CN103302040A - Screening method for lithium-ion battery consistency - Google Patents

Screening method for lithium-ion battery consistency Download PDF

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Publication number
CN103302040A
CN103302040A CN2013102324782A CN201310232478A CN103302040A CN 103302040 A CN103302040 A CN 103302040A CN 2013102324782 A CN2013102324782 A CN 2013102324782A CN 201310232478 A CN201310232478 A CN 201310232478A CN 103302040 A CN103302040 A CN 103302040A
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China
Prior art keywords
battery
capacity
internal resistance
voltage
voltage drop
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Pending
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CN2013102324782A
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Chinese (zh)
Inventor
赵章宏
郭静斐
李良学
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GAOPING TANGYIXIN NEW ENERGY TECHNOLOGY Co Ltd
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GAOPING TANGYIXIN NEW ENERGY TECHNOLOGY Co Ltd
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Priority to CN2013102324782A priority Critical patent/CN103302040A/en
Publication of CN103302040A publication Critical patent/CN103302040A/en
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Abstract

The invention relates to the technical field of the detection of a battery, and in particular relates to a screening method for lithium-ion battery consistency. The method is characterized in that the screening is carried out according to the limit capacity, the limit internal resistance and the limit voltage droop in a high-temperature environment, a low-temperature environment or a normal-temperature environment of a single battery; the battery is charged and discharged, so that the screening can be further carried out by comparing the variation of the capacity, the voltages and the currents in the charging and discharging processes, the application efficiency of the single battery can be improved, the service life of the single battery can be prolonged, and the safety of the single battery can be improved.

Description

The conforming screening technique of lithium ion battery
Technical field
The present invention relates to the battery detecting technical field, particularly relate to the conforming screening technique of a kind of lithium ion battery.
Background technology
At present, has energy density high, long service life, being widely used of the green power supply that security performance is good----lithium ion battery.Lithium ion battery is widely used in the fields such as energy storage, power.Test is found, the same battery of making, and will be lower than the service life of cell the service life of battery pack, and this explanation battery consistency obviously affects the service life of battery.In the connection in series-parallel of battery was used, the consistency problem of battery affected efficient and the life-span of battery, and safety problem is also influential.So the conforming requirement that combines the cell of battery pack should be stricter.
Guarantee the uniformity of battery, will guarantee that at first every initial performance of battery is consistent, the self discharge of battery will be consistent, and fading rate in use will be consistent.The conforming screening of current battery mainly is to utilize under normal temperature, low temperature and the hot environment battery capacity, internal resistance, voltage, discharge and recharge discharge platform and self discharge difference is screened.
The battery that screens falls by different temperatures lower limit constant volume scope, restriction internal resistance scope and stop voltage, can guarantee that battery initial performance, self-discharge performance are consistent, do not verify whether battery discharging and recharging in the process of using be synchronous, can not guarantee that fading rate in use is consistent.Reason is, the screening technique of existing battery can not reflect cell DC internal resistance and polarization resistance, and there is defective in the uniformity of battery.
The lithium ion battery group is to be formed by connecting through connection in series-parallel by a plurality of cells, but because the performance of each cell there are differences, the performance of battery pack is through having decline in various degree after certain charge and discharge cycles, show as that the conforming difference of monomer battery core becomes large in the acceleration of capacity attenuation and the battery pack, therefore must carry out strict selecting at battery before in groups.If the uniformity of cell is bad, charge and discharge process can strengthen the difference between the monomer battery core so, easily cause the part battery over-discharge or overcharge, and the performance of another part battery also can not get fully playing, finally cause the deteriorated of battery performance, the decay of battery pack cycle performance or inefficacy.
As everyone knows, the uniformity that how to guarantee each cell in the battery pack is the key that guarantees battery performance, also is that present lithium ion battery is at the bottleneck of various fields successful Application.
Summary of the invention
The purpose of this invention is to provide the conforming screening technique of a kind of lithium ion battery, it can guarantee under the state of work, and the charging and discharging state of lithium ion single battery that forms battery pack is synchronous, further improves the uniformity of battery.
Method of the present invention is to fall and screen according to the restriction capacity under cell high temperature, low temperature or the normal temperature varying environment, restriction internal resistance, stop voltage;
Battery discharges and recharges, and relatively capacity, voltage, curent change are done further screening in the charge and discharge process.
Method concrete steps of the present invention are as follows:
Filter out the lithium ion single battery of under equal conditions producing, namely the raw material of battery form and the preparation technology of battery waits and wants unanimously;
Battery is carried out outward appearance to be screened: battery must without flatulence, qualified without leakage, surface nothing scuffing and apparent size, filter out the qualified battery of outward appearance;
The qualified battery that filters out at room temperature under 20~30 ℃, is shelved preheating setting time: 14~28 days;
According to cell high temperature: 40~60 ℃, low temperature :-40~0 ℃ or normal temperature: the capacity under 20~30 ℃ the varying environment, internal resistance, voltage drop are added up and are screened;
Measure capacity, internal resistance, the voltage drop of standby screening battery under different temperature ranges;
Measured capacity, internal resistance and voltage drop out averaged;
Be greater than or less than the battery of the predetermined percentage of capacity, internal resistance, voltage drop mean value, be judged to be unusual battery, rejected;
The battery that previous step is not rejected carries out discharging and recharging of Work condition analogue, the charging and discharging currents scope is at 0.1~3C, capacity, voltage or current measurement data in the discharge process are derived, be drawn as curve map, the variation tendency of the capacity among the analytic curve figure, voltage or electric current is progressively rejected the battery that curve distribution is unusual.
The present invention has the following advantages compared with prior art:
The present invention can improve service efficiency, service life and the security of cell by being further to screen synchronously to capacity, voltage, electric current in the charge and discharge process of cell.
Description of drawings
Fig. 1 is screening process figure of the present invention,
Fig. 2 is 27 battery discharge voltage change curve distribution figure of the embodiment of the invention,
Fig. 3 is 16 battery discharge voltage change curve distribution figure of the embodiment of the invention,
Fig. 4 is 10 battery discharge voltage change curve distribution figure of the embodiment of the invention.
The specific embodiment
Method concrete steps of the present invention are as follows:
Filter out the lithium ion single battery of under equal conditions producing, namely the raw material of battery form and the preparation technology of battery waits and wants unanimously;
Battery is carried out outward appearance to be screened: battery must without flatulence, qualified without leakage, surface nothing scuffing and apparent size, filter out the qualified battery of outward appearance;
The qualified battery that filters out at room temperature under 20~30 ℃, is shelved preheating setting time: 14~28 days;
According to cell high temperature: 40~60 ℃, low temperature :-40~0 ℃ or normal temperature: the capacity under 20~30 ℃ the varying environment, internal resistance, voltage drop are added up and are screened;
Measure capacity, internal resistance, the voltage drop of standby screening battery under different temperature ranges;
Measured capacity, internal resistance and voltage drop out averaged;
Be greater than or less than the battery of the predetermined percentage of capacity, internal resistance, voltage drop mean value, be judged to be unusual battery, rejected;
The battery that previous step is not rejected carries out discharging and recharging of Work condition analogue, the charging and discharging currents scope is at 0.1~3C, capacity, voltage or current measurement data in the discharge process are derived, be drawn as curve map, the variation tendency of the capacity among the analytic curve figure, voltage or electric current is progressively rejected the battery that curve distribution is unusual;
To the screening of discharging of the lithium ion of 27 100Ah not rejecting;
The Work condition analogue that battery is discharged with 0.5C, 0.8C and 1C:
The charge-discharge test scheme:
Shelve: 60 seconds
Constant-current discharge: 50A deadline: 10 seconds; Voltage: 2.50V;
Shelve: 60 seconds
Constant-current discharge: 80A deadline: 10 seconds; Voltage: 2.50V;
Shelve: 60 seconds
Constant-current discharge: 100A deadline: 10 seconds; Voltage: 2.50V;
Shelve: stopped in 60 seconds
During Work condition analogue, shelve 3S writing time, electric discharge recording time 1S.
Data derive
Data analysis
Analyze the voltage change in the battery charge and discharge process, 27 batteries that analysis is found to screen carry out primary election 11 batteries that difference is large and give up in the situation that with current discharge, the variation of voltage has very large difference, remain 16 cells;
To the voltage change in the analysis of the battery after the primary election charge and discharge process, carry out two choosings, 6 batteries that difference is large and give up, remain 10 batteries;
Be further analyzed discovery through 10 batteries after two choosings, the variation of voltage in the process that discharges and recharges of remaining battery is consistent, screens complete.

Claims (1)

1. the conforming screening technique of lithium ion battery is characterized in that comprising the steps:
Filter out the lithium ion single battery of under equal conditions producing, namely the raw material of battery form and the preparation technology of battery waits and wants unanimously;
Battery is carried out outward appearance to be screened: battery must without flatulence, qualified without leakage, surface nothing scuffing and apparent size, filter out the qualified battery of outward appearance;
The qualified battery that filters out at room temperature under 20~30 ℃, is shelved preheating setting time: 14~28 days;
According to cell high temperature: 40~60 ℃, low temperature :-40~0 ℃ or normal temperature: the capacity under 20~30 ℃ the varying environment, internal resistance, voltage drop are added up and are screened;
Measure capacity, internal resistance, the voltage drop of standby screening battery under different temperature ranges;
Measured capacity, internal resistance and voltage drop out averaged;
Be greater than or less than the battery of the predetermined percentage of capacity, internal resistance, voltage drop mean value, be judged to be unusual battery, rejected;
The battery that previous step is not rejected carries out discharging and recharging of Work condition analogue, the charging and discharging currents scope is at 0.1~3C, capacity, voltage or current measurement data in the discharge process are derived, be drawn as curve map, the variation tendency of the capacity among the analytic curve figure, voltage or electric current is progressively rejected the battery that curve distribution is unusual.
CN2013102324782A 2013-06-13 2013-06-13 Screening method for lithium-ion battery consistency Pending CN103302040A (en)

Priority Applications (1)

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CN103316852A (en) * 2013-05-24 2013-09-25 上海中聚佳华电池科技有限公司 Battery selecting method
CN103464388A (en) * 2013-09-26 2013-12-25 上海动力储能电池***工程技术有限公司 Lithium ion battery screening method
CN103840225A (en) * 2014-03-27 2014-06-04 合肥国轩高科动力能源股份公司 Screening method for lithium ion battery
CN104190639A (en) * 2014-07-29 2014-12-10 江西世纪长河新电源有限公司 Self-discharge screening method of lithium ion batteries
CN104237802A (en) * 2014-09-23 2014-12-24 中国检验检疫科学研究院 Detection method for low-temperature performance uniformity of lithium ion batteries
CN104259114A (en) * 2014-09-16 2015-01-07 双登集团股份有限公司 Screening method of lithium ion batteries with high self-discharging capacities
CN104730463A (en) * 2013-12-20 2015-06-24 北汽福田汽车股份有限公司 Method for detecting consistency of single batteries
CN104991201A (en) * 2015-07-30 2015-10-21 国家电网公司 Lithium ion battery cell consistency evaluation system and method
CN105093125A (en) * 2015-07-30 2015-11-25 国家电网公司 Single nickel-hydrogen battery consistency evaluation system and method
CN105251706A (en) * 2015-11-03 2016-01-20 百顺松涛(天津)动力电池科技发展有限公司 Method for sorting lithium batteries
CN105396800A (en) * 2015-12-30 2016-03-16 哈尔滨工业大学 Screening method for lithium-ion storage battery
WO2016107198A1 (en) * 2014-12-30 2016-07-07 深圳市科陆电子科技股份有限公司 Method and device for analyzing and processing capacity drop of lithium battery energy storage system
CN105866701A (en) * 2016-06-27 2016-08-17 上海电气钠硫储能技术有限公司 Method for detecting uniformity of sodium-sulfur batteries
CN105903692A (en) * 2016-05-19 2016-08-31 四川长虹电器股份有限公司 Lithium ion battery consistency screening method
CN106207284A (en) * 2016-07-29 2016-12-07 中天储能科技有限公司 A kind of method promoting ferric phosphate lithium cell partial volume Capacity uniformity
CN106311634A (en) * 2016-08-30 2017-01-11 北京华特时代电动汽车技术有限公司 Battery module screening method and power battery pack screening method
CN106984561A (en) * 2017-03-09 2017-07-28 梅州市量能新能源科技有限公司 A kind of screening technique of power lithium-ion battery
CN107091991A (en) * 2017-04-28 2017-08-25 天津力神电池股份有限公司 Lithium ion battery voltage conformity classification method
CN107127166A (en) * 2017-05-22 2017-09-05 广东亿纬赛恩斯新能源***有限公司 A kind of method for separating and lithium battery of lithium battery uniformity
CN107983667A (en) * 2017-11-23 2018-05-04 中国东方电气集团有限公司 A kind of lithium ion battery grouping method
CN108267694A (en) * 2017-12-18 2018-07-10 合肥国轩高科动力能源有限公司 A kind of lithium ion battery internal resistance method for separating
CN108461858A (en) * 2018-03-23 2018-08-28 上海应用技术大学 A kind of screening technique that lithium titanate battery echelon utilizes
CN109332218A (en) * 2018-09-30 2019-02-15 江西安驰新能源科技有限公司 A kind of detection of lithium ion battery self discharge and combo technique
CN109683094A (en) * 2018-12-19 2019-04-26 武汉新能源研究院有限公司 A kind of quick method for separating and its sorting unit of lithium ion battery
CN110201913A (en) * 2019-05-29 2019-09-06 河南电池研究院有限公司 A kind of screening technique of soft bag lithium ionic cell consistency
CN110836741A (en) * 2019-11-20 2020-02-25 安徽必达新能源汽车产业研究院有限公司 Pure electric vehicle efficiency consistency online testing method
CN111842222A (en) * 2020-07-07 2020-10-30 横店集团东磁股份有限公司 Lithium battery capacity grading capacity compensation method, storage medium and lithium battery capacity grading equipment
CN112415416A (en) * 2020-11-12 2021-02-26 河北零点新能源科技有限公司 Method for rapidly detecting consistency of lithium batteries
CN113369176A (en) * 2021-06-13 2021-09-10 广州菲利斯太阳能科技有限公司 Sorting method and system for recycling retired batteries
CN113714152A (en) * 2021-08-26 2021-11-30 深圳市今朝时代股份有限公司 Energy storage type super capacitor screening method applied to aerospace power supply
CN113851657A (en) * 2021-10-19 2021-12-28 山东银成新能源科技有限公司 Preparation method of ultralow-temperature high-rate lithium ion battery for electronic cigarette
CN114035066A (en) * 2021-10-21 2022-02-11 合肥国轩高科动力能源有限公司 Lithium battery consistency evaluation method
CN114047444A (en) * 2021-11-09 2022-02-15 中国南方电网有限责任公司超高压输电公司广州局 Storage battery health condition evaluation method and device
CN114589123A (en) * 2022-04-25 2022-06-07 江西安驰新能源科技有限公司 Battery consistency screening method
CN114918159A (en) * 2022-05-16 2022-08-19 杭州煦达新能源科技有限公司 Screening method of retired lithium ion power battery

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CN103316852A (en) * 2013-05-24 2013-09-25 上海中聚佳华电池科技有限公司 Battery selecting method
CN103464388B (en) * 2013-09-26 2015-04-01 上海动力储能电池***工程技术有限公司 Lithium ion battery screening method
CN103464388A (en) * 2013-09-26 2013-12-25 上海动力储能电池***工程技术有限公司 Lithium ion battery screening method
CN104730463A (en) * 2013-12-20 2015-06-24 北汽福田汽车股份有限公司 Method for detecting consistency of single batteries
CN103840225A (en) * 2014-03-27 2014-06-04 合肥国轩高科动力能源股份公司 Screening method for lithium ion battery
CN103840225B (en) * 2014-03-27 2016-09-14 合肥国轩高科动力能源有限公司 A kind of screening technique of lithium ion battery
CN104190639A (en) * 2014-07-29 2014-12-10 江西世纪长河新电源有限公司 Self-discharge screening method of lithium ion batteries
CN104259114A (en) * 2014-09-16 2015-01-07 双登集团股份有限公司 Screening method of lithium ion batteries with high self-discharging capacities
CN104237802A (en) * 2014-09-23 2014-12-24 中国检验检疫科学研究院 Detection method for low-temperature performance uniformity of lithium ion batteries
WO2016107198A1 (en) * 2014-12-30 2016-07-07 深圳市科陆电子科技股份有限公司 Method and device for analyzing and processing capacity drop of lithium battery energy storage system
CN104991201A (en) * 2015-07-30 2015-10-21 国家电网公司 Lithium ion battery cell consistency evaluation system and method
CN105093125A (en) * 2015-07-30 2015-11-25 国家电网公司 Single nickel-hydrogen battery consistency evaluation system and method
CN105251706A (en) * 2015-11-03 2016-01-20 百顺松涛(天津)动力电池科技发展有限公司 Method for sorting lithium batteries
CN105396800A (en) * 2015-12-30 2016-03-16 哈尔滨工业大学 Screening method for lithium-ion storage battery
CN105903692B (en) * 2016-05-19 2018-05-25 四川长虹电器股份有限公司 Lithium ion battery conformity classification method
CN105903692A (en) * 2016-05-19 2016-08-31 四川长虹电器股份有限公司 Lithium ion battery consistency screening method
CN105866701B (en) * 2016-06-27 2019-01-29 上海电气钠硫储能技术有限公司 A kind of sodium-sulphur battery consistency detecting method
CN105866701A (en) * 2016-06-27 2016-08-17 上海电气钠硫储能技术有限公司 Method for detecting uniformity of sodium-sulfur batteries
CN106207284A (en) * 2016-07-29 2016-12-07 中天储能科技有限公司 A kind of method promoting ferric phosphate lithium cell partial volume Capacity uniformity
CN106311634A (en) * 2016-08-30 2017-01-11 北京华特时代电动汽车技术有限公司 Battery module screening method and power battery pack screening method
CN106984561A (en) * 2017-03-09 2017-07-28 梅州市量能新能源科技有限公司 A kind of screening technique of power lithium-ion battery
CN107091991A (en) * 2017-04-28 2017-08-25 天津力神电池股份有限公司 Lithium ion battery voltage conformity classification method
CN107127166A (en) * 2017-05-22 2017-09-05 广东亿纬赛恩斯新能源***有限公司 A kind of method for separating and lithium battery of lithium battery uniformity
CN107127166B (en) * 2017-05-22 2019-06-25 广东亿纬赛恩斯新能源***有限公司 A kind of method for separating and lithium battery of lithium battery consistency
CN107983667A (en) * 2017-11-23 2018-05-04 中国东方电气集团有限公司 A kind of lithium ion battery grouping method
CN108267694A (en) * 2017-12-18 2018-07-10 合肥国轩高科动力能源有限公司 A kind of lithium ion battery internal resistance method for separating
CN108461858A (en) * 2018-03-23 2018-08-28 上海应用技术大学 A kind of screening technique that lithium titanate battery echelon utilizes
CN109332218A (en) * 2018-09-30 2019-02-15 江西安驰新能源科技有限公司 A kind of detection of lithium ion battery self discharge and combo technique
CN109332218B (en) * 2018-09-30 2021-06-15 江西安驰新能源科技有限公司 Self-discharge detection and matching process of lithium ion battery
CN109683094A (en) * 2018-12-19 2019-04-26 武汉新能源研究院有限公司 A kind of quick method for separating and its sorting unit of lithium ion battery
CN110201913A (en) * 2019-05-29 2019-09-06 河南电池研究院有限公司 A kind of screening technique of soft bag lithium ionic cell consistency
CN110201913B (en) * 2019-05-29 2020-12-29 河南电池研究院有限公司 Screening method for consistency of soft package lithium ion battery
CN110836741A (en) * 2019-11-20 2020-02-25 安徽必达新能源汽车产业研究院有限公司 Pure electric vehicle efficiency consistency online testing method
CN111842222A (en) * 2020-07-07 2020-10-30 横店集团东磁股份有限公司 Lithium battery capacity grading capacity compensation method, storage medium and lithium battery capacity grading equipment
CN112415416A (en) * 2020-11-12 2021-02-26 河北零点新能源科技有限公司 Method for rapidly detecting consistency of lithium batteries
CN113369176A (en) * 2021-06-13 2021-09-10 广州菲利斯太阳能科技有限公司 Sorting method and system for recycling retired batteries
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CN113714152B (en) * 2021-08-26 2023-02-28 深圳市今朝时代股份有限公司 Energy storage type super capacitor screening method applied to aerospace power supply
CN113714152A (en) * 2021-08-26 2021-11-30 深圳市今朝时代股份有限公司 Energy storage type super capacitor screening method applied to aerospace power supply
CN113851657A (en) * 2021-10-19 2021-12-28 山东银成新能源科技有限公司 Preparation method of ultralow-temperature high-rate lithium ion battery for electronic cigarette
CN114035066A (en) * 2021-10-21 2022-02-11 合肥国轩高科动力能源有限公司 Lithium battery consistency evaluation method
CN114047444A (en) * 2021-11-09 2022-02-15 中国南方电网有限责任公司超高压输电公司广州局 Storage battery health condition evaluation method and device
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CN114918159A (en) * 2022-05-16 2022-08-19 杭州煦达新能源科技有限公司 Screening method of retired lithium ion power battery

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Application publication date: 20130918