CN103183906A - Flame-retardant phenolic glass fibre reinforced plastic composite material - Google Patents
Flame-retardant phenolic glass fibre reinforced plastic composite material Download PDFInfo
- Publication number
- CN103183906A CN103183906A CN2011104429402A CN201110442940A CN103183906A CN 103183906 A CN103183906 A CN 103183906A CN 2011104429402 A CN2011104429402 A CN 2011104429402A CN 201110442940 A CN201110442940 A CN 201110442940A CN 103183906 A CN103183906 A CN 103183906A
- Authority
- CN
- China
- Prior art keywords
- parts
- fire
- retardant
- reinforced plastics
- fiberglass reinforced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a flame-retardant phenolic glass fibre reinforced plastic composite material, and belongs to the technical field of thermosetting moulding compounds. The flame-retardant phenolic glass fibre reinforced plastic composite material is composed of the raw materials in the following parts by weight: 89-90 parts of phenolic resin, 8-12 parts of curing agent, 2.2-3 parts of curing accelerator, 5-10 parts of flame retardant, 2.5-3.2 parts of release agent, 95-102 parts of mineral fillers, 42-50 parts of reinforced fibres, and 7-10 parts of flame retardant. The flame-retardant phenolic glass fibre reinforced plastic composite material has the characteristics of being high in strength, convenient to process, good in flame retardance, and the like.
Description
Technical field
The invention belongs to the duroplastic moulding materials technical field, be specifically related to a kind of fire-retardant phenolic fiberglass reinforced plastics matrix material.
Background technology
The phenolic fiberglass reinforced plastics material is with its intensity height, cheaply enjoys people to like always, but still burning easily when the phenolic fiberglass reinforced plastics material runs into burning things which may cause a fire disaster causes damage of material, and can cause Serious Accident, therefore is necessary to promote its flame retardant properties.
Summary of the invention
Task of the present invention is that a kind of fire-retardant phenolic fiberglass reinforced plastics matrix material with excellent fire retardant effect will be provided.
Task of the present invention is finished like this, a kind of fire-retardant phenolic fiberglass reinforced plastics matrix material, and it is that raw material by following parts by weight constitutes:
85～90 parts in resol;
8～12 parts in solidifying agent;
2.2～3 parts of curing catalysts;
5～10 parts of fire retardants;
2.5～3.2 parts of releasing agents;
95～102 parts of mineral fillers;
42～50 parts of fortifying fibres.
In one embodiment of the present of invention, described resol is that sulfuric acid is as the resol of Catalyst Production.
In an alternative embodiment of the invention, described solidifying agent is six methylene radical tetramines.
Among another embodiment of the present invention, described curing catalyst is calcium oxide.
Among another embodiment of the present invention, described fire retardant is decabromodiphynly oxide or TDE.
Of the present invention also have among the embodiment, and described releasing agent is Zinic stearas.
More of the present invention and among embodiment, described filler is for referring to calcium carbonate.
Among of the present invention and then embodiment, described fortifying fibre is glass fibre.
Fire-retardant phenolic fiberglass reinforced plastics matrix material provided by the invention has characteristics such as intensity is good, convenient formation, good flame resistance.Through test, flexural strength 90MPa, 240 ℃ of heat-drawn wires, flame retardant properties reach UL-94-V-0 level (1.6mm).
Embodiment
Embodiment 1
85 parts in resol (sulfuric acid as Catalyst Production);
8 parts of six methylene radical tetramines;
2.2 parts in calcium oxide;
5 parts of decabromodiphynly oxides;
2.5 parts of Zinic stearass;
95 parts in calcium carbonate;
42 parts in glass fibre.
During concrete enforcement, the accurate above-mentioned each component of weighing after mixing then, is transferred to and plasticates 6 minutes in the mill at first successively, and then cooling is pulverized behind the pulling-on piece, namely obtains the fire-retardant phenolic fiberglass reinforced plastics matrix material of true qualities.
Embodiment 2
87 parts in resol (sulfuric acid as Catalyst Production);
9.2 parts of six methylene radical tetramines;
2.4 parts in calcium oxide;
6.8 parts of decabromodiphynly oxides;
2.8 parts of Zinic stearass;
97 parts in calcium carbonate;
45 parts in glass fibre;
1 part of carbon black.
During concrete enforcement, the accurate above-mentioned each component of weighing after mixing then, is transferred to and plasticates 6 minutes in the mill at first successively, and then cooling is pulverized behind the pulling-on piece, namely obtains the fire-retardant phenolic fiberglass reinforced plastics matrix material of black.
Embodiment 3
88 parts in resol (sulfuric acid as Catalyst Production);
11.2 parts of six methylene radical tetramines;
2.7 parts in calcium oxide;
8.8 parts of decabromodiphynly oxides;
3.0 parts of Zinic stearass;
100 parts in calcium carbonate;
47 parts in glass fibre;
Green 3 parts of phthalein cyanogen.
During concrete enforcement, the accurate above-mentioned each component of weighing after mixing then, is transferred to and plasticates 6 minutes in the mill at first successively, and then cooling is pulverized behind the pulling-on piece, namely obtains green fire-retardant phenolic fiberglass reinforced plastics material.
Embodiment 4
90 parts in resol (sulfuric acid as Catalyst Production);
11.8 parts of six methylene radical tetramines;
2.9 parts in calcium oxide;
9.8 parts of decabromodiphynly oxides;
3.2 parts of Zinic stearass;
102 parts in calcium carbonate;
49 parts in glass fibre;
Blue 3 parts of phthalein cyanogen.
During concrete enforcement, the accurate above-mentioned each component of weighing after mixing then, is transferred to and plasticates 6 minutes in the mill at first successively, and then cooling is pulverized behind the pulling-on piece, namely obtains blue fire-retardant phenolic fiberglass reinforced plastics material.
Through test, above-mentioned fire-retardant phenolic fiberglass reinforced plastics matrix material has following performance:
Claims (8)
1.
A kind of fire-retardant phenolic fiberglass reinforced plastics matrix material is characterized in that it is that raw material by following parts by weight constitutes:
85 ~ 90 parts in resol;
8 ~ 12 parts in solidifying agent;
2.2 ~ 3 parts of curing catalysts;
5 ~ 10 parts of fire retardants;
2.5 ~ 3.2 parts of releasing agents;
95 ~ 102 parts of mineral fillers;
42 ~ 50 parts of fortifying fibres.
2.
Fire-retardant phenolic fiberglass reinforced plastics matrix material according to claim 1 is characterized in that described resol is that sulfuric acid is as the resol of Catalyst Production.
3.
Fire-retardant phenolic fiberglass reinforced plastics matrix material according to claim 1 is characterized in that described solidifying agent is six methylene radical tetramines.
4.
Fire-retardant phenolic fiberglass reinforced plastics matrix material according to claim 1 is characterized in that described curing catalyst is calcium oxide.
5.
Fire-retardant phenolic fiberglass reinforced plastics matrix material according to claim 1 is characterized in that described fire retardant is decabromodiphynly oxide or TDE.
6.
Fire-retardant phenolic fiberglass reinforced plastics matrix material according to claim 1 is characterized in that described releasing agent is Zinic stearas.
7.
Fire-retardant phenolic fiberglass reinforced plastics matrix material according to claim 1 is characterized in that described filler is for referring to calcium carbonate.
8.
Fire-retardant phenolic fiberglass reinforced plastics matrix material according to claim 1 is characterized in that described fortifying fibre is glass fibre
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104429402A CN103183906A (en) | 2011-12-27 | 2011-12-27 | Flame-retardant phenolic glass fibre reinforced plastic composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104429402A CN103183906A (en) | 2011-12-27 | 2011-12-27 | Flame-retardant phenolic glass fibre reinforced plastic composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103183906A true CN103183906A (en) | 2013-07-03 |
Family
ID=48675365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104429402A Pending CN103183906A (en) | 2011-12-27 | 2011-12-27 | Flame-retardant phenolic glass fibre reinforced plastic composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103183906A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277485A (en) * | 2014-11-03 | 2015-01-14 | 合肥华信电动科技发展有限公司 | Flame retardant glass fiber reinforced plastic |
| CN107325481A (en) * | 2017-08-16 | 2017-11-07 | 常州信息职业技术学院 | A kind of phenoplasts inspection shaft well lid and preparation method thereof |
| CN110774675A (en) * | 2019-11-12 | 2020-02-11 | 河北华强科技开发有限公司 | Fire-resistant glass fiber reinforced plastic composite board and manufacturing method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101343397A (en) * | 2008-08-22 | 2009-01-14 | 常熟东南塑料有限公司 | Halogen-free flame-proof phenolic plastic |
-
2011
- 2011-12-27 CN CN2011104429402A patent/CN103183906A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101343397A (en) * | 2008-08-22 | 2009-01-14 | 常熟东南塑料有限公司 | Halogen-free flame-proof phenolic plastic |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104277485A (en) * | 2014-11-03 | 2015-01-14 | 合肥华信电动科技发展有限公司 | Flame retardant glass fiber reinforced plastic |
| CN107325481A (en) * | 2017-08-16 | 2017-11-07 | 常州信息职业技术学院 | A kind of phenoplasts inspection shaft well lid and preparation method thereof |
| CN110774675A (en) * | 2019-11-12 | 2020-02-11 | 河北华强科技开发有限公司 | Fire-resistant glass fiber reinforced plastic composite board and manufacturing method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103183931B (en) | Phenolic epoxy glass fibre reinforced plastic forming material | |
| CN101343397A (en) | Halogen-free flame-proof phenolic plastic | |
| CN103183909A (en) | Flame-retardant antibacterial phenolic moulding compound | |
| CN103183907A (en) | High-temperature-resistant phenolic glass fibre reinforced plastic material | |
| CN103160068A (en) | Phenolic glass fiber reinforced plastic composite material | |
| CN103183902A (en) | Antibacterial phenolic moulding compound | |
| CN103183906A (en) | Flame-retardant phenolic glass fibre reinforced plastic composite material | |
| CN103160071A (en) | Halogen-free flame-retardation phenolic fiber reinforced plastic composite material | |
| CN103183918A (en) | Thermosetting moulding compound filled with glass beads | |
| CN105061984A (en) | Flame-retardant antimicrobial phenolic plastic | |
| CN103183908A (en) | High-temperature-resistant phenolic moulding compound | |
| CN102850716B (en) | Flame retardant conductive composite material | |
| CN103183903A (en) | Flame-retardant phenolic resin forming material modified by epoxy resin | |
| CN103172976A (en) | Method for manufacturing helmet by using flame-retardant heat-resistant high-performance hybrid glass fiber prepreg | |
| CN103160073A (en) | Modified phenolic glass fiber reinforced plastic composite material | |
| CN103160067A (en) | Epoxy resin modified phenolic molding compound | |
| CN102875965A (en) | Preparation method of flame-retardant conducting composite material | |
| CN103160065A (en) | Flame-retardation polystyrene-modified phenolic resin composite material | |
| CN103254610A (en) | Flame-retardant glass fiber-reinforced polyphenylene ether composite material | |
| CN103183917A (en) | Halogen-free flame-retardant thermosetting moulding compound filled with glass beads | |
| CN103183916A (en) | Halogen-free flame-retardant conductive polymer moulding compound | |
| CN103183919A (en) | Conductive phenolic resin forming material | |
| CN103183913A (en) | Phenolic composite material filled with metal fibres | |
| CN103160069A (en) | Flame-retardation nano-rubber-modified phenolic resin composite material | |
| CN102719090A (en) | Preparation process of conductive halogen-free flame-retardant PA/PE(polyamide/polyethylene) alloy material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130703 |