CN103159185A - Multiple ozone generating device - Google Patents

Multiple ozone generating device Download PDF

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Publication number
CN103159185A
CN103159185A CN2012101997935A CN201210199793A CN103159185A CN 103159185 A CN103159185 A CN 103159185A CN 2012101997935 A CN2012101997935 A CN 2012101997935A CN 201210199793 A CN201210199793 A CN 201210199793A CN 103159185 A CN103159185 A CN 103159185A
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China
Prior art keywords
electrode
discharging gap
electrode pair
ozone generating
pair
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Pending
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CN2012101997935A
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Chinese (zh)
Inventor
伊学农
宋桃莉
金鑫
王峰
赵青
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University of Shanghai for Science and Technology
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University of Shanghai for Science and Technology
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Priority to CN2012101997935A priority Critical patent/CN103159185A/en
Publication of CN103159185A publication Critical patent/CN103159185A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a multiple ozone generating device which is formed by a plurality of electrode couples, and the electrode couples are distributed from inside to outside in a concentric-circle mode in sequence. Each electrode couple is composed of an inner electrode and an outer electrode, the inner electrode is connected with a high-voltage terminal, the outer electrode is grounded, the inner electrode of each electrode couple is coated with dielectrics, a discharging gap is arranged between the inner electrode and the outer electrode, and a discharging gap is arranged between two adjacent electrode couples. Double cooling liquid is used in the multiple ozone generating device, a cooling oil layer is arranged on the outer side of each outer electrode, and the innermost layer of the device is filled with cooling water. The discharging gap of each electrode couple and the discharging gap between the electrode couple and the adjacent electrode couple on the outer layer are in a communicating state, and a stainless steel jacket is arranged on the outermost layer of the whole device. The technical problems that the efficiency of existing high-voltage corona discharge type ozone generating is low, an ozone generating device is high in running cost and the like are solved, the use ratio of raw material gas is improved, ozone concentration is increased, and discharging tube consumption and electric-discharge energy consumption are reduced, so that cost is lowered.

Description

Multiple ozone generating apparatus
Technical field
The invention belongs to energy-conserving and environment-protective, electronics and electrochemical field, be specifically related to a kind of multiple ozone generating apparatus.
Background technology
Ozone has been Duoed an active Sauerstoffatom ozone than oxygen molecule, and chemical property is active especially, is a kind of strong oxidizer, can kill rapidly airborne bacterium under finite concentration, without any poisonous residual, can not form secondary pollution, be described as " oxygenant and the sterilizing agent that clean most ".But ozone is easy to decompose and can't stores, and on-the-spot the use produced at the scene of need, and ozonizer all need be used in the every place that can use ozone.
Ozonizer is be used to the equipment configuration of producing ozone, and ozonizer is at tap water, sewage, and industrial oxidation, the field widespread uses such as space sterilization, and obtain good effect.It is that prepared using high-frequency and high-voltage corona discharge produces ozone that ozonizer adopts air or oxygen, divides by the mode of ozone generation, and ozonizer mainly contains three kinds: high-voltage corona discharge formula, uviolizing formula and electrolyzing.
What use was maximum at present is high-voltage corona discharge formula ozonizer, this ozonizer is to use the high-tension current of certain frequency to make the high-voltage corona electric field, make in electric field or the oxygen molecule generation electrochemical reaction around electric field, thereby generation ozone is a kind of central ozone advanced production technology of industrial mass production that has been applied to.
Existing high-voltage corona discharge formula ozonizer need to consume a large amount of electric energy when discharge, and consumable quantity is large when existing discharge tube to make, in ozonizer, discharge tube takes up space greatly, the insufficient volume of ozonizer that causes of space utilization is also very large, the low series of problems that waits of unstripped gas utilization ratio.
Summary of the invention
The object of the present invention is to provide a kind of multiple ozone method for generation and equipment, it mainly solves the technical problem that existing electrion formula ozonizer exists, improve the utilization ratio of unstripped gas, increase ozone concn, save consumptive material and the discharge power consumption of discharge tube, thereby reduce production costs and use cost.
The technical problem that will solve required for the present invention can be achieved through the following technical solutions:
A kind of multiple ozone generating apparatus, it is characterized in that, comprise: plurality of electrodes pair, being successively from inside to outside concentric(al) circles distributes, each described electrode comprises by interior electrode and outer electrode, and described interior electrode connects high-pressure side, described outer electrode ground terminal, being discharging gap between described interior electrode and described outer electrode, is discharging gap between two adjacent described electrode pairs; Cooling fluid is arranged at outside the described outer electrode of described electrode pair, and described concentrically ringed innermost layer; And overcoat, be arranged at the outermost layer of described plurality of electrodes.
Further, multiple ozone generating apparatus of the present invention can also have such feature:
Described cooling fluid is two cooling fluids, comprises water coolant and cooling oil reservoir, and wherein, described water coolant is arranged at described concentrically ringed innermost layer, the described outer electrode outside of described cooling oil reservoir setting and described electrode pair.
Further, multiple ozone generating apparatus of the present invention can also have such feature:
Described electrode pair comprises: electrode pair I, electrode pair II, and electrode pair n, each described electrode pair is followed successively by interior electrode, dielectric substance, discharging gap, outer electrode, cooling oil reservoir from inside to outside, discharging gap in the electrode pair I and the discharging gap between electrode pair I and electrode pair II are UNICOM, the discharging gap that each described electrode pair is interior and the outer electrode that is adjacent between discharging gap be UNICOM.
Further, multiple ozone generating apparatus of the present invention can also have such feature:
The interior electrode that adjacent electrode is right and outer electrode alternative arrangement, the interior electrode of the outer electrode of each electrode pair and the outer field electrode pair that is adjacent has formed again another electrode pair, the actual composition of adjacent two electrode pairs be 3 electrode pairs.
Further, multiple ozone generating apparatus of the present invention can also have such feature:
The air outlet (13) of the gas source air inlet of source of the gas gas (12) and ozone is positioned at a side.
Further, multiple ozone generating apparatus of the present invention can also have such feature:
The front end of the discharging gap in the electrode pair I is gas source air inlet, the front end of the discharging gap between electrode pair I and electrode pair II is the air outlet, the front end of the discharging gap in each electrode pair is gas source air inlet, and the front end of the discharging gap between two adjacent described electrode pairs is the air outlet.
Further, multiple ozone generating apparatus of the present invention can also have such feature: described overcoat is stainless steel outer sleeve.
Beneficial effect of the present invention:
This ozone generating apparatus is from inside to outside the concentric(al) circles distribution by a plurality of electrode pairs and consists of, internal and external electrode alternative arrangement in electrode pair, in every adjacent 2 electrode pairs, the outer electrode of each electrode pair has consisted of again another electrode pair with the interior electrode of a rear electrode pair that is adjacent, therefore in fact form 3 electrode pairs, ozone production efficient increases substantially, and has reduced energy consumption, and the material of having saved discharge equipment takes up space with institute.
Discharging gap between the discharging gap in each electrode pair and a rear electrode pair that is adjacent is UNICOM, therefore, in complete discharge process, the distance of the discharging gap of source of the gas gas stream warp is 2 times of general high voltage corona discharge type ozonizer, reduce unstripped gas also unreacted is complete and just flow out from the air outlet, unstripped gas is fully reacted generation ozone, has improved the utilization ratio of unstripped gas, and the ozone concn of generation also increases.
Equipment adopts two cooling fluids, and the outside of each electrode pair outer electrode is cooling oil reservoir, and the equipment innermost layer is full of water coolant, and the cooling performance of whole equipment improves greatly, avoids ozone can't in time coolingly to decompose because temperature is too high, good cooling results, and power consumption reduces.
Above-mentioned measures is conducive to improve the ozone factor of created gase of ozonizer.
Under identical ozone concn, use the ozonizer volume of this ozone generating pipe little, airframe structure more advances compactness, and whole equipment configuration is compact, has reduced occupation of land and space, and raw materials cost and working cost all will reduce simultaneously.
Description of drawings
Fig. 1 is the sectional view of multiple ozone generating apparatus.
Fig. 2 is the side-view of multiple ozone generating apparatus.
Reference numeral:
Interior electrode I 1, dielectric substance 2, discharging gap 3, outer electrode I 4, cooling oil reservoir 5, interior electrode II 6, outer electrode II 7, electrode pair I 8, electrode pair II 9, water coolant 10, stainless steel outer sleeve 11, gas source air inlet 12, air outlet 13, elliptical electrode pair 14, ground terminal 15 and high-pressure side 16.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.Should be understood that following examples are only for explanation the present invention but not for limiting scope of the present invention.
The experimental technique of unreceipted actual conditions in the following example, usually according to normal condition, or the condition that manufacturer provides is carried out.
Embodiment 1
Fig. 1 is the sectional view of multiple ozone generating apparatus.Fig. 2 is the side-view of multiple ozone generating apparatus.As shown in Fig. 1-2, this multiple ozone generating apparatus from inside to outside is the concentric(al) circles distribution by a plurality of electrode pairs and consists of,
Each described electrode comprises by interior electrode and outer electrode, and described interior electrode connects high-pressure side 16, and described outer electrode ground terminal 15 is discharging gap 3 between interior electrode and described outer electrode, is discharging gap 3 between two adjacent described electrode pairs.
Cooling fluid is arranged at the described outer electrode outside of described electrode pair, and concentrically ringed innermost layer.
Overcoat is arranged at the outermost layer of plurality of electrodes, can adopt stainless steel outer sleeve 11.
As shown in Fig. 1-2, in the present embodiment, cooling fluid is two cooling fluids, comprises water coolant 10 and cooling oil reservoir 5, and water coolant 10 is arranged at concentrically ringed innermost layer, and cooling oil reservoir 5 arranges the outer electrode outside with electrode pair.
Because this equipment adopts two cooling fluids, the outside of each electrode pair outer electrode is cooling oil reservoir 5, and the equipment innermost layer is full of water coolant 10, and the cooling performance of whole equipment improves greatly, avoids ozone can't in time coolingly to decompose because temperature is too high.
As shown in Fig. 1-2, in the present embodiment, each electrode pair is comprised of interior electrode and outer electrode respectively, and this equipment is water coolant 10, plurality of electrodes to, stainless steel outer sleeve 11 from inside to outside successively.
Equipment center is full of water coolant, and the equipment outermost is stainless steel outer sleeve 11.
Electrode pair comprises: electrode pair I 8, electrode pair II 9, and electrode pair n, each electrode pair are followed successively by interior electrode, dielectric substance, discharging gap 3, outer electrode, cooling oil reservoir 5 from inside to outside.Scribbling dielectric substance on interior electrode, is cooling oil reservoir outside outer electrode.
The discharging gap 3 that discharging gap 3 in electrode pair I 8 and electrode pair I 8 and electrode pair II are 9 is UNICOM, the discharging gap 3 that each electrode pair is interior and the outer electrode that is adjacent between discharging gap 3 be UNICOM.
Discharging gap between the discharging gap in each electrode pair and the electrode pair that is adjacent is that to make the distance of the discharging gap of source of the gas gas stream warp be 2 times of general high voltage corona discharge type ozonizer in UNICOM.
The interior electrode that adjacent electrode is right and outer electrode alternative arrangement, the interior electrode of the outer electrode of each electrode pair and the outer field electrode pair that is adjacent has formed again another electrode pair, the actual composition of adjacent two electrode pairs be 3 electrode pairs.
As depicted in figs. 1 and 2, the air outlet 13 of the gas source air inlet 12 of source of the gas gas and ozone is positioned at a side.The front end of the discharging gap 3 in electrode pair I 8 is gas source air inlet 12, the front end of the discharging gap 3 that electrode pair I 8 and electrode pair II are 9 is air outlet 13, the front end of the discharging gap 3 in each electrode pair is gas source air inlet 12, and the front end of the discharging gap 3 between two adjacent electrode pairs is air outlet 13.
Principle of work summary of the present invention:
As shown in Figure 1, source of the gas gas is from each gas source air inlet 12, the corresponding discharging gap 3 of flowing through.
Discharging gap 3 front ends in electrode pair I 8 are gas source air inlet 12, unstripped gas is flowed into by gas source air inlet 12, the high energy particle collision of discharging gap 3 and internal and external electrode (interior electrode I 1 and the outer electrode I 4) discharge generation of flowing through, make its ionization generate Sauerstoffatom, Sauerstoffatom, oxygen molecule and electronics any other gas molecule in the gap is (as airborne N 2, CO 2Deng) or other in the middle of induce under the effect of medium and generate ozone.Because the discharging gap 3 of 9 of the discharging gap 3 in electrode pair I 8 and electrode pair I 8, electrode pair II is UNICOM, the front end of the discharging gap 3 that electrode pair I 8, electrode pair II are 9 is air outlet 13, and ozone air outlet 13 thus flows out, collection ozone.
This multiple ozone generating apparatus solves the running cost high-technology problem that the low and ozone generating-device of the efficiency of ozone generation that exists occurs existing high-voltage corona discharge formula ozone, improved the utilization ratio of unstripped gas, increase ozone concn, save consumptive material and the discharge power consumption of discharge tube, thereby reduced cost.
Embodiment 2
Adopt the iodimetry,iodometry of stipulating in CJ/T322-2010 " water treatment ozonizer " standard to detect concentration and the output of ozone.Use this equipment, compare with general corona discharge type ozone generating apparatus, the ozone factor of created gase will improve 30-40% at least, ozone concn can reach 60-170mg/L, per kilogram ozone current consumption drops to 15KWh, per kilogram ozone current consumption reduces 20-30%, can reduce 40m if produce the 20Kg/h occupation area of equipment 2The left and right, corresponding floor space reduces 20-40%.
Above the specific embodiment of the present invention is illustrated, but the present invention is as limit, only otherwise break away from aim of the present invention, the present invention can also have various variations.

Claims (7)

1. a multiple ozone generating apparatus, is characterized in that, comprising:
Plurality of electrodes pair, being successively from inside to outside concentric(al) circles distributes, each described electrode comprises by interior electrode and outer electrode, described interior electrode connects high-pressure side (16), described outer electrode ground terminal (15), being discharging gap (3) between described interior electrode and described outer electrode, is discharging gap (3) between two adjacent described electrode pairs;
Cooling fluid is arranged at outside the described outer electrode of described electrode pair, and described concentrically ringed innermost layer; And
Overcoat is arranged at the outermost layer of described plurality of electrodes.
2. multiple ozone generating apparatus according to claim 1 is characterized in that:
Described cooling fluid is two cooling fluids, comprises water coolant (10) and cooling oil reservoir (5),
Wherein, described water coolant (10) is arranged at described concentrically ringed innermost layer,
Described cooling oil reservoir (5) arranges the described outer electrode outside with described electrode pair.
3. multiple ozone generating apparatus according to claim 1 and 2 is characterized in that:
Described electrode pair comprises: electrode pair I (8), electrode pair II (9), and electrode pair n, each described electrode pair is followed successively by interior electrode, dielectric substance, discharging gap (3), outer electrode, cooling oil reservoir (5) from inside to outside, discharging gap (3) in electrode pair I (8) and the discharging gap (3) between electrode pair I (8) and electrode pair II (9) are UNICOM, the discharging gap (3) that each described electrode pair is interior and the outer electrode that is adjacent between discharging gap (3) be UNICOM.
4. multiple ozone generating apparatus according to claim 3 is characterized in that:
The interior electrode that adjacent electrode is right and outer electrode alternative arrangement, the interior electrode of the outer electrode of each electrode pair and the outer field electrode pair that is adjacent has formed again another electrode pair, the actual composition of adjacent two electrode pairs be 3 electrode pairs.
5. multiple ozone generating apparatus according to claim 3 is characterized in that:
The air outlet (13) of the gas source air inlet of source of the gas gas (12) and ozone is positioned at a side.
6. multiple ozone generating apparatus according to claim 5 is characterized in that:
The front end of the discharging gap (3) in electrode pair I (8) is gas source air inlet (12), the front end of the discharging gap (3) between electrode pair I (8) and electrode pair II (9) is air outlet (13), the front end of the discharging gap (3) in each electrode pair is gas source air inlet (12), and the front end of the discharging gap (3) between two adjacent described electrode pairs is air outlet (13).
7. multiple ozone generating apparatus according to claim 1, it is characterized in that: described overcoat is stainless steel outer sleeve (11).
CN2012101997935A 2012-06-18 2012-06-18 Multiple ozone generating device Pending CN103159185A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106865502A (en) * 2017-04-11 2017-06-20 南京永研电子有限责任公司 A kind of plasma ozone generating-device
CN107037190A (en) * 2017-04-21 2017-08-11 成都赋阳技术开发有限公司 A kind of lifting/lowering type water-quality COD detection means
CN108069403A (en) * 2017-12-13 2018-05-25 广州畅驰机电设备有限公司 A kind of self cooling high-concentrated ozone system of low temperature
CN110054160A (en) * 2019-05-27 2019-07-26 华南理工大学 Integrated super pressure type ozone generating pipe
CN110697657A (en) * 2019-10-25 2020-01-17 恒天摩尔科技(山东)有限公司 Double-gas-path ozone generator and toilet deodorization equipment
CN111470474A (en) * 2013-10-04 2020-07-31 得利满技术股份公司 Ozone generator
CN116514068A (en) * 2023-07-05 2023-08-01 天津奥尔斯曼新能源科技有限公司 High-concentration split plate type ozone generator with gradual change of depth of discharge gap

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1421382A (en) * 2001-11-22 2003-06-04 三菱电机株式会社 Ozone generator
CN2719811Y (en) * 2004-08-26 2005-08-24 陈莲 High concentration ozone generator
CN201209121Y (en) * 2007-10-18 2009-03-18 多元水环保技术产业(中国)有限公司 High efficient ozone generator
CN101993046A (en) * 2010-11-29 2011-03-30 福建新大陆环保科技有限公司 Multi-gap discharge unit for ozone generator
CN102259840A (en) * 2010-05-29 2011-11-30 福建新大陆环保科技有限公司 Spiral cylindric discharging unit for ozone generator

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1421382A (en) * 2001-11-22 2003-06-04 三菱电机株式会社 Ozone generator
CN2719811Y (en) * 2004-08-26 2005-08-24 陈莲 High concentration ozone generator
CN201209121Y (en) * 2007-10-18 2009-03-18 多元水环保技术产业(中国)有限公司 High efficient ozone generator
CN102259840A (en) * 2010-05-29 2011-11-30 福建新大陆环保科技有限公司 Spiral cylindric discharging unit for ozone generator
CN101993046A (en) * 2010-11-29 2011-03-30 福建新大陆环保科技有限公司 Multi-gap discharge unit for ozone generator

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111470474A (en) * 2013-10-04 2020-07-31 得利满技术股份公司 Ozone generator
CN111470474B (en) * 2013-10-04 2023-08-04 得利满技术股份公司 Ozone generator
CN106865502A (en) * 2017-04-11 2017-06-20 南京永研电子有限责任公司 A kind of plasma ozone generating-device
CN107037190A (en) * 2017-04-21 2017-08-11 成都赋阳技术开发有限公司 A kind of lifting/lowering type water-quality COD detection means
CN108069403A (en) * 2017-12-13 2018-05-25 广州畅驰机电设备有限公司 A kind of self cooling high-concentrated ozone system of low temperature
CN110054160A (en) * 2019-05-27 2019-07-26 华南理工大学 Integrated super pressure type ozone generating pipe
CN110054160B (en) * 2019-05-27 2024-04-16 华南理工大学 Integrated ultrahigh-pressure ozone generating tube
CN110697657A (en) * 2019-10-25 2020-01-17 恒天摩尔科技(山东)有限公司 Double-gas-path ozone generator and toilet deodorization equipment
CN116514068A (en) * 2023-07-05 2023-08-01 天津奥尔斯曼新能源科技有限公司 High-concentration split plate type ozone generator with gradual change of depth of discharge gap
CN116514068B (en) * 2023-07-05 2023-09-12 天津奥尔斯曼新能源科技有限公司 High-concentration split plate type ozone generator with gradual change of depth of discharge gap

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Application publication date: 20130619