CN103288496A - Quick-acting amino acid molybdenum fertilizer - Google Patents

Quick-acting amino acid molybdenum fertilizer Download PDF

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Publication number
CN103288496A
CN103288496A CN2013101743670A CN201310174367A CN103288496A CN 103288496 A CN103288496 A CN 103288496A CN 2013101743670 A CN2013101743670 A CN 2013101743670A CN 201310174367 A CN201310174367 A CN 201310174367A CN 103288496 A CN103288496 A CN 103288496A
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amino acid
quick
molecular weight
molydbenum
press
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CN2013101743670A
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Inventor
杨文杰
徐建明
单宏业
周颖
张旭娟
宋丹丹
贺倩
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Huaiyin Normal University
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Huaiyin Normal University
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Priority to CN2013101743670A priority Critical patent/CN103288496A/en
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Abstract

The invention discloses a quick-acting amino acid molybdenum fertilizer, wherein a complexing reaction is generated on molybdenic acid and amino acid with equal mol dosage at normal temperature and normal pressure, and the reactant serves as the quick-acting amino acid molybdenum fertilizer of crops. The amino acid molybdenum fertilizer has the characteristics of being conveniently used and easily absorbed by plants, thereby being capable of greatly improving the root activity of the crops and the contents of chlorophyll and protein, promoting the growth and development of the crops and effectively improving the yield and quality of the crops.

Description

Quick-acting amino acid molydbenum fertilizers
Technical field
The present invention relates to crop fertilizer, be specifically related to a kind of quick-acting amino acid molydbenum fertilizer.
Background technology
Molybdenum has direct or indirect influence as the minimum micronutrient element of a kind of requirement for the many physiological processs in the plant vital activity and resistance.As enzyme co-factor important in the plant materialss such as nitrate reductase, for the absorption of nitrogen, assimilation and very important effect is fixedly arranged.Exploitation efficient water soluble organic molydbenum fertilizer is studied rational fertilizing method, to promoting crop root to the absorption of macroelement such as nitrogen, phosphorus, potassium, strengthens the growing way of plant, promotes photosynthesis, and the yield and quality that improves crop has very important meaning.
Summary of the invention
The objective of the invention is to: a kind of quick-acting amino acid molydbenum fertilizer is provided, and employing is converted the waterleaf face and is sprayed, and is beneficial to crop to absorption and the transhipment of molybdenum, promotes growing of crop, improves the yield and quality of crop.
Technical solution of the present invention is: it carries out coordination reaction at normal temperatures and pressures by equimolar molybdic acid and amino acid, it is characterized in that: its reaction product is as the quick-acting amino acid molydbenum fertilizers of crop; The effective molybdenum mass content of amino acid molydbenum fertilizer is 0.5%; The working concentration of amino acid molydbenum fertilizer is effective molybdenum 0.5-1.0mg/kg, adopts to convert the waterleaf face and spray and apply fertilizer.
Wherein, amino acid is L-Ala, L-glutamic acid, glycine, aspartic acid or l-asparagine.
Wherein, the compound method of quick-acting amino acid molydbenum fertilizers is: add the 179.97g molybdic acid of pressing molecular weight calculating and press the 75.07g glycine that molecular weight calculates in 2L water, or press the 89.09g L-Ala that molecular weight calculates, or press the 147.13g L-glutamic acid that molecular weight calculates, or press the 133.10 g aspartic acids that molecular weight calculates, or press the 132.12 g l-asparagines that molecular weight calculates, by coordination reaction preparation amino acid molydbenum fertilizer aqua.
Amino acid molydbenum fertilizer of the present invention have conveniently use, easily by characteristics such as plant absorbing, can significantly improve root system vigor and chlorophyll and the Protein content of crop, promote growing of crop, effectively improve the yield and quality of crop.
Embodiment
Further specify technical solution of the present invention below in conjunction with specific embodiment, these embodiment can not be interpreted as it is restriction to technical scheme.
Embodiment 1: add the 179.97g molybdic acid of pressing molecular weight calculating and press the 75.07g glycine that molecular weight calculates in 2L water, get the organic molydbenum fertilizer of aqua after coordination reaction finishes.
Embodiment 2: add the 179.97g molybdic acid of pressing molecular weight calculating and press the 89.09g L-Ala that molecular weight calculates in 2L water, get the organic molydbenum fertilizer of aqua after coordination reaction finishes.
Embodiment 3: add the 179.97g molybdic acid of pressing molecular weight calculating and press the 147.13g L-glutamic acid that molecular weight calculates in 2L water, get the organic molydbenum fertilizer of aqua after coordination reaction finishes.
Embodiment 4: add the 179.97g molybdic acid of pressing molecular weight calculating and press the 133.10 g aspartic acids that molecular weight calculates in 2L water, get the organic molydbenum fertilizer of aqua after coordination reaction finishes.
Embodiment 5: add the 179.97g molybdic acid of pressing molecular weight calculating and press the 132.12 g l-asparagines that molecular weight calculates in 2L water, get the organic molydbenum fertilizer of aqua after coordination reaction finishes.
Test example 1:
1. under the foliage-spray amino acid molydbenum fertilizer condition, cucumber seedling is to the absorbing state of metallic elements such as molybdenum and calcium, potassium, magnesium.
2. for examination fertilizer: the quick-acting amino acid molydbenum fertilizers of effective molybdenum content 0.5% of the present invention.
3. grind No. 8 in cucumber seeds Tianjin
4. experimental technique: with deionized water rinsing repeatedly, then, seed is bound up with gauze behind the 1% clorox sterilization 30min, put in the clear water and soaked 3-4 hour, place 50-55 degree warm water to soak again 15 minutes; Place 25 ℃ of following vernalization 3d, select seed of the same size then, change in the incomplete Hoagland nutritive medium that does not contain molybdenum, in growth cabinet, cultivate, (12h/12h) round the clock, temperature is 26 ℃/20 ℃, illumination 65Klx, relative humidity 70%; When treating that cucumber seedling grows to 3 leaves, 1 heart, the effective molybdenum of foliage-spray is quick-acting amino acid molybdenums, Sodium orthomolybdate and the clear water of 1.0mg/kg, and every processing repeats 3 times, detects the content of molybdenum and phosphorus in the seedling, calcium, potassium, magnesium behind the 7d, sees Table 1.
The content of molybdenum and phosphorus, calcium, potassium, magnesium (ug/gDW) in table 1. cucumber seedling
Figure 206875DEST_PATH_IMAGE002
Annotate: ABC is that 1% level is remarkable, and abc is that 5% level is remarkable.
As can be seen from Table 1, cucumber seedling is sprayed quick-acting amino acid molydbenum fertilizers, more be conducive to plant to the absorption of other nutritive elements such as molybdenum and phosphorus, calcium, potassium, magnesium.
Test example 2:
1. under the foliage-spray amino acid molydbenum fertilizer condition, effects on physiological indexes such as cucumber seedling dry weight, fresh weight, root system vigor, chlorophyll cellulose content and protein content.
2. for examination fertilizer: the quick-acting amino acid molydbenum fertilizers of effective molybdenum content 0.5% of the present invention.
3. grind No. 8 in cucumber seeds Tianjin
4. experimental technique: with deionized water rinsing repeatedly, then, seed is bound up with gauze behind the 1% clorox sterilization 30min, put in the clear water and soaked 3-4 hour, place 50-55 degree warm water to soak again 15 minutes; Place 25 ℃ of following vernalization 3d, select seed of the same size then, change in the incomplete Hoagland nutritive medium that does not contain molybdenum, in growth cabinet, cultivate, (12h/12h) round the clock, temperature is 26 ℃/20 ℃, illumination 65Klx, relative humidity 70%; When treating that cucumber seedling grows to 3 leaves, 1 heart, the effective molybdenum of foliage-spray is quick-acting amino acid molybdenums, Sodium orthomolybdate and the clear water of 1.0mg/kg, and every processing repeats 3 times, detects fresh weight, dry weight, root system vigor, chlorophyll content and the protein content of seedling behind the 7d, sees Table 2.
Part physiology index and protein content in table 2. cucumber seedling
Figure 2013101743670100002DEST_PATH_IMAGE004
Annotate: ABC is that 1% level is remarkable, and abc is that 5% level is remarkable.
By table 2 as can be seen, spray the amino acid molydbenum fertilizer in the cucumber seedling phase and can significantly improve physical signs such as root system vigor, chlorophyll content, and can effectively improve Protein content.

Claims (3)

1. quick-acting amino acid molydbenum fertilizers, it carries out coordination reaction at normal temperatures and pressures by equimolar molybdic acid and amino acid, it is characterized in that: its reaction product is as the quick-acting amino acid molydbenum fertilizers of crop; The effective molybdenum mass content of amino acid molydbenum fertilizer is 0.5%; The working concentration of amino acid molydbenum fertilizer is effective molybdenum 0.5-1.0mg/kg, adopts to convert the waterleaf face and spray and apply fertilizer.
2. quick-acting amino acid molydbenum fertilizer according to claim 1, it is characterized in that: amino acid is L-Ala, L-glutamic acid, glycine, aspartic acid or l-asparagine.
3. quick-acting amino acid molydbenum fertilizer according to claim 1, the compound method that it is characterized in that it is: add the 179.97g molybdic acid of pressing molecular weight calculating and press the 75.07g glycine that molecular weight calculates in 2L water, or press the 89.09g L-Ala that molecular weight calculates, or press the 147.13g L-glutamic acid that molecular weight calculates, or press the 133.10 g aspartic acids that molecular weight calculates, or press the 132.12 g l-asparagines that molecular weight calculates, by coordination reaction preparation amino acid molydbenum fertilizer aqua.
CN2013101743670A 2013-05-13 2013-05-13 Quick-acting amino acid molybdenum fertilizer Pending CN103288496A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104446797A (en) * 2014-12-03 2015-03-25 秦怀跃 Method for preparing amino acid fertilizer from ammonium aspartate

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1046886A (en) * 1990-01-09 1990-11-14 孙圣格 Means for leaf feeding of plants and preparation method thereof
CN1468831A (en) * 2002-07-18 2004-01-21 邵建华 Application of amino acid-trace element chelate in composite fertilizer
CN101225007A (en) * 2008-02-03 2008-07-23 武汉市科洋生物工程有限公司 Special biological fish-fertilizer for aquaculture and preparation method thereof
CN102303990A (en) * 2010-10-13 2012-01-04 四川国光农化股份有限公司 Medicinal fertilizer composition
CN102627498A (en) * 2012-04-11 2012-08-08 湖南农业大学 Fruit and vegetable flower and fruit protecting micro-fertilizer and preparation method thereof
CN102964175A (en) * 2012-11-12 2013-03-13 北京依科曼生物技术有限公司 Composite amino-acid-containing water-soluble fertilizer and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1046886A (en) * 1990-01-09 1990-11-14 孙圣格 Means for leaf feeding of plants and preparation method thereof
CN1468831A (en) * 2002-07-18 2004-01-21 邵建华 Application of amino acid-trace element chelate in composite fertilizer
CN101225007A (en) * 2008-02-03 2008-07-23 武汉市科洋生物工程有限公司 Special biological fish-fertilizer for aquaculture and preparation method thereof
CN102303990A (en) * 2010-10-13 2012-01-04 四川国光农化股份有限公司 Medicinal fertilizer composition
CN102627498A (en) * 2012-04-11 2012-08-08 湖南农业大学 Fruit and vegetable flower and fruit protecting micro-fertilizer and preparation method thereof
CN102964175A (en) * 2012-11-12 2013-03-13 北京依科曼生物技术有限公司 Composite amino-acid-containing water-soluble fertilizer and preparation method thereof

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Title
ANA MARIA V.S.V.CAVALEIRO,ET AL.: ""Molybdenum(Ⅵ)Complexation by Amino-Acids.Part1.Species in Aqueous Solution of Sodium Molybdate and L-Aspartate"", 《TRANSITION MET.CHEM.》 *
满江等: ""助邦牌氨基酸钼肥在新疆哈巴河县大豆上的试验"", 《农村科技》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104446797A (en) * 2014-12-03 2015-03-25 秦怀跃 Method for preparing amino acid fertilizer from ammonium aspartate

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Application publication date: 20130911