CN103160388A - Lens cleaning solution and wet tissue - Google Patents
Lens cleaning solution and wet tissue Download PDFInfo
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- CN103160388A CN103160388A CN2013100799414A CN201310079941A CN103160388A CN 103160388 A CN103160388 A CN 103160388A CN 2013100799414 A CN2013100799414 A CN 2013100799414A CN 201310079941 A CN201310079941 A CN 201310079941A CN 103160388 A CN103160388 A CN 103160388A
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Abstract
The invention relates to a lens cleaning solution which is mainly formed by mixing a water-solubility solvent with the boiling point smaller than 100 DEG C, a surface active agent, an ant-fogging agent and water. The invention also provides a wet tissue using the lens cleaning solution. Compared with the prior art, the water-solubility solvent with the boiling point smaller than 100 DEG C, the surface active agent, the anti-fogging agent and other functional medicament are selectively compounded, and the advantages of the components in the lens cleaning aspect are fully exerted, so that the lens cleaning solution and the wet tissue containing the lens cleaning solution not only can well clean dust, fingerprints, oil stains and other spots on the lens, but also has good anti-fogging performance, and can avoid the problems of rusting, mildew and the like caused by water being attached to the parts such as a lens frame and a lens bracket so as to avoid affecting the service life of eyeglasses.
Description
Technical field
The present invention relates to a kind of eyeglass cleaning liquor and wet tissue.
Background technology
People are in the process of using glasses, often can encounter following two problems: first, eyeglass can be stained with the dirts such as dust, fingerprint and oil stain unavoidably in the process of using, if it is not cleaned, can affect optical property and the image quality of eyeglass, eyesight to the user causes certain injury, therefore needs often to clean eyeglass, to keep its degree of cleaning and transmittance; Second, self anti-fog performance of a lot of eyeglasses is not very desirable, when entering the high environment of temperature from a low environment of temperature or after with mouth mask, nose being covered winter, when the hot gas of nose ejection runs into ice-cold eyeglass, last layer fog all can condense on eyeglass, cause not seeing, particularly abnormally dangerous for the people who drives a conveyance.
For the cleaning problems of eyeglass, general way mainly contains two kinds at present: (1) adopts the cleaning cloth wiping; (2) complete with flushing with clean water again after the aqueous cleaning with liquid detergent, body wash etc.Adopt the mode of cleaning cloth wiping to be merely able to remove the non-intractable dirts such as dust, for intractable dirts such as oil stains, the cleaning capacity of cleaning cloth obviously not, and, in the process of using the cleaning cloth wiping, just be easy to the scratch lens coating if overexert, affect the optical property of eyeglass.Use again the mode of flushing with clean water after the aqueous cleaning of employing liquid detergent, body wash etc., although can effectively remove the intractable dirts such as oil stain of lens surface, but but easily on eyeglass and the periphery residual lower water mark, simultaneously, in cleaning process, water can be encountered and the problem such as cause getting rusty, mouldy unavoidably in the position such as picture frame, mirror holder, affects the work-ing life of glasses.
For the anti-undesirable problem of fog effect of eyeglass self, except applying on eyeglass expensive coating with good anti-fog effect, other good terms of settlement not at present.
Above-mentioned two problems, people often can encounter in the process of using glasses simultaneously, especially in winter.Therefore, adopt which kind of method when eyeglass being carried out effectively cleaning, the anti-fog effect of eyeglass is effectively improved be one of direction that people pay close attention to.
Summary of the invention
In view of this, provide a kind of eyeglass cleaning liquor that can address the above problem and wet tissue real in necessary.
A kind of eyeglass cleaning liquor, described eyeglass cleaning liquor are mainly mixed by water-soluble solvent, tensio-active agent, antifogging agent and the water of boiling point less than 100 ℃.
Preferably, in described eyeglass cleaning liquor, the quality percentage composition of described water-soluble solvent is 5%～70%, and the quality percentage composition of described tensio-active agent is 0.5%～5%, and the quality percentage composition of described antifogging agent is 0.001%～5%.
A kind of wet tissue, it comprises base material, is added with eyeglass cleaning liquor as above in described base material.
Preferably, the mass ratio of the addition of described eyeglass cleaning liquor and described base material is 1～3:1.
Compared with prior art, the present invention selectively carries out composite to boiling point less than functional medicines such as the water-soluble solvent of 100 ℃, tensio-active agent, antifogging agents, give full play to the advantage of each component aspect the cleaning eyeglass, the wet tissue that makes eyeglass cleaning liquor provided by the present invention and contain this eyeglass cleaning liquor not only has better cleaning power to the spots such as dust, fingerprint, greasy dirt on eyeglass, also has good anti-fog performance, and can avoid encountering the problems such as water causes getting rusty, mouldy because of positions such as picture frame, mirror holders, affect the work-ing life of glasses.
Embodiment
Embodiment of the present invention provides a kind of eyeglass cleaning liquor, and it is mainly mixed by water-soluble solvent, tensio-active agent, antifogging agent and the water of boiling point less than 100 ℃.
Preferably, in above-mentioned eyeglass cleaning liquor provided by the present invention, the quality percentage composition of described water-soluble solvent is 5%～70%, and the quality percentage composition of described tensio-active agent is 0.5%～5%, and the quality percentage composition of described antifogging agent is 0.001%～5%.
Below, effect and the kind of each component of comprising in above-mentioned eyeglass cleaning liquor provided by the present invention is specifically described.
Water-soluble solvent:
In the present invention, the effect of described water-soluble solvent mainly contains two aspects: on the one hand, utilize water-soluble solvent to dissolve to be attached to the dirt on eyeglass, to play the effect of cleaning; On the other hand, because boiling point all has good volatility usually less than the water-soluble solvent of 100 ℃, therefore, after the complete eyeglass of wiping, the liquid that remains on eyeglass can disappear along with the quick volatilization of described water-soluble solvent, thereby eyeglass is become dry after wiping fast, avoided the generation of water mark.
Preferably, described water-soluble solvent is at least a in alcohols, ketone, and wherein, alcoholic solvent comprises methyl alcohol, ethanol, propyl alcohol, Virahol and composition thereof, and ketone comprises acetone, butanone and composition thereof.
Tensio-active agent:
In the present invention, described tensio-active agent is mainly used in dissolving, removing the intractable dirts such as oil stain that are attached to lens surface.
Because the chemical property of nonionogenic tenside and amphoterics is gentleer, and has well collaborative complex role between the two, not only can remove the intractable spot on eyeglass, also can reduce it to the destruction of lens coating, therefore, in the present embodiment, described tensio-active agent is preferably nonionogenic tenside, amphoterics or its mixture.
Further, when described tensio-active agent was the mixture of nonionogenic tenside and amphoterics, the mass ratio between nonionogenic tenside and amphoterics was 1:0.1～1.
preferably, described ionic surfactant pack is drawn together alkyl glycoside (APG), at least a in the alcohol amide class, wherein, alkyl glycoside is specially the alkyl glycoside of 8-16 carbon, be the alkyl glycoside of 8-10 as the APG0810(carbon chain lengths), the APG1214(carbon chain lengths is the alkyl glycoside of 12-14), the APG0814(carbon chain lengths is the alkyl glycoside of 8-14), the APG0816(carbon chain lengths is the alkyl glycoside of 8-16), the APG1216(carbon chain lengths is the alkyl glycoside of 12-16) etc., the alcohol amide class comprises lauric monoethanolamide, lauric acid diethyl amide, cocounut oil acyl single ethanol amide, at least a in cocounut oil acyl diglycollic amide.
Preferably, alkyl glycoside is preferably the alkyl glycoside that carbon chain lengths is 8-14, and this series products comprises GLUCOPON215CS UP, GLUCOPON225DK, GLUCOPON600CS UP, the GLUCOPON650EC etc. of German Cognis company on the market.
preferably, described amphoterics comprises betanin derivative, the both sexes acetate, at least a in the sulfo-succinic acid salt, wherein, described betanin derivative comprises AMONYL 380LC, octyl group/decyl amido propyl betaine, the ricinoleic acid amide CAB, dodecyl oxyethyl group sultaine, dodecyl hydroxypropyl sultaine, dodecyl sulfobetaine, at least a in the lauroyl CAB, described both sexes Acetates comprises cocounut oil both sexes sodium acetate, cocounut oil both sexes diacetic acid disodium, at least a in sweet almond oil both sexes sodium-acetate, described sulfo-succinic acid salt comprises polyoxyethylene glycol-5 lauryl citric acid disodium sulfosuccinate, the lauryl alcohol disodium sulfosuccinate, ricinoleic acid amide monoethanolamine disodium sulfosuccinate, at least a in the lauryl disodium sulfosuccinate.
Antifogging agent:
Antifogging agent is to reach antifog purpose by the wetting property that changes lens surface.In general, antifogging agent changes the wetting property of lens surface and can carry out from both direction: a direction, that the contact angle that increases as far as possible lens surface and water makes it trend towards 180 degree, to improve the hydrophobic performance of lens surface, like this, just be easy to tumble under himself action of gravitation at the droplet that forms on eyeglass after the steam condensation, and make eyeglass keep good transparency; Another direction, that the contact angle that reduces as far as possible lens surface and water makes it trend towards 0 degree, thereby improve the hydrophilicity of lens surface, like this, just be not easy after the steam condensation to condense into droplet at lens surface but form transparent moisture film, so also can make eyeglass keep good transparency.
In the present embodiment, described antifogging agent comprises at least a in silicone oil antifogging agent, metal or metal oxide nanoparticles antifogging agent.Described silicone oil antifogging agent series products comprises the XIAMETER OFX-0193 silicone oil of DOW CORNING company and the silok2215 of Si Luoke.Metal or metal oxide nanoparticles antifogging agent comprise at least a in SiO2 nanoparticle antifogging agent, TiO2 nanoparticle antifogging agent, ZnO nano particle antifogging agent, Al nanoparticle antifogging agent, Ti nanoparticle antifogging agent, Co nanoparticle antifogging agent.Simultaneously, to the lens coating injury, the particle diameter of nanoparticle antifogging agent is less than 100nm for fear of nanoparticle, and more preferably particle diameter is less than 50nm.
Preferably, when antifogging agent was metal or metal oxide nanoparticles antifogging agent, its addition in described eyeglass cleaning liquor was 0.001%～0.1%, more preferably 0.005%～0.05%.
In the present embodiment, in order further to strengthen the anti-fog performance of described eyeglass cleaning liquor, also be added with membrane-forming agent in described eyeglass cleaning liquor.
Preferably, in described eyeglass cleaning liquor, the quality percentage composition of described membrane-forming agent is 0.01%～10%.
In the present embodiment, described membrane-forming agent is mainly used to coordinate with antifogging agent to form one deck wetting ability or hydrophobic film at lens surface, with wetting ability or the hydrophobic nature of further change lens surface, thereby reach the anti-fog performance of the described eyeglass cleaning liquor of further raising.Simultaneously, the antifogging agent kind of using when eyeglass cleaning liquor provided by the present invention is during as metal or metal oxide nanoparticles antifogging agent, described membrane-forming agent can also help metal or metal oxide nanoparticles to disperse in the cleaning emulsion, is beneficial to metal or metal oxide nanoparticles and can be scattered in uniformly the surface of eyeglass after wiping.
preferably, described membrane-forming agent comprises the cellulose family membrane-forming agent, the polyacrylic membrane-forming agent, at least a in the vinyl membrane-forming agent, wherein, described cellulose family membrane-forming agent comprises Natvosol, the carboxylic propyl methocel, carboxymethyl cellulose, described polyacrylic membrane-forming agent comprises vinylformic acid (ester) class/octyl acrylamide multipolymer (representing the DERMACRYL79 film-forming polymer of commodity such as AkzoNobel company), acrylate/C10-30 alkyl acrylate cross-linked polymer, the aqueous solution of sodium polyacrylate and acrylic copolymer (as Polyquart ampho149 and the Mirapol Surf-S210 of Cognis company), described vinyl membrane-forming agent comprises polyvinyl alcohol, polyvinylpyrrolidone.
Preferably, adhere to lens surface in order to suppress the eyeglass cleaning liquor in use to produce too much foam and affect the smooth finish of eyeglass, can also add defoamer in described eyeglass cleaning liquor.
Preferably, described defoamer comprises polyethers, lipid acid and derivative thereof, at least a in silicone based.
Preferably, described defoamer uses silicone based defoamer, and this series products comprises the XIAMETER PMX-200 of silok201-6000cs, silok210-100cs, silok210-350cs and silok210-500cs, DOW CORNING company of Si Luoke company and the Y-14865 of Momentive company etc. on the market.
Preferably, the addition of described defoamer is 0.05%～5%.
Understandable, based on different needs, can also add the auxiliary compositions such as solubilizing agent, tinting material, pH adjusting agent, sequestrant, sanitas, sterilant, dispersion agent, thickening material and spices in described eyeglass cleaning liquor.
The present invention also provides a kind of wet tissue, and it comprises base material and is added on the interior eyeglass cleaning liquor as above of described base material.
Preferably, in described wet tissue, the mass ratio of described eyeglass cleaning liquor and base material is 1～3:1, that is, the eyeglass cleaning liquor of 1～3 mass parts is added in the base material of 1 mass parts.
In described wet tissue provided by the present invention, described base material can be non-woven fabrics, woven, paper etc.
Preferably, the base material of described wet tissue is non-woven fabrics.
As follows, be the blending process of two kinds of alternative eyeglass cleaning liquors providing of present embodiment and utilize described eyeglass cleaning liquor to make the step of wet tissue:
Embodiment 1
The blending process of eyeglass cleaning liquor:
Water is added in the allotment bucket, after adding successively GLUCOPON215CS UP, cocounut oil acyl diglycollic amide, cocounut oil alkylamidoalkyl CAB, Virahol, Mirapol Surf-S210, XIAMETEROFX-0193 silicone oil, Y-14865, spices, sanitas, sequestrant to mix, the pH value that adds appropriate pH adjusting agent will clean emulsion is adjusted to 7-8 and gets final product, concrete adding proportion such as the following table of each component:
Wet tissue is made:
Be that 1.5:1 adds above-mentioned eyeglass cleaning liquor in base material to according to mass ratio, then cut according to actual desired size and namely make required wet tissue, wherein, the mode that described eyeglass cleaning liquor adds in the base material comprises the modes such as dipping, spray.
Embodiment 2
Eyeglass cleaning liquor blending process:
The DERMACRYL79 film-forming polymer is added in ethanol after dissolve complete, neutralize with trolamine, then be added to the water, after adding successively again GLUCOPON215CS UP, cocounut oil both sexes sodium acetate, acetone, nano silicon, Y-14865, sanitas, sequestrant, spices to mix, the pH value that adds appropriate pH adjusting agent will clean emulsion is adjusted to 6.5-7.5 and gets final product, concrete adding proportion such as the following table of each component:
Wet tissue is made:
Be that 2.5:1 adds above-mentioned eyeglass cleaning liquor in base material to according to mass ratio, then cut according to actual desired size and namely make required wet tissue, wherein, the mode that described eyeglass cleaning liquor adds in the base material comprises the modes such as dipping, spray.
Compared with prior art, the present invention selectively carries out composite to boiling point less than functional medicines such as the water-soluble solvent of 100 ℃, tensio-active agent, antifogging agents, give full play to the advantage of each component aspect the cleaning eyeglass, the wet tissue that makes eyeglass cleaning liquor provided by the present invention and contain this eyeglass cleaning liquor not only has better cleaning power to the spots such as dust, fingerprint, greasy dirt on eyeglass, also has good anti-fog performance, and can avoid encountering the problems such as water causes getting rusty, mouldy because of positions such as picture frame, mirror holders, affect the work-ing life of glasses.
In addition, those skilled in the art also can do other variation in spirit of the present invention.Therefore the variation that these are done according to spirit of the present invention is within all should being included in the present invention's scope required for protection.
Claims (13)
1. eyeglass cleaning liquor, it is characterized in that: described eyeglass cleaning liquor is mainly mixed by water-soluble solvent, tensio-active agent, antifogging agent and the water of boiling point less than 100 ℃.
2. eyeglass cleaning liquor as claimed in claim 1, it is characterized in that: in described eyeglass cleaning liquor, the quality percentage composition of described water-soluble solvent is 5%～70%, and the quality percentage composition of described tensio-active agent is 0.5%～5%, and the quality percentage composition of described antifogging agent is 0.001%～5%.
3. eyeglass cleaning liquor as claimed in claim 1 or 2, is characterized in that: further be mixed with membrane-forming agent in described eyeglass cleaning liquor.
4. eyeglass cleaning liquor as claimed in claim 3, it is characterized in that: in described eyeglass cleaning liquor, the quality percentage composition of described membrane-forming agent is 0.01%～10%.
5. eyeglass cleaning liquor as claimed in claim 1, it is characterized in that: described water-soluble solvent is selected from least a in alcohols, ketone, wherein, alcoholic solvent comprises methyl alcohol, ethanol, propyl alcohol, Virahol and composition thereof, and ketone comprises acetone, butanone and composition thereof.
6. eyeglass cleaning liquor as claimed in claim 1, it is characterized in that: described tensio-active agent is nonionogenic tenside, amphoterics or its mixture, wherein, described ionic surfactant pack is drawn together at least a in alkyl glycoside, alcohol amide class, and described amphoterics comprises at least a in betanin derivative, both sexes acetate, sulfo-succinic acid salt.
7. eyeglass cleaning liquor as claimed in claim 6, it is characterized in that: described tensio-active agent is the mixture of nonionogenic tenside and amphoterics, in described tensio-active agent, the mass ratio between described nonionogenic tenside and amphoterics is 1:0.1～1.
8. eyeglass cleaning liquor as claimed in claim 1 is characterized in that: described antifogging agent is selected from least a in silicone oil antifogging agent, metal or metal oxide nanoparticles antifogging agent.
9. eyeglass cleaning liquor as claimed in claim 8, it is characterized in that: described antifogging agent is metal or metal oxide nanoparticles antifogging agent, in described eyeglass cleaning liquor, the quality percentage composition of described metal or metal oxide nanoparticles antifogging agent is 0.001%～0.1%.
10. eyeglass cleaning liquor as claimed in claim 3 is characterized in that: described membrane-forming agent is selected from least a in cellulose family membrane-forming agent, polyacrylic membrane-forming agent, vinyl membrane-forming agent.
11. eyeglass cleaning liquor as claimed in claim 1, it is characterized in that: described eyeglass cleaning liquor comprises that further the quality percentage composition is 0.05%～5% defoamer, and described defoamer is selected from polyethers, lipid acid and derivative thereof, at least a in silicone based.
12. a wet tissue, it comprises base material, it is characterized in that: be added with eyeglass cleaning liquor as claimed in claim 1 in described base material.
13. wet tissue as claimed in claim 12 is characterized in that: the addition of described eyeglass cleaning liquor and the mass ratio of described base material are 1～3:1.
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| CN103417154A (en) * | 2013-07-26 | 2013-12-04 | 广州联庄科技有限公司 | Mobile-phone antibacterial cleaning wet tissue |
| CN103740480A (en) * | 2013-11-27 | 2014-04-23 | 南通晶鑫光学玻璃有限公司 | Cleaning care agent for organic glass lens |
| CN104531390A (en) * | 2014-12-27 | 2015-04-22 | 湖北吉隆表面工程有限公司 | Fingerprint cleaning fluid |
| CN104745335A (en) * | 2015-02-02 | 2015-07-01 | 江苏科技大学 | Resin lens cleaning agent and preparation method thereof |
| CN105125128A (en) * | 2015-07-24 | 2015-12-09 | 杭州国光旅游用品有限公司 | Glass anti-fog wet wipes and production method thereof |
| CN105419979A (en) * | 2015-11-23 | 2016-03-23 | 上海银京医用卫生材料有限公司 | Lens cleaning towel |
| CN105778739A (en) * | 2016-03-16 | 2016-07-20 | 于昊 | Anti-fogging liquid for glasses |
| WO2016169345A1 (en) * | 2015-04-20 | 2016-10-27 | 无锡市豪雅微纤科技有限公司 | Anti-fogging cleaning cloth |
| CN106350292A (en) * | 2016-08-24 | 2017-01-25 | 苏州宝丽洁日化有限公司 | Anti-fog glasses wet tissue with functions of cleaning and sterilizing, and preparation method of anti-fog glasses wet tissue |
| CN106434034A (en) * | 2016-07-11 | 2017-02-22 | 成都嘉鹏科技有限公司 | Glass cleaning agent suitable for spray cleaning and preparation method thereof |
| CN104059786B (en) * | 2014-06-25 | 2017-05-24 | 厦门金泰生物科技有限公司 | Kitchen wet tissue complex formulation liquid and preparation method thereof |
| CN106753869A (en) * | 2016-12-19 | 2017-05-31 | 安徽长庚光学科技有限公司 | A kind of dirt-removing cleaning wet tissue for optical lens |
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| CN103740480A (en) * | 2013-11-27 | 2014-04-23 | 南通晶鑫光学玻璃有限公司 | Cleaning care agent for organic glass lens |
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