CN103173049B - A kind of protective system containing composite modifier - Google Patents
A kind of protective system containing composite modifier Download PDFInfo
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- CN103173049B CN103173049B CN201310060580.9A CN201310060580A CN103173049B CN 103173049 B CN103173049 B CN 103173049B CN 201310060580 A CN201310060580 A CN 201310060580A CN 103173049 B CN103173049 B CN 103173049B
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Abstract
The invention discloses a kind of protective system containing composite modifier, it is made up of first and second liang of components, does is described first component made up of the raw material of following weight parts: epoxy resin E51? 75-85, HCPE 15-20, titanium dioxide 5-10, pure aluminium silicate 3-5, sodium laurylsulfonate 3-5, sodium Diacetate 2-4, coumarone 3-4, ethyl propenoate 3-4, nanoclay 4-6, polyacrylamide 2-3, diethylamine 2-3, dibutyl phthalate 2-3, ethylene glycol 4-6, ferrocene 3-4, ethylenediamine tetramethylene fork Alendronate 1-2, trolamine 2-3, fatty alcohol-polyoxyethylene ether 1-2, composite modifier 10-16, dimethylbenzene 25-30, propyl carbinol 8-10, N-phenyl-3-TSL 8330 0.8-1, dimethyl silicone oil 0.5-1, the paint film that the present invention produces is good to metal adhesion, and structure pore is little, compact structure, has excellent sticking power, and snappiness is good, excellent in cushion effect, corrosion resistance nature strong, plays efficient provide protection to matrix metal.
Description
Technical field
The present invention relates generally to a kind of coating, particularly relates to a kind of protective system containing composite modifier.
Background technology
Along with industrial technological advancement, the use of metallic substance is more and more extensive, and the etching problem of metal and component thereof, throughout the every field of national economy, causes massive losses to human society.In order to reduce the loss of corrosion, people take a lot of safeguard procedures, but sfgd. general, most economical, the most practical up to now or coating protection, in various aseptic technic, the aseptic technic of coating is most widely used general.Anticorrosion with coat with its easy construction, economic and practical, not by device area, shape the feature such as constraint and be widely used;
In protective system, critical role is occupied in numerous paint kind epoxy resin; be widely used as a kind of coated material of anti-corrosion of metal; there is excellent cohesive force, chemical-resistant resistance, protection against corrosion and water resistance; its output increases day by day; new variety occur in succession; it is extremely rising coating variety; by adding the kind of different fillers and adjustment solidifying agent; the anti-corrosive paint of epoxy resin of different properties can be made; be applicable to the anticorrosion needs of different occasion, reach good protected effect.
But the problems such as the anticorrosion time limit is short, abrasion resistance is poor, paint film is unstable, environmental pollution that metal current protective system technology exists limit its fast development, in order to improve the performance of epoxy coating, modification being carried out to it there is important scientific meaning and commercial value.
Summary of the invention
The object of the invention is just to provide a kind of protective system containing composite modifier.
The present invention is achieved by the following technical solutions:
A protective system containing composite modifier, it is made up of first and second liang of components, and described first component is made up of the raw material of following weight parts:
Epoxy resin E5175-85, HCPE 15-20, titanium dioxide 5-10, pure aluminium silicate 3-5, sodium laurylsulfonate 3-5, sodium Diacetate 2-4, coumarone 3-4, ethyl propenoate 3-4, nanoclay 4-6, polyacrylamide 2-3, diethylamine 2-3, dibutyl phthalate 2-3, ethylene glycol 4-6, ferrocene 3-4, ethylenediamine tetramethylene fork Alendronate 1-2, trolamine 2-3, fatty alcohol-polyoxyethylene ether 1-2, composite modifier 10-16, dimethylbenzene 25-30, propyl carbinol 8-10, N-phenyl-3-TSL 8330 0.8-1, dimethyl silicone oil 0.5-1,
Described composite modifier is made up of the raw material of following weight parts:
35-40 degree Beaume water glass 40-50, Tai-Ace S 150 90-100, nanometer silicon dioxide particle 35-45, sorbitan monooleate 1-2, Soxylat A 25-7 1-2, Xylo-Mucine 1-2, Sodium dodecylbenzene sulfonate 2-4, dicumyl peroxide 1-2, N-phenyl-3-TSL 8330 0.8-1, vinyltriethoxysilane 0.6-1, hydrochloric acid, water are appropriate;
The preparation method of described composite modifier comprises the following steps:
(1) in the 35-40 degree Beaume water glass of above-mentioned weight part, dropwise add the hydrochloric acid soln that concentration is 8-10%, constantly measure the PH of mixed solution, when PH is 4.5-5, stop adding, for subsequent use;
(2) Xylo-Mucine of above-mentioned weight part and Sodium dodecylbenzene sulfonate mixing are dissolved in 15-20 times of water, must B be expected;
(3) in the Tai-Ace S 150 of above-mentioned weight part, suitable quantity of water is added, slowly add the 35-40 degree Beaume water glass solution after above-mentioned acidifying under agitation, period constantly drips above-mentioned material B, the PH of regulation system is between 9-10, the temperature of reaction of system is 75-85 DEG C, 35-40 degree Beaume water glass solution after above-mentioned acidifying dropwises rear continuation and stirs 3-5 minute, and reaction terminates;
(4) the mixed solution ageing 2-3 hour at 85-95 DEG C after reaction being terminated;
(5) nanometer silicon dioxide particle of above-mentioned weight part is distributed in water, obtain the suspension of nano-silica-containing, mix with the batch mixing after above-mentioned ageing, add each raw material of residue, high speed 1500-2000 rev/min of centrifugal mixer 20-30 minute, dry, be ground into ultrafine powder, be described composite modifier;
The preparation method of described first component is:
(1) by the epoxy resin E51 of above-mentioned weight part, HCPE, dimethylbenzene and propyl carbinol mixing and stirring;
(2) add each raw material of residue to be more fully uniformly dispersed, then carry out being ground to fineness and reach 50-60 μm, obtain described first component;
Described component B is made up of the raw material of following weight parts:
M-xylene diamine 80-90,1,2-phenylenediamine 7-10, dimethylbenzene 10-16, propyl carbinol 6-10, vinyl acetic monomer 6-10;
The preparation method of described component B is:
Each raw material mixing of above-mentioned weight part is added in dispersion tank, starts height and stir, be uniformly dispersed, filter, obtain described component B;
By first and second liang of components obtained above according to the mixing of 6-10:1 weight ratio, stir 30-40 minute to evenly, can apply or be sprayed on the metallic surface through oil removing, processing of rust removing.
Advantage of the present invention is:
The paint film that the present invention produces is good to metal adhesion; structure pore is little; compact structure; there is excellent sticking power; snappiness is good, excellent in cushion effect, corrosion resistance nature strong, and play efficient provide protection to matrix metal, the composite modifier added further increases surface gloss and the physical and mechanical properties of paint film; make paint film have better scrub resistance, weathering resistance, enhance the quality of paint film.
Embodiment
Embodiment 1
A protective system containing composite modifier, it is made up of first and second liang of components, and described first component is made up of the raw material of following weight parts (kilogram):
Epoxy resin E5175-85, HCPE (cl content 65%-M) 15-20, titanium dioxide 5-10, pure aluminium silicate 3-5, sodium laurylsulfonate 3-5, sodium Diacetate 2-4, coumarone 3-4, ethyl propenoate 3-4, nanoclay 4-6, polyacrylamide 2-3, diethylamine 2-3, dibutyl phthalate 2-3, ethylene glycol 4-6, ferrocene 3-4, ethylenediamine tetramethylene fork Alendronate 1-2, trolamine 2-3, fatty alcohol-polyoxyethylene ether 1-2, composite modifier 10-16, dimethylbenzene 25-30, propyl carbinol 8-10, N-phenyl-3-TSL 8330 0.8-1, dimethyl silicone oil 0.5-1,
Described composite modifier is made up of the raw material of following weight parts:
35-40 degree Beaume water glass 50, Tai-Ace S 150 100, nanometer silicon dioxide particle 45, sorbitan monooleate 2, Soxylat A 25-7 2, Xylo-Mucine 1, Sodium dodecylbenzene sulfonate 4, dicumyl peroxide 2, N-phenyl-3-TSL 8330 0.8, vinyltriethoxysilane 1, hydrochloric acid, water are appropriate;
The preparation method of described composite modifier comprises the following steps:
(1) in the 35-40 degree Beaume water glass of above-mentioned weight part, dropwise add the hydrochloric acid soln that concentration is 10%, constantly measure the PH of mixed solution, when PH is 4.5, stop adding, for subsequent use;
(2) Xylo-Mucine of above-mentioned weight part and Sodium dodecylbenzene sulfonate mixing are dissolved in 20 times of water, must B be expected;
(3) in the Tai-Ace S 150 of above-mentioned weight part, suitable quantity of water is added, slowly add the 35-40 degree Beaume water glass solution after above-mentioned acidifying under agitation, period constantly drips above-mentioned material B, the PH of regulation system is between 10, the temperature of reaction of system is 85 DEG C, 35-40 degree Beaume water glass solution after above-mentioned acidifying dropwises rear continuation stirring 5 minutes, and reaction terminates;
(4) the mixed solution ageing 3 hours at 95 DEG C after reaction being terminated;
(5) nanometer silicon dioxide particle of above-mentioned weight part is distributed in water, obtains the suspension of nano-silica-containing, mix with the batch mixing after above-mentioned ageing, add each raw material of residue, high speed 2000 revs/min of centrifugal mixers 30 minutes, dry, be ground into ultrafine powder, be described composite modifier;
The preparation method of described first component is:
(1) by the epoxy resin E51 of above-mentioned weight part, HCPE, dimethylbenzene and propyl carbinol mixing and stirring;
(2) add each raw material of residue to be more fully uniformly dispersed, then carry out being ground to fineness and reach 60 μm, obtain described first component;
Described component B is made up of the raw material of following weight parts:
M-xylene diamine 90,1,2-phenylenediamine 10, dimethylbenzene 16, propyl carbinol 10, vinyl acetic monomer 10;
The preparation method of described component B is:
Each raw material mixing of above-mentioned weight part is added in dispersion tank, starts height and stir, be uniformly dispersed, filter, obtain described component B;
By first and second liang of components obtained above according to the mixing of 10:1 weight ratio, stir 40 minutes to evenly, can apply or be sprayed on the metallic surface through oil removing, processing of rust removing.
Performance test:
100 days cut salt mist experiments: paint film without foaming, without coming off, cut place corrosion diffusion 0.9mm;
100 days salt mist experiments: paint film without foaming, without coming off, non-corroding;
Abrasion resistance is tested: pass through for 10000 times, paint film is without breakage;
Acid resistance (sulphuric acid soln of 5%, 25 DEG C, 50h): paint film without foaming, without coming off, non-corroding;
Alkali resistance (sodium hydroxide solution of 5%, 25 DEG C, 600h): paint film without foaming, without coming off, non-corroding;
Resistance to salt water (sodium chloride solution of 5%, 25 DEG C, 800h): paint film without foaming, without coming off, non-corroding;
Snappiness 1mm;
Sticking power 13Mpa.
Claims (1)
1. the protective system containing composite modifier, it is characterized in that it is made up of first and second liang of components, described first component is made up of the raw material of following weight parts:
Epoxy resin E5175-85, HCPE 15-20, titanium dioxide 5-10, pure aluminium silicate 3-5, sodium laurylsulfonate 3-5, sodium Diacetate 2-4, coumarone 3-4, ethyl propenoate 3-4, nanoclay 4-6, polyacrylamide 2-3, diethylamine 2-3, dibutyl phthalate 2-3, ethylene glycol 4-6, ferrocene 3-4, ethylenediamine tetramethylene fork Alendronate 1-2, trolamine 2-3, fatty alcohol-polyoxyethylene ether 1-2, composite modifier 10-16, dimethylbenzene 25-30, propyl carbinol 8-10, N-phenyl-3-TSL 8330 0.8-1, dimethyl silicone oil 0.5-1,
Described composite modifier is made up of the raw material of following weight parts:
35-40 degree Beaume water glass 40-50, Tai-Ace S 150 90-100, nanometer silicon dioxide particle 35-45, sorbitan monooleate 1-2, Soxylat A 25-7 1-2, Xylo-Mucine 1-2, Sodium dodecylbenzene sulfonate 2-4, dicumyl peroxide 1-2, N-phenyl-3-TSL 8330 0.8-1, vinyltriethoxysilane 0.6-1, hydrochloric acid, water are appropriate;
The preparation method of described composite modifier comprises the following steps:
(1) in the 35-40 degree Beaume water glass of above-mentioned weight part, dropwise add the hydrochloric acid soln that concentration is 8-10%, constantly measure the pH of mixed solution, when pH is 4.5-5, stop adding, for subsequent use;
(2) Xylo-Mucine of above-mentioned weight part and Sodium dodecylbenzene sulfonate mixing are dissolved in 15-20 times of water, must B be expected;
(3) in the Tai-Ace S 150 of above-mentioned weight part, suitable quantity of water is added, slowly add the 35-40 degree Beaume water glass solution after above-mentioned acidifying under agitation, period constantly drips above-mentioned material B, the pH of regulation system is between 9-10, the temperature of reaction of system is 75-85 DEG C, 35-40 degree Beaume water glass solution after above-mentioned acidifying dropwises rear continuation and stirs 3-5 minute, and reaction terminates;
(4) the mixed solution ageing 2-3 hour at 85-95 DEG C after reaction being terminated;
(5) nanometer silicon dioxide particle of above-mentioned weight part is distributed in water, obtain the suspension of nano-silica-containing, mix with the batch mixing after above-mentioned ageing, add each raw material of residue, high speed 1500-2000 rev/min of centrifugal mixer 20-30 minute, dry, be ground into ultrafine powder, be described composite modifier;
The preparation method of described first component is:
(1) by the epoxy resin E51 of above-mentioned weight part, HCPE, dimethylbenzene and propyl carbinol mixing and stirring;
(2) add each raw material of residue to be more fully uniformly dispersed, then carry out being ground to fineness and reach 50-60 μm, obtain described first component;
Described component B is made up of the raw material of following weight parts:
M-xylene diamine 80-90,1,2-phenylenediamine 7-10, dimethylbenzene 10-16, propyl carbinol 6-10, vinyl acetic monomer 6-10;
The preparation method of described component B is:
Each raw material mixing of above-mentioned weight part is added in dispersion tank, starts height and stir, be uniformly dispersed, filter, obtain described component B;
By first and second liang of components obtained above according to the mixing of 7-10:1 weight ratio, stir 30-40 minute to evenly, can apply or be sprayed on the metallic surface through oil removing, processing of rust removing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310060580.9A CN103173049B (en) | 2013-02-26 | 2013-02-26 | A kind of protective system containing composite modifier |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310060580.9A CN103173049B (en) | 2013-02-26 | 2013-02-26 | A kind of protective system containing composite modifier |
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| CN103173049A CN103173049A (en) | 2013-06-26 |
| CN103173049B true CN103173049B (en) | 2016-03-30 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103603205B (en) * | 2013-10-24 | 2016-01-13 | 安徽柏拉图涂层织物有限公司 | A kind of mat fabric coating |
| CN103756529A (en) * | 2013-12-07 | 2014-04-30 | 铜陵新九鼎铜文化产业有限公司 | Copper sculpture paint with characteristics of heat resistance, ultraviolet resistance and aging resistance |
| CN103709896A (en) * | 2013-12-07 | 2014-04-09 | 铜陵新九鼎铜文化产业有限公司 | Flexible and antiseptic epoxy resin paint for copper sculptures |
| CN104524645A (en) * | 2014-12-19 | 2015-04-22 | 常熟市雷号医疗器械有限公司 | Carotid endarterectomy suction head |
| CN106590349A (en) * | 2016-12-28 | 2017-04-26 | 毛葵燕 | Anticorrosive coating containing compound modifier |
| CN113385536B (en) * | 2021-06-29 | 2023-03-14 | 山东德利铝业科技有限公司 | Battery aluminum foil production method for improving surface dyne value |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1085585A (en) * | 1993-09-26 | 1994-04-20 | 徐晓南 | Protective system |
| CN1175608A (en) * | 1996-09-03 | 1998-03-11 | 武汉市高校新技术研究所 | High polymer corrosion-proof paint for alloy with rust |
| CN1580153A (en) * | 2004-05-20 | 2005-02-16 | 中国人民解放军海军装备技术研究所 | Modified perchloride polyethylene special coating |
| CN101691464A (en) * | 2009-09-07 | 2010-04-07 | 郭再春 | High performance chlorinated polyethylene-epoxy resin anticorrosive coating system |
| CN102120909A (en) * | 2010-12-23 | 2011-07-13 | 天津科瑞达涂料化工有限公司 | Anticorrosive paint for weather-resistant corrosion-resistant steel pipe outer wall |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6090266A (en) * | 1983-10-24 | 1985-05-21 | Onahama Sakai Kagaku Kk | Novel pigment |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1085585A (en) * | 1993-09-26 | 1994-04-20 | 徐晓南 | Protective system |
| CN1175608A (en) * | 1996-09-03 | 1998-03-11 | 武汉市高校新技术研究所 | High polymer corrosion-proof paint for alloy with rust |
| CN1580153A (en) * | 2004-05-20 | 2005-02-16 | 中国人民解放军海军装备技术研究所 | Modified perchloride polyethylene special coating |
| CN101691464A (en) * | 2009-09-07 | 2010-04-07 | 郭再春 | High performance chlorinated polyethylene-epoxy resin anticorrosive coating system |
| CN102120909A (en) * | 2010-12-23 | 2011-07-13 | 天津科瑞达涂料化工有限公司 | Anticorrosive paint for weather-resistant corrosion-resistant steel pipe outer wall |
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Effective date of registration: 20160224 Address after: 244100 new road, West Lake Town Development Zone, lion mountain, Tongling, Anhui Applicant after: Anhui Mingzhu Pigment Technology Co., Ltd. Address before: Wu Song Zhen Tongling County of Anhui province Tongling 244100 Union City Village Applicant before: Anhui Mingzhu Pigment Technology Co., Ltd. |
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Effective date of registration: 20190415 Address after: 246127 Yangtang Formation No. 31, Jiliu Village, Chaling Town, Huaining County, Anqing City, Anhui Province Patentee after: Huaining Sanhe Cleaning Services Ltd. Address before: 244100 New Town Road, West Lake Town Development Zone, Tongling, Anhui Patentee before: Tongling Guofang Plumbing Technology Co., Ltd. |
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Effective date of registration: 20220110 Address after: 230000 room 322, Zhangji Township People's government, Feidong County, Hefei City, Anhui Province Patentee after: Anhui ruicai Construction Engineering Co.,Ltd. Address before: 246127 Yangtang Formation No. 31, Jiliu Village, Chaling Town, Huaining County, Anqing City, Anhui Province Patentee before: HUAINING SANHE CLEANING SERVICE CO.,LTD. |
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