CN103319949A - OGS (One Glass Solution) glass protecting ink as well as preparation method and application thereof - Google Patents
OGS (One Glass Solution) glass protecting ink as well as preparation method and application thereof Download PDFInfo
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- CN103319949A CN103319949A CN2013102420737A CN201310242073A CN103319949A CN 103319949 A CN103319949 A CN 103319949A CN 2013102420737 A CN2013102420737 A CN 2013102420737A CN 201310242073 A CN201310242073 A CN 201310242073A CN 103319949 A CN103319949 A CN 103319949A
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- printing ink
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- protection printing
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- Inks, Pencil-Leads, Or Crayons (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Abstract
The invention discloses an OGS (One Glass Solution) glass protecting ink as well as a preparation method and an application thereof. The protecting ink comprises the following components in parts by weight: 6-10 parts of aliphatic polyurethane acrylic ester, 3-5 parts of N-vinyl pyrrolidone, 0.3-0.5 part of 2,4,6-trimethylbenzene formyl-diphenyl phosphine oxide, 1-2 parts of octadecanol, 0.1-0.2 part of an antifoaming agent, 0.1-0.2 part of a flatting agent, 0.3-0.4 part of a plasticizing agent and 1-2 parts of pigment blue. The protecting ink can effectively protect a glass substrate, prevent the erosion of hydrofluoric acids on glass, is mechanical cutting resisting and applicable to production in large scale, and saves the labor and materials.
Description
Technical field
What the present invention relates to is a kind of glass protection printing ink and preparation and application, in particular a kind of OGS glass protection printing ink, its preparation method and application thereof.
Background technology
At present, the OGS glass protection mainly contains three kinds of modes: a kind of a kind of is to paste the protection film in order to paste peelable glue, and another kind is printing protection printing ink.Although paste the superior performance of mode glass hydrofluoric acid resistant behind secondary hardening of peelable glue, be not suitable for large stretch of produce and in CNC finishing impression process the edge can play the limit, need every a slice tear-off to remove inefficiency.It is cheap that the mode of subsides protection film is made simple consumptive material, but face equally the problem of inefficiency.The mode of printing protection printing ink is optimum so far protected mode, is applicable to scale of mass production, protects effective.Protection ink performance in the market is immature, and the hydrofluoric acid resistant performance is poor, is difficult for moving back film, cleans difficulty, in high volume production process, can consume the production time in a large number, and increase the human and material resources cost.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of OGS protection printing ink, its preparation method and application thereof are provided.
The invention discloses a kind of OGS glass protection printing ink, by weight, comprise following component:
Wherein, the molecular-weight average of described stearyl alcohol is 6000, and described defoamer is organic silicon modified by polyether oxygen alkane.Described flow agent is fluorine-carbon modified polyacrylic ester.Described softening agent is phthalic ester.
The present invention discloses the preparation method of this OGS glass protection printing ink, may further comprise the steps:
(1) aliphatic urethane acrylate and NVP are stirred in proportion;
(2) 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide, stearyl alcohol, defoamer, flow agent, softening agent are poured in order successively in the mixture of step (1) and stirred;
(3) phthalocyanine blue is poured in the mixture of step (2) and stirred;
(4) mixture with step (3) fully grinds on three-roll grinder.
The invention also discloses the manufacture craft that this OGS glass protection printing ink is applied to the OGS face glass.
This technique may further comprise the steps:
(S1) with screen printer silk-screen protection printing ink, half tone order number was 250～300 orders after base plate glass was strengthened;
(S2) base plate glass that silk-screen is good was 70 ℃～90 ℃ bakings 5～7 minutes;
(S3) baked base plate glass is solidified 140s～200s at 320～400nmUV curing machine.
(S4) base plate glass after the curing is finished touch-control processing procedure, glass cutting, edging operation;
(S5) will immerse in 80 ℃～90 ℃ hot water through the base plate glass of step 4, soak through 1～3 minute, the printing ink to be protected rear taking-up base plate glass that comes off fully.
Be viscous state under this protection printing ink normal temperature, can be on 320～400nmUV curing machine, chemical crosslink reaction occurs rapidly in 140s～200s,, hydrofluoric acid resistant coating hard, wear-resisting at glass surface formation one deck.
The present invention has the following advantages compared to existing technology:
1. the present invention has overcome that ink solidification toasts length consuming time in the existing curing technology, the deficiency that can not solidify at short notice.
2. the used starting material of ink formulations are easy to buy, and the proportioning process is simple.Effectively the protective glass substrate stops hydrofluoric acid to the erosion of glass, anti-cut mechanically.
3. adopt neutral hot water to move back film, avoided traditional alkali lye to move back film to the corrosion of glass and circuit, move back film rapidly, convenience, safety, environmental protection.Be applicable to produce in enormous quantities, save human and material resources.
Embodiment
The below is described in detail embodiments of the invention, and the present embodiment is implemented under take technical solution of the present invention as prerequisite, has provided detailed embodiment and concrete operating process.
Embodiment 1
Take by weighing the raw material of following components by weight percent: 6 parts of aliphatic urethane acrylates; 3 parts of NVPs; 2; 0.3 part of 4,6-trimethylbenzoyl-diphenyl phosphine oxide, 1 part of stearyl alcohol; 0.1 part in organic silicon modified by polyether oxygen alkane; 0.1 part of fluorine-carbon modified polyacrylic ester, 0.3 part of phthalic ester, 1 part of phthalocyanine blue.Wherein the molecular-weight average of stearyl alcohol is 6000, and organic silicon modified by polyether oxygen alkane is as defoamer, to reach the purpose of abundant froth breaking; Fluorine-carbon modified polyacrylic ester is as flow agent, can impel printing ink in the drying and forming-film process, form one smooth, smooth, film uniformly; Phthalic ester can reduce the high polymer material glass transition temperature and improve plasticity as softening agent.
Adopt above raw material to prepare OGS glass protection printing ink, may further comprise the steps:
(1) aliphatic urethane acrylate and NVP are stirred by above proportioning;
(2) 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide, stearyl alcohol, organic silicon modified by polyether oxygen alkane, fluorine-carbon modified polyacrylic ester, phthalic ester are poured in order successively in the mixture of step (1) and stirred;
(3) phthalocyanine blue is poured in the mixture of step (2) and stirred;
(4) mixture with step (3) fully grinds on three-roll grinder.
Embodiment 2
Take by weighing the raw material of following components by weight percent: 8 parts of aliphatic urethane acrylates; 4 parts of NVPs; 2; 0.4 part of 4,6-trimethylbenzoyl-diphenyl phosphine oxide, 1.5 parts of stearyl alcohol; 0.15 part in organic silicon modified by polyether oxygen alkane; 0.15 part of fluorine-carbon modified polyacrylic ester, 0.35 part of phthalic ester, 1.5 parts of phthalocyanine blues.Its preparation method is with embodiment 1.
Embodiment 3
Take by weighing the raw material of following components by weight percent: 10 parts of aliphatic urethane acrylates; 5 parts of NVPs; 2; 0.5 part of 4,6-trimethylbenzoyl-diphenyl phosphine oxide, 2 parts of stearyl alcohol; 0.2 part in organic silicon modified by polyether oxygen alkane; 0.2 part of fluorine-carbon modified polyacrylic ester, 0.4 part of phthalic ester, 2 parts of phthalocyanine blues.Its preparation method is with embodiment 1.
The OGS glass protection printing ink hydrofluoric acid resistant performance of the present invention's preparation is good, moves back film and cleaning easily, safety, and environmental protection is applicable to produce in enormous quantities, is suitable as and makes the OGS face glass, and Application Example is as follows:
Embodiment 4
The manufacture craft of OGS face glass may further comprise the steps:
(S1) base plate glass is strengthened, used the screen printer silk-screen on the base plate glass of strengthening in the OGS glass protection printing ink of embodiment 1 preparation, half tone order number is 300 orders;
(S2) base plate glass that silk-screen is good was 70 ℃ of bakings 5 minutes;
(S3) baked base plate glass is solidified 140s at 320nmUV curing machine;
(S4) base plate glass after the curing is finished touch-control processing procedure, glass cutting, edging operation;
(S5) will immerse in 80 ℃ of hot water through the base plate glass of step 4, soak through 3 minutes, the printing ink to be protected rear taking-up base plate glass that comes off fully.
Embodiment 5
The manufacture craft of OGS face glass may further comprise the steps:
(S1) base plate glass is strengthened, used the screen printer silk-screen on the base plate glass of strengthening in the OGS glass protection printing ink of embodiment 2 preparations, half tone order number is 280 orders;
(S2) base plate glass that silk-screen is good was 70 ℃ of bakings 6 minutes;
(S3) baked base plate glass is solidified 170s at 350nmUV curing machine;
(S4) base plate glass after the curing is finished touch-control processing procedure, glass cutting, edging operation;
(S5) will immerse in 85 ℃ of hot water through the base plate glass of step 4, soak through 2 minutes, the printing ink to be protected rear taking-up base plate glass that comes off fully.
Embodiment 6
The manufacture craft of OGS face glass may further comprise the steps:
(S1) base plate glass is strengthened, used the screen printer silk-screen on the base plate glass of strengthening in the OGS glass protection printing ink of embodiment 3 preparations, half tone order number is 250 orders;
(S2) base plate glass that silk-screen is good was 90 ℃ of bakings 7 minutes;
(S3) baked base plate glass is solidified 200s at 400nmUV curing machine;
(S4) base plate glass after the curing is finished touch-control processing procedure, glass cutting, edging operation;
(S5) will immerse in 90 ℃ of hot water through the base plate glass of step 4, soak through 1 minute, the printing ink to be protected rear taking-up base plate glass that comes off fully.
The above; only for the better embodiment of the present invention, but protection scope of the present invention is not limited to this, anyly is familiar with those skilled in the art in the technical scope that the present invention discloses; the variation that can expect easily or replacement all should be encompassed within protection scope of the present invention.
Claims (8)
1. an OGS glass protection printing ink is characterized in that, by weight, comprises following component:
2. a kind of OGS glass protection printing ink as claimed in claim 1, it is characterized in that: the molecular-weight average of described stearyl alcohol is 6000.
3. a kind of OGS glass protection printing ink as claimed in claim 1, it is characterized in that: described defoamer is organic silicon modified by polyether oxygen alkane.
4. such as each described a kind of OGS glass protection printing ink of claims 1 to 3, it is characterized in that: described flow agent is fluorine-carbon modified polyacrylic ester.
5. such as each described a kind of OGS glass protection printing ink of claims 1 to 3, it is characterized in that: described softening agent is phthalic ester.
6. the preparation method such as each described OGS glass protection printing ink of claim 1 to 5 is characterized in that, may further comprise the steps:
(1) aliphatic urethane acrylate and NVP are stirred in proportion;
(2) 2,4,6-trimethylbenzoyl-diphenyl phosphine oxide, stearyl alcohol, defoamer, flow agent, softening agent are poured in order successively in the mixture of step (1) and stirred;
(3) phthalocyanine blue is poured in the mixture of step (2) and stirred;
(4) mixture with step (3) fully grinds on three-roll grinder.
As claim 1 to 5 as described in each OGS glass protection printing ink be applied to the manufacture craft of OGS face glass.
One kind as claimed in claim 7 OGS glass protection printing ink be applied to the manufacture craft of OGS face glass, work being characterised in that, may further comprise the steps:
(S1) with screen printer silk-screen protection printing ink, half tone order number was 250～300 orders after base plate glass was strengthened;
(S2) base plate glass that silk-screen is good was 70 ℃～90 ℃ bakings 5～7 minutes;
(S3) baked base plate glass is solidified 140s～200s at 320～400nmUV curing machine;
(S4) base plate glass after the curing is finished touch-control processing procedure, glass cutting, edging operation;
(S5) will immerse in 80 ℃～90 ℃ hot water through the base plate glass of step 4, soak through 1～3 minute, the printing ink to be protected rear taking-up base plate glass that comes off fully.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310242073.7A CN103319949B (en) | 2013-06-18 | 2013-06-18 | OGS (One Glass Solution) glass protecting ink as well as preparation method and application thereof |
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| CN201310242073.7A CN103319949B (en) | 2013-06-18 | 2013-06-18 | OGS (One Glass Solution) glass protecting ink as well as preparation method and application thereof |
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| CN103319949A true CN103319949A (en) | 2013-09-25 |
| CN103319949B CN103319949B (en) | 2014-10-22 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104151925A (en) * | 2014-07-22 | 2014-11-19 | 深圳市宇顺电子股份有限公司 | High-temperature-resistant ink, preparation method thereof and OGS touch panel |
| CN104530817A (en) * | 2014-12-12 | 2015-04-22 | 惠州市至上新材料有限公司 | UV silk-screen printing ink for tearable protective films for mobile-phone glass screens |
| CN105038401A (en) * | 2015-08-14 | 2015-11-11 | 华南理工大学 | Washable touch screen temporary protection ink as well as preparation method and application thereof |
| CN106497497A (en) * | 2016-10-09 | 2017-03-15 | 广州惠利电子材料有限公司 | Antiacid peelable glue and its preparation method and application |
| CN107264099A (en) * | 2017-07-13 | 2017-10-20 | 山东交通学院 | A kind of printing process of pattern |
| CN108102460A (en) * | 2018-01-08 | 2018-06-01 | 广州昊毅化工科技有限公司 | Infrared ray cured ink and its preparation method and application |
| CN110228949A (en) * | 2018-03-05 | 2019-09-13 | 蓝思科技（长沙）有限公司 | A kind of small size cover board manufacture craft |
| CN112391081A (en) * | 2020-10-29 | 2021-02-23 | 惠州市百时达化工有限公司 | Hot water deinking type peelable glass UV ink and use method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104151925A (en) * | 2014-07-22 | 2014-11-19 | 深圳市宇顺电子股份有限公司 | High-temperature-resistant ink, preparation method thereof and OGS touch panel |
| CN104530817A (en) * | 2014-12-12 | 2015-04-22 | 惠州市至上新材料有限公司 | UV silk-screen printing ink for tearable protective films for mobile-phone glass screens |
| CN105038401A (en) * | 2015-08-14 | 2015-11-11 | 华南理工大学 | Washable touch screen temporary protection ink as well as preparation method and application thereof |
| CN105038401B (en) * | 2015-08-14 | 2017-12-19 | 华南理工大学 | A kind of washable touch screen protects ink and preparation method and application temporarily |
| CN106497497A (en) * | 2016-10-09 | 2017-03-15 | 广州惠利电子材料有限公司 | Antiacid peelable glue and its preparation method and application |
| CN107264099A (en) * | 2017-07-13 | 2017-10-20 | 山东交通学院 | A kind of printing process of pattern |
| CN107264099B (en) * | 2017-07-13 | 2018-03-16 | 山东交通学院 | A kind of printing process of pattern |
| CN108102460A (en) * | 2018-01-08 | 2018-06-01 | 广州昊毅化工科技有限公司 | Infrared ray cured ink and its preparation method and application |
| CN110228949A (en) * | 2018-03-05 | 2019-09-13 | 蓝思科技（长沙）有限公司 | A kind of small size cover board manufacture craft |
| CN112391081A (en) * | 2020-10-29 | 2021-02-23 | 惠州市百时达化工有限公司 | Hot water deinking type peelable glass UV ink and use method thereof |
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| CN103319949B (en) | 2014-10-22 |
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Address after: 361101 No. 29 Xiang Xiang Road, torch garden, Xiangan District, Fujian, Xiamen Patentee after: XIAMEN HOWER MATERIAL CO., LTD. Address before: 361101 No. 29 Xiang Xiang Road, torch garden, Xiangan District, Fujian, Xiamen Patentee before: Xiamen Hower Material Co., Ltd. |