CN103194858B - Elastic composite of a kind of high dielectric constant and low dielectric loss and preparation method thereof - Google Patents
Elastic composite of a kind of high dielectric constant and low dielectric loss and preparation method thereof Download PDFInfo
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- CN103194858B CN103194858B CN201310141622.1A CN201310141622A CN103194858B CN 103194858 B CN103194858 B CN 103194858B CN 201310141622 A CN201310141622 A CN 201310141622A CN 103194858 B CN103194858 B CN 103194858B
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Abstract
The present invention relates to elastic composite of a kind of high dielectric constant and low dielectric loss and preparation method thereof, comprise the following steps: suspension layoutprocedure, electrostatic spinning process and last handling process.The present invention is by controlling CNT orientations and improve the excess effusion value of composite in the base, and then by increasing the content of CNT, while improving the dielectric constant of composite, its dielectric loss is remained on a lower level, solve the problem that dielectricity composite high-k and low-dielectric loss can not be taken into account.
Description
Technical field
The present invention relates to a kind of elastic composite preparation and method thereof of high dielectric constant and low dielectric loss, especially relating to a kind of by controlling the CNT high-k of orientations acquisition, the elastic composite of low-dielectric loss and preparation method thereof in the base.
Background technology
In recent years, high-k, low-dielectric loss elastomer based dielectric material are paid close attention to widely because it receives in the potential using value in the such as field such as accumulator, sensor, artificial-muscle.CNT/elastic composite can obtain higher dielectric constant by low CNT carrying capacity while the mechanical performance that maintenance is good, but significantly improving usually along with the significantly raising of dielectric loss of this dielectric constant, limits its application in practice.Just because of this, CNT/elastic composite how is made to have high-k concurrently and low-dielectric loss has become a difficult problem.For solving this difficult problem, a kind of conventional method is using the CNT of nucleocapsid structure as filler, namely at the peripheral coated one deck insulating shell layer of CNT, while guarantee fine dispersion, play the energy barrier effect of insulating shell layer, stop the electric charge circulation between CNT, thus reduce the dielectric loss of composite, and CNT inside still remains electric conductivity, by increasing content of carbon nanotubes, the dielectric constant of composite just can be improve.Another kind method carries out finishing to CNT, increase the functional group having excellent compatibility with matrix, as-COOH,-OH etc., improve CNT dispersion in the base, thus improve the excess effusion value of composite, and then by increasing the consumption of CNT, while raising dielectric constant, reduce dielectric loss.But in composite prepared by these two kinds of methods, CNT is random dispersion, be easy between them form overlap joint, cause dielectric loss to reduce limited, and surface modification and coated process is complicated, be difficult to control.
Chinese patent application " high-dielectric composite material containing CNT and preparation method thereof " (number of patent application: 03104776.9) propose employing CNT CNT, admire sour barium BaTIO
3with the composite that organic Kynoar (PVDF) is made, its dielectric constant can up to 450.But for the composite of filled conductive filler, time near excess effusion value, because the factors such as current leakage make the dielectric loss of material significantly increase.The material of high dielectric loss has limited to the application of composite greatly.In addition, admire sour barium BaTIO
3a large amount of fillings result in equally composite modulus increase, limit the increase of deformation quantity.
Chinese patent application " Polyaryletherketone/nanotubeine-carbon nanotubeine-carbon composite material with high dielectric property and preparation method thereof " (number of patent application: adopt polyaniline as insulating barrier enveloped carbon nanometer tube 201110233290.0), by solution plastic film mulch legal system for carbon nano-tube/poly aryl ether ketone composite, the coated process of CNT is very complicated, wayward, during excess effusion value, dielectric loss significantly increases, increase to 9.97 by 0.34, greatly limit the application of dielectric material.
Summary of the invention
The present invention devises elastic composite of a kind of high dielectric constant and low dielectric loss and preparation method thereof, and its problem solved is: the problem that (1) dielectric composite material high-k and low-dielectric loss can not be taken into account; (2) in the elastic composite of existing preparation method gained, CNT is random dispersion, is easy to form overlap joint between CNT, causes dielectric loss limited, and surface modification and coated process complicated, be difficult to control.
In order to solve the technical problem of above-mentioned existence, present invention employs following scheme:
An elastic composite preparation method for high dielectric constant and low dielectric loss, comprises the following steps:
Step 1, carbon nanotube dispersed is obtained the good suspension a of carbon nanotube dispersed in dispersant, wherein the mass ratio of CNT and dispersant is 0.1%-8%; Be dissolved in by elastomer in solvent, obtain consoluet solution b, the mass ratio of its elastomer and solvent is 8%-30%; Described suspension a is mixed with described solution b and stirs, obtains CNT/elastomer/solvent suspension liquid; Wherein, CNT is 0.5wt%-10wt% relative to elastomeric content; Elastomer is 5%-20% relative to the content of the gross mass of CNT/elastomer/solvent suspension liquid;
Step 2, described CNT/elastomer/solvent suspension liquid is carried out electrostatic spinning process, obtain CNT/elastomer composite tunica fibrosa;
Step 3, described CNT/elastomer composite tunica fibrosa is carried out post processing, get rid of the space that formation piled up by fiber, obtain CNT/elastic composite that is closely knit and surface smoothing.
In described CNT/elastomer/solvent suspension liquid, CNT is 0.5wt%-10wt% relative to elastomeric content, preferred 0.5wt%-4wt%.Content of carbon nanotubes very little, has no significant effect the dielectric properties of gained composite; In addition, stability due to electrostatic spinning is subject to the impact of CNT/elastomer/solvent suspension liquid viscosity, and viscosity again limit the amount of solvent and dispersant, further limit the addition of CNT, if the too high levels of CNT, it is difficult to fine dispersion in a small amount of dispersant.Meanwhile, the length of CNT should be less than 5um, if its length is long, can affects its dispersion in dispersant, and affect its orientation along machine direction in electrostatic spinning process.
In described CNT/elastomer/solvent suspension liquid, elastomer is 5%-20% relative to the content of the gross mass of CNT/elastomer/solvent suspension liquid, preferably 5%-15%, more preferably 8%-12%.Very little, because strand intermolecular forces is too small in electrostatic spinning process, be difficult to tangle forms continuous print fiber to elastomer content; Elastomer content is excessive, and be greater than electric field force at electrostatic spinning process Middle molecule inter-chain entanglement active force, gained fiber easily occurs that pearl alters, and makes distribution of fiber diameters uneven.
Further, the dispersant used in step 1 is oxolane, any one in acetone, ethanol, methyl alcohol, toluene or DMF (DMF).
Further, the described solvent used in step 1 is elastomer good solvent, and described elastomer good solvent is the organic solvent that the boiling point of normal atmosphere pressure is less than 80 DEG C.Such solvent is easily volatilization fast in electrostatic spinning process, carries out secondary dissolving or swelling final destruction fibre structure to prevent the following solvent obtained and volatilize to gained fiber.
Further, the described solvent used in step 1 is carrene, any one in chloroform, oxolane, DMF, acetone, MEK, cyclohexane, benzene, ethyl acetate, ethanol or methyl alcohol.
Further, the elastomer used in step 1 is Polyurethane Thermoplastic Elastomer (TPU), any one or multiple in styrene analog thermoplastic elastomer, thermoplastic polyester elastomer (TPEE) or thermoplastic polyamide elastomer (TPAE).These elastomers are the thermoplastic elastomer (TPE)s having glass segments or crystallized region under normal temperature.The elastomer of these kinds can form uniform diameter, elastomeric fibre that pattern is good after electrostatic spinning, and because they have glass segments or crystallized region under normal temperature condition, makes the elastomeric fibre of spinning gained can be good at keeping pattern.
Further, treating apparatus is used to comprise plastics injector for medical purpose, BGG high voltage direct current generator and the metal roller with Surface coating aluminium-foil paper in step 2 in electrostatic spinning; The anode of BGG high voltage direct current generator connects syringe needle, negative electrode connection metal cylinder, and described CNT/elastomer/solvent suspension liquid produces to spray and forms fiber under the progradation and electric field action of syringe; In described electrostatic spinning process, the voltage that BGG high voltage direct current generator provides is 8-15KV, connects flight lead from being 15-25cm between metal roller and plastics injector for medical purpose, and metal roller rotating speed is 300-450m/min.
Electrostatic spinning is a kind of simple, widely applicable processing method preparing sub-micro, nanofiber, comprises preparation various elastomer, composite and ceramic fibre.Described in electrostatic spinning during CNT/elastomer/solvent suspension liquid, elastomer molecules chain, under the induction of electric field force, produces to spray and forms fiber; And CNT is also under the traction of electric field force and elastomer molecules chain, arranges along fiber-wall-element model; Pass through the cylinder of High Rotation Speed again as receiving system, make fiber under the traction of high speed rotary-drum, along drum rotating direction orientations, and then CNT/elastomer composite tunica fibrosa that in obtaining, carbon nanotubes is height-oriented.
In described electrostatic spinning process, voltage is 8-15KV.If voltage is too small, except fiber morphology cannot ensure, little electrostatic force can cause CNT to decline along the degree of orientation of machine direction; If voltage is excessive, electrostatic force is greater than the entanglement effect of elastomer molecules interchain, can cause the rapid resilience of strand, and a large amount of pearl alters to cause fiber to occur, affects the degree of orientation of CNT further.
In described electrostatic spinning process, connect flight lead from being 15-25cm.If apart from too short, the fiber aerial time of staying is too short, is unfavorable for the volatilization of solvent, and then affects the pattern of fiber; If apart from long, the fiber amount of deflection produced because of electrostatic force is excessive, is unfavorable for the reception of cylinder to fiber, affects the orientations of fiber on cylinder further.
In described electrostatic spinning process: drum rotation speed is 300-450m/min.If rotating speed is excessively slow, the velocity of rotation of cylinder is less than the wire vent speed of fiber, and a large amount of fibers has little time will pile up film forming through the traction of cylinder, and the degree of orientation of fiber reduces greatly; If rotating speed is too fast, cylinder rotates the wire vent direction that the air-flow caused can upset fiber, also can affect the orientations of fiber.
Further, last handling process described in step 3 is pressure sintering, and pressure sintering is by described CNT/elastomer composite tunica fibrosa melting under certain pressure and temperature, forms described CNT/elastic composite after cooling.
Pressure in described pressure sintering is less than 5MPa, and temperature is the above 20-30 DEG C of melt temperature of polymer.The distortion of CNT/elastomer composite tunica fibrosa can be caused when pressure is excessive, cause the orientation of CNT to destroy even Second Aggregation, affect the dielectric properties of composite.Described pressure sintering is applicable to the elastomer of melt temperature lower than decomposition temperature, and described solvent method is applicable to the elastomer of melt temperature higher than decomposition temperature.
Further, last handling process described in step 3 is solvent method, solvent method is dripped by a small amount of solvent in described CNT/elastomer composite tunica fibrosa surface, and give certain pressure, polymer secondary is dissolved, and due to pressure restriction keep shape there is not large deformation, obtain described CNT/elastic composite subsequently after drying.
A kind of elastic composite being prepared the high dielectric constant and low dielectric loss of gained by said method.The excess effusion value that the present invention obtains elastic composite can improve 460%; During excess effusion value, dielectric constant can improve 104%, and dielectric loss remains on the reduced levels of <1.
A kind of dielectric properties assay method of elastic composite of high dielectric constant and low dielectric loss, comprise the following steps: by conductive silver glue acetone diluted, and brush evenly respectively with the upper and lower surface that fine, soft fur brush amasss the elastic composite electrode test piece of the high dielectric constant and low dielectric loss for 1cm*1cm in obtained thick 0.5mm, upper and lower surface; Then dry in the convection oven of 60 DEG C, conductive silver glue is solidified, be i.e. obtained electrode; Adopt Agilent 4294A type electric impedance analyzer test electrode at room temperature, 10
2-10
7dielectric constant in the frequency range of Hz and dielectric loss.
Elastic composite of this high dielectric constant and low dielectric loss and preparation method thereof, compared with traditional preparation method, has following beneficial effect:
(1) the present invention is by controlling CNT orientations and improve the excess effusion value of composite in the base, and then by increasing the content of CNT, while improving the dielectric constant of composite, its dielectric loss is remained on a lower level, solve the problem that dielectricity composite high-k and low-dielectric loss can not be taken into account.
(2) CNT in the present invention under the effect of electric field force and elastomer molecules chain orientation are induced, arranges along fiber-wall-element model in electrostatic spinning process; Pass through the cylinder of High Rotation Speed again as receiving system, make fiber under the traction of high speed rotary-drum, along drum rotating direction orientations, and then CNT/elastomer composite tunica fibrosa that in obtaining, carbon nanotubes is height-oriented.
Accompanying drawing explanation
Fig. 1: CNT dispersity schematic diagram in elastomer matrix in the present invention.
Description of reference numerals:
1-strand; 2-CNT.
Detailed description of the invention
Below in conjunction with Fig. 1, the present invention will be further described:
Embodiment one: using amino content be the thermoplastic polyurethane (TPU) of 34% as elastomer matrix, preparation content of carbon nanotubes be 0.5%, the CNT/TPU dielectric composite material of CNT orientation.
1) configure TPU/ oxolane (THF) solution, at 50 DEG C, constant temperature 2h to TPU dissolves completely; By the carboxy-modified CNT of certain mass concentration at DMF (DMF) dispersant ultrasonic disperse 2h; Mixed with carbon nano tube suspension by above-mentioned TPU/THF solution, magnetic agitation, form the CNT/TPU/THF/DMF suspension of even carbon nanotube dispersion, wherein THF and DMF mass ratio is 7:3.TPU is 5g; CNT is 0.025g; THF is 31.5g; DMF is 13.5g.
2) above-mentioned solution is placed in plastics injector for medical purpose, adopts flat end stainless steel syringe needle, by the syringe needle that its needle point sand paper polishes; The anode of high pressure generator connects syringe needle, negative electrode connection metal cylinder, and polymer solution produces to spray and forms fiber under the progradation and electric field action of syringe.Voltage is provided by BGG high voltage direct current generator (High Technologies Co., Ltd., Beijing Electromechanical Academy, China).Using the metal roller of Surface coating aluminium-foil paper as receiving system, external diameter is the rotating speed High Rotation Speed of metal roller with 400m/min of 10cm.
3) after a large amount of composite fibre piles up film forming, by tunica fibrosa 700 DEG C, hot-forming under 0.5Mpa pressure, get rid of the space that formation piled up by fiber, obtain CNT/TPU composite that is closely knit, surface smoothing.
4) composite is cut into thick 0.5mm, upper and lower surface amasss as 1cm*1cm, coat silver electrode respectively on upper and lower two surfaces, make the electrode test piece that area is 1cm*1cm.With Agilent 4294A type electric impedance analyzer test its at room temperature, 10
2-10
7dielectric constant in the frequency range of Hz.The dielectric constant of the CNT obtained/TPU composite and dielectric loss data are in table 1.
Embodiment two: preparation method and method of testing are with embodiment one, and the content unlike CNT is 1.2%.Test result is in table 1.
Embodiment three: preparation method and method of testing are with embodiment one, and the content unlike CNT is 1.6%.Test result is in table 1.
Embodiment four: preparation method and method of testing are with embodiment one, and the content unlike CNT is 2.0%.Test result is in table 1.
Embodiment five: preparation method and method of testing are with embodiment one, and the content unlike CNT is 2.8%.Test result is in table 1.
Embodiment six: preparation method and method of testing are with embodiment one, and the content unlike CNT is 4.0%.Test result is in table 1.
Comparative example one: using THF solution degree be the TPU of 98% as elastomer matrix, adopt solution plastic film mulch legal system for content of carbon nanotubes be 0.5%, the CNT/TPU dielectric composite material of CNT random dispersion.
1) configure TPU/ oxolane (THF) solution, at 50 DEG C, constant temperature 2h to TPU dissolves completely; By the carboxy-modified CNT of certain mass concentration at DMF (DMF) dispersant ultrasonic disperse 2h; Mixed with carbon nano tube suspension by above-mentioned TPU/THF solution, magnetic agitation, form the CNT/TPU/THF/DMF suspension of even carbon nanotube dispersion, wherein THF and DMF mass ratio is 7:3.
2) spread in tetrafluoro groove by above-mentioned CNT/TPU/TPU/DMF suspension, slowly volatilize at ambient temperature, after about 1 day, the THF in solvent divides basic volatilization completely.Secondly, tetrafluoro groove is transferred in 80 DEG C of baking ovens the DMF removed in solvent.Finally vacuumize 4h under 80 DEG C of conditions, obtains CNT/TPU composite that is closely knit, surface smoothing.
3) composite is cut into thick 0.5mm, upper and lower surface amasss as 1cm*1cm, coat silver electrode respectively on upper and lower two surfaces, make the electrode test piece that area is 1cm*1cm.With Agilent 4294A type electric impedance analyzer test its at room temperature, 10
2-10
7dielectric constant in the frequency range of Hz.The dielectric constant of the CNT obtained/TPU composite and dielectric loss data are in table 1.
Comparative example two: preparation method and method of testing are with comparative example one, and the content unlike CNT is 1.0%.Test result is in table 1.
Comparative example three: preparation method and method of testing are with comparative example one, and the content unlike CNT is 1.2%.Test result is in table 1.
The excess effusion value of the CNT dielectric composite material adopting traditional solution plastic film mulch legal system standby is 0.5%, and the excess effusion value of the CNT dielectric composite material adopting method provided by the invention to prepare is 2.8%, improves 460%.Further, data as can be seen from table one, adopt CNT dielectric composite material prepared by method provided by the invention, its dielectric loss all remains on the reduced levels of <1, and dielectric constant can reach 104.9, reach the effect that high-k and low-dielectric loss get both.In addition, when the dielectric constant of above-mentioned two kinds of method gained composites is close, adopt the composite that method of the present invention is obtained, its dielectric loss is all much smaller than the composite obtained by conventional solution method; When the dielectric loss of above-mentioned two kinds of method gained composites is close, adopt the composite that method of the present invention is obtained, its dielectric constant is much larger than the composite obtained by conventional solution method.
Above by reference to the accompanying drawings to invention has been exemplary description; obvious realization of the present invention is not subject to the restrictions described above; as long as have employed the various improvement that method of the present invention is conceived and technical scheme is carried out; or design of the present invention and technical scheme directly applied to other occasion, all in protection scope of the present invention without to improve.
Claims (10)
1. an elastic composite preparation method for high dielectric constant and low dielectric loss, comprises the following steps:
Step 1, carbon nanotube dispersed is obtained the good suspension a of carbon nanotube dispersed in dispersant, wherein the mass ratio of CNT and dispersant is 0.1%-8%; Be dissolved in by elastomer in solvent, obtain consoluet solution b, the mass ratio of its elastomer and solvent is 8%-30%; Described suspension a is mixed with described solution b and stirred, obtains CNT/elastomer/solvent suspension liquid, CNT is 0.5wt%-10wt% relative to elastomeric content;
Step 2, described CNT/elastomer/solvent suspension liquid is carried out electrostatic spinning process, obtain CNT/elastomer composite tunica fibrosa; Wherein, in described electrostatic spinning process, voltage is 8 ~ 15KV, and connect flight lead from being 15 ~ 25cm, drum rotation speed is 300 ~ 450m/min;
Step 3, described CNT/elastomer composite tunica fibrosa is carried out post processing, get rid of the space that formation piled up by fiber, obtain CNT/elastic composite that is closely knit and surface smoothing.
2. the elastic composite preparation method of high dielectric constant and low dielectric loss according to claim 1, it is characterized in that: the dispersant used in step 1 is oxolane, any one in acetone, ethanol, methyl alcohol, toluene or DMF (DMF).
3. the elastic composite preparation method of high dielectric constant and low dielectric loss according to claim 1, it is characterized in that: the described solvent used in step 1 is elastomer good solvent, described elastomer good solvent is the organic solvent that the boiling point of normal atmosphere pressure is less than 80 DEG C.
4. the elastic composite preparation method of high dielectric constant and low dielectric loss according to claim 3, is characterized in that: described organic solvent is any one in carrene, chloroform, oxolane, DMF, acetone, MEK, cyclohexane, benzene, ethyl acetate, ethanol or methyl alcohol.
5. the elastic composite preparation method of high dielectric constant and low dielectric loss according to claim 1, is characterized in that: the elastomer used in step 1 is Polyurethane Thermoplastic Elastomer (TPU), any one or multiple in styrene analog thermoplastic elastomer, thermoplastic polyester elastomer (TPEE) or thermoplastic polyamide elastomer (TPAE).
6. the elastic composite preparation method of high dielectric constant and low dielectric loss according to claim 1, is characterized in that: use treating apparatus to comprise plastics injector for medical purpose, BGG high voltage direct current generator and the metal roller with Surface coating aluminium-foil paper in step 2 in electrostatic spinning; The anode of BGG high voltage direct current generator connects syringe needle, negative electrode connection metal cylinder, and described CNT/elastomer/solvent suspension liquid produces to spray and forms fiber under the progradation and electric field action of syringe.
7. the elastic composite preparation method of high dielectric constant and low dielectric loss according to claim 1, it is characterized in that: last handling process described in step 3 is pressure sintering, pressure sintering is by described CNT/elastomer composite tunica fibrosa melting under certain pressure and temperature, forms described CNT/elastic composite after cooling.
8. the elastic composite preparation method of high dielectric constant and low dielectric loss according to claim 7, it is characterized in that: the pressure in described pressure sintering is less than 5MPa, temperature is the above 20-30 DEG C of melt temperature of polymer.
9. the elastic composite preparation method of high dielectric constant and low dielectric loss according to claim 1, it is characterized in that: last handling process described in step 3 is solvent method, solvent method is dripped by a small amount of solvent in described CNT/elastomer composite tunica fibrosa surface, and give certain pressure, polymer secondary is dissolved, and due to pressure restriction keep shape there is not large deformation, obtain described CNT/elastic composite subsequently after drying.
10. the elastic composite of high dielectric constant and low dielectric loss that obtains of a claim 1 to 9 preparation method described in any one.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418089A (en) * | 2008-12-03 | 2009-04-29 | 中国热带农业科学院农产品加工研究所 | Method for preparing natural rubber-carbon nano tube composite material by using static electricity self-assembly |
| CN101899177A (en) * | 2010-07-09 | 2010-12-01 | 北京化工大学 | High dielectric constant and low-modulus dielectric elastomer material and preparation method thereof |
| CN101899185A (en) * | 2010-06-21 | 2010-12-01 | 中国科学院苏州纳米技术与纳米仿生研究所 | Method for making carbon nano tube/polystyrene composite conductive material |
| CN102115530A (en) * | 2009-12-30 | 2011-07-06 | 上海杰事杰新材料(集团)股份有限公司 | Method for preparing polyester-ether elastomer/carbon nanotube composite material |
| CN102673070A (en) * | 2012-05-24 | 2012-09-19 | 苏州大学 | Asymmetrical layer-shaped resin matrix composite material and preparation method thereof |
| CN102702745A (en) * | 2012-06-15 | 2012-10-03 | 苏州大学 | Preparation method of carbon nanotube/thermosetting resin composite material |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090230363A1 (en) * | 2007-11-14 | 2009-09-17 | Samsung Electro-Mechanics Co., Ltd. | Polymer composite |
| JP5674143B2 (en) * | 2011-03-09 | 2015-02-25 | 株式会社豊田中央研究所 | Dielectric material |
-
2013
- 2013-04-23 CN CN201310141622.1A patent/CN103194858B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418089A (en) * | 2008-12-03 | 2009-04-29 | 中国热带农业科学院农产品加工研究所 | Method for preparing natural rubber-carbon nano tube composite material by using static electricity self-assembly |
| CN102115530A (en) * | 2009-12-30 | 2011-07-06 | 上海杰事杰新材料(集团)股份有限公司 | Method for preparing polyester-ether elastomer/carbon nanotube composite material |
| CN101899185A (en) * | 2010-06-21 | 2010-12-01 | 中国科学院苏州纳米技术与纳米仿生研究所 | Method for making carbon nano tube/polystyrene composite conductive material |
| CN101899177A (en) * | 2010-07-09 | 2010-12-01 | 北京化工大学 | High dielectric constant and low-modulus dielectric elastomer material and preparation method thereof |
| CN102673070A (en) * | 2012-05-24 | 2012-09-19 | 苏州大学 | Asymmetrical layer-shaped resin matrix composite material and preparation method thereof |
| CN102702745A (en) * | 2012-06-15 | 2012-10-03 | 苏州大学 | Preparation method of carbon nanotube/thermosetting resin composite material |
Non-Patent Citations (3)
| Title |
|---|
| Cheng Yang等.Modified carbon nanotube composites with high dielectric constant, low dielectric loss and large energy density.《ScienceDirect》.2009,第47卷(第4期), * |
| 江枫丹.聚氨酯碳纳米管纳米复合材料的制备及结构与性能的研究.《中国博士学位论文全文数据库(电子期刊)》.2011,(第11期), * |
| 王川.静电纺丝法制备PU/MWNTs纳米复合材料及其性能的研究.《中国优秀硕士学位论文全文数据库(电子期刊)》.2009,(第10期), * |
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