CN103254709A - Two-component emulsion water-in-water multi-color paint and preparation method thereof - Google Patents
Two-component emulsion water-in-water multi-color paint and preparation method thereof Download PDFInfo
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Abstract
The invention especially relates to a two-component emulsion water-in-water multi-color paint and a preparation method thereof, which belongs to the field of building and ornament materials. The two-component emulsion water-in-water multi-color paint is characterized in that the paint comprises a component I and a component II and is prepared by mixing the component I and the component II according to a ratio of 5: 4, wherein the component I is a dispersion-phase particle, and the component II is a continuous-phase aqueous emulsion paint. According to the invention, the dispersion-phase particle and the continuous-phase aqueous emulsion paint of the multi-color paint are separately prepared, and stable storage and transport performances can be obtained; the dispersion-phase particle and the continuous-phase aqueous emulsion paint are mixed in proportion to obtain a finished product before construction, so considerable disadvantages of a traditional water-in-water multi-color paint like continuous changing of the performance of the traditional water-in-water multi-color paint during the process of storage and transport are overcome, and quality stability of the multi-color paint is guaranteed.
Description
Technical field
The present invention discloses a kind of architectural decoration material field, particularly a kind of pair of component emulsion-type water bag water multicolor finish and preparation method thereof.
Background technology
Water bag water multicolor finish is very popular product innovation type in the building coating industry in recent years, and product is theoretical basis with physicochemical colloid technology and process for treating surface; Liquid aqueous resin refinement is rolled into the multiple gluey hydrate colour particle that varies in size, varies in color, and even stable suspension disperses to be in the special external phase aqueous emulsion paint, through a construction molding, and the effect of decorative patterns of the artificial granite stone material of finished product can reach the degree of mixing the spurious with the genuine; Product is form of construction work with the spraying, substitutes stone material and be widely used in decoration of exterior wall in recent years, but have environmental protection and energy saving, easy construction, durable in use, reprocess characteristics easily, development prospect is very wide; Since water bag aqueous systems store, stable bad in transportation and the construction, after when practical application, being difficult to guarantee to construct, the consistence of paint film effect, this is the major cause that limits product is promoted on a large scale.
Summary of the invention
The objective of the invention is to the color particle of the disperse phase of colorful finished product lacquer and the separately preparation of external phase aqueous emulsion paint, has stable storage transport performance, become finished product and construct again being mixed in proportion in when construction, changed traditional water bag water multi-color lacquer performance with the many shortcomings that store, transportation generation persistence changes, a kind of pair of component emulsion-type water bag water multicolor finish of the stability of assurance multi-color lacquer quality and preparation method thereof.
For realizing that the technical scheme that purpose of the present invention adopts is: a kind of pair of component emulsion-type water bag water multicolor finish is characterized in that: after comprising that component one and component two are mixed according to the ratio of 5:4, be finished product;
Described component one is the component of the color particle weight part of disperse phase:
Deionized water 25-30 part
Natvosol 0.5-1 part
Ammonium salt dispersion agent 0.5-1 part
Negatively charged ion wetting agent 0.2-0.5 part
Defoamer 0.2-0.5 part
Sanitas 0.2-0.5 part
Water-washed kaoline 8-10 part
Rutile titanium white powder 1-3 part
1250 order talcum powder 4-6 parts
PH conditioning agent 0.1-0.5 part
Ethylene glycol 0.2-0.5 part
Film coalescence aid 1-3 part
Pure acrylate elastic emulsion 25-30 part
Gel reaction agent 0.1-0.3 part
Complex protection colloidal solution A 10-15 part
Pre-molten thickening material 10-15 part;
Described component two is the component of external phase aqueous emulsion paint weight part:
Deionized water 25-30 part
Organosilicon crylic acid latex 55-60 part
Sanitas 0.2-0.5 part
Mould inhibitor 0.5-1.0 part
Ethylene glycol 2-4 part
Film coalescence aid 3-5 part
Defoamer 0.5-1 part
PH conditioning agent 0.5-1 part
Pre-molten thickening material 10-12 part.
The preparation method of described a kind of pair of component emulsion-type water bag water multicolor finish may further comprise the steps composition:
A. under whipped state, Natvosol is slowly added deionized water, observed into translucent viscous fluid in high speed dispersion 10-15 minute;
B. add ammonium salt dispersion agent, negatively charged ion wetting agent, defoamer and sanitas, and add water-washed kaoline, rutile titanium white powder and 1250 order talcum powder, high speed dispersion 20-30 minute to fineness≤60 μ m;
C. under the middling speed whipped state, add PH conditioning agent, ethylene glycol, film coalescence aid and pure acrylate elastic emulsion successively, and slowly add gel reaction agent, complex protection colloidal solution A and pre-molten thickening material;
D. base paint is mixed colours as required;
The various colored paints that E. will mix up look use churned mechanically method to carry out granulation with after complex protection colloidal solution B mixes according to the ratio of 1:1, and packing becomes component one;
F. under whipped state organosilicon crylic acid latex is slowly poured in the deionized water, slowly added organosilicon crylic acid latex, sanitas, mould inhibitor, ethylene glycol, film coalescence aid, defoamer, PH conditioning agent and pre-molten thickening material successively and mix, packing becomes component two;
G. after before construction, component one and component two being mixed according to the ratio of 5:4, be finished product; After stirring gently, can construct, mixed finished product need must be finished using at mixed 24 hours.
Described complex protection colloidal solution A is the aqueous solution of 8% protection glue.
Described complex protection colloidal solution B is the aqueous solution of 8% protection glue and 3% gel reaction agent.
The present invention has following advantage:
The present invention is with the color particle of the disperse phase of colorful finished product lacquer and the separately preparation of external phase aqueous emulsion paint, has stable storage transport performance, become finished product and construct again being mixed in proportion in when construction, change traditional water bag water multi-color lacquer performance with the many shortcomings that store, transportation generation persistence changes, guaranteed the stability of multi-color lacquer quality.
Embodiment
The present invention will be described in detail below in conjunction with specific embodiment.
Illustrated embodiments of the present invention:
A kind of pair of component emulsion-type water bag water multicolor finish is characterized in that: after comprising that component one and component two are mixed according to the ratio of 5:4, be finished product;
Described component one is the component of the color particle weight part of disperse phase:
28.0 parts of deionized waters
0.8 part of Natvosol
0.6 part of ammonium salt dispersion agent
0.2 part of negatively charged ion wetting agent
0.3 part of defoamer
Sanitas 0.2-part
9.0 parts of water-washed kaolines
2.0 parts in rutile titanium white powder
5.0 parts of 1250 order talcum powder
0.15 part of PH conditioning agent
0.2 part of ethylene glycol
1.4 parts of film coalescence aid
28.0 parts of pure acrylate elastic emulsions
0.1 part of gel reaction agent
12.0 parts of complex protection colloidal solution A
12.0 parts of pre-molten thickening materials;
Described component two is the component of external phase aqueous emulsion paint weight part:
25.25 parts of deionized waters
57.5 parts of organosilicon crylic acid latexs
0.25 part of sanitas
0.50 part of mould inhibitor
2.5 parts of ethylene glycol
3.0 parts of film coalescence aid
0.50 part of defoamer
0.50 part of PH conditioning agent
10.30 parts of pre-molten thickening materials.
The preparation method of described a kind of pair of component emulsion-type water bag water multicolor finish may further comprise the steps composition:
A. under whipped state, Natvosol is slowly added deionized water, observed into translucent viscous fluid in high speed dispersion 10-15 minute;
B. add ammonium salt dispersion agent, negatively charged ion wetting agent, defoamer and sanitas, and add water-washed kaoline, rutile titanium white powder and 1250 order talcum powder, high speed dispersion 20-30 minute to fineness≤60 μ m;
C. under the middling speed whipped state, add PH conditioning agent, ethylene glycol, film coalescence aid and pure acrylate elastic emulsion successively, and slowly add gel reaction agent, complex protection colloidal solution A and pre-molten thickening material;
D. base paint is mixed colours as required;
The various colored paints that E. will mix up look use churned mechanically method to carry out granulation with after complex protection colloidal solution B mixes according to the ratio of 1:1, and packing becomes component one;
F. under whipped state organosilicon crylic acid latex is slowly poured in the deionized water, slowly added organosilicon crylic acid latex, sanitas, mould inhibitor, ethylene glycol, film coalescence aid, defoamer, PH conditioning agent and pre-molten thickening material successively and mix, packing becomes component two;
G. after before construction, component one and component two being mixed according to the ratio of 5:4, be finished product; After stirring gently, can construct, mixed finished product need must be finished using at mixed 24 hours.
Claims (4)
1. a two component emulsion-type water bag water multicolor finish is characterized in that: after comprising that component one and component two are mixed according to the ratio of 5:4, be finished product;
Described component one is the component of the color particle weight part of disperse phase:
Deionized water 25-30 part
Natvosol 0.5-1 part
Ammonium salt dispersion agent 0.5-1 part
Negatively charged ion wetting agent 0.2-0.5 part
Defoamer 0.2-0.5 part
Sanitas 0.2-0.5 part
Water-washed kaoline 8-10 part
Rutile titanium white powder 1-3 part
1250 order talcum powder 4-6 parts
PH conditioning agent 0.1-0.5 part
Ethylene glycol 0.2-0.5 part
Film coalescence aid 1-3 part
Pure acrylate elastic emulsion 25-30 part
Gel reaction agent 0.1-0.3 part
Complex protection colloidal solution A 10-15 part
Pre-molten thickening material 10-15 part;
Described component two is the component of external phase aqueous emulsion paint weight part:
Deionized water 25-30 part
Organosilicon crylic acid latex 55-60 part
Sanitas 0.2-0.5 part
Mould inhibitor 0.5-1.0 part
Ethylene glycol 2-4 part
Film coalescence aid 3-5 part
Defoamer 0.5-1 part
PH conditioning agent 0.5-1 part
Pre-molten thickening material 10-12 part.
2. the preparation method of above-mentioned a kind of pair of component emulsion-type water bag water multicolor finish, it is characterized in that: described this method may further comprise the steps composition:
A. under whipped state, Natvosol is slowly added deionized water, disperse to observe in 10-15 minute translucent viscous fluid;
B. add ammonium salt dispersion agent, negatively charged ion wetting agent, defoamer and sanitas, and add water-washed kaoline, rutile titanium white powder and 1250 order talcum powder, high speed dispersion 20-30 minute to fineness≤60 μ m;
C. under whipped state, add PH conditioning agent, ethylene glycol, film coalescence aid and pure acrylate elastic emulsion successively, and slowly add gel reaction agent, complex protection colloidal solution A and pre-molten thickening material;
D. base paint is mixed colours as required;
The various colored paints that E. will mix up look use churned mechanically method to carry out granulation with after complex protection colloidal solution B mixes according to the ratio of 1:1, and packing becomes component one;
F. under whipped state organosilicon crylic acid latex is slowly poured in the deionized water, slowly added organosilicon crylic acid latex, sanitas, mould inhibitor, ethylene glycol, film coalescence aid, defoamer, PH conditioning agent and pre-molten thickening material successively and mix, packing becomes component two;
G. after before construction, component one and component two being mixed according to the ratio of 5:4, be finished product; After stirring gently, can construct, mixed finished product need must be finished using at mixed 24 hours.
3. a kind of crowd of preparation method who scrapes type water bag water multicolor finish according to claim 2 is characterized in that: described complex protection colloidal solution A is the aqueous solution of 8% protection glue.
4. a kind of crowd of preparation method who scrapes type water bag water multicolor finish according to claim 2 is characterized in that: described complex protection colloidal solution B is the aqueous solution of 8% protection glue and 3% gel reaction agent.
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| CN201310124675.2A CN103254709B (en) | 2013-04-11 | 2013-04-11 | A kind of Two-component emulsion water-in-water multi-color paint and preparation method thereof |
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| CN201310124675.2A CN103254709B (en) | 2013-04-11 | 2013-04-11 | A kind of Two-component emulsion water-in-water multi-color paint and preparation method thereof |
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| CN103254709A true CN103254709A (en) | 2013-08-21 |
| CN103254709B CN103254709B (en) | 2016-12-28 |
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| CN103773099A (en) * | 2014-01-23 | 2014-05-07 | 广州市诚美涂饰工程有限公司 | Colorful basic paint and preparation method thereof |
| CN103952051A (en) * | 2014-05-22 | 2014-07-30 | 富思特新材料科技发展股份有限公司 | Internally-crosslinked multicolor paint and preparation method thereof |
| CN103965724A (en) * | 2014-04-28 | 2014-08-06 | 长沙拼牌涂料有限公司 | Weather-proof and easy-to-clean finishing coat composition |
| CN104046184A (en) * | 2014-05-23 | 2014-09-17 | 芜湖朗润新材料有限公司 | Aqueous slice multi-color paint |
| CN104087103A (en) * | 2014-07-14 | 2014-10-08 | 西北永新涂料有限公司 | Liquid aqueous multi-color granite coating and preparation method thereof |
| CN104194501A (en) * | 2014-09-19 | 2014-12-10 | 苏州洛特兰新材料科技有限公司 | Colorful oil-water emulsion coating |
| CN104194457A (en) * | 2014-08-29 | 2014-12-10 | 亚士漆(上海)有限公司 | Toning base paint for sand-wall multicolor coating, and sand-wall multicolor coating and preparation method thereof |
| CN104212288A (en) * | 2014-09-04 | 2014-12-17 | 山东秦恒科技有限公司 | Water-based colourful building coating and preparation method thereof |
| CN104231759A (en) * | 2014-09-19 | 2014-12-24 | 苏州洛特兰新材料科技有限公司 | Colorful quick-drying nitrocellulose paint |
| CN104250521A (en) * | 2013-06-25 | 2014-12-31 | 东莞市长佑涂料有限公司 | Granite multicolor paint and preparation method thereof |
| CN104263168A (en) * | 2014-07-16 | 2015-01-07 | 宿州众力融创新型建材有限公司 | Water-in-water multicolor paint and preparation method thereof |
| CN104293055A (en) * | 2014-09-30 | 2015-01-21 | 陈潮汉 | Aqueous brushing type colorful paint and preparation method thereof |
| CN104761966A (en) * | 2014-01-07 | 2015-07-08 | 天津恒圣迦南建筑材料有限公司 | Lime-based granite imitation coating material |
| CN104761967A (en) * | 2015-03-10 | 2015-07-08 | 安徽省贝安居建筑节能材料科技有限公司 | W/W sand brick-containing rock coating |
| CN104818617A (en) * | 2015-05-11 | 2015-08-05 | 湖州金特莱丝织有限公司 | Novel fabric coating |
| CN104817916A (en) * | 2015-05-07 | 2015-08-05 | 烟台安家丽涂料科技有限公司 | Water-in-water colorful paint and preparation method thereof |
| CN104974603A (en) * | 2015-08-03 | 2015-10-14 | 苏州舒而适纺织新材料科技有限公司 | External wall multicolor paint |
| CN106433472A (en) * | 2016-11-02 | 2017-02-22 | 亚士漆(上海)有限公司 | Novel waterborne water-in-water multi-color coating and method for preparing same |
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| CN107699078A (en) * | 2017-10-12 | 2018-02-16 | 广东华兹卜新材料科技有限公司 | A kind of gel-type water-in-water multicolor coating and preparation method thereof |
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| CN104250521A (en) * | 2013-06-25 | 2014-12-31 | 东莞市长佑涂料有限公司 | Granite multicolor paint and preparation method thereof |
| CN104761966A (en) * | 2014-01-07 | 2015-07-08 | 天津恒圣迦南建筑材料有限公司 | Lime-based granite imitation coating material |
| CN103773099A (en) * | 2014-01-23 | 2014-05-07 | 广州市诚美涂饰工程有限公司 | Colorful basic paint and preparation method thereof |
| CN103965724A (en) * | 2014-04-28 | 2014-08-06 | 长沙拼牌涂料有限公司 | Weather-proof and easy-to-clean finishing coat composition |
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| CN104046184A (en) * | 2014-05-23 | 2014-09-17 | 芜湖朗润新材料有限公司 | Aqueous slice multi-color paint |
| CN104046184B (en) * | 2014-05-23 | 2016-04-13 | 芜湖朗润新材料有限公司 | Water-based sliver multi-color lacquer |
| CN104087103A (en) * | 2014-07-14 | 2014-10-08 | 西北永新涂料有限公司 | Liquid aqueous multi-color granite coating and preparation method thereof |
| CN104263168A (en) * | 2014-07-16 | 2015-01-07 | 宿州众力融创新型建材有限公司 | Water-in-water multicolor paint and preparation method thereof |
| CN104194457A (en) * | 2014-08-29 | 2014-12-10 | 亚士漆(上海)有限公司 | Toning base paint for sand-wall multicolor coating, and sand-wall multicolor coating and preparation method thereof |
| CN104212288A (en) * | 2014-09-04 | 2014-12-17 | 山东秦恒科技有限公司 | Water-based colourful building coating and preparation method thereof |
| CN104231759B (en) * | 2014-09-19 | 2016-06-29 | 苏州洛特兰新材料科技有限公司 | A kind of quick-drying nitrocellulose multicolor finish |
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| CN106433472B (en) * | 2016-11-02 | 2018-12-14 | 亚士漆(上海)有限公司 | Novel aqueous water-in-water multicolor coating and preparation method thereof |
| CN106433472A (en) * | 2016-11-02 | 2017-02-22 | 亚士漆(上海)有限公司 | Novel waterborne water-in-water multi-color coating and method for preparing same |
| CN106883697A (en) * | 2017-02-27 | 2017-06-23 | 河北晨阳工贸集团有限公司 | A kind of dumb light water-in-water multicolor coating |
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Effective date of registration: 20220111 Address after: 071300 East District of Boye Economic Development Zone, Baoding City, Hebei Province Patentee after: Hebei sankeshu coating Co.,Ltd. Address before: 518 No. 351100 Putian province Fujian City Licheng Liyuan Road North Patentee before: SKSHU PAINT Co.,Ltd. |
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