 | 2000-10-11 | 巴斯福股份公司 | 可发泡苯乙烯聚合物的制备方法 |
CN1310740A (zh) * | 1998-07-27 | 2001-08-29 | 巴斯福股份公司 | 含膨胀性石墨粒子的发泡性苯乙烯聚合物的制备工艺 |
CN1329634A (zh) * | 1998-12-09 | 2002-01-02 | 巴斯福股份公司 | 发泡性聚苯乙烯粒子的制备工艺 |
EP1514895A2 (en) * | 2003-06-11 | 2005-03-16 | Synbra Technology B.V. | Activated graphite-containing particulate, expandable polystyrene |
CN101891852A (zh) * | 2009-05-22 | 2010-11-24 | 上海碧虎节能保温材料有限公司 | 聚苯乙烯/膨胀石墨复合发泡材料的制备 |
CN102947373A (zh) * | 2010-04-21 | 2013-02-27 | 西博拉技术有限公司 | 颗粒状可发性聚合物、该聚合物的制法及该聚合物的应用 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103788397A (zh) * | 2014-02-19 | 2014-05-14 | 哈尔滨工业大学 | 一种含层离石墨的阻燃可发性聚苯乙烯球粒的制备方法 |
CN104109298A (zh) * | 2014-06-05 | 2014-10-22 | 北京天利合兴保温建材有限责任公司 | 改性挤塑板及其制备方法 |
CN104403217A (zh) * | 2014-09-16 | 2015-03-11 | 北京天利合兴保温建材有限责任公司 | 改性挤塑板原料及改性挤塑板制造方法 |
CN104403218A (zh) * | 2014-09-16 | 2015-03-11 | 北京天利合兴保温建材有限责任公司 | 改性挤塑板及其制造方法 |
CN104403216A (zh) * | 2014-09-16 | 2015-03-11 | 北京天利合兴保温建材有限责任公司 | 改性挤塑板原料及改性挤塑板制造方法 |
CN105295085A (zh) * | 2015-11-26 | 2016-02-03 | 苗鹏 | 一种可发性低导热阻燃聚苯乙烯珠粒的制备方法 |
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