CN103289236A - PVC (polyvinyl chloride) wood-like grain master batch and application thereof - Google Patents

PVC (polyvinyl chloride) wood-like grain master batch and application thereof Download PDF

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Publication number
CN103289236A
CN103289236A CN2013102276276A CN201310227627A CN103289236A CN 103289236 A CN103289236 A CN 103289236A CN 2013102276276 A CN2013102276276 A CN 2013102276276A CN 201310227627 A CN201310227627 A CN 201310227627A CN 103289236 A CN103289236 A CN 103289236A
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parts
pvc
component
weight
wood
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Inventor
蒋永清
杨应龙
***
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GUANGDONG HUASHENG ELECTRICAL APPLIANCES CO Ltd
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GUANGDONG HUASHENG ELECTRICAL APPLIANCES CO Ltd
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Priority to CN2013102276276A priority Critical patent/CN103289236A/en
Priority to PCT/CN2013/079174 priority patent/WO2014194547A1/en
Publication of CN103289236A publication Critical patent/CN103289236A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/12—Making granules characterised by structure or composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/286—Chlorinated polyethylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58—Component parts, details or accessories; Auxiliary operations
    • B29B7/72—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B29B7/7461—Combinations of dissimilar mixers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/02—Making granules by dividing preformed material
    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B29C2948/9259—Angular velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92885—Screw or gear
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895—Barrel or housing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2427/06—Homopolymers or copolymers of vinyl chloride

Abstract

The invention discloses a PVC (polyvinyl chloride) wood-like grain master batch, comprising a component A and a component B, wherein the component A includes 0-80 parts by weight of PVC resin, 2.5-7.0 pars by weight of heat stabilizer, 5.0-15 parts by weight of processing agent, 0-25 parts by weight of filler, 0.5-15 parts by weight of dispersing agent, 0.2-5.0 parts by weight of weather-resistant agent, and 5.0-70 parts by weight of pigment; and the component B comprises 20-80 parts by weight of PVC resin, 2.5-7.0 by weight parts of heat stabilizer, 5.0-15 parts by weight of processing agent, 0-30 parts by weight of filler, 0.5-15 parts by weight of dispersing agent, 0.2-5.0 parts by weight of weather-resistant agent, and 5.0-40 parts by weight of pigment. By adopting the PVC wood-like grain master batch disclosed by the invention, the effects of bright colors, good weather resistance, excellent mechanical property, clear wood grain lines and vivid wood grains can be formed in the products such as different formula systems of hard PVC plastic materials, PVC doors and windows, PVC boards and the like.

Description

A kind of PVC imitates wood grain color master batch and its application
Technical field
The invention belongs to plastic manufacturing technology field, and in particular to a kind of PVC imitates wood grain color master batch and its PVC plastic section bar prepared.
Background technology
In recent years, PVC plastic door and window, PVC plastic profile shapes, PVC board etc. are widely popularized and applied at home.As the phychology of the Nature is pressed close in the raising and serious hope of people's esthetic requirement, the imitation wood line appearance of PVC plastic material products becomes one of popular problem in the industry.
Traditional imitation wood line method is to paste one layer of wood grain film in PVC profile outer surface, gives a kind of wooden sensation.Wood grain film mainly using resin as basement membrane, by print roller stamp grain pattern be made, but the complex forming technology of this wood grain film, high cost and wooden " validity " it is poor.Therefore, developing a kind of material that can substitute wood grain film, there is provided a kind of wood effect is good, processing is simple and low cost wood grain material is part thing too impatient to wait.
The content of the invention
Wood grain color master batch is imitated it is an object of the present invention to provide a kind of PVC.
It is a further object to provide the preparation method that a kind of above-mentioned PVC imitates wood grain color master batch.
It is a further object to provide a kind of method that imitation wood line color PVC plastic section bar is prepared using above-mentioned PVC imitation woods line master batch, and thus obtained imitation wood line color PVC plastic section bar.
The technical solution used in the present invention is：
A kind of PVC imitates wood grain color master batch, it is made up of two kinds of components of A and B, wherein, component A includes 100 parts of polyvinyl chloride resin, 2.5~7.0 parts of heat stabilizer, 5.0~15 parts of processing aid, 0~25 part of filler, 0.5~15 part of dispersant, 0.2~5.0 part of weather resisting agent, 5.0~70 parts of pigment, by weight；
B component includes 100 parts of polyvinyl chloride resin, 2.5~7.0 parts of heat stabilizer, 5.0~15 parts of processing aid, 0~30 part of filler, 0.5~15 part of dispersant, 0.2~5.0 part of weather resisting agent, 5.0~40 parts of pigment, by weight.
Polyvinyl chloride resin in the component A is SG-1, SG-2, SG-3, SG-5, SG-7, SG-8, molecular weight are more than any of 2500 polyvinyl chloride resin；Polyvinyl chloride resin in the B component is any two the mixture in the polyvinyl chloride resin of SG-1, SG-2, SG-3, SG-5, SG-7, SG-8, molecular weight more than 2500.
The heat stabilizer is one or two kinds of mixtures in calcium zinc stabilizer, rare earth lead salt compound stabilizer, dibasic lead phosphite, tribasic lead phosphate, organic tin stabilizer.
The filler is one or more mixtures in powdered whiting, precipitated calcium carbonate, magnesium carbonate, clay, talcum powder, barium sulfate, aluminium hydroxide, magnesium hydroxide, kaolin.
The processing aid is methyl methacrylate（m）- butadiene（b）- styrene（s）Terpolymer（MBS）, acrylonitrile-butadiene-styrene copolymer（ABS）, nitrile rubber（NBR）, ethylene propylene diene rubber（POE）, acrylic acid esters co-polymer（ACR), haloflex（CPE）In at least one.
The dispersant is at least one in paraffin, PE waxes, PP waxes, vinyl bis-stearamides, stearic acid, calcium stearate, zinc stearate.
The weather resisting agent is one or two kinds of mixtures in antioxidant, ultra-violet absorber.
Above-described PVC imitates the preparation method of wood grain color master batch, comprises the following steps：
（1）Component A weighs to each raw material is prepared and high-speed stirred is well mixed by formula ratio；
（2）Well mixed component A raw material is added to granulate in double screw extruder component A particle is made, wherein processing technology is as follows：Temperature is 160 ~ 185 DEG C, 15~30rpm of rate of feeding, 30~45rpm of screw speed；
（3）B component weighs to each raw material is prepared and high-speed stirred is well mixed by formula ratio；
（4）Well mixed B component raw material is added to granulate in double screw extruder B component particle is made, wherein processing technology is as follows：Temperature is 165~205 DEG C, 15~30rpm of rate of feeding, 30~45rpm of screw speed；
A kind of preparation method of imitation wood line color PVC plastic section bar, comprises the following steps：
(1) the component A particle added in PVC plastic profile shapes, PVC plastic sheet material or Wood-plastic foam sheet material raw material in the imitative wood grain color master batches of above-described PVC, is poured into extruder hopper after stirring；
(2) B component particle is added in screw rod spout and extruded, surface, which is made, by mouth mold sizing cooling shaping after screw rod shearing melting in material the PVC plastic section bar of imitative wood grain effect；
Wherein, the mass ratio of Masterbatch and PVC plastic section bar raw material for：PVC plastic profile shapes/PVC plastic sheet material/100 parts of Wood-plastic foam sheet material raw material, 1~3 part of Masterbatch component A, 1~3 part of Masterbatch B component.Preferably PVC plastic profile shapes/PVC plastic sheet material/100 parts of Wood-plastic foam sheet material raw material, 1.5~2.5 parts of Masterbatch component A, 1~2 part of Masterbatch B component.
The imitation wood line color PVC plastic section bar prepared by the above method.
The beneficial effects of the invention are as follows：Wood grain color master batch is imitated using PVC of the present invention, excellent bright in luster, good weatherability, mechanical performance, wood grain svelteness, wood grain effect true to nature are formed in the products such as the hard PVC section bar, PVC door and windows, PVC board of different formulations system.
Brief description of the drawings
Fig. 1 is the flow sheet of PVC wood grain Masterbatch component A；
Fig. 2 is the flow sheet of PVC wood grain Masterbatch B component；
Fig. 3 is the PVC profile flow sheet of addition component A and B component；
Fig. 4 is the design sketch for the wood-grain imitating PVC section bar that embodiment 1 is prepared；
Fig. 5 is the design sketch for the wood-grain imitating PVC section bar that embodiment 2 is prepared；
Fig. 6 is the design sketch for the wood-grain imitating PVC section bar that embodiment 3 is prepared；
Fig. 7 is the design sketch for the wood-grain imitating PVC section bar that embodiment 4 is prepared.
Embodiment
With reference to embodiment, the present invention is further illustrated, but is not limited thereto.Unless otherwise specified, " part " in following examples refers both to " mass parts ".
Embodiment 1
Prepared according to parts by weight shown in each component in table 1.
The Masterbatch each group distribution ratio of 1 embodiment of table 1（Mass parts）
Title material Component A B component
PVC  SG-3 / 30
PVC  SG-7 100 70
Calcium zinc stabilizer 5.0 5.5
Haloflex 8.0 7.0
Precipitated calcium carbonate 25.0 15
ACR-401 2.0 2.0
Stearic acid 0.6 1.5
Tissuemat E 0.8 1.5
1010 0.4 0.6
UV531 0.2 0.3
Carbon black 3.0 3.5
Organic yellow 15.0 /
It is organic red 7.0 /
Iron oxide yellow / 9.0
Iron oxide red / 15.0
Preparation method：
The first step：All material is poured into homogenizer according to the parts by weight of component A in formula table and stirred, its temperature is stirred to 100 DEG C and is discharged in extruder hopper, material is granulated by melting extrusion and component A particle is made.Wherein processing technology is as follows：Temperature is 160 ~ 185 DEG C, rate of feeding 30rpm, screw speed 45rpm, as shown in Figure 1；
Second step：All material is poured into homogenizer according to the parts by weight of B component in formula table and stirred, its temperature is stirred to 110 DEG C and is discharged in extruder hopper, material is granulated by melting extrusion and B component particle is made.Wherein processing technology is as follows：Temperature is 160 ~ 185 DEG C, rate of feeding 30rpm, screw speed 45rpm, as shown in Figure 2.
Using（As shown in Figure 3）：
1st, 2 parts of component A particles are added in formula system is SG-7 or SG-8 100 parts of PVC plastic section bar or PVC plastic sheet material raw material, is poured into after stirring in extruder hopper；
2 and then 1 part of B component particle is added in screw rod spout.Material after screw rod shearing melting by mouth mold shape cooling shaping surface be made have that lines are wider, the PVC plastic section bar of wood grain clearly coffee-like wood effect, see Fig. 4.
Embodiment 2
Embodiment 2 is prepared according to parts by weight shown in each component of table 2.
The Masterbatch each group distribution ratio of 2 embodiment of table 2（Mass parts）
Title material Component A B component
PVC  SG-1 / 20
PVC  SG-5 100 80
Rare earth lead salt compound stabilizer 5.5 6.0
Haloflex 7.0 7.0
Precipitated calcium carbonate 5.0 30
ACR-401 1.5 1.5
MBS / 2.0
Stearic acid 0.8 2.0
Tissuemat E 0.8 2.0
1010 0.4 0.6
UV531 0.2 0.3
Carbon black 3.0 1.5
Organic yellow 20 /
It is organic red 5.0 /
Iron oxide yellow / 5.0
Iron oxide red / 5.0
Preparation method：
The first step：All material is poured into homogenizer according to the parts by weight of component A in formula table and stirred, its temperature is stirred to 100 DEG C and is discharged in extruder hopper, material is granulated by melting extrusion and component A particle is made.Wherein processing technology is as follows：Temperature is 170 ~ 185 DEG C, rate of feeding 30rpm, screw speed 45rpm；
Second step：All material is poured into homogenizer according to the parts by weight of B component in formula table and stirred, its temperature is stirred to 110 DEG C and is discharged in extruder hopper, material is granulated by melting extrusion and B component particle is made.Wherein processing technology is as follows：Temperature is 170 ~ 190 DEG C, rate of feeding 30rpm, screw speed 45rpm.
Using：
1st, 2 parts of component A particles are added in 100 parts of high filled PVC section bar or Wood-plastic foam sheet material raw material that the PVC plastic section bar for being SG-5 in formula system or formula are SG-7, are poured into after stirring in extruder hopper；
2 and then the B component particle of 1 parts by weight is added in the specific spout of screw rod.Material is made surface and has lines fine and smooth after screw rod shearing melting by mouth mold cooling shaping of shaping, the PVC plastic section bar of wood grain clearly red English walnut wood effect, sees Fig. 5.
Embodiment 3
Embodiment 3 is prepared according to parts by weight shown in each component of table 3
The Masterbatch each group distribution ratio of 3 embodiment of table 3（Mass parts）
Title material Component A B component
2500-PVC of macromolecule / 15
PVC  SG-5 100 85
Calcium zinc stabilizer 5.5 6.0
Haloflex 8.0 7.0
Precipitated calcium carbonate 5.0 8.0
MBS / 2.0
Stearic acid 0.8 2.0
Tissuemat E 0.8 2.0
1010 0.4 0.6
UV531 0.2 0.3
Carbon black 2.5 7.0
Organic yellow 8 /
It is organic red 4.0 /
Iron oxide yellow / 5.0
Iron oxide red / 2.0
Preparation method：
All material is poured into homogenizer and stirred by the first step according to the parts by weight of component A in formula table, and its temperature is stirred to 100 DEG C and is discharged in extruder hopper, and material is granulated by melting extrusion and component A particle is made.Wherein processing technology is as follows：Temperature is 170 ~ 190 DEG C, rate of feeding 30rpm, screw speed 45rpm；
All material is poured into homogenizer and stirred by second step according to the parts by weight of B component in formula table, and its temperature is stirred to 110 DEG C and is discharged in extruder hopper, and material is granulated by melting extrusion and B component particle is made.Wherein processing technology is as follows：Temperature is 170 ~ 195 DEG C, rate of feeding 30rpm, screw speed 45rpm.
Using：
1st, 2 parts of component A particle is added in formula system is 100 parts of superelevation filled PVC plastic irregular profile or Wood-plastic foam sheet material raw material, is poured into after stirring in extruder hopper；
2 and then 1 part of B component particle is added in the specific spout of screw rod.Material is made surface and forms that lines are fine and smooth after screw rod shearing melting by mouth mold cooling shaping of shaping, the PVC plastic section bar of wood grain clearly black walnut wood effect, sees Fig. 6.
Embodiment 4
Embodiment 4 is prepared according to parts by weight shown in each component of table 4
The Masterbatch each group distribution ratio of 4 embodiment of table 4（Mass parts）
Title material Component A B component
PVC  SG-3 / 25
PVC  SG-8 100 75
Calcium zinc stabilizer 5.5 6.0
Haloflex 8.0 7.0
Precipitated calcium carbonate 5.0 8.0
MBS / 2.0
Stearic acid 0.8 2.0
Paraffin 0.8 2.0
1010 0.4 0.6
UV531 0.2 0.3
Carbon black 3.5 8.0
Organic yellow 15.0 /
It is organic red 10.0 /
Iron oxide yellow / 8.0
Iron oxide red / 2.0
Preparation method：
All material is poured into homogenizer and stirred by the first step according to the parts by weight of component A in formula table, and its temperature is stirred to 100 DEG C and is discharged in extruder hopper, and material is granulated by melting extrusion and component A particle is made.Wherein processing technology is as follows：Temperature is 170 ~ 190 DEG C, rate of feeding 30rpm, screw speed 45rpm；
All material is poured into homogenizer and stirred by second step according to the parts by weight of B component in formula table, and its temperature is stirred to 110 DEG C and is discharged in extruder hopper, and material is granulated by melting extrusion and B component particle is made.Wherein processing technology is as follows：Temperature is 170 ~ 195 DEG C, rate of feeding 30rpm, screw speed 45rpm.
Using：
1 adds 2 parts of component A particle in formula system is 100 parts of superelevation filled PVC plastic irregular profile or Wood-plastic foam sheet material raw material, is poured into after stirring in extruder hopper；
2 and then 1 part of B component particle is added in the specific spout of screw rod.Material is made surface and forms that lines are fine and smooth after screw rod shearing melting by mouth mold cooling shaping of shaping, the PVC plastic section bar of wood grain clearly black walnut wood effect, sees Fig. 7.
Wood-grain imitating PVC section bar prepared by embodiment 1 ~ 4, excellent physical properties, weather resistance is good, and outward appearance is beautiful, with good practicality and appreciating.
Above example is only to introduce the preferred case of the present invention, to those skilled in the art, and any obvious changes and improvements carried out in the scope without departing substantially from spirit of the present invention are regarded as the part of the present invention.

Claims (10)

1. a kind of PVC imitates wood grain color master batch, it is made up of two kinds of components of A and B, wherein, component A includes 100 parts of polyvinyl chloride resin, 2.5~7.0 parts of heat stabilizer, 5.0~15 parts of processing aid, 0~25 part of filler, 0.5~15 part of dispersant, 0.2~5.0 part of weather resisting agent, 5.0~70 parts of pigment, by weight；
B component includes 100 parts of polyvinyl chloride resin, 2.5~7.0 parts of heat stabilizer, 5.0~15 parts of processing aid, 0~30 part of filler, 0.5~15 part of dispersant, 0.2~5.0 part of weather resisting agent, 5.0~40 parts of pigment, by weight.
2. PVC according to claim 1 imitates wood grain color master batch, it is characterised in that the polyvinyl chloride resin in the component A is SG-1, SG-2, SG-3, SG-5, SG-7, SG-8, molecular weight are more than any of 2500 polyvinyl chloride resin；Polyvinyl chloride resin in the B component is any two the mixture in the polyvinyl chloride resin of SG-1, SG-2, SG-3, SG-5, SG-7, SG-8, molecular weight more than 2500.
3. PVC according to claim 1 imitates wood grain color master batch, it is characterised in that the heat stabilizer is one or two kinds of mixtures in calcium zinc stabilizer, rare earth lead salt compound stabilizer, dibasic lead phosphite, tribasic lead phosphate, organic tin stabilizer.
4. PVC according to claim 1 imitates wood grain color master batch, characterized in that, the filler is one or more mixtures in powdered whiting, precipitated calcium carbonate, magnesium carbonate, clay, talcum powder, barium sulfate, aluminium hydroxide, magnesium hydroxide, kaolin.
5. PVC according to claim 1 imitates wood grain color master batch, it is characterised in that the processing aid is methyl methacrylate（m）- butadiene（b）- styrene（s）Terpolymer, acrylonitrile-butadiene-styrene copolymer, nitrile rubber, ethylene propylene diene rubber, acrylic acid esters co-polymer, at least one in haloflex.
6. PVC according to claim 1 imitates wood grain color master batch, it is characterised in that the dispersant is at least one in paraffin, PE waxes, PP waxes, vinyl bis-stearamides, stearic acid, calcium stearate, zinc stearate.
7. PVC according to claim 1 imitates wood grain color master batch, it is characterised in that the weather resisting agent is one or two kinds of mixtures in antioxidant, ultra-violet absorber.
8. the PVC described in any one of claim 1~7 imitates the preparation method of wood grain color master batch, comprise the following steps：
（1）Component A weighs to each raw material is prepared and high-speed stirred is well mixed by formula ratio；
（2）Well mixed component A raw material is added to granulate in double screw extruder component A particle is made, wherein processing technology is as follows：Temperature is 160 ~ 185 DEG C, 15~30rpm of rate of feeding, 30~45rpm of screw speed；
（3）B component weighs to each raw material is prepared and high-speed stirred is well mixed by formula ratio；
（4）Well mixed B component raw material is added to granulate in double screw extruder B component particle is made, wherein processing technology is as follows：Temperature is 165~205 DEG C, 15~30rpm of rate of feeding, 30~45rpm of screw speed.
9. a kind of preparation method of imitation wood line color PVC plastic section bar, comprises the following steps：
(1) the component A particle added in PVC plastic profile shapes, PVC plastic sheet material or Wood-plastic foam sheet material raw material in the imitative wood grain color master batches of the PVC described in any one of claim 1~8, is poured into extruder hopper after stirring；
(2) B component particle is added in screw rod spout and extruded, surface, which is made, by mouth mold sizing cooling shaping after screw rod shearing melting in material the PVC plastic section bar of imitative wood grain effect；
Wherein, the mass ratio of Masterbatch and PVC plastic section bar raw material for：PVC plastic profile shapes/PVC plastic sheet material/100 parts of Wood-plastic foam sheet material raw material, 1~3 part of Masterbatch component A, 1~3 part of Masterbatch B component.
10. the imitation wood line color PVC plastic section bar prepared by claim 9.
CN2013102276276A 2013-06-08 2013-06-08 PVC (polyvinyl chloride) wood-like grain master batch and application thereof Pending CN103289236A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1074650A (en) * 1993-01-05 1993-07-28 张鸿雁 A kind of simulative synthetic wood and manufacture method thereof that natural wood veins is arranged
CN1403500A (en) * 2002-10-06 2003-03-19 杨中龙 Mixed and extruded wood grain-imitating plastic-steel shapes and the production process
CN101492987A (en) * 2009-03-05 2009-07-29 华之杰塑料建材有限公司 Weather resistant wood-grain imitating PVC plastic profiled bar and method for manufacturing same
CN101701097A (en) * 2009-09-16 2010-05-05 居泽林 Formula of color polyvinyl chloride (PVC) section and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3464595B2 (en) * 1997-08-06 2003-11-10 信越化学工業株式会社 Vinyl chloride resin composition for molded articles with wood pattern
CN101885885B (en) * 2010-07-20 2012-05-16 广州市波斯塑胶颜料有限公司 Color master batch for hard PVC and preparation method thereof
CN103131119A (en) * 2013-01-31 2013-06-05 杜县南 Color master batch and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1074650A (en) * 1993-01-05 1993-07-28 张鸿雁 A kind of simulative synthetic wood and manufacture method thereof that natural wood veins is arranged
CN1403500A (en) * 2002-10-06 2003-03-19 杨中龙 Mixed and extruded wood grain-imitating plastic-steel shapes and the production process
CN101492987A (en) * 2009-03-05 2009-07-29 华之杰塑料建材有限公司 Weather resistant wood-grain imitating PVC plastic profiled bar and method for manufacturing same
CN101701097A (en) * 2009-09-16 2010-05-05 居泽林 Formula of color polyvinyl chloride (PVC) section and preparation method thereof

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