CN103175495A - Standard silicon dioxide wafer and production method thereof - Google Patents

Standard silicon dioxide wafer and production method thereof Download PDF

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CN103175495A
CN103175495A CN2013100624763A CN201310062476A CN103175495A CN 103175495 A CN103175495 A CN 103175495A CN 2013100624763 A CN2013100624763 A CN 2013100624763A CN 201310062476 A CN201310062476 A CN 201310062476A CN 103175495 A CN103175495 A CN 103175495A
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silicon dioxide
wafer
thickness
layer
passivation layer
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CN103175495B (en
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李�杰
王智
苏俊铭
张旭升
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Shanghai Huali Microelectronics Corp
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Shanghai Huali Microelectronics Corp
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Abstract

The invention provides a standard silicon dioxide wafer and a production method thereof. The standard silicon dioxide wafer comprises a wafer, a silicon dioxide layer formed on the wafer and in standard thickness, and a passivation layer formed on the silicon dioxide layer. The silicon dioxide layer can be separated from the external environment by the passivation layer, the thickness of the silicon dioxide layer is kept unchanged, and accordingly the interference of the standard silicon dioxide wafer upon measurement precision of a measuring machine is avoided.

Description

Silicon dioxide standard wafer and manufacture method thereof
Technical field
The present invention relates to integrated circuit and make field, particularly a kind of silicon dioxide standard wafer and manufacture method thereof.
Background technology
Along with the development of semiconductor technology, process constantly descends.Accordingly, the silicon dioxide thickness as dielectric layer is also constantly reducing in integrated circuit.Along with the decline of silicon dioxide thickness, in order to keep the stability of silicon dioxide thickness, accuracy and stability that the standard wafer of silicon dioxide is measured are had higher requirement.
Usually, the silicon dioxide standard wafer is to form the silicon dioxide of standard thickness on substrate.Before the film thickness of the silicon dioxide of measuring the board measurement products, first measure the thickness of the silicon dioxide of described silicon dioxide standard wafer, if measurement result within the limits prescribed, the accuracy of judgement measurement board meets the requirements, and can continue the silica membrane of product is carried out thickness measure; If measurement result exceeds the scope of regulation, the accuracy of judgement measurement board is undesirable, need correcting measuring board again, until measure the scope that the measurement result of board falls into regulation, could continue the silica membrane of product is carried out thickness measure.If variation has occured in the thickness of the silicon dioxide of silicon dioxide standard wafer, be stable even measure board like this, certain deviation can occur with standard thickness in the thickness of the silicon dioxide that it is measured.That is to say, adopt the silicon dioxide standard wafer to determine that the accuracy of measurement board and the prerequisite of stability are that the thickness of the silicon dioxide of silicon dioxide standard wafer is fixed.
As shown in Figure 1, silicon dioxide standard wafer 100 comprises the silica 1 02 of the standard thickness on wafer 101 and formation and described wafer 101.Usually, silicon dioxide standard wafer 100 is positioned in air for a long time, and steam and other pollutants in air can be adsorbed in the surface of silica 1 02, also can form one deck natural oxidizing layer on its surface because of the oxidation reaction of nature in addition.Therefore, the result that the measurement board is measured silica 1 02 thickness of the silicon dioxide standard wafer 100 after above-mentioned long-term placement can exceed specialized range, and the result of its detect thickness can be larger than standard thickness usually.But, for the operator, can't judge that whether above-mentioned deviation is to cause owing to measuring the unstable of board, therefore can cause a lot of puzzlements to the operator.
Therefore, be necessary to develop a kind of silicon dioxide standard wafer, the thickness of its silicon dioxide is remained unchanged.
Summary of the invention
The object of the present invention is to provide a kind of silicon dioxide standard wafer and manufacture method thereof, continue the phenomenon that changes with the thickness of the silicon dioxide that solves existing silicon dioxide standard wafer, thereby cause measuring the unsettled problem of board measurement result.
For solving the problems of the technologies described above, the invention provides a kind of silicon dioxide standard wafer, comprising: wafer, be formed at the silicon dioxide layer of the standard thickness on described wafer and be formed at passivation layer on described silicon dioxide layer.
Optionally, on described silicon dioxide standard wafer, passivation layer is polysilicon or silicon nitride.
Optionally, on described silicon dioxide standard wafer, the thickness of described passivation layer more than or equal to
Figure BDA00002865239700022
Optionally, on described silicon dioxide standard wafer, the thickness of described passivation layer is
Figure BDA00002865239700023
Optionally, on described silicon dioxide standard wafer, the thickness of silicon dioxide layer less than
Accordingly, the present invention also provides a kind of manufacture method of silicon dioxide standard wafer, comprising:
Step 1 a: wafer is provided;
Step 2: the silicon dioxide layer that forms standard thickness on described wafer;
Step 3: form passivation layer on described silicon dioxide layer.
Optionally, in the manufacture method of described silicon dioxide standard wafer, in described step 3, adopt the LPCVD method on described silicon dioxide layer deposit spathic silicon as described passivation layer.
Optionally, in the manufacture method of described silicon dioxide standard wafer, described step 3 comprises:
Adopt LPCVD method deposit spathic silicon on described silicon dioxide layer; And
Described polysilicon is carried out annealing in process, to form described passivation layer.
Optionally, in the manufacture method of described silicon dioxide standard wafer, the temperature of described annealing in process is 700 ℃~800 ℃, and the time is 30 minutes~45 minutes.
Optionally, in the manufacture method of described silicon dioxide standard wafer, in described step 3, adopt the LPCVD method on described silicon dioxide layer deposited silicon nitride as described passivation layer.
Optionally, in the manufacture method of described silicon dioxide standard wafer, the thickness of described passivation layer more than or equal to
Figure BDA00002865239700021
Optionally, in the manufacture method of described silicon dioxide standard wafer, the thickness of described passivation layer
Figure BDA00002865239700031
Figure BDA00002865239700032
Optionally, in the manufacture method of described silicon dioxide standard wafer, the thickness of silicon dioxide layer less than
Figure BDA00002865239700033
On silicon dioxide standard wafer provided by the invention, also comprise passivation layer on described silicon dioxide layer.Passivation layer can be kept apart described silicon dioxide layer and external environment; because being arranged, the protection silicon dioxide layer surface of passivation layer can not adsorb steam or other airborne pollutants; also can not exist simultaneously the surface by the problem of autoxidation, thereby the silicon dioxide layer thickness that makes keep immobilizing.Therefore, measure board when measuring above-mentioned silicon dioxide standard wafer, because the silicon dioxide layer thickness is to keep changeless, therefore when measurement result exceeds specialized range, the accuracy that can judge described measurement board goes wrong, and needs the measuring system of correcting measuring board again.
Description of drawings
Fig. 1 is the structural representation of existing silicon dioxide standard wafer;
Fig. 2 is the structural representation of the silicon dioxide standard wafer of one embodiment of the invention;
Fig. 3-Fig. 4 is the structural representation of device in each step in the manufacture method of silicon dioxide standard wafer of one embodiment of the invention.
Embodiment
Below in conjunction with the drawings and specific embodiments, silicon dioxide standard wafer and the manufacture method thereof that the present invention proposes is described in further detail.According to the following describes and claims, advantages and features of the invention will be clearer.It should be noted that, accompanying drawing all adopts very the form of simplifying and all uses non-ratio accurately, only in order to convenient, the purpose of the aid illustration embodiment of the present invention lucidly.
As shown in Figure 2, the silicon dioxide standard wafer 200 of one embodiment of the invention comprises: wafer 201, be formed at the silicon dioxide layer 202 of the standard thickness on described wafer 201 and be formed at passivation layer 203 on described silicon dioxide layer 202.Wherein, described passivation layer 203 is polysilicon or silicon nitride.
In order to guarantee the protective effect of 203 pairs of silicon dioxide layers 202 of passivation layer, thickness that can described passivation layer 203 be set to more than or equal to Preferably, the thickness of described passivation layer 203 is
Figure BDA00002865239700035
Describe the manufacture method of silicon dioxide standard wafer in detail below in conjunction with Fig. 2 to Fig. 4.
Step 1: as shown in Figure 3, provide a wafer 201, the thickness of described wafer 201 is about 775 μ m;
Step 2: as shown in Figure 4, form the silicon dioxide layer 202 of standard thickness on described wafer 201;
Along with improving constantly of semiconductor integrated level, process constantly descends, and therefore the silicon dioxide thickness as dielectric layer is also constantly reducing.Accordingly, the thickness of the silicon dioxide layer 202 of silicon dioxide standard wafer 200 is corresponding reducing also, and is preferred, the thickness of silicon dioxide layer less than
Figure BDA00002865239700041
Step 3: as shown in Figure 2, form passivation layer 203 on described silicon dioxide layer 202.
Specifically, the wafer 201 after step 2 is placed on Low Pressure Chemical Vapor Deposition(LPCVD, low-pressure chemical vapor phase deposition) in boiler tube, furnace tube temperature is risen to 500 ℃~700 ℃, preferably 620 ℃.Under low voltage control, pass into the reacting gas SiH4 of certain flow ratio, the certain thickness polysilicon of reactive deposition is as described passivation layer 203.In order to improve the protection effect of 203 pairs of silicon dioxide layers 202 of passivation layer, usually, the thickness requirement of passivation layer 203 is greater than 500 thickness
Figure BDA00002865239700042
Preferably, the thickness of described passivation layer 203 is
Figure BDA00002865239700043
So far, formed silicon dioxide standard wafer 200 as shown in Figure 2.
In the present embodiment, the employing polysilicon of described passivation layer 203.Should be understood that, all can be used as passivation layer to the material that silicon dioxide layer 202 can play isolated protective effect, for example can also form one deck silicon nitride as passivation layer 203 on described silicon dioxide layer 202 by LPCVD technique.
In order further to improve the protection effect of 203 pairs of silicon dioxide layers 202 of passivation layer; in another embodiment of the present invention; the wafer that has deposited polysilicon is put into the normal pressure boiler tube carry out the high temperature anneal; furnace tube temperature rises between 700 ℃~800 ℃; pass into the N2 of certain flow, the processing time is 30 minutes~45 minutes.As described passivation layer 203, the compactness of the polysilicon after annealing in process is improved with the polysilicon of annealed processing, so it is to the protection effect of silicon dioxide layer 202 also corresponding being improved.
In sum, also comprise passivation layer on described silicon dioxide layer.Described passivation layer can be kept apart described silicon dioxide layer and external environment; because being arranged, the protection silicon dioxide layer surface of passivation layer can not adsorb steam or other airborne pollutants; also can not exist simultaneously the surface by the problem of autoxidation, thereby the silicon dioxide layer thickness that makes keep immobilizing.Therefore, measure board when measuring above-mentioned silicon dioxide standard wafer, because the silicon dioxide layer thickness is to keep changeless, therefore when measurement result exceeds specialized range, the accuracy that can judge described measurement board goes wrong, and needs the measuring system of correcting measuring board again.
Foregoing description is only the description to preferred embodiment of the present invention, is not any restriction to the scope of the invention, and any change, modification that the those of ordinary skill in field of the present invention is done according to above-mentioned disclosure all belong to the protection domain of claims.

Claims (13)

1. silicon dioxide standard wafer comprises: wafer and be formed at the silicon dioxide layer of the standard thickness on described wafer, it is characterized in that, and also comprise the passivation layer that is formed on described silicon dioxide layer.
2. silicon dioxide standard wafer as claimed in claim 1, is characterized in that, passivation layer is polysilicon or silicon nitride.
3. silicon dioxide standard wafer as claimed in claim 1, is characterized in that, the thickness of described passivation layer more than or equal to
Figure FDA00002865239600011
4. silicon dioxide standard wafer as claimed in claim 3, is characterized in that, the thickness of described passivation layer is
Figure FDA00002865239600012
5. silicon dioxide standard wafer as claimed in claim 1, is characterized in that, the thickness of silicon dioxide layer less than
Figure FDA00002865239600013
6. the manufacture method of a silicon dioxide standard wafer comprises:
Step 1 a: wafer is provided;
Step 2: the silicon dioxide layer that forms standard thickness on described wafer;
Step 3: form passivation layer on described silicon dioxide layer.
7. the manufacture method of silicon dioxide standard wafer as claimed in claim 6, is characterized in that, in described step 3, adopt the LPCVD method on described silicon dioxide layer deposit spathic silicon as described passivation layer.
8. the manufacture method of silicon dioxide standard wafer as claimed in claim 6, is characterized in that, described step 3 comprises:
Adopt LPCVD method deposit spathic silicon on described silicon dioxide layer; And
Described polysilicon is carried out annealing in process, to form described passivation layer.
9. the manufacture method of silicon dioxide standard wafer as claimed in claim 8, is characterized in that, the temperature of described annealing in process is 700 ℃~800 ℃, and the time is 30 minutes~45 minutes.
10. the manufacture method of silicon dioxide standard wafer as claimed in claim 6, is characterized in that, in described step 3, adopt the LPCVD method on described silicon dioxide layer deposited silicon nitride as described passivation layer.
11. the manufacture method of silicon dioxide standard wafer as claimed in claim 6 is characterized in that, the thickness of described passivation layer more than or equal to
Figure FDA00002865239600014
12. the manufacture method of silicon dioxide standard wafer as claimed in claim 11 is characterized in that, the thickness of described passivation layer
Figure FDA00002865239600021
13. the manufacture method of silicon dioxide standard wafer as claimed in claim 6 is characterized in that, the thickness of silicon dioxide layer less than
Figure FDA00002865239600022
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CN101872768A (en) * 2010-06-11 2010-10-27 清华大学 Ferroelectric dynamic random storage based on bismuth based storage materials and preparation method thereof
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