CN103254789A

CN103254789A - Anti-rust oil employing China wood oil as base oil and preparation method thereof

Info

Publication number: CN103254789A
Application number: CN2013101316952A
Authority: CN
Inventors: 芮明功
Original assignee: MAANSHAN TUORUI METAL SURFACE TECHNOLOGY Co Ltd
Current assignee: MAANSHAN TUORUI METAL SURFACE TECHNOLOGY Co Ltd
Priority date: 2013-04-17
Filing date: 2013-04-17
Publication date: 2013-08-21

Abstract

The invention discloses anti-rust oil employing China wood oil as base oil and a preparation method thereof. The anti-rust oil comprises the components including China wood oil, zinc naphthenate, a film-forming agent, anilino-methyl ethyl silane, an antioxygen 1035, butter, nano-ceramic powder, ethyl acetate, methyl-phenoxide, diethylene glycol monoethyl ether and dibutyl phthalate. The anti-rust oil prepared by the preparation method is good in adhesive force on metal surface, fast to dry, good in salt spray resistance, environment-friendly and free of pollution. The China wood oil is adopted as the base oil; and the film-forming agent is added. Thus, the film-forming speed is fast; the surface of the anti-rust oil is not easily oxidized; the appearance of a work-piece is not easily affected; and the overall performance is good. The anti-rust oil is simple in preparation method, low in cost and suitable for large-scale production.

Description

A kind of is the slushing oil and preparation method thereof of base oil with tung oil

Technical field

The present invention relates to a kind of rush-resisting material, being specifically related to a kind of is the slushing oil and preparation method thereof of base oil with tung oil.

Background technology

Metallic corrosion is to make one of principal mode of fastening piece destruction; can cause very big loss to automobile, motorcycle and various vehicle, machinery; according to statistics; it is annual because the direct economic loss that metallic corrosion causes accounts for the 2-4% of total value of production in national economy; for avoiding corrosion, reducing the loss; people have adopted various methods, protect metal fastenings with antirust grease, are one of present modal means of defences.

Summary of the invention

The object of the present invention is to provide a kind of is the slushing oil and preparation method thereof of base oil with tung oil.

The present invention adopts following technical scheme:

Be the slushing oil of base oil with tung oil, the weight part of its constitutive material is: tung oil 78-85, zinc naphthenate 4.5-5.5, membrane-forming agent 8.0-9.0, anilinomethyl triethoxysilane 1.2-1.5, oxidation inhibitor 1035 0.5-0.7, butter 3.0-4.0, nano-ceramic powder 1.5-2.5, ethyl acetate 3.5-5.5, methyl-phenoxide 4.0-5.0, diethylene glycol monoethyl ether 12-15 and dibutyl phthalate 13-18.

Be the slushing oil of base oil with tung oil, the weight part of its constitutive material is: tung oil 82, zinc naphthenate 5.0, membrane-forming agent 8.5, anilinomethyl triethoxysilane 1.4, oxidation inhibitor 1,035 0.6, butter 3.5, nano-ceramic powder 2.0, ethyl acetate 4.5, methyl-phenoxide 4.5, diethylene glycol monoethyl ether 13 and dibutyl phthalate 15.

Be the preparation method of the slushing oil of base oil with tung oil, may further comprise the steps:

(1) measures tung oil by the weight part of constitutive material, add heated and stirred in the reactor, add diethylene glycol monoethyl ether during to 130-140 ℃, reaction 18-25min;

(2) in step (1), add membrane-forming agent, oxidation inhibitor 1035 and ethyl acetate, continue to stir, be cooled to 23-28 ℃;

(3) weight part by constitutive material adds other constitutive material in step (2), and continuation gets product after stirring the 2.0-3.5h filtration.

The preparation method of described membrane-forming agent is as follows:

(1) at first 18-22 part vinylbenzene, 3.5-4.5 part dimethylbenzene, 2.0-3.0 part ethylene glycol diglycidylether, 8-12 part E-12 Resins, epoxy are mixed in the adding reactor, reaction is 2-3 hour under 70-110 ℃ of temperature;

(2) in the reactor of step (1), add 15-18 part MALEIC ANHYDRIDE, 1.3-1.5 part ethyl acetate, 1-2 part vinyltrimethoxy silane, 1.5-1.8 part linking agent TAIC, mix, reaction is 3-5 hour under 50-80 ℃ of temperature condition, namely.

Beneficial effect of the present invention:

Slushing oil, the fast drying good at metallic surface sticking power of the present invention's preparation, salt spray resistance is good, and is environment friendly and pollution-free, and employing tung oil is base oil, and added membrane-forming agent, film forming speed is fast, and the slushing oil surface is difficult for oxidation, is difficult for influencing the outward appearance of workpiece, good combination property, and preparation method of the present invention is simple, and cost is low, is fit to scale operation.

Embodiment

Embodiment 1: be the slushing oil of base oil with tung oil, the weight part of its constitutive material (kg) is: tung oil 82, zinc naphthenate 5.0, membrane-forming agent 8.5, anilinomethyl triethoxysilane 1.4, oxidation inhibitor 1,035 0.6, butter 3.5, nano-ceramic powder 2.0, ethyl acetate 4.5, methyl-phenoxide 4.5, diethylene glycol monoethyl ether 13 and dibutyl phthalate 15.

(1) measures tung oil by the weight part of constitutive material, add heated and stirred in the reactor, add diethylene glycol monoethyl ether during to 135 ℃, reaction 22min;

(2) in step (1), add membrane-forming agent, oxidation inhibitor 1035 and ethyl acetate, continue to stir, be cooled to 25 ℃;

(3) weight part by constitutive material adds other constitutive material in step (2), and continuation gets product after stirring the 2.8h filtration.

The preparation method of membrane-forming agent is as follows:

(1) at first 18 parts of vinylbenzene, 4.5 parts of dimethylbenzene, 3.0 parts of ethylene glycol diglycidylethers, 8 parts of E-12 Resins, epoxy are mixed and add in the reactor, reaction is 2-3 hour under 70-110 ℃ of temperature;

(2) add 18 parts of MALEIC ANHYDRIDE, 1.5 parts of ethyl acetate, 1 part of vinyltrimethoxy silane, 1.8 parts of linking agent TAIC in the reactor of step (1), mix, reaction is 3-5 hour under 50-80 ℃ of temperature condition, namely.

The over-all properties of the slushing oil of above-described embodiment 1 preparation is as follows:

1, sticking power/level≤1 grade; 2, neutral salt spray corrosion test (h) 〉=89; 3, humid heat test (h)＞1130; 4, oil film time of drying (min) 16-18; 5, coating thickness (μ m)＜4.7; 6, ultraviolet (UV) aging test (h)＞395.

Claims

1. one kind is the slushing oil of base oil with tung oil, it is characterized in that the weight part of its constitutive material is: tung oil 78-85, zinc naphthenate 4.5-5.5, membrane-forming agent 8.0-9.0, anilinomethyl triethoxysilane 1.2-1.5, oxidation inhibitor 1035 0.5-0.7, butter 3.0-4.0, nano-ceramic powder 1.5-2.5, ethyl acetate 3.5-5.5, methyl-phenoxide 4.0-5.0, diethylene glycol monoethyl ether 12-15 and dibutyl phthalate 13-18.

2. according to claim 1 is the slushing oil of base oil with tung oil, it is characterized in that the weight part of its constitutive material is: tung oil 82, zinc naphthenate 5.0, membrane-forming agent 8.5, anilinomethyl triethoxysilane 1.4, oxidation inhibitor 1,035 0.6, butter 3.5, nano-ceramic powder 2.0, ethyl acetate 4.5, methyl-phenoxide 4.5, diethylene glycol monoethyl ether 13 and dibutyl phthalate 15.

One kind as claimed in claim 1 be the preparation method of the slushing oil of base oil with tung oil, it is characterized in that may further comprise the steps:

4. according to claim 1 is the slushing oil of base oil with tung oil, and it is characterized in that: the preparation method of described membrane-forming agent is as follows: