CN103242737B - 一种海洋重防腐环氧富铝锰稀土纳米涂料及其制备方法 - Google Patents
一种海洋重防腐环氧富铝锰稀土纳米涂料及其制备方法 Download PDFInfo
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- CN103242737B CN103242737B CN201310187500.6A CN201310187500A CN103242737B CN 103242737 B CN103242737 B CN 103242737B CN 201310187500 A CN201310187500 A CN 201310187500A CN 103242737 B CN103242737 B CN 103242737B
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 40
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 37
- 239000004411 aluminium Substances 0.000 title claims abstract description 35
- 239000004593 Epoxy Substances 0.000 title claims abstract description 30
- 239000002103 nanocoating Substances 0.000 title claims abstract description 20
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 20
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000005260 corrosion Methods 0.000 title abstract description 25
- 229910052748 manganese Inorganic materials 0.000 title abstract description 3
- 239000011572 manganese Substances 0.000 title abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 73
- 238000000576 coating method Methods 0.000 claims abstract description 55
- 239000011248 coating agent Substances 0.000 claims abstract description 50
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 40
- 239000002904 solvent Substances 0.000 claims abstract description 40
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000003822 epoxy resin Substances 0.000 claims abstract description 23
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 23
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 17
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims description 26
- -1 aluminium manganese rare earth Chemical class 0.000 claims description 24
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 17
- 230000003260 anti-sepsis Effects 0.000 claims description 17
- JOLVYUIAMRUBRK-UHFFFAOYSA-N 11',12',14',15'-Tetradehydro(Z,Z-)-3-(8-Pentadecenyl)phenol Natural products OC1=CC=CC(CCCCCCCC=CCC=CCC=C)=C1 JOLVYUIAMRUBRK-UHFFFAOYSA-N 0.000 claims description 15
- YLKVIMNNMLKUGJ-UHFFFAOYSA-N 3-Delta8-pentadecenylphenol Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1 YLKVIMNNMLKUGJ-UHFFFAOYSA-N 0.000 claims description 15
- JOLVYUIAMRUBRK-UTOQUPLUSA-N Cardanol Chemical compound OC1=CC=CC(CCCCCCC\C=C/C\C=C/CC=C)=C1 JOLVYUIAMRUBRK-UTOQUPLUSA-N 0.000 claims description 15
- FAYVLNWNMNHXGA-UHFFFAOYSA-N Cardanoldiene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1 FAYVLNWNMNHXGA-UHFFFAOYSA-N 0.000 claims description 15
- PTFIPECGHSYQNR-UHFFFAOYSA-N cardanol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 claims description 15
- 229920006122 polyamide resin Polymers 0.000 claims description 15
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical group CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims description 12
- 229940083466 soybean lecithin Drugs 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 11
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 238000010276 construction Methods 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 abstract description 21
- 229910000831 Steel Inorganic materials 0.000 abstract description 13
- 239000010959 steel Substances 0.000 abstract description 13
- 238000000034 method Methods 0.000 abstract description 9
- 238000005553 drilling Methods 0.000 abstract description 3
- 239000011159 matrix material Substances 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 18
- 229910052725 zinc Inorganic materials 0.000 description 17
- 239000011701 zinc Substances 0.000 description 17
- 239000003973 paint Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 239000000758 substrate Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- 230000001681 protective effect Effects 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229910000676 Si alloy Inorganic materials 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 5
- 239000013530 defoamer Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 239000002481 rotproofing Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- 239000012745 toughening agent Substances 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010349 cathodic reaction Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000006255 coating slurry Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- ATTFYOXEMHAYAX-UHFFFAOYSA-N magnesium nickel Chemical compound [Mg].[Ni] ATTFYOXEMHAYAX-UHFFFAOYSA-N 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- LGERWORIZMAZTA-UHFFFAOYSA-N silicon zinc Chemical compound [Si].[Zn] LGERWORIZMAZTA-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
Description
实例 | 实例1 | 实例2 | 实例3 | 实例4 |
耐中性盐雾时间 | 1082小时 | 1034小时 | 1062小时 | 1032小时 |
Claims (1)
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CN201310187500.6A CN103242737B (zh) | 2013-05-20 | 2013-05-20 | 一种海洋重防腐环氧富铝锰稀土纳米涂料及其制备方法 |
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CN201310187500.6A CN103242737B (zh) | 2013-05-20 | 2013-05-20 | 一种海洋重防腐环氧富铝锰稀土纳米涂料及其制备方法 |
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CN103242737A CN103242737A (zh) | 2013-08-14 |
CN103242737B true CN103242737B (zh) | 2015-04-22 |
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CN110158022A (zh) * | 2019-05-17 | 2019-08-23 | 安徽省汉甲机电设备科技有限公司 | 一种提高船用碳素钢耐腐蚀性的方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102002271A (zh) * | 2010-11-04 | 2011-04-06 | 江苏麟龙新材料股份有限公司 | 含稀土-钛-镍-锰的耐海洋气候防腐处理用的涂料 |
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US5677367A (en) * | 1995-08-15 | 1997-10-14 | Savin; Ronald R. | Graphite-containing compositions |
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Patent Citations (2)
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CN102002271A (zh) * | 2010-11-04 | 2011-04-06 | 江苏麟龙新材料股份有限公司 | 含稀土-钛-镍-锰的耐海洋气候防腐处理用的涂料 |
CN102051079A (zh) * | 2010-11-04 | 2011-05-11 | 江苏麟龙新材料股份有限公司 | 含镁-稀土-钛-锰的耐海洋气候防腐处理用的涂料 |
Non-Patent Citations (1)
Title |
---|
"电弧喷涂Zn-Al-Mg-La-Ce涂层的耐腐蚀性能";邢士波等;《北京科技大学学报》;20121031;第34卷(第10期);1167-1172 * |
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Owner name: SHANDONG LONGQUAN PIPELINE ENGINEERING CO., LTD. Free format text: FORMER OWNER: XING SHIBO Effective date: 20150204 |
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Free format text: CORRECT: ADDRESS; FROM: 056038 HANDAN, HEBEI PROVINCE TO: 255200 ZIBO, SHANDONG PROVINCE |
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Effective date of registration: 20150204 Address after: 255200, No. 36, Shandong Road, Boshan District, Shandong, Zibo Applicant after: Shandong Longquan Pipeline Engineering Co., Ltd. Address before: 056038 Department of materials engineering, Institute of equipment manufacturing, Hebei University of Engineering, Hebei, Handan Applicant before: Xing Shibo |
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Denomination of invention: Marine heavy anti-corrosion epoxy nano coating rich in aluminium, manganese and rare earth and preparation method thereof Effective date of registration: 20170523 Granted publication date: 20150422 Pledgee: CITIC Bank, Limited by Share Ltd, Zibo branch Pledgor: Shandong Longquan Pipeline Engineering Co., Ltd. Registration number: 2017990000431 |
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Date of cancellation: 20190723 Granted publication date: 20150422 Pledgee: CITIC Bank, Limited by Share Ltd, Zibo branch Pledgor: Shandong Longquan Pipeline Engineering Co., Ltd. Registration number: 2017990000431 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Marine heavy anti-corrosion epoxy nano coating rich in aluminium, manganese and rare earth and preparation method thereof Effective date of registration: 20190815 Granted publication date: 20150422 Pledgee: CITIC Bank, Limited by Share Ltd, Zibo branch Pledgor: Shandong Longquan Pipeline Engineering Co., Ltd. Registration number: Y2019370000011 |