CN103237877A - Composition for cleaning of hard surfaces - Google Patents
Composition for cleaning of hard surfaces Download PDFInfo
- Publication number
- CN103237877A CN103237877A CN201180057917XA CN201180057917A CN103237877A CN 103237877 A CN103237877 A CN 103237877A CN 201180057917X A CN201180057917X A CN 201180057917XA CN 201180057917 A CN201180057917 A CN 201180057917A CN 103237877 A CN103237877 A CN 103237877A
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- CN
- China
- Prior art keywords
- composition
- alkyl
- water
- weight
- alkaline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 79
- 238000004140 cleaning Methods 0.000 title claims abstract description 35
- 150000001412 amines Chemical class 0.000 claims abstract description 39
- 125000000217 alkyl group Chemical group 0.000 claims description 25
- 239000003945 anionic surfactant Substances 0.000 claims description 22
- 150000002500 ions Chemical class 0.000 claims description 22
- 230000003165 hydrotropic effect Effects 0.000 claims description 20
- -1 ethyleneoxy group Chemical group 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000003630 growth substance Substances 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 14
- 239000000654 additive Substances 0.000 claims description 10
- 230000000996 additive effect Effects 0.000 claims description 10
- 239000002585 base Substances 0.000 claims description 10
- 125000000129 anionic group Chemical group 0.000 claims description 9
- 239000003153 chemical reaction reagent Substances 0.000 claims description 9
- 239000006210 lotion Substances 0.000 claims description 9
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 239000008139 complexing agent Substances 0.000 claims description 8
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 125000002252 acyl group Chemical group 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 125000001118 alkylidene group Chemical group 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 238000009472 formulation Methods 0.000 abstract description 3
- 239000002736 nonionic surfactant Substances 0.000 abstract description 2
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 abstract description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000003752 hydrotrope Substances 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 22
- 238000010790 dilution Methods 0.000 description 15
- 239000012895 dilution Substances 0.000 description 15
- 239000013543 active substance Substances 0.000 description 10
- 238000003556 assay Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 238000005202 decontamination Methods 0.000 description 5
- 230000003588 decontaminative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000007046 ethoxylation reaction Methods 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 241000282326 Felis catus Species 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 230000000536 complexating effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229930182478 glucoside Natural products 0.000 description 3
- 229930182470 glycoside Natural products 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XMVBHZBLHNOQON-UHFFFAOYSA-N 2-butyl-1-octanol Chemical group CCCCCCC(CO)CCCC XMVBHZBLHNOQON-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical group CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 150000008131 glucosides Chemical class 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- 238000004018 waxing Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- GIEMHYCMBGELGY-UHFFFAOYSA-N 10-undecen-1-ol Chemical compound OCCCCCCCCCC=C GIEMHYCMBGELGY-UHFFFAOYSA-N 0.000 description 1
- QCYOIFVBYZNUNW-UHFFFAOYSA-N 2-(dimethylazaniumyl)propanoate Chemical compound CN(C)C(C)C(O)=O QCYOIFVBYZNUNW-UHFFFAOYSA-N 0.000 description 1
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- HLCFGWHYROZGBI-JJKGCWMISA-M Potassium gluconate Chemical compound [K+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O HLCFGWHYROZGBI-JJKGCWMISA-M 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 241000270666 Testudines Species 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 125000005466 alkylenyl group Chemical group 0.000 description 1
- AJXBTRZGLDTSST-UHFFFAOYSA-N amino 2-methylprop-2-enoate Chemical class CC(=C)C(=O)ON AJXBTRZGLDTSST-UHFFFAOYSA-N 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000008504 concentrate Nutrition 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- NSFKBZXCXCJZDQ-UHFFFAOYSA-N cumene;sodium Chemical compound [Na].CC(C)C1=CC=CC=C1 NSFKBZXCXCJZDQ-UHFFFAOYSA-N 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229940050410 gluconate Drugs 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000004224 potassium gluconate Substances 0.000 description 1
- 235000013926 potassium gluconate Nutrition 0.000 description 1
- 229960003189 potassium gluconate Drugs 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- MSXHSNHNTORCAW-GGLLEASOSA-M sodium;(2s,3s,4s,5r,6s)-3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].O[C@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O MSXHSNHNTORCAW-GGLLEASOSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 239000010913 used oil Substances 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/02—Cleaning by the force of jets or sprays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60S—SERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
- B60S1/00—Cleaning of vehicles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to the use of an alkaline aqueous composition comprising a) an amine oxide b) a nonionic surfactant, not being an amine oxide, and c) a cationic hydrotrope having the formula (I), where R = C6-C22 hydrocarbyl, R1 and R2 are independently C1-C4 alkyl, n is at least 12, and at most 25, and X- is an anion, e.g. halide or methylsulphate; for removal of dirt from hard surfaces. In particular the composition significantly reduces the amount of traffic film remaining on the surface after brushless vehicle cleaning as compared to presently applied formulation concepts. Further, the invention relates to certain such compositions and intermediates to make these.
Description
Technical field
The present invention relates to the purposes of some composition and described composition, for scrubbing from crust, be particularly useful for the brushless cleaning of vehicle (for example car and motorbus).
Background technology
Automatically the carwash method is used for many years, and in the field of exploitation new engine, brush and chemical many activities is arranged.But brushless carwash is the cleaning method of wanting to protect many clients' preferences of top coat.
Be well known that brushless carwash causes less damage to the surface.The shortcoming of brushless carwash is to stay grey traffic film after cleaning from the teeth outwards.This film is removed by surface in contact easily.
In brushless carwash, used chemical and the particular formulations used play important effect aspect the amount of staying lip-deep this traffic film after cleaning reducing.In addition, chemical should be very effective under lower concentration, and have very low environmental impact.
Development is after many years in equipment and formulation art, and the traffic film is still problem.
WO 2005/113735 briefly discloses the crust watersoluble cleaning composition that has less than 7.0 pH, it comprises a) nonionogenic tenside, more specifically be selected from oxyalkylated side chain or straight chain alcohol, amine oxide, polyhydritic alcohol, trimethyl-glycine and composition thereof, b) oxyalkylated cats product, c) the water-soluble organic acid organic solvent of hydroxyl-functional, and d).
WO 03/087280 briefly discloses vehicle drying and polishing composition, it comprises a) alkyl ether amine, b) alkyl diamine, c) quaternary ammonium compound of propoxylation or mixed oxyalkylization, the compound that for example has two ethyls, a methyl and a polyoxypropylene group, and d) comprise the stablizer of neutralizing acid and/or nonionogenic tenside, it can be for example amine oxide, oxyalkylated alcohol (its can by end-blocking) or alkyl glycoside or its mixture.Said composition can further comprise the quaternary ammonium compound of ethoxylation, for example PEG 15 cocoyl ammonio methacrylates.
US 5929024 discloses the cleaning of hard surfaces composition that comprises at least a tensio-active agent, described tensio-active agent for example is selected from the nonionogenic tenside of a) ethoxylation, b) has the alkyl polyglucoside of C8-C20 alkyl, c) amine oxide, and composition thereof, and further comprise for example d) have a trialkyl ammonium salts of the ethoxylation of maximum 5 EO unit.
EP 1074606 discloses the liquid detergent preparation as the cleaning of hard surfaces agent, and it comprises the pure and mild C of alkyl-sulphate, sulfated alkyl ether, beet alkali surface activator, ethoxylation
8-22Alkyl poly glucoside, said preparation also can comprise amine oxide.
US 6015780 briefly discloses surfactant composition, and it contains a) C
12Trimethyl-glycine, b) C
4-C
22Alkyl and/or alkenyl oligosaccharides glycosides, preferred few glucoside, and c) Fatty Alcohol(C12-C14 and C12-C18) (ether) vitriol and d randomly) fatty alcohol ethoxylate and/or e) amine oxide.
US 2006/0009369 briefly discloses the cleaning of hard surfaces composition, and alcohol, amine oxide and/or alkyl poly glucoside that it can comprise for example ethoxylation wherein use C
9C
11Alkyl polyglucoside is as specific examples.
US 2009/0188533 relates to particularly be used to the preparation of removing dissimilar traffic films.Disclosed preparation comprises a) at least a anion surfactant, and b) at least a have three C
1-C
4The polyoxyalkylene ammonium cation tensio-active agent of alkyl and a polyoxyalkylene chain, and c) alkaline reagents.Optional supplementary component can comprise at least a multi-carboxylic acid chelating agents, at least a nonionic or amphoterics, at least a hydrotropic agent, inorganic and/or organic acid and at least a silicate.
Up to the present, be used in combination some positively charged ion cosurfactant with nonionogenic tenside and seem to confirm to be when using brushless cleaning method, to reduce the best mode of staying lip-deep traffic film, but still have improved space so that this problem minimizes, because client constantly seeks better cleaning.
Summary of the invention
An object of the present invention is at least part of the demand that satisfies in this area, and be provided at from the crust scrubbing aspect show efficient, especially for the preparation of brushless carwash.
Another object of the present invention provides the preparation that comprises the compound with advantageous environment character.
Have been found that the alkaline waterborne compositions scrubbing from the crust very effectively that comprises following component now, and compare with the formulating of recipe of present use and to reduce the amount of behind brushless carwash, staying lip-deep traffic film especially significantly:
A) amine oxide,
B) nonionogenic tenside of non-oxide amine and
C) has the water-soluble growth substance of positively charged ion of formula (I)
R=C wherein
6-C
22Alkyl, R
1And R
2Be C independently
1– C
4Alkyl or alkyl group, n is at least 12 and maximum 25, and X
-Be negatively charged ion, for example halide-ions or methylsulfuric acid radical ion.
Therefore, first aspect the present invention relates to the purposes of above-mentioned preparation, is used for cleaning of hard surfaces, is particularly useful for brushless carwash.
Second aspect, the present invention relates to above-mentioned preparation itself, wherein the summation of amine oxide and nonionogenic tenside and hydrotropic weight ratio are 1:3 to 5:3, and condition is if having any anion surfactant and/or amphoterics in said composition, and then the molar weight of the water-soluble growth substance of positively charged ion of formula (I) is greater than the molar weight as any anionic group of the integral part of anion surfactant and/or amphoterics.
Said composition is used particularly well in brushless cleaning, is not confined to this purposes but should the fact should not be interpreted as it, because its cleaning of hard surfaces to all kinds is all very effective.
From following detailed Description Of The Invention, find out these and other aspect of the present invention easily.
Detailed Description Of The Invention
The present invention relates to the purposes of alkaline waterborne compositions, be used for cleaning of hard surfaces, be particularly useful for reducing the amount of staying lip-deep traffic film behind brushless carwash, described alkaline waterborne compositions comprises:
A) amine oxide,
B) nonionogenic tenside of non-oxide amine,
C) has the water-soluble growth substance of positively charged ion of formula (I)
R=C wherein
6-C
22Alkyl, preferred C
6-C
22Alkyl or alkyl group or alkenyl, more preferably C
8– C
20Alkyl or alkyl group or alkenyl, most preferably C
10– C
18Alkyl or alkyl group or alkenyl; R
1And R
2Be C independently
1– C
4Alkyl or alkyl group, preferable methyl or ethyl, most preferably R
1And R
2It all is methyl; N is at least 12 and maximum 25, and is preferred maximum 20, most preferably maximum 17; And X
-Be negatively charged ion, for example halide-ions or methylsulfuric acid radical ion,
D) randomly other conventional additive and
E) surplus is water.
Point out optional additive d) can comprise other tensio-active agent.If have any anion surfactant and/or amphoterics in said composition, then the molar weight of the water-soluble growth substance of positively charged ion of formula (I) is greater than the molar weight as any anionic group of the integral part of anion surfactant and/or amphoterics.But, preferably in said composition, do not have anion surfactant.In another embodiment, there are not anion surfactant or amphoterics.
Another aspect of the present invention is above-mentioned alkaline water-based composition itself, and wherein the summation of amine oxide and nonionogenic tenside and hydrotropic weight ratio are 1:3 to 5:3.
Term " anionic group " refers to the anionic group of covalent bonding in anion surfactant or amphoterics.For example, has formula R-OSO
3 -A
+The sulfate radical of the alkyl-sulphate of (wherein R is the alkyl with at least 6 carbon atoms) and alkyl R covalent bonding, and these groups constitute anion surfactant together.Do not consider the counter ion among the formula I in this respect, for example X
-, CH for example
3OSO
3 -In addition, amine oxide is not regarded as amphoterics in this article.If have any anion surfactant and/or amphoterics in said composition, the mol ratio of the cats product of the anionic group of this tensio-active agent and formula (I) preferably less than 1:2, is more preferably less than 1:3 less than 1:1.Most preferably, this waterborne compositions does not contain anion surfactant and amphoterics.Its reason is the water-soluble growth substance of positively charged ion of (I) of avoiding having formula and the complexing between the anion surfactant, and this complexing is not desirable, because its interference makes the nonionogenic tenside solubilising by the water-soluble growth substance of positively charged ion.
Nonionogenic tenside is known to be good wetting agent, and is present in usually in the composition of cleaning of hard surfaces.The most common ground, the cleaning of hard surfaces composition contains basic component.Many nonionogenic tensides (especially exist a large amount of ionogen for example those solution of alkali metal hydroxide, alkaline auxiliary lotion and/or complexing agent in) in basic solution are solvable inadequately, therefore need exist hydrotropic agent to improve their solubleness.Good hydrotropic agent is good wetting agent not necessarily.Its main task is to improve the solubleness of nonionogenic tenside, and therefore improves the wetting ability of said composition, because the dissolving now of original insoluble nonionogenic tenside also can be brought into play its wetting ability.The many hydrotropic agents that are used for nonionogenic tenside have been described in various publications.Hydrotropic example like this is ethanol, sodium xylene sulfonate, cumene sodium sulfonate, alkyl glycoside and oxyalkylated quaternary ammonium compound.
Alkaline compositions in this article refers to pH〉7 composition, by adding alkaline reagents, for example alkali metal hydroxide, alkaline auxiliary lotion and/or alkaline complexing agent obtain this pH.In one embodiment, pH is higher than 7.1, and in another embodiment, it is higher than 7.5.In the present invention, provide pH as the value that when measuring said composition for 25 ℃, obtains.Described alkali metal hydroxide is sodium hydroxide or potassium hydroxide preferably.Described alkaline auxiliary lotion can be alkaline carbonate or alkali metal hydrocarbonate, for example yellow soda ash, salt of wormwood, sodium bicarbonate or saleratus, alkalimetal silicate, for example water glass or Starso, or alkali metal phosphate, for example sodium orthophosphate.The alkaline auxiliary lotion that plays a role by complexing is for example trisodium phosphate and tripoly phosphate sodium STPP and corresponding sylvite.The example of organic washing-assisting detergent/complexing agent is aminocarboxylate, for example sodium nitrilo triacetate (Na
3NTA), sodium ethylene diamine tetracetate (EDTA), diethylene triaminepentaacetic acid(DTPA) sodium, 1,3-trimethylenedinitrilo-tertraacetic acid sodium and hydroxyethylethylene diamine tri-acetic acid sodium; Amino polyphosphonate, for example nitrilo trimethylene phosphonic salt; Organophosphate; Multi-carboxylate, for example Citrate trianion; Polymerization of carboxylic acid salt and basic metal gluconate are as gluconic acid sodium salt or potassium gluconate.
The amine oxide component preferably has following formula:
R wherein
3Be alkyl or the acyl group that contains 8-22 carbon atom, B is O or NH, and y is 0 or 1, and condition is to work as R
3When being acyl group, y must be 1; R
4And R
5Be C independently
1-C
4Alkyl or alkyl group or group (AO)
zH, wherein AO is the alkylidene group oxygen base with 2-4 carbon atom, and z is 1 to 5 number.
Point out that amine oxide is classified as nonionogenic tenside sometimes, classify as amphoterics sometimes, classify as zwitterionics sometimes, classify as cats product sometimes, mention as the tensio-active agent of particular variety sometimes.For avoiding confusion, amine oxide is regarded as the tensio-active agent of particular variety in this article, but not is regarded as roughly belonging to nonionogenic tenside, amphoterics, cats product or the big class of any other tensio-active agent.
Non-ionic surfactant component is the oxirane adducts preferably, is pure oxirane adducts suitably, and it preferably has following formula:
R
6O–(PO)
a(EO)
b(PO)
cH （IV）
R wherein
6Be C
8To C
18Alkyl or alkyl group, preferred C
8To C
12, PO is propylidene oxygen base unit, EO is the ethyleneoxy group unit, a=0-5, preferred 0-4, most preferably 0-2; B=1-20, preferred 1-12, more preferably 2-8, most preferably 2-5; And c=0-5, preferred 0-4, more preferably 0-2, most preferably 0.Therefore, C
8– C
18-alcohol alkoxylate also can contain maximum 5 propylidene oxygen base unit except 1-20 ethyleneoxy group unit.When existing, propylidene oxygen base unit number can be as small as 0.1 mole of PO of every mol of alcohol.Can be random or add in block in ethyleneoxy group unit and propylidene oxygen base unit.Block can add on the alcohol with any order.Alcoxylates also can contain the alkyl that position endways has 1-4 carbon atom.Alcoxylates preferably contains 2-8 ethyleneoxy group unit and 0-2 propylidene oxygen base unit.The alkyl of nonionogenic tenside can be straight or branched, saturated or undersaturated.Suitable linear nonionogenic tenside is C
9-C
11Alcohol+4,5 or 6 moles of EO, C
11Alcohol+3,4,5,6,7 or 8 moles of EO, tridecyl alcohol+4,5,6,7 or 8 mole EO and C
10-C
14Alcohol+8 moles of EO+2 mole PO.Suitable branching nonionogenic tenside is 2-Ethylhexyl Alcohol+3,4 or 5 mole EO, 2-Ethylhexyl Alcohol+2 mole PO+4,5 or 6 moles of EO, 2-propyl enanthol+3,4,5 or 6 mole EO and 2-propyl enanthol+1 mole PO+4 mole EO.Another example is 2-butyl octanol+5,6 or 7 moles of EO.When discussing the alkylation degree, the numerical value of mentioning all is a mole mean number.
Compositions for use can be enriched material or instant solution among the present invention, and preferably comprises
I) 0.03-20 weight % amine oxide,
Ii) 0.03-20 weight % nonionogenic tenside,
Iii) 0.015-20 weight % hydrotropic agent,
Iv) 0.03-40 weight % alkali metal hydroxide, alkaline auxiliary lotion and/or alkaline complexing agent,
V) randomly other conventional additive and
Vi) surplus is water.
Scope relate to the instant solution of dilution than lower part, higher part relates to concentrated solution.Concentrated solution can provide and reduce transportation cost and easily dilutable and easy-operating advantage.Typical case's enriched material can dilute 80 to 200 times to form instant solution.Point out that such dilution can be carried out in one or more steps, for example enriched material can be diluted 50 times, supply with the final user then, and further dilute 4 times to obtain instant solution.In supply chain, this is with the minimized accurately dilution effective means that obtains simultaneously of transportation cost.
The weight ratio of amine oxide and nonionogenic tenside is generally 1:2 to 8:3, and the summation of amine oxide and nonionogenic tenside and hydrotropic weight ratio are generally 1:3 to 5:3.
Concentrate composition of the present invention is limpid or muddy slightly, and stable.The clarity interval is 0-30 ℃ suitably, preferred 0-40 ℃, and more preferably 0-50 ℃, most preferably 0-60 ℃ or higher.This can regulate by the relative quantity that changes hydrotropic agent, amine oxide and nonionogenic tenside.This enriched material contains the water of at least 50 weight % usually, suitably the water of at least 70 weight %, common maximum 95 weight %, maximum 90 weight % suitably.
Another embodiment of the present invention relates to the intermediate that can be used for making preparation of the present invention.More specifically, because movement requirement, can make the enriched material of no alkaline component, such enriched material can be not moisture, or contain and be less than 50% water.Therefore the present invention also relates to intermediate, and it comprises:
One or more amine oxides of 0.5-50%w/w,
One or more nonionogenic tensides of 0.5-50%w/w,
One or more of 0.5-50%w/w have the water-soluble growth substance of positively charged ion of formula (I)
R=C wherein
6-C
22Alkyl, R
1And R
2Be C independently
1– C
4Alkyl or alkyl group, n is at least 12 and maximum 25; And X
-Be negatively charged ion,
Randomly other conventional additive and
The water of 0.0-50%w/w,
Until amounting to 100 weight %, wherein the pH of this intermediate is lower than 8.In one embodiment, the pH of this intermediate is lower than 7.5.In another embodiment, pH is higher than 7.0, preferably is higher than 7.1.This intermediate can dilute with water, if desired, can be combined with aforesaid alkaline reagents, to form preparation of the present invention.
All embodiments of the present invention can further contain other hydrotropic agent and tensio-active agent and conventional additive, for example thickening material, solvent, tinting material, anti-dirt deposition agent, sanitas, inhibiter and foaming regulator again.
General experiment
In order to assess the cleaning efficiency of different preparations under different extent of dilution, use following program:
The high pressure cleaner assay
With containing the PTFE(tetrafluoroethylene) Turtle
Wax Extra handles Whiteboard5.5 * 9cm plate, with the soft cloth polishing, uses the oil smoke mixture available from the train diesel engine then onboard.This is the soil types of very difficult removing and the worst case that is used for simulation traffic film.With Minolta Chroma Meter CR-200 reflexometer earlier after the waxing, after contamination, measure the reflectivity of each plate again.Then plate magnetic is fixed on the bigger plate.With container that cleaning liquor is housed through pipe connection to pump, pump again through pipe connection to the flat fan nozzle, this nozzle is installed in can be vertically and on the stand that moves horizontally, and controls by cable and electric motor with by applying pressurized air.When nozzle moves horizontally, by under 4 bar pressures, with about 2 liters/minute flow rate of liquid its pump being crossed the flat fan nozzle, apply cleaning liquor onboard in face of plate.For rinse step, use one group of three conical nozzle that is connected to running water pipe through high-pressure pump.These nozzles also are installed on the above-mentioned stand.After applying cleaning liquor 1 minute, when nozzle moves horizontally and swings up and down simultaneously in face of the plate, be used to from the P21/23-130 of Australian Speck-Kolbenpumpenfabrik type ram pump under 80 bar pressures with about 4.5 liters/minute flow rate of liquid through this group nozzle pumping tap water to wash plate.Between cleaner assay, cross tap water by pump, carefully wash this pipe to remove any residual cleaning liquid of last test.After flushing, measure the reflectivity of each plate again with reflexometer.As the comparison between decontamination %(cleaner plate and the contamination plate) or as luminance loss's (comparison between plate cleaner plate and waxing, nonstaining) expression cleaning capacity.For the composition of good cleaning, the loss of gained brightness value therefore should be low as far as possible.
Notice that the value that provides only is used as relatively but not absolute value.
Be used for value relatively and use the used oil smoke mixture acquisition of same batch.For each test of using the particular composition operation, use 3 plates, and test carries out at least twice.Therefore, unless indicate separately, these values are average results of the test carried out at least six plates.Each test is provided the scope that has these results.
All solution and water remain on 20 ℃ of 15 –.In all following embodiment, unless make separate stipulations all percentages.
Embodiment 1
Manufacturing has the composition of the reagent of regulation in the table 1.So that this solution show shown in the amount in clarity interval add hydrotropic agent.To be tried solution dilution to 1:40 and 1:80.By the cleaning capacity that is tried solution of above-mentioned high pressure cleaner assay assessment dilution, collection is in table 2.
Table 1
1All amounts provide as weight %, and refer to the live vol of each component in the said composition
OX-91-4;
R648;
4AG6206;
5Ex Stephan;
14D-W970;
8Iminobisuccinate ex Bayer;
9Ex Merck
Table 2
| Composition | Decontamination (%) under the 1:40 dilution | Decontamination (%) under the 1:80 dilution |
| 1 | 90±5 | 53±11 |
| The A(contrast) | 88±7 | 10±3 |
| The B(contrast) | 83±7 | 8±2 |
Embodiment 2-3
Manufacturing has the composition of the reagent of regulation in the table 3.So that this solution show shown in the amount in clarity interval add hydrotropic agent.Water will be tried solution dilution to 1:20.By the cleaning capacity that is tried solution of following cleaner assay assessment dilution, collection is in table 4.
Cleaner assay:
Use available from the slush mixture of train diesel engine and smear the white paint plate.Tried solution with 25 milliliters and---in this case for being diluted to preparation 2, the C and 3 in the table 3 of 1:20---being poured on the top of greasy dirt plate and at this and stopping 1 minute.Then with a large amount of current flushing plates.All solution and water remain on the temperature of 20 ℃ of about 15 –.All are tried solution and are placed on the same plate, and the result provides as the ordering of compound, wherein 1 are judged as optimum by visual inspection.Collection is in table 4.
Table 3
Table 4
| Composition | Ordering |
| 2 | 2 |
| The C(contrast) | 3 |
| 3 | 1 |
The comparative composition ordering of non-oxidation amine is minimum.
Embodiment 4
In this embodiment, use not as soluble nonionogenic tenside among the embodiment 2-3.Manufacturing has the composition of the reagent of regulation in the table 5.So that this solution show shown in the amount in clarity interval add hydrotropic agent.To be tried solution dilution to 1:20.Assess the cleaning capacity that is tried solution of dilution by high pressure cleaner assay of in " general experiment ", describing.The brightness value loss that is obtained by the high pressure cleaner assay is presented in the table 6.
Table 5
Table 6
Can know and find out, amine oxide be added to having produced the have better clean-up performance composition of (lower luminance loss) in the cleaning compositions.In addition, the composition that has added amine oxide has wideer clarity interval.
Embodiment 5
In this embodiment, nonionogenic tenside or nonionogenic tenside+hydrotropic influence are removed in checking from said composition.Manufacturing has the composition of the reagent of regulation in the table 7.The gross activity content of tensio-active agent is 6.7%(w/w in each preparation).Composition 5 meets the present invention, lacks nonionogenic tenside among the composition E, lacks nonionogenic tenside and hydrotropic agent in the composition F.
To be tried solution dilution to 1:60.Assess the cleaning capacity that is tried solution of dilution by high pressure cleaner assay of in " general experiment ", describing.The decontamination % value that is obtained by the high pressure cleaner assay is presented in the table 8.
Table 7
Table 8
| Composition | Decontamination (%) under the 1:60 dilution |
| 5 | 61 |
| The E(contrast) | 44 |
| The F(contrast) | 31 |
Therefore from above-described embodiment, know and find out, component in the composition of the present invention a), b) and c) all good cleaning effect is made positive contribution, and this effect works in coordination with, because if lack a kind of component in the said composition, can not compensate by adding more another component.
Claims (21)
1. alkaline waterborne compositions is used for the purposes of cleaning of hard surfaces, and described alkaline waterborne compositions comprises:
A) amine oxide,
B) nonionogenic tenside of non-oxide amine,
C) has the water-soluble growth substance of positively charged ion of formula (I)
R=C wherein
6-C
22Alkyl, R
1And R
2Be C independently
1– C
4Alkyl, n is at least 12 and maximum 25; And X
-Be negatively charged ion,
D) randomly, other conventional additive and
E) water of surplus;
Condition is if having any anion surfactant and/or amphoterics in described composition, and then the molar weight of the water-soluble growth substance of positively charged ion of formula (I) is greater than the molar weight as any anionic group of the integral part of anion surfactant and/or amphoterics.
2. according to the purposes of claim 1, wherein said composition comprises anion surfactant and/or amphoterics, and wherein the mol ratio of the anionic group in anion surfactant and/or the amphoterics and the water-soluble growth substance of positively charged ion is less than 1:3.
3. according to the purposes of claim 1, wherein said composition does not contain anion surfactant and amphoterics.
4. according to the purposes of claim 1, wherein said composition comprises alkali metal hydroxide, alkaline auxiliary lotion and/or alkaline complexing agent.
5. according to the purposes of claim 1-4, wherein said amine oxide has following formula:
R wherein
3Be alkyl or the acyl group that contains 8-22 carbon atom, B is O or NH, and y is 0 or 1, and condition is to work as R
3When being acyl group, y must be 1; R
4And R
5Be C independently
1-C
4Alkyl or group (AO)
zH, wherein AO is the alkylidene group oxygen base with 2-4 carbon atom, and z is 1 to 5 number.
6. according to the purposes of claim 1-5, wherein said nonionogenic tenside has following formula:
R
6O–(PO)
a(EO)
b(PO)
cH （IV）
R wherein
6Be C
8To C
18Alkyl, PO are propylidene oxygen base unit, and EO is the ethyleneoxy group unit, a=0-5, b=1-20, and c=0-5.
7. according to the purposes of claim 1-6, wherein said composition comprises:
I) 0.03-20 weight % amine oxide,
Ii) 0.03-20 weight % nonionogenic tenside,
Iii) 0.015-20 weight % hydrotropic agent,
Iv) 0.03-40 weight % alkali metal hydroxide, alkaline auxiliary lotion and/or alkaline complexing agent,
V) randomly other conventional additive and
Vi) surplus is water.
8. according to the purposes of claim 1-7, wherein the weight ratio of amine oxide and nonionogenic tenside is 1:2 to 8:3.
9. according to the purposes of claim 1-8, wherein the summation of amine oxide and nonionogenic tenside and hydrotropic weight ratio are 1:3 to 5:3.
10. according to the purposes of claim 1-9, it is used for brushless carwash, preferably uses waterworks.
11. the method for cleaning of hard surfaces, comprise to described surface add the composition described in claim 1-9 of cleaning significant quantity and use waterworks wash as described in the step on surface.
12. alkaline waterborne compositions, it comprises:
A) amine oxide,
B) nonionogenic tenside of non-oxide amine,
C) has the water-soluble growth substance of positively charged ion of formula (I)
R=C wherein
6-C
22Alkyl, R
1And R
2Be C independently
1– C
4Alkyl, n is at least 12 and maximum 25; And X
-Be negatively charged ion,
D) randomly other conventional additive and
E) surplus is water;
Wherein the summation of amine oxide and nonionogenic tenside and hydrotropic weight ratio are 1:3 to 5:3; And
Condition is if having any anion surfactant and/or amphoterics in described composition, and then the molar weight of the water-soluble growth substance of positively charged ion of formula (I) is greater than the molar weight as any anionic group of the integral part of anion surfactant and/or amphoterics.
13. according to the composition of claim 12, it comprises anion surfactant and/or amphoterics, wherein the mol ratio of the anionic group in anion surfactant and/or the amphoterics and the water-soluble growth substance of positively charged ion is less than 1:3.
14. according to the composition of claim 12, wherein said composition does not contain anion surfactant and amphoterics.
15. according to the composition of claim 12, it comprises alkali metal hydroxide, alkaline auxiliary lotion and/or alkaline complexing agent.
16. according to the composition of claim 12-15, wherein said amine oxide has following formula:
R wherein
3Be alkyl or the acyl group that contains 8-22 carbon atom, B is O or NH, and y is 0 or 1, and condition is to work as R
3When being acyl group, y must be 1; R
4And R
5Be C independently
1-C
4Alkyl or group (AO)
zH, wherein AO is the alkylidene group oxygen base with 2-4 carbon atom, and z is 1 to 5 number.
17. according to the composition of claim 12-16, wherein said nonionogenic tenside has following formula:
R
6O–(PO)
a(EO)
b(PO)
cH （IV）
R wherein
6Be C
8To C
18Alkyl, PO are propylidene oxygen base unit, and EO is the ethyleneoxy group unit, a=0-5, b=1-20, and c=0-5.
18. according to the composition of claim 12-17, it comprises:
I) 0.03-20 weight % amine oxide,
Ii) 0.03-20 weight % nonionogenic tenside,
Iii) 0.015-20 weight % hydrotropic agent,
Iv) 0.03-40 weight % alkali metal hydroxide, alkaline auxiliary lotion and/or alkaline complexing agent,
V) randomly other conventional additive and
Vi) surplus is water.
19. according to the composition of claim 12-18, wherein the weight ratio of amine oxide and nonionogenic tenside is 1:2 to 8:3.
20. intermediate, it comprises:
One or more amine oxides of 0.5-50%w/w,
One or more nonionogenic tensides of 0.5-50%w/w,
One or more of 0.5-50%w/w have the water-soluble growth substance of positively charged ion of formula (I)
R=C wherein
6-C
22Alkyl, R
1And R
2Be C independently
1– C
4Alkyl, n is at least 12 and maximum 25; And X
-Be negatively charged ion,
Randomly other conventional additive and
The water of 0.0-50%w/w,
Until amounting to 100 weight %, wherein the pH of this intermediate is lower than 8, and it can be diluted and be combined the preparation that forms claim 12-19 with alkaline reagents.
21. form the method for compositions of claim 12-19, comprise dilute with water claim 13 intermediate and, if desired, the step of being combined with alkaline reagents.
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|---|---|---|---|
| US42040010P | 2010-12-07 | 2010-12-07 | |
| US61/420,400 | 2010-12-07 | ||
| EP10193983 | 2010-12-07 | ||
| EP10193983.3 | 2010-12-07 | ||
| PCT/EP2011/071687 WO2012076432A1 (en) | 2010-12-07 | 2011-12-05 | Composition for cleaning of hard surfaces |
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|---|---|
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| CN103237877B CN103237877B (en) | 2014-11-05 |
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ID=43923687
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| CN111088122A (en) * | 2019-12-25 | 2020-05-01 | 北京桂华悦洗科技有限公司 | Anhydrous car washing liquid and preparation method thereof |
| CN115895790A (en) * | 2022-11-30 | 2023-04-04 | 四川科宏达集团有限责任公司 | Anion-cation surfactant compound cleaning agent and preparation method thereof |
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| WO2016014732A1 (en) | 2014-07-23 | 2016-01-28 | The Procter & Gamble Company | Fabric and home care treatment compositions |
| EP3172298B1 (en) | 2014-07-23 | 2019-01-02 | The Procter and Gamble Company | Fabric and home care treatment compositions |
| EP3172299B1 (en) | 2014-07-23 | 2019-09-25 | The Procter and Gamble Company | Fabric and home care treatment compositions |
| WO2016014802A1 (en) | 2014-07-23 | 2016-01-28 | The Procter & Gamble Company | Fabric and home care treatment compositions |
| MX2017000980A (en) | 2014-07-23 | 2017-04-27 | Procter & Gamble | Treatment compositions. |
| EP3172300B1 (en) | 2014-07-23 | 2018-12-26 | The Procter and Gamble Company | Fabric and home care treatment composition |
| WO2016073722A1 (en) | 2014-11-06 | 2016-05-12 | The Procter & Gamble Company | Apertured webs and methods for making the same |
| US9920284B2 (en) | 2015-04-22 | 2018-03-20 | S. C. Johnson & Son, Inc. | Cleaning composition with a polypropdxylated 2-(trialkylammonio)ethanol ionic liquid |
| US9340742B1 (en) * | 2015-05-05 | 2016-05-17 | Afton Chemical Corporation | Fuel additive for improved injector performance |
| CA3010919A1 (en) | 2016-01-25 | 2017-08-03 | The Procter & Gamble Company | Treatment compositions |
| JP6738900B2 (en) | 2016-01-25 | 2020-08-12 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Treatment composition |
| US10947480B2 (en) | 2016-05-17 | 2021-03-16 | Conopeo, Inc. | Liquid laundry detergent compositions |
| EP3532584A1 (en) | 2016-10-26 | 2019-09-04 | S.C. Johnson & Son, Inc. | Disinfectant cleaning composition with quaternary amine ionic liquid |
| US10676694B2 (en) | 2016-12-22 | 2020-06-09 | The Procter & Gamble Company | Fabric softener composition having improved detergent scavenger compatibility |
| EP4056158B1 (en) | 2017-02-16 | 2024-03-06 | The Procter & Gamble Company | Absorbent articles with substrates having repeating patterns of apertures comprising a plurality of repeat units |
| US11390821B2 (en) | 2019-01-31 | 2022-07-19 | Afton Chemical Corporation | Fuel additive mixture providing rapid injector clean-up in high pressure gasoline engines |
| US10946838B2 (en) * | 2019-03-21 | 2021-03-16 | Ford Global Technologies, Llc | Cleaning apparatus for sensor |
| US11873461B1 (en) | 2022-09-22 | 2024-01-16 | Afton Chemical Corporation | Extreme pressure additives with improved copper corrosion |
| US12024686B2 (en) | 2022-09-30 | 2024-07-02 | Afton Chemical Corporation | Gasoline additive composition for improved engine performance |
| US11795412B1 (en) | 2023-03-03 | 2023-10-24 | Afton Chemical Corporation | Lubricating composition for industrial gear fluids |
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- 2011-12-05 EP EP11790632.1A patent/EP2649171B1/en not_active Not-in-force
- 2011-12-05 BR BR112013013487A patent/BR112013013487A2/en not_active IP Right Cessation
- 2011-12-05 CN CN201180057917.XA patent/CN103237877B/en not_active Expired - Fee Related
- 2011-12-05 US US13/991,769 patent/US20130298948A1/en not_active Abandoned
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2016
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| US3959157A (en) * | 1973-06-04 | 1976-05-25 | Colgate-Palmolive Company | Non-phosphate detergent-softening compositions |
| US20090188533A1 (en) * | 1999-04-20 | 2009-07-30 | Ecolab Inc. | Composition and method for road-film removal |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111088122A (en) * | 2019-12-25 | 2020-05-01 | 北京桂华悦洗科技有限公司 | Anhydrous car washing liquid and preparation method thereof |
| CN115895790A (en) * | 2022-11-30 | 2023-04-04 | 四川科宏达集团有限责任公司 | Anion-cation surfactant compound cleaning agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112013013487A2 (en) | 2016-10-11 |
| US20170073615A1 (en) | 2017-03-16 |
| CN103237877B (en) | 2014-11-05 |
| WO2012076432A1 (en) | 2012-06-14 |
| EP2649171A1 (en) | 2013-10-16 |
| EP2649171B1 (en) | 2014-10-29 |
| US20130298948A1 (en) | 2013-11-14 |
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