Background technology
Wallpaper is a kind of application house decorative material quite widely.Therefore the incomparable characteristics of multiple other house decorative material such as color is various because wallpaper has, pattern is abundant, luxurious style, safety and environmental protection, easy construction, price are suitable are in the developed country such as America and Europe, Southeast Asia, Japan with regionally obtain popularizing of certain degree.Wallpaper is divided into a lot of classes, as coating wallpaper, overlay film wallpaper, embossing wallpaper etc.Usually produce body paper with bleached wood pulp, then process through the processing of different operations, cover as coating, printing, embossing or surface and mould, dispatch from the factory after cutting, packing.Because have certain intensity, appearance attractive in appearance and good water repelling property, be widely used in the interior decoration in dwelling house, office, hotel etc.
At present along with the raising of living standards of the people, now more and more higher to the requirement of interior decoration and air quality aspect, but to pollute be but the main aspect that causes at present room air pollution for house decorative material and furniture.Paint, wallpaper, glued board, wood shavings filler, the materials such as interior wall coating all contain the harmful substances such as formaldehyde, benzene, above material all has suitable carcinogenic, so the ornament materials that be badly in need of a kind of environmental protection of exploitation on market, purifies the air of a room is to satisfy the people to the requirement of interior decoration and people's health.
Tea Polyphenols is the general name of Polyphenols of Tea, comprises flavanol compound, anthocyanin class, flavonoids, flavonols and phenolic acid class etc.Wherein important with flavanol compound material (catechin).Tea Polyphenols claims again tea to tan or tea tannin, is one of Main Ingredients and Appearance that forms the tealeaves color, smell and taste, is also one of Main Ingredients and Appearance that has in tealeaves health care.Studies show that, the detoxifcation of Tea Polyphenols isoreactivity material tool and radiation resistance can effectively stop radioactive substance to invade marrow, and strontium 90 and Co 60 are excreted rapidly, are described as by health and medical circle " radiation jinx ".
Research finds that Tea Polyphenols has good antibacterial action, and it can kill clostridium botulinum and spore thereof, the ectotoxic activity of anti-bacteria.The various pathogens that cause diarrhoea, respiratory tract and skin infection there is antibacterial action.Tea Polyphenols has clearly inhibitory action to staphylococcus aureus, proteus, the Pseudomonas aeruginosa that causes pyogenic infection, burn, wound, and these three kinds of bacterial strains easily produce drug resistance to medicine, and the septicemia death rate that causes thus is up to 80%.Tang Yufang, Zhang Miaoling etc., the bacteriostatic activity research of Tea Polyphenols, 2005,22(5) research finds that Tea Polyphenols has stronger bacteriostatic activity to bacterium.
Tea Polyphenols also has and well goes the formaldehyde effect, Herrick F.W., Bock L.H.Thermosetting, exterior-plywood type adhesives from barkextracts.1958,8, middle research finds that formaldehyde can on C-6 and C-8, necleophilic reaction occur with tea polyphenolic compounds.The researcher also utilizes Tea Polyphenols to carry out the Preliminary Applications test as methanal trapping agent afterwards.Encourage and build honor, Yu Qilin etc., the response characteristic research of Tea Polyphenols and formaldehyde, 2008,8(2) research finds that Tea Polyphenols is a kind of good methanal trapping agent, can well remove formaldehyde.
We study and find tea dust and Tea Polyphenols are added in hanging raw stock, can not only kill the bacterium in wallpaper itself and manufacture process, when wallpaper is applied in interior decoration, suppresses and kill indoor bacterium; And can also remove timber and indoor formaldehyde, play the effect that purifies air.
Summary of the invention
Cause the problem of indoor pollution for solving house decorative material, the invention provides a kind of hanging raw stock and manufacture method thereof of adding tea dust and Tea Polyphenols.
Technical scheme of the present invention is as follows:
Hanging raw stock disclosed in this invention is comprised of long fiber wood pulp, staple fibre wood pulp, tea dust, Tea Polyphenols, sizing agent and auxiliary agent
The mass ratio of hanging raw stock disclosed in this invention consists of:
Long fiber wood pulp 10% ~ 90%
Staple fibre wood pulp 5% ~ 80%
Tea dust 1% ~ 10%
Tea Polyphenols 1% ~ 10%
Sizing agent 0.1% ~ 5%
Auxiliary agent 1% ~ 20%.
Preferably:
Long fiber wood pulp 20% ~ 80%
Staple fibre wood pulp 10% ~ 70%
Tea dust 1% ~ 5%
Tea Polyphenols 1% ~ 5%
Sizing agent 0.2% ~ 3%
Auxiliary agent 2% ~ 15%.
More preferably:
Long fiber wood pulp 30% ~ 70%
Staple fibre wood pulp 20% ~ 60%
Tea dust 1% ~ 3%
Tea Polyphenols 1% ~ 3%
Sizing agent 0.5% ~ 1%
Auxiliary agent 5% ~ 10%.
Hanging raw stock disclosed in this invention, wherein sizing agent is cationic dispersion rosin size and or alkyl ketene dimer.
Hanging raw stock disclosed in this invention, wherein the auxiliary agent agent be selected from starch, calcium carbonate, epoxy polyester, polyacrylamide, polyethylene glycol oxide or polyamine epichlorohydrin resin one or more.
Hanging raw stock manufacture method disclosed in this invention comprises the following steps:
(1) pulping: add hydrabrusher to carry out pulping long fiber wood pulp and staple fibre wood pulp, straight pulping concentration is 2% ~ 4%,
(2) making beating: the slurries after pulping are sent in beater pulled an oar, control beating degree 20-50
oSR,
(3) applying glue: making beating joins the tea dust after ultramicronising, Tea Polyphenols, sizing agent and auxiliary agent in slurries and mix afterwards,
(4) starching moulding: adopt the fourdrinier wire starching, online concentration 0.5% ~ 1%, the online slurry pH value: 7.0 ~ 8.5,
(5) after the starching moulding, through fourdrinier wire dehydration, squeezing, dry press polish, batch ornamenting and get hanging raw stock,
Quantitative 85 ~ the 110g/m of hanging raw stock that wherein makes
3Moisture 4% ~ 9%; Opacity 88% ~ 95%; Dry tensile strength 3.5 ~ 5.8KN/m; Wet tensile (strength) 0.65 ~ 1.5KN/m; Tearability 810 ~ 1500mN; Green deformation 0 ~ 0.8%; Air-dry distortion-0.1 ~-0.6%.
The present invention adds tea dust and Tea Polyphenols in hanging raw stock to, on the one hand can be with the tea dust recycling of passing into disuse, can also prevent the pollution of the environment on the other hand, the wallpaper of manufacturing can not only be killed the bacterium in wallpaper itself and manufacture process, when wallpaper is applied in interior decoration, suppresses and kill indoor bacterium; And can also remove timber and indoor formaldehyde, play the effect that purifies air.
The specific embodiment
The following examples are to describe in further detail of the present invention.
Embodiment 1
1.1 hanging raw stock forms
Long fiber wood pulp 70%
Staple fibre wood pulp 10%
Tea dust 10%
Tea Polyphenols 1%
Alkyl ketene dimer 5%
Starch 4%
1.2 manufacture method
(1) pulping: add hydrabrusher to carry out pulping long fiber wood pulp and staple fibre wood pulp, straight pulping concentration is 2%,
(2) making beating: the slurries after pulping are sent in beater pulled an oar, control beating degree 20-50
oSR,
(3) applying glue: making beating joins the tea dust after ultramicronising, Tea Polyphenols, sizing agent and auxiliary agent in slurries and mix afterwards,
(4) starching moulding: adopt the fourdrinier wire starching, online concentration 0.5%, the online slurry pH value: 7.0 ~ 8.5,
(5) after the starching moulding, through fourdrinier wire dehydration, squeezing, dry press polish, batch ornamenting and get hanging raw stock,
1.3 wallpaper restraining and sterilizing bacteria effect
The wallpaper tiling of preparation is positioned in the closed chamber of 10 square metres.Adopt the shock method of GB/T18883-2002 to measure the total plate count that the wallpaper placement is front and place room air after 48 hours.
Result shows that the total plate count in placing the wallpaper cup is 2579cfu/m
3, indoor total plate count is 2434 cfu/m after wallpaper 48 hours and place
3So result shows that wallpaper of the present invention has well antibacterial and bactericidal action.
1.4 wallpaper removes effect of formaldehyde
The test method that provides according to building material industry standard JC/T 1074-2008 is removed the effect of formaldehyde test to described wallpaper, and result is referring to table 1, and the interpolation tea dust that table 1 provides for the embodiment of the present invention 1 and the wallpaper of Tea Polyphenols are except the aldehyde test result.
The interpolation tea dust that table 1 embodiment of the present invention 1 provides and the wallpaper of Tea Polyphenols are except the aldehyde test result
Time (h) |
0 |
24 |
48 |
72 |
96 |
120 |
144 |
168 |
Concentration (mg/m
3)
|
2.0 |
0.495 |
0.416 |
0.374 |
0.35 |
0.328 |
0.314 |
0.304 |
Efficient (%) |
— |
75.2 |
79.2 |
81.3 |
82.5 |
83.6 |
84.3 |
84.8 |
As shown in Table 1, can reach 84.8% except formaldehyde efficient after embodiment of the present invention 168h, illustrate that the wallpaper of interpolation tea dust provided by the invention and Tea Polyphenols has the ability of removing efficiently, lastingly formaldehyde.
Embodiment 2
2.1 hanging raw stock forms
Long fiber wood pulp 60%
Staple fibre wood pulp 20%
Tea dust 1%
Tea Polyphenols 10%
Alkyl ketene dimer 0.1%
Epoxy polyester 0.9%
Starch 2%
Calcium carbonate 6%
2.2 manufacture method
(1) pulping: add hydrabrusher to carry out pulping long fiber wood pulp and staple fibre wood pulp, straight pulping concentration is 4%,
(2) making beating: the slurries after pulping are sent in beater pulled an oar, control beating degree 20-50
oSR,
(3) applying glue: making beating joins the tea dust after ultramicronising, Tea Polyphenols, sizing agent and auxiliary agent in slurries and mix afterwards,
(4) starching moulding: adopt the fourdrinier wire starching, online concentration 1%, the online slurry pH value: 7.0 ~ 8.5,
(5) after the starching moulding, through fourdrinier wire dehydration, squeezing, dry press polish, batch ornamenting and get hanging raw stock,
2.3 wallpaper restraining and sterilizing bacteria effect
The wallpaper tiling of preparation is positioned in the closed chamber of 10 square metres.Adopt the shock method of GB/T18883-2002 to measure the total plate count that the wallpaper placement is front and place room air after 48 hours.
Result shows that the total plate count in placing the wallpaper cup is 2589cfu/m
3, indoor total plate count is 2367 cfu/m after wallpaper 48 hours and place
3So result shows that wallpaper of the present invention has well antibacterial and bactericidal action.
2.4 wallpaper removes effect of formaldehyde
The test method that provides according to building material industry standard JC/T 1074-2008 is removed the effect of formaldehyde test to described wallpaper, and result is referring to table 2, and the interpolation tea dust that table 2 provides for the embodiment of the present invention 2 and the wallpaper of Tea Polyphenols are except the aldehyde test result.
The interpolation tea dust that table 2 embodiment of the present invention 2 provides and the wallpaper of Tea Polyphenols are except the aldehyde test result
Time (h) |
0 |
24 |
48 |
72 |
96 |
120 |
144 |
168 |
Concentration (mg/m
3)
|
2.0 |
0.298 |
0.220 |
0.179 |
0.158 |
0.135 |
0.125 |
0.120 |
Efficient (%) |
— |
85.1 |
89 |
91.1 |
92.1 |
93.3 |
93.8 |
94 |
As shown in Table 2, can reach 94% except formaldehyde efficient after the embodiment of the present invention 1 68h, illustrate that the wallpaper of interpolation tea dust provided by the invention and Tea Polyphenols has the ability of removing efficiently, lastingly formaldehyde.
Embodiment 3
3.1 hanging raw stock forms
Long fiber wood pulp 50%
Staple fibre wood pulp 30%
Tea dust 5%
Tea Polyphenols 5%
Alkyl ketene dimer 3%
Starch 2%
Calcium carbonate 5%
3.2 manufacture method
(1) pulping: add hydrabrusher to carry out pulping long fiber wood pulp and staple fibre wood pulp, straight pulping concentration is 3%,
(2) making beating: the slurries after pulping are sent in beater pulled an oar, control beating degree 20-50
oSR,
(3) applying glue: making beating joins the tea dust after ultramicronising, Tea Polyphenols, sizing agent and auxiliary agent in slurries and mix afterwards,
(4) starching moulding: adopt the fourdrinier wire starching, online concentration 0.8%, the online slurry pH value: 7.0 ~ 8.5,
(5) after the starching moulding, through fourdrinier wire dehydration, squeezing, dry press polish, batch ornamenting and get hanging raw stock,
3.3 wallpaper restraining and sterilizing bacteria effect
The wallpaper tiling of preparation is positioned in the closed chamber of 10 square metres.Adopt the shock method of GB/T18883-2002 to measure the total plate count that the wallpaper placement is front and place room air after 48 hours.
Result shows that the total plate count in placing the wallpaper cup is 2568cfu/m
3, indoor total plate count is 2387 cfu/m after wallpaper 48 hours and place
3So result shows that wallpaper of the present invention has well antibacterial and bactericidal action.
3.4 wallpaper removes effect of formaldehyde
The test method that provides according to building material industry standard JC/T 1074-2008 is removed the effect of formaldehyde test to described wallpaper, and result is referring to table 3, and the interpolation tea dust that table 3 provides for the embodiment of the present invention 3 and the wallpaper of Tea Polyphenols are except the aldehyde test result.
The interpolation tea dust that table 3 embodiment of the present invention 3 provides and the wallpaper of Tea Polyphenols are except the aldehyde test result
Time (h) |
0 |
24 |
48 |
72 |
96 |
120 |
144 |
168 |
Concentration (mg/m
3)
|
2.0 |
0.308 |
0.230 |
0.189 |
0.168 |
0.145 |
0.135 |
0.130 |
Efficient (%) |
— |
84.6 |
88.5 |
91 |
91.6 |
92.8 |
93.3 |
93.5 |
As shown in Table 3, can reach 93.5% except formaldehyde efficient after the embodiment of the present invention 1 68h, illustrate that the wallpaper of interpolation tea dust provided by the invention and Tea Polyphenols has the ability of removing efficiently, lastingly formaldehyde.
Embodiment 4
4.1 hanging raw stock forms
Long fiber wood pulp 50%
Staple fibre wood pulp 40%
Tea dust 2%
Tea Polyphenols 2%
Alkyl ketene dimer 0.8%
Polyacrylamide 0.2%
Starch 2%
Calcium carbonate 3%
4.2 manufacture method
Manufacture method is with embodiment 3.
4.3 wallpaper restraining and sterilizing bacteria effect
The wallpaper tiling of preparation is positioned in the closed chamber of 10 square metres.Adopt the shock method of GB/T18883-2002 to measure the total plate count that the wallpaper placement is front and place room air after 48 hours.
Result shows that the total plate count in placing the wallpaper cup is 2548cfu/m
3, indoor total plate count is 2327 cfu/m after wallpaper 48 hours and place
3So result shows that wallpaper of the present invention has well antibacterial and bactericidal action.
4.4 wallpaper removes effect of formaldehyde
The test method that provides according to building material industry standard JC/T 1074-2008 is removed the effect of formaldehyde test to described wallpaper, and result is referring to table 4, and the interpolation tea dust that table 4 provides for the embodiment of the present invention 4 and the wallpaper of Tea Polyphenols are except the aldehyde test result.
The interpolation tea dust that table 4 embodiment of the present invention 4 provides and the wallpaper of Tea Polyphenols are except the aldehyde test result
Time (h) |
0 |
24 |
48 |
72 |
96 |
120 |
144 |
168 |
Concentration (mg/m
3)
|
2.0 |
0.298 |
0.213 |
0.182 |
0.168 |
0.149 |
0.124 |
0.119 |
Efficient (%) |
— |
85.1 |
89.4 |
90.9 |
91.6 |
92.6 |
93.8 |
94.1 |
As shown in Table 4, can reach 94.1% except formaldehyde efficient after the embodiment of the present invention 1 68h, illustrate that the wallpaper of interpolation tea dust provided by the invention and Tea Polyphenols has the ability of removing efficiently, lastingly formaldehyde.
Although illustrated and described embodiments of the invention, for the ordinary skill in the art, be appreciated that without departing from the principles and spirit of the present invention and can carry out multiple variation, modification, replacement and modification to these embodiment, scope of the present invention is limited by claims and equivalent thereof.