CN103305073A - Wear-resisting water wood paint and preparation method thereof - Google Patents

Wear-resisting water wood paint and preparation method thereof Download PDF

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Publication number
CN103305073A
CN103305073A CN2013102925958A CN201310292595A CN103305073A CN 103305073 A CN103305073 A CN 103305073A CN 2013102925958 A CN2013102925958 A CN 2013102925958A CN 201310292595 A CN201310292595 A CN 201310292595A CN 103305073 A CN103305073 A CN 103305073A
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water
abrasion
agent
wood lacquer
resistance water
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CN103305073B (en
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洪杰
何玲玲
林伟
陈瑞金
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Skshu Paint Co Ltd
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Skshu Paint Co Ltd
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Abstract

The invention relates to the technical field of wood paints, particularly to a wear-resisting water wood paint and a preparation method thereof. The wear-resisting water wood paint comprises the following components of, by weight percentage, water of 8-12%, water dispersant of 0.5-1.0%, water wetting agent of 0.1-0.5%, water defoamer of 0.05-0.2%, titanium dioxide powder of 0-5%, kaolin of 3-5%, talcum powder of 8-12%, calcium carbonate of 8-12%, precipitated barium sulfate of 1-4%, water pure acrylic resin of 35-45%, film forming additive of 5.9-7.6%, antifreezing agent of 0.5-1.2%, water multifunctional additive of 0.1-0.2%, preservative bactericide of 0.1-0.2%, antiblocking additive of 0.2-0.5%, flatting agent of 0.5-1.0% and thickening agent of 0.8-1.5%, with the balance being water. The wear-resisting water wood paint has a good wear-resisting, anti-knocking and antiblocking performance, good wrapping effects on color fillers and color paste, effective protection on base materials from any damage, a strong adhesive force with the surface of the base materials and meanwhile a good scratch-resistant, color developing and repainting performance.

Description

A kind of abrasion-resistance water wood lacquer and preparation method thereof
Technical field
The present invention relates to a kind of wood lacquer technical field, particularly a kind of abrasion-resistance water wood lacquer and preparation method thereof.
Background technology
At present aqueous woodware paint is progressively replacing solvent based coating as the supercoat of timber product because of its lower VOC content, owing to be solvent and easy to use with water; In DIY woodwork coating market and industrial woodwork coating market more and more used, but because have that wear resistance not, anti-knocking property are poor, the resistance to blocking difference is the development of about aqueous woodware paint of stagnating always.
Summary of the invention
The object of the present invention is to provide a kind of high-wearing feature, high anti-knocking property and high conglutination-resistance; and color stuffing and mill base there is good parcel; can effectively protect base material not to be subjected to any destruction; has superpower cohesive force with substrate surface; has high scratch resistance simultaneously, the abrasion-resistance water wood lacquer of good color developing and recoatability.
The present invention is achieved in that a kind of abrasion-resistance water wood lacquer, it is characterized in that: comprise following components in weight percentage:
Figure BDA00003503408300011
Figure BDA00003503408300021
Described aqueous dispersant is a kind of in polyacrylic acid sodium salt waterborne pigment dispersant and the polycarboxylate sodium's type dispersion agent, rises and disperses and stabilization; Wherein also available hydrophobically modified multipolymer amine salt dispersion agent replacement of aqueous dispersant.
Described aqueous wetting agent adopts non-ionic wetting agent, mainly contains simple function group, oleoyl epoxy alkane segmented copolymer, to the color stuffing dissemination, and improves color developing.
Described water-based defoamer is a kind of in non-ionic type defoamer, the molecular level defoamer, but has good consistency and principal characteristic.
Described titanium dioxide is a kind of in anatase thpe white powder and the Rutile type Titanium Dioxide, plays the covering effect.
Described kaolin adopts calcined kaolin, plays a part to fill and reduce cost.
Described talcum powder adopts 1250 order talcum powder.
Described calcium carbonate adopts 800 order water-ground limestones.
Described process white adopts ultra-fine barium sulfate, and Mohs' hardness be 2.5-3.5 and oil number is 15-20, improves the wear resistance of paint film.
Described water-based pure acrylic resin contains nucleocapsid structure, minimum film-forming temperature is 45 ℃-55 ℃, the Tg value is 40 ℃-90 ℃, have good resistance to blocking and dry heat resistance, color stuffing is wrapped up, can effectively protect base material not to be subjected to any destruction, and have good cohesive force with substrate surface; Described water-based pure acrylic resin also available water-based benzene emulsion is replaced.
Described frostproofer adopts the propylene glycol frostproofer, prevents freezing film forming matter when storing for-5 ℃ to 0 ℃.
Described water-soluble multifunctional auxiliary agent adopts the AMP-95 multifunctional assistant, works the potential of hydrogen effect of regulating.
Described film coalescence aid is a kind of or two kinds of mixing arbitrarily in dipropylene glycol butyl ether and the dipropylene glycol methyl ether, helps film forming matter film forming at low temperatures; Above-mentioned film coalescence aid also can adopt the lauryl alcohol ester to replace.
Described anticorrosion and bactericidal agent adopts the isothiazolinone disinfecting agent that does not contain VOC, has thermotolerance, plays the sterilization and anticorrosion effect simultaneously.
Described antiblocking auxiliary agent has excellent anti-scratch scratch and resistance to blocking.
Described flow agent adopts polyether-modified polydimethylsiloxane interpolymer flow agent, reduces coating surface tension force, improves the ground wettability, shrinkproof permeability, and coating surperficial smooth improved scratch resistance and adhesion inhibiting properties simultaneously.
Described thickening material adopts non-ionic associative type rheology modifier, and this non-ionic associative type rheology modifier is hydrophobically modified urethane, and film forming matter is played thickening power.
The preparation method of described abrasion-resistance water wood lacquer, this method may further comprise the steps composition:
Step 1: water is added in the dispersion cylinder, according to above-mentioned weight percent, after adding aqueous dispersant, aqueous wetting agent, water-based defoamer, titanium dioxide, kaolin, talcum powder, calcium carbonate, process white successively under the 600r/min speed whipped state;
Step 2: disperse 15min to survey fineness to≤40 under the 2000r/min rotating speed, namely fineness is qualified;
Step 3: under the 1000r/min whipped state, add water-based pure acrylic resin, film coalescence aid, frostproofer, anticorrosion and bactericidal agent, antiblocking auxiliary agent, flow agent, thickening material and excess water successively, get final product after fully stirring 30min.
The present invention compared with prior art has following advantage:
1, have good wear resistance and color stuffing and mill base had good parcel, particularly with hundred yuan of banknotes or blank sheet of paper card paint film is polished, coating surface does not have tangible cut, and banknote or blank sheet of paper card surface do not have down the color of mill base yet;
2, have good anti-knocking property, it is characterized in that beaing coating surface with table tennis, the marking that coating surface stays after not having table tennis to beat;
3, have good resistance to blocking, can prevent effectively that article paint film in transportation from sticking together, the protection base material is not subjected to any destruction, and has superpower cohesive force with substrate surface;
4, have good color developing and recoatability, color developing is in paint film that time of surface drying soon, grinds paint film with forefinger, and paint film color does not have tangible aberration; Obstacle when recoatability is second time construction has good levelling property.
Embodiment
The present invention will be described in detail below in conjunction with specific embodiment.
Embodiment 1: a kind of abrasion-resistance water wood lacquer comprises following components in weight percentage:
Figure BDA00003503408300041
Figure BDA00003503408300051
Embodiment 2: a kind of abrasion-resistance water wood lacquer comprises following components in weight percentage:
Figure BDA00003503408300052
Figure BDA00003503408300061
Embodiment 3: a kind of abrasion-resistance water wood lacquer comprises following components in weight percentage:
Figure BDA00003503408300062
Figure BDA00003503408300071
Most preferred embodiment: a kind of abrasion-resistance water wood lacquer comprises following components in weight percentage:
Figure BDA00003503408300072
The preparation method of above-mentioned abrasion-resistance water wood lacquer, this method may further comprise the steps composition:
Step 1: water is added in the dispersion cylinder, according to above-mentioned weight percent, after adding aqueous dispersant, aqueous wetting agent, water-based defoamer, titanium dioxide, kaolin, talcum powder, calcium carbonate, process white successively under the 600r/min speed whipped state;
Step 2: disperse 15min to survey fineness to≤40 under the 2000r/min rotating speed, namely fineness is qualified;
Step 3: under the 1000r/min whipped state, add water-based pure acrylic resin, film coalescence aid, frostproofer, anticorrosion and bactericidal agent, antiblocking auxiliary agent, flow agent, thickening material and excess water successively, get final product after fully stirring 30min.

Claims (10)

1. abrasion-resistance water wood lacquer is characterized in that: comprise following components in weight percentage:
Figure FDA00003503408200011
2. abrasion-resistance water wood lacquer according to claim 1 is characterized in that: described aqueous dispersant is preferably a kind of in polyacrylic acid sodium salt waterborne pigment dispersant and the polycarboxylate sodium's type dispersion agent.
3. abrasion-resistance water wood lacquer according to claim 1 is characterized in that: described aqueous wetting agent adopts non-ionic wetting agent, mainly contains simple function group, oleoyl epoxy alkane segmented copolymer.
4. abrasion-resistance water wood lacquer according to claim 1 is characterized in that: described water-based defoamer is preferably a kind of in non-ionic type defoamer, the molecular level defoamer.
5. abrasion-resistance water wood lacquer according to claim 1 is characterized in that: described titanium dioxide is preferably a kind of in anatase thpe white powder and the Rutile type Titanium Dioxide.
6. abrasion-resistance water wood lacquer according to claim 1, it is characterized in that: described water-based pure acrylic resin contains nucleocapsid structure, and minimum film-forming temperature is 45 ℃-55 ℃, and the Tg value is 40 ℃-90 ℃.
7. abrasion-resistance water wood lacquer according to claim 1 is characterized in that: described film coalescence aid is preferably a kind of in dipropylene glycol butyl ether and the dipropylene glycol methyl ether or two kinds to be mixed arbitrarily.
8. abrasion-resistance water wood lacquer according to claim 1 is characterized in that: described anticorrosion and bactericidal agent adopts the isothiazolinone disinfecting agent that does not contain VOC; Described flow agent adopts polyether-modified polydimethylsiloxane interpolymer flow agent.
9. abrasion-resistance water wood lacquer according to claim 1 is characterized in that: described thickening material adopts non-ionic associative type rheology modifier, and this non-ionic associative type rheology modifier is preferably hydrophobically modified urethane.
10. method for preparing the described abrasion-resistance water wood lacquer of claim 1, it is characterized in that: described this method may further comprise the steps composition:
Step 1: water is added in the dispersion cylinder, according to above-mentioned weight percent, after adding aqueous dispersant, aqueous wetting agent, water-based defoamer, titanium dioxide, kaolin, talcum powder, calcium carbonate, process white successively under the 600r/min speed whipped state;
Step 2: disperse 15min to survey fineness to≤40 under the 2000r/min rotating speed, namely fineness is qualified;
Step 3: under the 1000r/min whipped state, add water-based pure acrylic resin, film coalescence aid, frostproofer, anticorrosion and bactericidal agent, antiblocking auxiliary agent, flow agent, thickening material and excess water successively, get final product after fully stirring 30min.
CN201310292595.8A 2013-07-12 2013-07-12 A kind of abrasion-resistance water woodcare paint and preparation method thereof Active CN103305073B (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103555189A (en) * 2013-10-22 2014-02-05 三棵树涂料股份有限公司 Healthy and environment-friendly dual-component wear-resisting floor paint and preparation method thereof
CN103614040A (en) * 2013-11-04 2014-03-05 三棵树涂料股份有限公司 Aqueous woodenware enclosing priming paint and its preparation method
CN104592840A (en) * 2014-12-30 2015-05-06 三棵树涂料股份有限公司 Scratch-endurable high-performance aqueous semi-dumb white paint for woodwork and preparation method thereof
CN106009989A (en) * 2016-06-03 2016-10-12 上海展辰涂料有限公司 Waterborne wood paint adhesive force enhancement undercoat and topcoat
CN106609085A (en) * 2016-12-26 2017-05-03 大连佳秀百隆新材料股份有限公司 Monocomponent polyacrylate woodware paint
CN106634553A (en) * 2017-01-05 2017-05-10 辽阳意邦新型建材集团有限公司 Water-dispersible environment-friendly waterborne wood coating with insect-killing and anion-releasing properties and preparation method thereof
CN107201119A (en) * 2017-06-26 2017-09-26 界首市通泽建材销售有限公司 A kind of preparation method of abrasion-resistance water woodcare paint
CN107556848A (en) * 2016-07-01 2018-01-09 青岛环秀涂料有限公司 A kind of graphene aqueous woodware paint and method of preparation and use
CN109535912A (en) * 2018-11-28 2019-03-29 韶关市合众化工有限公司 A kind of aqueous woodware paint of polyarylsulfone (PAS) modified acrylic resin emulsion
CN111434736A (en) * 2019-01-22 2020-07-21 青岛明派水漆有限公司 Environment-friendly water-based paint and preparation method thereof
CN111732879A (en) * 2020-05-28 2020-10-02 广东维拓化工股份有限公司 Antiviral healthy plant water-based enamel-like paint and preparation method thereof

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CN101280142A (en) * 2007-04-04 2008-10-08 中山市孙大化工科技有限公司 Environment-friendly aqueous nanometer fireproof flame-retardant coating and preparation thereof
CN101486861A (en) * 2008-01-18 2009-07-22 深圳市海川实业股份有限公司 Environment friendly antibacterial waterborne paint and preparation thereof

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CN1398931A (en) * 2002-05-28 2003-02-26 北京化工大学 Water-thinned latex paint containing nano calcium carbonate for cuter wall and its prepn process
CN101280142A (en) * 2007-04-04 2008-10-08 中山市孙大化工科技有限公司 Environment-friendly aqueous nanometer fireproof flame-retardant coating and preparation thereof
CN101125998A (en) * 2007-09-29 2008-02-20 佛山市顺德区华隆涂料实业有限公司 Metal corsslinking molecular film-forming bi-component water carpentry paint and preparation method thereof
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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103555189A (en) * 2013-10-22 2014-02-05 三棵树涂料股份有限公司 Healthy and environment-friendly dual-component wear-resisting floor paint and preparation method thereof
CN103555189B (en) * 2013-10-22 2016-11-09 三棵树涂料股份有限公司 Healthy and environment-friendlydual-component dual-component wear-resisting floor paint and preparation method thereof
CN103614040A (en) * 2013-11-04 2014-03-05 三棵树涂料股份有限公司 Aqueous woodenware enclosing priming paint and its preparation method
CN103614040B (en) * 2013-11-04 2016-10-19 三棵树涂料股份有限公司 A kind of aqueous wooden ware seal coat and preparation method thereof
CN104592840B (en) * 2014-12-30 2017-10-27 三棵树涂料股份有限公司 Mute white finish paint of a kind of high-performance water-based woodenware half of damage resistant and preparation method thereof
CN104592840A (en) * 2014-12-30 2015-05-06 三棵树涂料股份有限公司 Scratch-endurable high-performance aqueous semi-dumb white paint for woodwork and preparation method thereof
CN106009989A (en) * 2016-06-03 2016-10-12 上海展辰涂料有限公司 Waterborne wood paint adhesive force enhancement undercoat and topcoat
CN107556848A (en) * 2016-07-01 2018-01-09 青岛环秀涂料有限公司 A kind of graphene aqueous woodware paint and method of preparation and use
CN106609085A (en) * 2016-12-26 2017-05-03 大连佳秀百隆新材料股份有限公司 Monocomponent polyacrylate woodware paint
CN106634553A (en) * 2017-01-05 2017-05-10 辽阳意邦新型建材集团有限公司 Water-dispersible environment-friendly waterborne wood coating with insect-killing and anion-releasing properties and preparation method thereof
CN106634553B (en) * 2017-01-05 2019-04-12 辽宁意邦新型材料科技集团有限公司 A kind of environment-friendly water-based woodcare paint of water dispersible and preparation method with desinsection and release anionic property
CN107201119A (en) * 2017-06-26 2017-09-26 界首市通泽建材销售有限公司 A kind of preparation method of abrasion-resistance water woodcare paint
CN109535912A (en) * 2018-11-28 2019-03-29 韶关市合众化工有限公司 A kind of aqueous woodware paint of polyarylsulfone (PAS) modified acrylic resin emulsion
CN111434736A (en) * 2019-01-22 2020-07-21 青岛明派水漆有限公司 Environment-friendly water-based paint and preparation method thereof
CN111732879A (en) * 2020-05-28 2020-10-02 广东维拓化工股份有限公司 Antiviral healthy plant water-based enamel-like paint and preparation method thereof

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