CN103275526B - 一种含镍-锰-硅的无铬锌铝涂层防腐涂料 - Google Patents
一种含镍-锰-硅的无铬锌铝涂层防腐涂料 Download PDFInfo
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- CN103275526B CN103275526B CN201310000093.3A CN201310000093A CN103275526B CN 103275526 B CN103275526 B CN 103275526B CN 201310000093 A CN201310000093 A CN 201310000093A CN 103275526 B CN103275526 B CN 103275526B
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- coating
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- chromium
- silicon
- aluminium alloy
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- 238000000576 coating method Methods 0.000 title claims abstract description 68
- 239000011248 coating agent Substances 0.000 title claims abstract description 62
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 29
- 229910052804 chromium Inorganic materials 0.000 title claims abstract description 27
- 239000011651 chromium Substances 0.000 title claims abstract description 27
- 230000001681 protective effect Effects 0.000 title claims abstract description 20
- 239000010703 silicon Substances 0.000 title claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 29
- 229910000611 Zinc aluminium Inorganic materials 0.000 claims abstract description 28
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 26
- 239000000956 alloy Substances 0.000 claims abstract description 26
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 18
- 239000011701 zinc Substances 0.000 claims abstract description 15
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 13
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 13
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims description 9
- 239000012535 impurity Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 22
- 239000008367 deionised water Substances 0.000 abstract description 21
- 229910021641 deionized water Inorganic materials 0.000 abstract description 21
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Diphosphoinositol tetrakisphosphate Chemical compound OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 abstract description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 20
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 abstract description 20
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 abstract description 10
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract description 10
- 239000012964 benzotriazole Substances 0.000 abstract description 10
- 229950002895 cellaburate Drugs 0.000 abstract description 10
- 229920005552 sodium lignosulfonate Polymers 0.000 abstract description 10
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 abstract description 10
- OMQSJNWFFJOIMO-UHFFFAOYSA-J zirconium tetrafluoride Chemical compound F[Zr](F)(F)F OMQSJNWFFJOIMO-UHFFFAOYSA-J 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- -1 cellaburate Chemical compound 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 12
- 238000005260 corrosion Methods 0.000 description 11
- 239000003973 paint Substances 0.000 description 11
- 230000007797 corrosion Effects 0.000 description 10
- DQIPXGFHRRCVHY-UHFFFAOYSA-N chromium zinc Chemical compound [Cr].[Zn] DQIPXGFHRRCVHY-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 230000035939 shock Effects 0.000 description 5
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000036952 cancer formation Effects 0.000 description 1
- 231100000504 carcinogenesis Toxicity 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 229910001430 chromium ion Inorganic materials 0.000 description 1
- 239000006255 coating slurry Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- XUIMIQQOPSSXEZ-OUBTZVSYSA-N silicon-29 atom Chemical compound [29Si] XUIMIQQOPSSXEZ-OUBTZVSYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-NJFSPNSNSA-N silicon-30 atom Chemical compound [30Si] XUIMIQQOPSSXEZ-NJFSPNSNSA-N 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
中性盐雾腐蚀寿命 | 300℃耐湿热性寿命 | 涂层耐冲击性 | 硝酸铵快速腐蚀寿命 | |
实施例1 | 大于1400小时 | 大于240小时 | 50N | 大于9小时 |
实施例2 | 大于1200小时 | 大于200小时 | 50N | 大于8小时 |
实施例3 | 大于1200小时 | 大于200小时 | 50N | 大于8小时 |
实施例4 | 大于1200小时 | 大于200小时 | 50N | 大于8小时 |
实施例5 | 大于1200小时 | 大于200小时 | 50N | 大于8小时 |
Claims (1)
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CN201310000093.3A CN103275526B (zh) | 2013-01-03 | 2013-01-03 | 一种含镍-锰-硅的无铬锌铝涂层防腐涂料 |
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CN201310000093.3A CN103275526B (zh) | 2013-01-03 | 2013-01-03 | 一种含镍-锰-硅的无铬锌铝涂层防腐涂料 |
Publications (2)
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CN103275526A CN103275526A (zh) | 2013-09-04 |
CN103275526B true CN103275526B (zh) | 2015-12-02 |
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CN108410334A (zh) * | 2018-02-07 | 2018-08-17 | 兰州理工大学 | 一种铝合金表面涂层 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101338091A (zh) * | 2008-08-15 | 2009-01-07 | 上海达克罗涂复工业有限公司 | 无铬金属防腐涂料、制备方法及使用方法 |
CN102070926A (zh) * | 2010-11-04 | 2011-05-25 | 江苏麟龙新材料股份有限公司 | 含稀土-钛-锰的耐海洋气候防腐处理用的涂料 |
CN102199372A (zh) * | 2011-04-12 | 2011-09-28 | 合肥云荣机电科技有限公司 | 用于多晶硅铸锭炉的石墨烯- La2Ti2O7/锌-铝-锆系耐腐蚀涂层 |
CN102277022A (zh) * | 2011-08-17 | 2011-12-14 | 南京工业大学 | 一种水性无铬达克罗涂液及其制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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AU2003216511A1 (en) * | 2002-03-05 | 2003-09-22 | Chemnova Technologies, Inc. | Surface base-coat formulation for metal alloys |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101338091A (zh) * | 2008-08-15 | 2009-01-07 | 上海达克罗涂复工业有限公司 | 无铬金属防腐涂料、制备方法及使用方法 |
CN102070926A (zh) * | 2010-11-04 | 2011-05-25 | 江苏麟龙新材料股份有限公司 | 含稀土-钛-锰的耐海洋气候防腐处理用的涂料 |
CN102199372A (zh) * | 2011-04-12 | 2011-09-28 | 合肥云荣机电科技有限公司 | 用于多晶硅铸锭炉的石墨烯- La2Ti2O7/锌-铝-锆系耐腐蚀涂层 |
CN102277022A (zh) * | 2011-08-17 | 2011-12-14 | 南京工业大学 | 一种水性无铬达克罗涂液及其制备方法 |
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Effective date of registration: 20151104 Address after: 312590, Zhejiang, Shaoxing province Xinchang County town of the end of the Village No. 350 Applicant after: XINCHANG COUNTY KANGHONG MACHINERY TECHNOLOGY Co.,Ltd. Address before: Fei River Road in Baohe District of Hefei city of Anhui Province Wang Ying 230051 B District No. 56 facade Applicant before: Zhang Jun |
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Inventor after: Xie Hai Inventor before: Zhang Jun |
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Denomination of invention: A chromium free zinc aluminum coating anti-corrosion coating containing nickel manganese silicon Effective date of registration: 20221026 Granted publication date: 20151202 Pledgee: Jiangsu SINOSURE technology microfinance Co.,Ltd. Pledgor: MOUMOU HOLDING GROUP Co.,Ltd. Registration number: Y2022980019559 |
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