CN103333419B - A kind of neoprene cable protective cover material that contains itaconate - Google Patents

A kind of neoprene cable protective cover material that contains itaconate Download PDF

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CN103333419B
CN103333419B CN201310219474.0A CN201310219474A CN103333419B CN 103333419 B CN103333419 B CN 103333419B CN 201310219474 A CN201310219474 A CN 201310219474A CN 103333419 B CN103333419 B CN 103333419B
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neoprene
itaconate
weight
add
haloflex
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CN103333419A (en
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谷道荣
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Dongying Alumni Internet Technology Co.,Ltd.
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ANHUI RONGJIU OPTICAL FIBER COMMUNICATION Co Ltd
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Abstract

The invention discloses a kind of neoprene cable protective cover material that contains itaconate, it is to be made by the raw material of following weight parts: haloflex 80-90, neoprene 22-25, modified aluminium hydroxide 80-90, white carbon 5-6, triphosphoric acid toluene diphenyl ester 2-4, sulphur 1.5-2.3, silane coupler KH792? 1.2-2.4, coating celestite powder 30-40, ATEC 1-2, chlorinated paraffin wax 5-7, coumarone indene resin 3-6, itaconate 1.3-2.2, antioxidant NBC? 1.5-2.5, crosslinking agent? TAC? 0.5-1, zinc stearate 2-4, calcium oxide 0.4-0.8, zinc oxide 1-2, antioxidant 1076? 0.8-1.2, antioxidant 2246? 0.3-0.5, OPEO 1-2, magnesia 1-2.

Description

A kind of neoprene cable protective cover material that contains itaconate
Technical field
The present invention relates to CABLE MATERIALS field, is exactly a kind of neoprene cable protective cover material that contains itaconate.
Background technology
Cable cover(ing) is the outermost layer of cable, if VV is polyvinyl chloride insulation, pvc sheath, outside wear to being protection tube. Cable sheath material not only needs there is good physical property, as hot strength, elongation at break etc., also needs to have good fire resistance simultaneously.
Summary of the invention
The object of the present invention is to provide a kind of neoprene cable protective cover material that contains itaconate.
Above-mentioned purpose realizes by following scheme:
A neoprene cable protective cover material that contains itaconate, is characterized in that: it is to be made by the raw material of following weight parts:
Haloflex 80-90, neoprene 22-25, modified aluminium hydroxide 80-90, white carbon 5-6, triphosphoric acid toluene diphenyl ester 2-4, sulphur 1.5-2.3, silane coupler KH7921.2-2.4, coating celestite powder 30-40, ATEC 1-2, chlorinated paraffin wax 5-7, coumarone indene resin 3-6, itaconate 1.3-2.2, antioxidant NBC 1.5-2.5, crosslinking agent TAC0.5-1, zinc stearate 2-4, calcium oxide 0.4-0.8, zinc oxide 1-2, antioxidant 1076 0.8-1.2, antioxidant 2246 0.3-0.5, OPEO 1-2, magnesia 1-2;
The preparation method of described coating celestite powder is: celestite powder alcohol carries out ball milling dispersion treatment 5-6 hour, add therein again and be equivalent to the OPEO of its weight 3-5%, the deionized water of 6-8%, agitating heating 25-35 minute in 70-80 DEG C of water bath with thermostatic control, compound liquid, then add in compound liquid the inside and be equivalent to the Al that the concentration of its weight 10-15% is 24-27%2(SO4)3Solution adds proper ammonia to regulate pH value for 8-11 simultaneously, stirs after 30-40min, leaves standstill after 3-4 hour, after filtration, after washing, dry processing, at 500-550 DEG C of sintering 5-7 hour, naturally cool to room temperature and get final product;
The preparation method of described modified aluminium hydroxide is: in aluminium hydroxide, add and be equivalent to the butyl acrylate of its weight 1-2%, the di-2-ethylhexyl maleate of 0.4-0.8%, silane coupling A-151 of 2.8-3.5%, put into and mediate still, temperature is controlled at 60-65 DEG C, stir 2-3h, after dry, after pulverizing and get final product.
Described a kind of neoprene cable protective cover material that contains itaconate, is characterized in that: preparation method comprises the following steps:
(1) neoprene is plasticated at 76-82 DEG C on banbury, the neoprene of plasticating is cooling for subsequent use;
(2) haloflex is plasticated at 70-80 DEG C on banbury, the haloflex of plasticating is cooling for subsequent use;
(3) haloflex that the neoprene of step (1) gained being plasticated is plasticated in step (2) gained is put into banbury by weight, closes refining 8-12 minute at 95-105 DEG C;
(4) add by weight again all the other raw materials, mixing 10-13 minute at 85-95 DEG C;
(5) double screw extruder extruding pelletization, to obtain final product.
Beneficial effect of the present invention is: modified aluminium hydroxide, by composite modified, can improve its addition, increases the flame retardant effect of cable sheath material. Coating celestite powder can increase intensity of the present invention and fire resistance.
Detailed description of the invention
A neoprene cable protective cover material that contains itaconate, it is to be made by the raw material of following weight parts (kg):
Haloflex 87, neoprene 25, modified aluminium hydroxide 80, white carbon 6, triphosphoric acid toluene diphenyl ester 4, sulphur 2.3, silane coupler KH7922.4, coating celestite powder 30, ATEC 2, chlorinated paraffin wax 7, coumarone indene resin 6, itaconate 2.2, antioxidant NBC 2.5, crosslinking agent TAC0.7, zinc stearate 4, calcium oxide 0.8, zinc oxide 2, antioxidant 1076 1.2, antioxidant 2246 0.4, OPEO 2, magnesia 1;
The preparation method of described coating celestite powder is: celestite powder alcohol carries out ball milling dispersion treatment 6 hours, add therein again and be equivalent to the OPEO of its weight 5%, 8% deionized water, agitating heating 30 minutes in 75 DEG C of waters bath with thermostatic control, compound liquid, then add in compound liquid the inside and be equivalent to the Al that the concentration of its weight 12% is 25%2(SO4)3Solution, add proper ammonia to regulate pH value is 9 simultaneously, stirs after 35min, leaves standstill after 4 hours, after filtration, after washing, dry processing, 550 DEG C of sintering 7 hours, naturally cools to room temperature and get final product;
The preparation method of described modified aluminium hydroxide is: in aluminium hydroxide, add and be equivalent to the butyl acrylate of its weight 1%, 0.8% di-2-ethylhexyl maleate, 3.5% silane coupling A-151, put into and mediate still, temperature is controlled at 65 DEG C, stir 3h, dry after, after pulverizing and get final product.
Described a kind of neoprene cable protective cover material that contains itaconate, preparation method comprises the following steps:
(1) neoprene is plasticated at 78 DEG C on banbury, the neoprene of plasticating is cooling for subsequent use;
(2) haloflex is plasticated at 80 DEG C on banbury, the haloflex of plasticating is cooling for subsequent use;
(3) haloflex that the neoprene of step (1) gained being plasticated is plasticated in step (2) gained is put into banbury by weight, closes refining 12 minutes at 95 DEG C;
(4) add by weight again all the other raw materials, at 88 DEG C mixing 13 minutes;
(5) double screw extruder extruding pelletization, to obtain final product.
Test the present embodiment material property, oxygen index (OI) is 48%, and in horizontal vertical combustion testing, horizontal firing reaches FH-1 grade, and vertical combustion reaches FV-0 grade. Hot strength is 14.4MPa, elongation at break > 398%.

Claims (2)

1. a neoprene cable protective cover material that contains itaconate, it is characterized in that: it is to be made by the raw material of following weight parts: haloflex 80-90, neoprene 22-25, modified aluminium hydroxide 80-90, white carbon 5-6, triphosphoric acid toluene diphenyl ester 2-4, sulphur 1.5-2.3, silane coupler KH7921.2-2.4, coating celestite powder 30-40, ATEC 1-2, chlorinated paraffin wax 5-7, coumarone indene resin 3-6, itaconate 1.3-2.2, antioxidant NBC 1.5-2.5, crosslinking agent TAC0.5-1, zinc stearate 2-4, calcium oxide 0.4-0.8, zinc oxide 1-2, antioxidant 1076 0.8-1.2, antioxidant 2246 0.3-0.5, OPEO 1-2, magnesia 1-2, the preparation method of described coating celestite powder is: celestite powder alcohol carries out ball milling dispersion treatment 5-6 hour, add therein again the OPEO that is equivalent to its weight 3-5%, the deionized water of 6-8%, agitating heating 25-35 minute in 70-80 DEG C of water bath with thermostatic control, obtain compound liquid, add in compound liquid the inside again and be equivalent to Al2 (SO4) 3 solution that the concentration of its weight 10-15% is 24-27%, add proper ammonia to regulate pH value for 8-11 simultaneously, stir after 30-40min, leave standstill after 3-4 hour, after filtration, washing, after dry processing, at 500-550 DEG C of sintering 5-7 hour, naturally cool to room temperature and get final product, the preparation method of described modified aluminium hydroxide is: in aluminium hydroxide, add and be equivalent to the butyl acrylate of its weight 1-2%, the di-2-ethylhexyl maleate of 0.4-0.8%, silane coupling A-151 of 2.8-3.5%, put into and mediate still, temperature is controlled at 60-65 DEG C, stir 2-3h, after dry, after pulverizing and get final product.
2. a kind of neoprene cable protective cover material that contains itaconate according to claim 1, is characterized in that: preparation method comprises the following steps:
(1) neoprene is plasticated at 76-82 DEG C on banbury, the neoprene of plasticating is cooling for subsequent use;
(2) haloflex is plasticated at 70-80 DEG C on banbury, the haloflex of plasticating is cooling for subsequent use; (3) haloflex that the neoprene of step (1) gained being plasticated and step (2) gained are plasticated is put into banbury by weight, closes refining 8-12 minute at 95-105 DEG C;
(4) add by weight again all the other raw materials, mixing 10-13 minute at 85-95 DEG C;
(5) double screw extruder extruding pelletization, to obtain final product.
CN201310219474.0A 2013-06-04 2013-06-04 A kind of neoprene cable protective cover material that contains itaconate Active CN103333419B (en)

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103756067A (en) * 2013-12-13 2014-04-30 芜湖金鹰机械科技开发有限公司 Automobile motor wire harness rubber sheath
CN106832621A (en) * 2016-12-30 2017-06-13 安徽远征电缆科技有限公司 A kind of cable fire proofing
CN108384083A (en) * 2018-02-08 2018-08-10 合肥市大卓电力有限责任公司 A kind of flame-retardant electric wire and cable protective materials and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1156493A1 (en) * 2000-05-19 2001-11-21 Sagem Sa Crosslinkable semi-conductive composition and electrical cable with semi-conductive film
CN101613504A (en) * 2009-07-24 2009-12-30 青岛中阳消防科技有限公司 A kind of material and preparation method with temperature sensing cable material of CRT characteristic

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1156493A1 (en) * 2000-05-19 2001-11-21 Sagem Sa Crosslinkable semi-conductive composition and electrical cable with semi-conductive film
CN101613504A (en) * 2009-07-24 2009-12-30 青岛中阳消防科技有限公司 A kind of material and preparation method with temperature sensing cable material of CRT characteristic

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Address after: 243102 Anhui city of Ma'anshan province Dangtu County Economic Development Zone

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Denomination of invention: A chloroprene rubber cable sheath material containing itaconic acid ester

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