CN103173651A - Lead-free low-temperature alloy for fusible core of fuse at 212 DEG C and preparation method thereof - Google Patents
Lead-free low-temperature alloy for fusible core of fuse at 212 DEG C and preparation method thereof Download PDFInfo
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- CN103173651A CN103173651A CN 201310094614 CN201310094614A CN103173651A CN 103173651 A CN103173651 A CN 103173651A CN 201310094614 CN201310094614 CN 201310094614 CN 201310094614 A CN201310094614 A CN 201310094614A CN 103173651 A CN103173651 A CN 103173651A
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Abstract
The invention relates to a lead-free low-temperature alloy for the fusible core of a fuse at 212 DEG C, and the lead-free low-temperature alloy respectively comprises the following raw materials in percentage by weight: 0.4%-0.6% of Cu, 5.5%-6.5% of In, 0.4%-0.6% of Bi and the balance of Sn. The preparation method comprises the following steps of: (1) fusing tin: placing metallic tin into a stainless steel crucible, and heating on an electric furnace till the tin is fused; and (2) pouring: adding metallic copper at 280-320 DEG C, adding bismuth after the metallic copper is completely fused, adding indium after the bismuth is completely fused, adding a degassing agent after the indium is completely fused for degassing and deslagging, and pouring and moulding. The lead-free low-temperature alloy containing Sn, Cu, In and Bi, which is disclosed by the invention, is used for manufacturing the fusible core of a temperature fuse, achieves the fusing point of 212+/-2 DEG C, is an eutectic alloy, has the characteristics of uniform component, small fusing point range, low cost, and the like, is a lead-free environment-friendly material and has very good self social benefit and economic benefit.
Description
Technical field
The invention belongs to the alloy field, relate to the lead-free low-temperature alloy, especially a kind of 212 ℃ of fuse burn-out core lead-free low-temperature Alloy And Preparation Methods.
Background technology
Fusible core is the heart of Thermal Cutoffs, be the technological core of Thermal Cutoffs production technique, traditional Thermal Cutoffs mostly is tinsel, as a kind of material-lead that is harmful to environment, be detrimental to health in production and use procedure, environment is had great pollution.
Low-temperature alloy can be used for the protection of electronic circuit in electron trade, multiplex fusing core in making Thermal Cutoffs.It is that company is lived by thousand of the alpha of the U.S. and Japan that current low-temperature alloy leads the production firm of world's modern technique.
According to the retrieval, find the following patent documentation relevant to the application, wherein CN102296208A discloses a kind of lead-free low-temperature alloy of the fusing core for making Thermal Cutoffs, and its raw material consists of and weight percentage ranges is respectively: Bi:34%-36%; Zn:3.5%-4.5%; Sn: surplus; The step of its preparation method is: metallic tin is put into stainless crucible, heat on electric furnace, after the tin fusing, under 250-280 ℃, add metallic zinc, fusion clear after, then add bismuth metal, air release agent is degassed, slagging-off to carry out conventional adding after melting clearly, is cast into the low-temperature alloy rod that needs size.Patent documentation CN102912204A discloses a kind of lead-free low-temperature Alloy And Preparation Method and application, and this low-temperature alloy is comprised of tin, bismuth, three kinds of metals of indium, and each weight percentages of components is as follows: tin 15-17%; Bismuth 32-34%; Surplus is indium, and its preparation methods steps is: ⑴ melts tin; ⑵ melt bismuth; ⑶ melt indium; ⑷ degassed; ⑸ casting.Patent documentation CN101812623A discloses a kind of novel environment-friendly low-temperature alloy and preparation method thereof, and it mainly is made of indium, tin, bismuth, zinc, silver metal, on the basis that is associated gold at Bi-In-Sn, adds Zn, the metals such as Ag.
Front two pieces in above-mentioned patent documentation is the technical scheme of protection of the applicant application of this patent; from the application's other part be the composition of its alloy and component content different; the fusing point of final alloy is different; belong to different products; the 3rd piece of file is other applicants' technical scheme; have larger difference with the application's technical scheme, its product fusing point and component content are all different.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art part, provide a kind of melting range narrow, cost is low, 212 ℃ of fuse burn-out core lead-free low-temperature alloys of leadless environment-friendly, the preparation method of this simple, easy to operate alloy of step is provided simultaneously, and the fuse burn-out core of this alloy preparation, the fusing point of the low-temperature alloy of present method preparation is 212 ± 2 ℃.
The objective of the invention is to be achieved through the following technical solutions:
A kind of 212 ℃ of fuse burn-out core lead-free low-temperature alloys, its raw material consists of and weight percentage ranges is respectively:
Cu:0.4%-0.6%;
In:5.5%-6.5%;
Bi:0.4%-0.6%;
Sn: surplus.
And its raw material consists of and weight percent is:
Cu:0.5%;
In:6%;
Bi:0.5%;
Sn:93%。
A kind of preparation method of 212 ℃ of fuse burn-out core lead-free low-temperature alloys, preparation method's step is:
⑴ melt tin: metallic tin is put into stainless crucible, heat on electric furnace, and after the tin fusing,
⑵ casting: under 280-320 ℃, add metallic copper, fusion clear after, then add bismuth; After bismuth is molten clear, then add indium, moltenly add that air release agent is degassed, slagging-off after clear, be cast into the low-temperature alloy rod that needs size.
A kind of 212 ℃ of fuse burn-out cores carry out extrusion molding with the low-temperature alloy rod, and concrete steps are: with extrusion machine extruding low-temperature alloy rod, the low-temperature alloy silk of extruding corresponding size uses as the fusing core of Thermal Cutoffs.
Advantage of the present invention and positively effect are:
1, the lead-free low-temperature alloy that contains Sn, Cu, In, Bi of the present invention's preparation, ratio by the various compositions of meticulous adjusting, make the fusing point of the alloy of preparing reach 212 ± 2 ℃, melting range is narrow, this low-temperature alloy is eutectic alloy, have the characteristics such as homogeneous chemical composition, cost are low, be used for making the fusing core of Thermal Cutoffs, safe and reliable.
2, low-temperature alloy of the present invention is the leadless environment-friendly material, can replace traditional tinsel, and its composition is not leaded, is therefore the leadless environment-friendly material, has good social benefit and economic benefit.
Embodiment
Further illustrate the present invention below in conjunction with specific embodiment; It is emphasized that: to those skilled in the art, can be improved according to the above description or conversion, and all these improve and conversion all should belong to the protection domain of claims of the present invention.
A kind of 212 ℃ of fuse burn-out core lead-free low-temperature alloys, its concrete composition is Sn
93Cu
0.5In
6Bi
0.5, concrete composition and weight proportion are as follows:
Cu:0.5%;
In:6%;
Bi:0.5%;
Sn:93%。
Can also adopt the proportioning as following table, summation is 100%
Chemical composition % | Sn | Cu | In | Bi |
100% | 92-94 | 0.4-0.6 | 5.5-6.5 | 0.4-0.6 |
A kind of preparation method of 212 ℃ of fuse burn-out core lead-free low-temperature alloys, step is:
⑴ melt tin: by weight ratio metallic tin is put into stainless crucible, be heated to the tin fusing on electric furnace;
⑵ casting: under 280-320 ℃, add metallic copper, fusion clear after, then add bismuth; After bismuth is molten clear, then add indium, moltenly add that air release agent is degassed, slagging-off after clear, the low-temperature alloy rod that is cast into diameter and is;
⑶ extrusion molding: with the vertical extruders of 100 tons extruding, extrusion temperature is 80 ℃, the 5 holes extruding that mould is, and the low-temperature alloy silk of extruding diameter and being uses as the fusing core of Thermal Cutoffs.
The metallic tin that uses in the embodiment of the present invention, copper, bismuth, indium and air release agent are the known products of the industry.
The fusing point that confirms by experiment the alloy prepare reaches 212 ± 2 ℃.
Claims (4)
1. one kind 212 ℃ fuse burn-out core lead-free low-temperature alloys is characterized in that: its raw material consists of and weight percentage ranges is respectively:
Cu:0.4%-0.6%;
In:5.5%-6.5%;
Bi:0.4%-0.6%;
Sn: surplus.
2. 212 ℃ of fuse burn-out core lead-free low-temperature alloys according to claim 1 is characterized in that: its raw material consists of and weight percent is:
Cu:0.5%;
In:6%;
Bi:0.5%;
Sn:93%。
3. the preparation method of 212 ℃ of fuse burn-out core lead-free low-temperature alloys as claimed in claim 1, it is characterized in that: preparation method's step is:
⑴ melt tin: metallic tin is put into stainless crucible, heat on electric furnace, and after the tin fusing,
⑵ casting: under 280-320 ℃, add metallic copper, fusion clear after, then add bismuth; After bismuth is molten clear, then add indium, moltenly add that air release agent is degassed, slagging-off after clear, be cast into the low-temperature alloy rod that needs size.
4. 212 ℃ of fuse burn-out cores, it is characterized in that: the low-temperature alloy rod that claim 3 is prepared carries out extrusion molding, concrete steps are: with extrusion machine extruding low-temperature alloy rod, extrude the low-temperature alloy silk of corresponding size as the fusing core of Thermal Cutoffs.
Priority Applications (1)
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CN 201310094614 CN103173651A (en) | 2013-03-22 | 2013-03-22 | Lead-free low-temperature alloy for fusible core of fuse at 212 DEG C and preparation method thereof |
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CN 201310094614 CN103173651A (en) | 2013-03-22 | 2013-03-22 | Lead-free low-temperature alloy for fusible core of fuse at 212 DEG C and preparation method thereof |
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CN103173651A true CN103173651A (en) | 2013-06-26 |
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CN 201310094614 Pending CN103173651A (en) | 2013-03-22 | 2013-03-22 | Lead-free low-temperature alloy for fusible core of fuse at 212 DEG C and preparation method thereof |
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Application publication date: 20130626 |