CN103276250A - Nickel-chromium-iron alloy seamless tube - Google Patents

Nickel-chromium-iron alloy seamless tube Download PDF

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Publication number
CN103276250A
CN103276250A CN2013101943287A CN201310194328A CN103276250A CN 103276250 A CN103276250 A CN 103276250A CN 2013101943287 A CN2013101943287 A CN 2013101943287A CN 201310194328 A CN201310194328 A CN 201310194328A CN 103276250 A CN103276250 A CN 103276250A
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China
Prior art keywords
seamless tube
blank
nichrome
pickling
chromium
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Pending
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CN2013101943287A
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Chinese (zh)
Inventor
王清明
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SUZHOU BEST METAL PRODUCTS CO Ltd
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SUZHOU BEST METAL PRODUCTS CO Ltd
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Priority to CN2013101943287A priority Critical patent/CN103276250A/en
Publication of CN103276250A publication Critical patent/CN103276250A/en
Pending legal-status Critical Current

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  • Metal Extraction Processes (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a nickel-chromium-iron alloy seamless tube. The nickel-chromium-iron alloy seamless tube is prepared from the components: nickel, copper, manganese, carbon, silicon, sulphur, chromium, aluminum and the balance of iron and is prepared from the steps of: (1) inspecting a blank firstly; (2) carrying out first acid pickling on the blank; (3) carrying out coping treatment on the blank after first acid pickling; (4) carrying out lubrication, cold drawing and rolling, degreasing by virtue of acid pickling, heat treatment, acid pickling and coping on the blank; (5) judging whether the requirements of a finished product are satisfied or not, and repeating the fourth step if the requirements are not satisfied; (6) if the requirements are satisfied, carrying out shaping, straightening, acid pickling, sizing processing and flaw detection on the blank; and (7) finally, marking and warehousing the finished product. The nickel-chromium-iron alloy seamless tube has the functions of resistance to corrosion, high temperature, strong acid and strong alkali, and is saving in cost.

Description

A kind of nichrome seamless tube
Technical field
The present invention relates to a kind of manufacturing of seamless tube, be specifically related to the nichrome seamless tube that a kind of UNS NO6601 alloy is made.
Background technology
Seamless tube is a kind of circle that hollow section, periphery do not have seam that has, and is square, the rectangle steel.Seamless tube is to make hollow billet with steel ingot or the solid pipe hole that wears long, and makes through hot rolling, cold rolling or cold group then.Seamless tube has hollow section, a large amount of pipelines as conveyance fluid, steel pipe is compared with solid steel such as round steel, when the bending resistance twisting strength is identical, weight is lighter, be a kind of economic cross-section steel, be widely used in manufacturing structure spare and mechanical component, as steel scaffolding of using in oil drill rocker, truck drive shaft, bicycle frame and the building operation etc.
At aspects such as some high temperature, the mineral acid that is mixed with impurity and organic acid (as formic acid and acetic acid), corrosive environment of sea water, general pipe can't widespread use in this environment, and maintenance cost is bigger, can't promote on a large scale.
Therefore, the seamless tube of research and develop a kind of corrosion-resistant, high temperature resistant, anti-strong acid, anti-highly basic, saving cost is problem demanding prompt solution.
Summary of the invention
The object of the present invention is to provide the nichrome seamless tube of a kind of corrosion-resistant, high temperature resistant, anti-strong acid, anti-highly basic, saving cost.
Technical scheme of the present invention is, a kind of nichrome seamless tube, described nichrome seamless tube comprises by weight percentage: nickel is 58%-63%, copper is 0.06%-0.1%, manganese is 0.6%-1%, carbon is 0.07%-0.13%, and silicon is 0.44%-0.67%, and sulphur is 0.009%-0.015%, chromium is 21%-25%, aluminium is 1%-1.7%, and the iron of surplus, and the manufacturing step of described nichrome seamless tube is:
(1) at first blank is tested,
(2) then blank is carried out the pickling first time,
(3) the good blank of the pickling first time is carried out reconditioning and handles,
(4) to blank be lubricated, cold drawing and rolling, pickling deoil, thermal treatment, pickling and reconditioning are handled,
(5) judge whether to satisfy finished product, as not being repeating step 4 then,
(6) then carry out shaping aligning, pickling, scale processing and flaw detection in this way and handle,
(7) at last finished product is identified warehouse-in.
In a preferred embodiment of the present invention, described Acidwash solution is formed by hydrofluoric acid and nitric acid hybrid modulation, and the composition of the pickle solution in the described Acidwash solution comprises that mass percent is that nitric acid and the mass percent of 11%-13% is the hydrofluoric acid of 2.3%-5.5%.
In a preferred embodiment of the present invention, described lubricant is made of butter and lime, and concrete weight ratio is butter: lime=2:8.5.
In a preferred embodiment of the present invention, the scope of the rolling technological parameter deflection of described cold drawing and rolling is 1.3%-1.5%.
In a preferred embodiment of the present invention, described heat-treatment temperature range is 940 ℃-1180 ℃.
Of the present invention is a kind of nichrome seamless tube, the function that makes the Hastelloy seamless tube have corrosion-resistant, high temperature resistant, anti-strong acid, anti-highly basic and save cost.
Description of drawings
Fig. 1 be a preferred embodiment of the present invention process flow diagram.
Embodiment
Below preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that protection scope of the present invention is made more explicit defining.
Of the present invention is a kind of nichrome seamless tube, referring to shown in Figure 1, described nichrome seamless tube comprises by weight percentage: nickel is 58%-63%, and copper is 0.06%-0.1%, and manganese is 0.6%-1%, carbon is 0.07%-0.13%, silicon is 0.44%-0.67%, and sulphur is 0.009%-0.015%, and chromium is 21%-25%, aluminium is 1%-1.7%, and the iron of surplus.
The manufacturing step of described nichrome seamless tube is:
(1) at first blank is tested,
(2) then blank is carried out the pickling first time,
(3) the good blank of the pickling first time is carried out reconditioning and handles,
(4) to blank be lubricated, cold drawing and rolling, pickling deoil, thermal treatment, pickling and reconditioning are handled,
(5) judge whether to satisfy finished product, as not being repeating step 4 then,
(6) then carry out shaping aligning, pickling, scale processing and flaw detection in this way and handle,
(7) at last finished product is identified warehouse-in.
Further specify, described Acidwash solution is formed by hydrofluoric acid and nitric acid hybrid modulation, the composition of the pickle solution in the described Acidwash solution comprises that mass percent is that nitric acid and the mass percent of 11%-13% is the hydrofluoric acid of 2.3%-5.5%, described lubricant is made of butter and lime, concrete weight ratio is butter: lime=2:8.5, the scope of the rolling technological parameter deflection of described cold drawing and rolling is 1.3%-1.5%, and described heat-treatment temperature range is 940 ℃-1180 ℃.
Further specify, in heat treatment process, can not contact sulphur, phosphorus, lead and other low melting point metal, otherwise can damage the performance of material, should note removing such as dirts such as lubricating oil, fuel.Period is at 30min, hydrofluoric acid plays the effect of deoiling enough fast and effectively and tube surface is not had the influence of turning white of any peracid; the material of thin-walled tube also can adopt quick air cooling, and the above purpose reaches desirable surperficial corrosion resistance nature and improves, improve the superior performance standard 1.1-1.2 times.
A kind of nichrome seamless tube of the present invention, the function that makes the Hastelloy seamless tube have corrosion-resistant, high temperature resistant, anti-strong acid, anti-highly basic and save cost.
The above only is the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.

Claims (5)

1. nichrome seamless tube, it is characterized in that: described nichrome seamless tube comprises by weight percentage: nickel is 58%-63%, copper is 0.06%-0.1%, and manganese is 0.6%-1%, and carbon is 0.07%-0.13%, silicon is 0.44%-0.67%, sulphur is 0.009%-0.015%, and chromium is 21%-25%, and aluminium is 1%-1.7%, and the iron of surplus, the manufacturing step of described nichrome seamless tube is:
(1) at first blank is tested,
(2) then blank is carried out the pickling first time,
(3) the good blank of the pickling first time is carried out reconditioning and handles,
(4) to blank be lubricated, cold drawing and rolling, pickling deoil, thermal treatment, pickling and reconditioning are handled,
(5) judge whether to satisfy finished product, as not being repeating step 4 then,
(6) then carry out shaping aligning, pickling, scale processing and flaw detection in this way and handle,
(7) at last finished product is identified warehouse-in.
2. nichrome seamless tube according to claim 1, it is characterized in that: described Acidwash solution is formed by hydrofluoric acid and nitric acid hybrid modulation, and the composition of the pickle solution in the described Acidwash solution comprises that mass percent is that nitric acid and the mass percent of 11%-13% is the hydrofluoric acid of 2.3%-5.5%.
3. nichrome seamless tube according to claim 1, it is characterized in that: described lubricant is made of butter and lime, and concrete weight ratio is butter: lime=2:8.5.
4. nichrome seamless tube according to claim 1, it is characterized in that: the scope of the rolling technological parameter deflection of described cold drawing and rolling is 1.3%-1.5%.
5. nichrome seamless tube according to claim 1, it is characterized in that: described heat-treatment temperature range is 940 ℃-1180 ℃.
CN2013101943287A 2013-05-23 2013-05-23 Nickel-chromium-iron alloy seamless tube Pending CN103276250A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2013101943287A CN103276250A (en) 2013-05-23 2013-05-23 Nickel-chromium-iron alloy seamless tube

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Application Number Priority Date Filing Date Title
CN2013101943287A CN103276250A (en) 2013-05-23 2013-05-23 Nickel-chromium-iron alloy seamless tube

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CN103276250A true CN103276250A (en) 2013-09-04

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104174687A (en) * 2014-07-21 2014-12-03 苏州贝思特金属制品有限公司 Production method of 15CrMo thick-wall seamless steel pipe
CN108441710A (en) * 2018-05-29 2018-08-24 丹阳市曙光镍材有限公司 A kind of preparation process of high-performance nichrome
CN108707913A (en) * 2018-05-29 2018-10-26 丹阳市曙光镍材有限公司 A kind of production technology of environmentally protective anti-explosion heater nichrome resistance wire
CN111500955A (en) * 2020-04-17 2020-08-07 抚顺特殊钢股份有限公司 Manufacturing process of N06625 alloy profiled bar for nuclear power evaporator

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000119781A (en) * 1998-10-12 2000-04-25 Kobe Steel Ltd Heat transfer tube for heat exchange, with corrosion and wear resistance, and heating furnace and incinerator using the same
CN1974816A (en) * 2006-12-08 2007-06-06 杭正奎 High temperature Ni-Cr alloy and its production process
CN102606810A (en) * 2012-03-21 2012-07-25 苏州贝思特金属制品有限公司 Manufacture method of low carbon nickel chrome molybdenum niobium alloy stainless steel seamless steel tube
CN102620062A (en) * 2012-03-21 2012-08-01 苏州贝思特金属制品有限公司 Method for manufacturing low-carbon resisto seamless stainless steel tubes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000119781A (en) * 1998-10-12 2000-04-25 Kobe Steel Ltd Heat transfer tube for heat exchange, with corrosion and wear resistance, and heating furnace and incinerator using the same
CN1974816A (en) * 2006-12-08 2007-06-06 杭正奎 High temperature Ni-Cr alloy and its production process
CN102606810A (en) * 2012-03-21 2012-07-25 苏州贝思特金属制品有限公司 Manufacture method of low carbon nickel chrome molybdenum niobium alloy stainless steel seamless steel tube
CN102620062A (en) * 2012-03-21 2012-08-01 苏州贝思特金属制品有限公司 Method for manufacturing low-carbon resisto seamless stainless steel tubes

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104174687A (en) * 2014-07-21 2014-12-03 苏州贝思特金属制品有限公司 Production method of 15CrMo thick-wall seamless steel pipe
CN108441710A (en) * 2018-05-29 2018-08-24 丹阳市曙光镍材有限公司 A kind of preparation process of high-performance nichrome
CN108707913A (en) * 2018-05-29 2018-10-26 丹阳市曙光镍材有限公司 A kind of production technology of environmentally protective anti-explosion heater nichrome resistance wire
CN111500955A (en) * 2020-04-17 2020-08-07 抚顺特殊钢股份有限公司 Manufacturing process of N06625 alloy profiled bar for nuclear power evaporator

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Application publication date: 20130904