CN103155935A - Binary pesticide composition - Google Patents
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- CN103155935A CN103155935A CN2011104102547A CN201110410254A CN103155935A CN 103155935 A CN103155935 A CN 103155935A CN 2011104102547 A CN2011104102547 A CN 2011104102547A CN 201110410254 A CN201110410254 A CN 201110410254A CN 103155935 A CN103155935 A CN 103155935A
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Abstract
The invention discloses a binary pesticide composition. A first active component is selected from a compound A; a second active component is selected from indoxacarb or refined indoxacarb; and the compound A has the following structure described in the specification. The composition provided by the invention has the characteristics of obvious synergy, delayed pesticide resistance and the like, and can preventing and treating a plurality of pests.
Description
Technical field
The invention belongs to field of pesticides, relate to a kind of binary insecticides.
Background technology
Insecticide avoids having obvious effect aspect pest damage the various crops of protection, fruit tree, vegetables, afforestation and ornamental plants etc.
Chinese invention patent CN 101333213A discloses a kind of 1-substituted pyridyl-pyrazol acid amide compounds and has controlled the purposes of insect pest and disease, wherein compound 1.25 (hereinafter to be referred as compd A) can be used for preventing and treating various pests, especially lepidoptera pest is had outstanding control efficiency.
The insecticide that contains the single-activity component uses in control of insect continuously, and insect is developed immunity to drugs.Insecticide by two kinds of active components is mixed into blending ingredients by a certain percentage, often can improve preventive effect, reduces the consumption of active ingredient, saves cost, can delay the generation of pest resistance to insecticide simultaneously.
Can produce additional advantage and effect although disclose general compd A or its homologue and other Mixture Use of Insecticides in prior art, the technical scheme that contains the binary insecticides of compd A has no concrete open.
Summary of the invention
The object of the invention is to develop a kind of binary insecticides that contains compd A, the insecticide effect is day by day improved to satisfy agricultural and pest control aspect, urban health field the demand of constantly updating with kind.
Technical scheme of the present invention is as follows:
A kind of binary insecticides, active component one is selected from compd A, and active component two is selected from indoxacarb or smart indoxacarb; Described compd A has following structure:
In binary insecticides of the present invention, the ratio of weight and number of two kinds of active components is 1: 99～99: 1, is preferably 1: 20～20: 1.
Indoor biological activity determination demonstrates binary insecticides of the present invention and has good synergistic effect.Active component two in composition can be both that indoxacarb (being the mixture of S isomer and R isomer) can be also smart indoxacarb (100%S isomer).Because the R isomer does not have activity, when using indoxacarb as active component two, active ingredient is in the S isomer.
Composition of the present invention can be the finished product preparation form to be provided.Therefore, the present invention also comprises a kind of insecticides of dosage form.Take the binary insecticides as active component, make as required missible oil, suspending agent, water-dispersible granules, aqueous emulsion, soluble liquid, wetting powder, oil-suspending agent etc.In composition, the cumulative amount of active component is between 0.5%～95%, and preferred cumulative amount is between 1%-85%.Amount of application when in composition of the present invention, the content of active component depends on independent the use also depends on mixed ratio and synergistic effect degree.The optimum range of active component content is different according to the preparation type of composition.
The preparation of composition finished product preparation of the present invention can be by common processing method preparation, after being about to active substance and liquid-carrier (solvent) or solid carrier mixing, add one or more surfactants such as emulsifier, dispersant, wetting agent, adhesive, stabilizing agent and defoamer etc.Usually contain at least a carrier and at least a surfactant in composition.In all cases, should guarantee that present composition active component evenly distributes.
Missible oil contains 10～50% active component usually, 2～20% emulsifier, 0～20% other additives such as stabilizing agent, bleeding agent, corrosion inhibitor etc., and solvent (also containing in case of necessity cosolvent).
Suspending agent needs sand milling usually, to obtain stable non-deposition flowable product.Usually contain 5～75% active components in suspending agent, 5～15% dispersants, 0.1～10% thixotropic agent, 4～10% antifreezing agents, other additives of 0～10% such as defoamer, preservative, stabilizing agent, bleeding agent and thickener, and liquid-carrier surplus.
(aqueous dispersion) granule is made 10～100 international standard sieve mesh (1.676～0.152mm) particles usually, can be by extruding, dipping or the preparation of mist projection granulating method, usually (aqueous dispersion) granule surfactant for example stabilizing agent, wetting dispersing agent, disintegrant and adhesive of containing 0.5～75% active component and 5～20%, and inert carrier surplus.
Wetting powder contains 10～85% active component usually, except solid inert carrier, usually contains 3～10% dispersant, can also contain 0～10% stabilizing agent and (or) other additives, for example bleeding agent or sticker.
Aqueous emulsion is that former medicine, organic solvent, surfactant mixing are formed oil phase, and water, antifreezing agent are mixed, and becomes the transparent and homogeneous water.With high-shear emulsion machine high speed shear oil phase, slowly water is added oil phase simultaneously, common active ingredient 1～60%, surfactant 5～20%, antifreezing agent 2～10%, water surplus.
Microemulsion is that former medicine, organic solvent, surfactant, water are mixed, and becomes the transparent and homogeneous water.Common active ingredient 1～50%, surfactant 10～40%, antifreezing agent 2～10%, water surplus.
Soluble liquid is that active component, organic solvent, surfactant are mixed, and becomes transparent and homogeneous liquid.Common active ingredient 1～50%, surfactant 6～20%, organic solvent surplus.
Oil-suspending agent is with having active component, surfactant, oil base carrier to add sand milling in sand mill, until particle diameter is qualified, and common active ingredient 2～60%, surfactant 6～20%, oil base carrier surplus.
Moisture dispersion liquid and emulsion (composition that missible oil as of the present invention in dilute with water, wetting powder or concentrate obtain) are also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have dense thick pulpous state denseness.
The preparation of composition finished product preparation of the present invention can be adopted known (liquid or solid) carrier of those skilled in the art and various auxiliary agent.For example include but not limited to following all kinds of material.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., as one or more in toluene, dimethylbenzene, acetone, cyclohexanone, dimethylbenzene, benzene, cyclohexane, isopropyl alcohol, ethylene glycol, sorbierite, methyl alcohol, ethanol, butanols, dimethyl formamide, naphthalane, machine oil, benzinum etc.
Suitable solid carrier comprises natural or synthetic clay and silicate, and the solid carrier that is applicable to pulvis comprises the rock dust of natural formation, chalk, quartz, clay, imvite, silica, diatomite, float stone, gypsum, talcum, bentonite, kaolin, potter's clay and the synthetic mineral matter that grinds (as microdispersed silicic acid or aluminium oxide).The particulate vector that is fit to comprises broken and natural rock classification for example calcite, marble, float stone, sepiolite and dolomite and the synthetic particle made by the powder of organic matter and inorganic matter.
Suitable cosolvent is one or more in methyl alcohol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), ethyl acetate, butanone, dimethyl formamide etc.
Suitable emulsifier can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 600#, agriculture breast 1601#, agriculture breast 2201# etc.
Suitable dispersant can be for sodium lignin sulfonate, calcium lignosulfonate, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, methyl naphthalene sulfonate formaldehyde condensate, methanonaphthalene sodium sulfonate, oleic acid methylamino ethylsulfonic acid sodium, epoxidized polyether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, dibutyl naphthalene sulfonic acid-formaldehyde condensation product, alkylphenol-polyethenoxy based phosphates, methylcellulose etc.
Suitable wetting agent can be sodium sulphate, sldium lauryl sulfate, methanonaphthalene sodium sulfonate, neopelex, calcium dodecyl benzene sulfonate, Negel aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc.
Suitable thickener can be (as carbonyl methylol, polyvinyl alcohol, polyvinyl acetate) or the natural water-soluble polymer (as xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc.) that synthesizes, and adds in preparation with powder, particle or latex form.
Suitable defoamer is bubble enemy, silicone, C8～10 fatty alcohols, phosphoric acid ester, C10～20 saturated fat acids (as capric acid) and acid amides etc.
Suitable oxidant is: potassium chlorate, sodium chlorate, potassium perchlorate, sodium nitrate, potassium nitrate, potassium permanganate etc.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sodium alginate etc.In addition, defoamer can be silicone etc.
Can make aerosol when being used for preventing and treating the city insect, need to add therein propellant, also the bait formulation composition be can make, except containing active component, one or more foodstuffs that are suitable for insect's food-taking, optional attractant and optional wetting agent also contained.
Composition of the present invention is suitable for preventing and treating multiple important agriculture and forestry injurious insect or urban health insect, as mythimna separata, beet armyworm, cotton bollworm, cutworm, tomato moth, apple skin worm, rice leaf roller, corn borer, striped rice borer, diamond-back moth, cabbage caterpillar, fall webworm, tent caterpillar, gypsymoth, Asiatic migratory locust, soil insect, leaf miner, liriomyza bryoniae, aphid, mite class etc., city insect such as termite, blattaria, ant, fly class, mosquito class etc.Be used for fruit tree such as apple, pears, citrus, lichee etc., Cereal such as wheat, paddy rice etc., beans such as soybean, Kidney bean etc., cotton, vegetables such as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum etc., and flowers.When being used for control city insect, can be used for family, various public place, office space, and the trees of generation termite damage, dykes and dams etc.Therefore, the present invention also comprises the purposes of present composition control agriculture and forestry injurious insect or urban health insect.
The present invention also comprises a kind of method of controlling insect pest, the present composition can be imposed on the medium of insect that need to control or its growth with effective dose.Usually the comparatively suitable effective dose of selecting be per hectare 10 grams to 500 grams, preferred effective dose is that per hectare 15 grams are to 100 grams.
The present invention has following advantage:
The one, composition of the present invention shows obvious synergistic effect in certain ratio range, improved the control efficiency of this compound to insect.
The 2nd, said composition reduces the using dosage of compound in application, thereby reduces use cost, environmental contamination reduction.
The 3rd, in said composition, the mechanism of action of each active ingredient is different, does not have the problem of cross resistance, can delay the generation of pest resistance to insecticide with its pest control, and improves the control efficiency of antagonism population.
Embodiment
Following specific embodiment is used for further describing the present invention, but the present invention only limits to absolutely not these examples.In embodiment, each component percentage composition or proportioning are all by weight.Active component in each formula is calculated with effective content.
Formulation Example
The preparation of embodiment 1,10% compd A indoxacarb missible oil
By the formula requirement, 5 parts of compd As, 5 parts of indoxacarbs, 6 parts of agriculture breast 0201B, 4 parts of agriculture breast 0203B, 1.5 parts of agriculture breasts 1601,5 parts of methyl alcohol, dimethylbenzene are complemented to 100%, mix, use in case of necessity the hot bath heating for dissolving, namely obtain 10% compd A indoxacarb missible oil.
The preparation of embodiment 2,60% compd A indoxacarb wetting powder
By the formula requirement, with 15 parts of compd As, 45 parts of indoxacarbs, 2 parts of lauryl sodium sulfate, 4 parts of calcium lignosulfonates, 8 parts of condensation compound of methyl naphthalene sulfonic acid and formaldehyde, 2 parts tertbutyl ether, 6 parts of White Carbon blacks, 2 parts of detergent LS, precipitated calcium carbonate etc. are complemented to 100%, fully mix, after ultra-fine pulverizer disintegrating, namely obtain 60% compd A indoxacarb wetting powder.
The preparation of embodiment 3,15% compd A indoxacarb aqueous emulsion
By the formula requirement, with 5 parts of compd As, 10 parts of indoxacarbs, 10 parts of agriculture breasts 2201,4.5 parts of alkylaryl polyoxyethylene poly-oxygen propylene aethers, 2.5 parts of piperonyl butoxides, 10 parts of cyclohexanone, 5 parts of glycerine, be added together, make to be dissolved into even oil phase.Under high-speed stirred, water is complemented to 100%, join oil phase, form 15% compd A indoxacarb aqueous emulsion of favorable dispersibility.
The preparation of embodiment 4,9% compd A indoxacarb aqueous emulsion
By the formula requirement, with 6 parts of compd As, 3 parts of indoxacarbs, 8.5 parts of agriculture breast 507#, 3.5 parts of agriculture breast OX-8686,3 parts of agriculture breasts 1601,8 parts of dimethyl formamides, 0.5 part of tetradecanol, 5 parts of ethylene glycol, be added together, make to be dissolved into even oil phase.Under high-speed stirred, water is complemented to 100%, join oil phase, form 9% compd A indoxacarb aqueous emulsion of favorable dispersibility.
The preparation of embodiment 5,60% compd A indoxacarb water-dispersible granules
By the formula requirement; 45 parts of compd As, 15 parts of indoxacarbs, 8 parts of naphthalenesulfonic acid-formaldehyde condensates, 4 parts of methyl naphthalene sulfonate formaldehyde condensates, 6 parts of N-methyl-oleoyl-sodium taurocholates, 10 parts of sodium sulphate, kaolin etc. are complemented to 100%; carry out co-grinding; after adding again the water kneading, add and carry out granulation in the comminutor that the certain specification screen cloth is housed.And then drying, screening (by the screen cloth scope) namely get 60% compd A indoxacarb water-dispersible granules.
The preparation of embodiment 6,10% compd A indoxacarb suspending agent
By the formula requirement, 7.5 parts of compd As, 2.5 parts of indoxacarbs, 3 parts of methyl naphthalene sulfonate formaldehyde condensates, 3 parts of sodium lignin sulfonates, 6 parts of agriculture breast 0201B, 0.3 part of xanthans, 0.6 part of white carbon, 5 parts of ethylene glycol, water are complemented to 100%, add in the sand milling still, carry out porphyrize, make 10% compd A indoxacarb suspending agent.
Embodiment 7,10% compd A indoxacarb soluble concentrate
By the formula requirement, 2.5 parts of compd As, 7.5 parts of indoxacarbs, 15 parts of agriculture breasts 2201,2 parts of agriculture breast T-20,8 parts of agriculture breast NP-15,12 parts of dimethyl formamides, 8 parts of methyl alcohol, the molten fibers of methyl are complemented to 100%, mix, use in case of necessity the hot bath heating for dissolving, can make 10% compd A indoxacarb soluble concentrate.
The preparation of embodiment 8,6% compd A indoxacarb microemulsion
By the formula requirement, with 2 parts of compd As, 4 parts of indoxacarbs, 5 parts of triphenyl vinyl phenol polyoxyethylene (n
20) the peaceful breast 36 of ether phosphoric acid triethanolamine salt, 8 parts
#, 10 parts of agriculture breast OX-2681,20 parts of cyclohexanone, 8 parts of cyclohexanol are added together, make to be dissolved into even oil phase.Excess water, 5 parts of ethylene glycol are mixed, become the homogeneous water.Under high-speed stirred, water is joined oil phase or oil phase is joined water, form 6% compd A indoxacarb microemulsion of favorable dispersibility.
The preparation of embodiment 9,30% compd A indoxacarb oil-suspending agent
By the formula requirement, with 7.5 parts of compd As, 22.5 parts of indoxacarbs, 3 parts of agriculture breast S-80,2 parts of agriculture breast T-20,6 parts of agriculture breast 0201B, 3 parts of agriculture breasts 500
#, 2 parts of white carbon, surpluses soybean oil that methylates, add in the sand milling still, carry out porphyrize, make 30% compd A indoxacarb oil-suspending agent.
Indoor biological activity determination
Embodiment 10 compd As mix use to corn borer toxicity determination test with indoxacarb
For trying object: corn borer (Ostrinia furnacalis), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24～26 ℃, humidity: RH 60%, illumination: L: D=14: 10
Test medication liquid making method: accurately take respectively reagent agent with electronic analytical balance, after adding appropriate solvent to dissolve fully two kinds of former medicines respectively, be mixed with the desired concn mother liquor with the water that contains 0.1% Tween 80, two kinds of active ingredient mother liquors are hybridly prepared into mixed solution by a certain percentage, are diluted to respectively the serial liquid of tool finite concentration gradient by experimental scheme dosage.
Test method: adopt artificial feed culture plate method, 24 well culture plates of selection standard cleaning, every hole adds the 1ml artificial feed, after cooled and solidified, adds the 0.05ml liquid with continuous sampler to each hole of culture plate, then puts shady and cool place nature and dries in the shade.Select in the examination worm access culture plate of neat and consistent, 1, every hole, every processing repeats 4 times.Examination worm after processing is placed in observation ward, routine observation examination worm response situation, the 72h " Invest, Then Investigate " is dead, the borer population of living.
With abbott formula calculation correction lethality, the appliance computer program is obtained each for examination single dose and mixed virulence regression equation formula, LC50 value and 95% confidence limit of variant proportioning, with Sun Yunpei (SunY-P) method, obtain the mixed co-toxicity coefficient of each proportioning, estimate.If co-toxicity coefficient is summation action near 100, for synergistic effect, be starkly lower than 100 for picking up anti-effect apparently higher than 100.
Result of the test sees Table 1.As can be seen from the table, each proportioning is mixed all shows synergistic effect to corn borer to compd A for trying with indoxacarb.
Table 1: the compd A indoxacarb is to the indoor joint toxicity measuring result of corn borer
Embodiment 11 compd As mix use to beet armyworm toxicity determination test with indoxacarb
For trying object: beet armyworm (Spodoptera exigua), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24～26 ℃, humidity: RH 60%, illumination: L: D=14: 10
The liquid compound method is with embodiment 10.Test method: adopt infusion process to process, the cabbage leaves of greenhouse culture is fetched, make diameter 2cm leaf dish, the leaf dish is flooded 5s in liquid, dry in the shade after taking-up, put into the 9cm culture dish that is lined with filter paper, select in the examination worm access culture dish of neat and consistent, every processing repeats 4 times.Examination worm after processing is placed in observation ward, routine observation examination worm response situation, the 48h " Invest, Then Investigate " is dead, the borer population of living.
Calculate evaluation method with embodiment 10.
Result of the test sees Table 2.As can be seen from the table, each proportioning is mixed all shows synergistic effect to beet armyworm to compd A for trying with indoxacarb.
Table 2: the compd A indoxacarb is to the indoor joint toxicity measuring result of beet armyworm
Claims (7)
1. binary insecticides, active component one is selected from compd A, and active component two is selected from indoxacarb or smart indoxacarb; Described compd A has following structure:
The ratio of weight and number of two kinds of active components is 1: 99～99: 1.
2. according to composition claimed in claim 1, it is characterized in that: the ratio of weight and number of two kinds of active components is 1: 20～20: 1.
3. according to composition claimed in claim 1, it is characterized in that: can make as required missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
4. according to composition claimed in claim 3, it is characterized in that: in composition, the cumulative amount of active component is between 0.5%-95%.
5. according to composition claimed in claim 4, it is characterized in that: in composition, the cumulative amount of active component is between 1%-85%.
6. purposes of controlling agriculture and forestry injurious insect or urban health insect according to binary insecticides claimed in claim 1.
7. method of controlling insect pest is characterized in that: composition claimed in claim 1 is imposed on the medium of insect that needs control or its growth with effective dose.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110410254.7A CN103155935B (en) | 2011-12-09 | 2011-12-09 | Binary pesticide composition |
| PCT/CN2012/086186 WO2013083084A1 (en) | 2011-12-09 | 2012-12-07 | Synergistic composition with insecticidal activity |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110410254.7A CN103155935B (en) | 2011-12-09 | 2011-12-09 | Binary pesticide composition |
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| CN103155935B CN103155935B (en) | 2015-05-13 |
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| CN201110410254.7A Active CN103155935B (en) | 2011-12-09 | 2011-12-09 | Binary pesticide composition |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103651386A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition containing chlorfenapyr |
| CN104672025A (en) * | 2013-12-03 | 2015-06-03 | 广西新方向化学工业有限公司 | Chlorantraniliprole-containing pesticide fertilizer composition |
| CN105794825A (en) * | 2013-01-19 | 2016-07-27 | 陕西汤普森生物科技有限公司 | Insecticide composition containing tetrachlorantraniliprole and carbamic acid esters |
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| WO2006068669A1 (en) * | 2004-07-26 | 2006-06-29 | E.I. Dupont De Nemours And Company | Mixtures of anthranilamide invertebrate pest control agents |
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| CN101646349A (en) * | 2006-12-01 | 2010-02-10 | 杜邦公司 | Liquid formulations of carboxamide arthropodicides |
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2011
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| WO2006068669A1 (en) * | 2004-07-26 | 2006-06-29 | E.I. Dupont De Nemours And Company | Mixtures of anthranilamide invertebrate pest control agents |
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| CN101646349A (en) * | 2006-12-01 | 2010-02-10 | 杜邦公司 | Liquid formulations of carboxamide arthropodicides |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105794825A (en) * | 2013-01-19 | 2016-07-27 | 陕西汤普森生物科技有限公司 | Insecticide composition containing tetrachlorantraniliprole and carbamic acid esters |
| CN104672025A (en) * | 2013-12-03 | 2015-06-03 | 广西新方向化学工业有限公司 | Chlorantraniliprole-containing pesticide fertilizer composition |
| CN103651386A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition containing chlorfenapyr |
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