CN103146292B - 一种耐水煮聚酯粉末涂料及其制备方法和应用 - Google Patents
一种耐水煮聚酯粉末涂料及其制备方法和应用 Download PDFInfo
- Publication number
- CN103146292B CN103146292B CN201310042733.7A CN201310042733A CN103146292B CN 103146292 B CN103146292 B CN 103146292B CN 201310042733 A CN201310042733 A CN 201310042733A CN 103146292 B CN103146292 B CN 103146292B
- Authority
- CN
- China
- Prior art keywords
- polyester resin
- resin particle
- particle system
- vibrin
- acid number
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 103
- 239000011248 coating agent Substances 0.000 title claims abstract description 100
- 239000000843 powder Substances 0.000 title claims abstract description 95
- 229920000728 polyester Polymers 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title description 18
- 239000002253 acid Substances 0.000 claims abstract description 187
- 239000002245 particle Substances 0.000 claims abstract description 104
- 229920001225 polyester resin Polymers 0.000 claims abstract description 96
- 239000004645 polyester resin Substances 0.000 claims abstract description 96
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 93
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 50
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 21
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical class [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 7
- 239000000945 filler Substances 0.000 claims description 44
- 239000012752 auxiliary agent Substances 0.000 claims description 42
- 238000009835 boiling Methods 0.000 claims description 41
- 150000002148 esters Chemical class 0.000 claims description 38
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 18
- 239000000049 pigment Substances 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 15
- MZZSDCJQCLYLLL-UHFFFAOYSA-N Secalonsaeure A Natural products COC(=O)C12OC3C(CC1=C(O)CC(C)C2O)C(=CC=C3c4ccc(O)c5C(=O)C6=C(O)CC(C)C(O)C6(Oc45)C(=O)OC)O MZZSDCJQCLYLLL-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 239000012948 isocyanate Substances 0.000 claims description 8
- 150000002513 isocyanates Chemical class 0.000 claims description 8
- 238000007711 solidification Methods 0.000 claims description 8
- 230000008023 solidification Effects 0.000 claims description 8
- 239000012467 final product Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 abstract description 16
- -1 hydroxyalkyl acidamide Chemical compound 0.000 abstract description 16
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 16
- 238000002156 mixing Methods 0.000 description 10
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 9
- 239000005056 polyisocyanate Substances 0.000 description 9
- 229920001228 polyisocyanate Polymers 0.000 description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000000654 additive Substances 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 7
- 239000003963 antioxidant agent Substances 0.000 description 7
- 238000005282 brightening Methods 0.000 description 7
- 239000002270 dispersing agent Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 238000009736 wetting Methods 0.000 description 7
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- 241000723346 Cinnamomum camphora Species 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 229960000846 camphor Drugs 0.000 description 6
- 229930008380 camphor Natural products 0.000 description 6
- 239000004359 castor oil Substances 0.000 description 6
- 235000019438 castor oil Nutrition 0.000 description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 150000002989 phenols Chemical class 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- 239000001327 prunus amygdalus amara l. extract Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
- 238000010422 painting Methods 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- GNCOVOVCHIHPHP-UHFFFAOYSA-N 2-[[4-[4-[(1-anilino-1,3-dioxobutan-2-yl)diazenyl]-3-chlorophenyl]-2-chlorophenyl]diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(C)=O)C(=O)NC1=CC=CC=C1 GNCOVOVCHIHPHP-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 241000772413 Lutrogale perspicillata Species 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 230000008033 biological extinction Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001055 blue pigment Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000013467 fragmentation Methods 0.000 description 2
- 238000006062 fragmentation reaction Methods 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000001052 yellow pigment Substances 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000009027 insemination Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004482 other powder Substances 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
样品编号 | 耐水煮性能 |
A | 25小时 |
B | 22小时 |
C | 20小时 |
D | 18小时 |
E | 20小时 |
F | 20小时 |
G | 6小时 |
H | 8小时 |
I | 3小时 |
J | 2小时 |
K | 8小时 |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310042733.7A CN103146292B (zh) | 2013-02-04 | 2013-02-04 | 一种耐水煮聚酯粉末涂料及其制备方法和应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310042733.7A CN103146292B (zh) | 2013-02-04 | 2013-02-04 | 一种耐水煮聚酯粉末涂料及其制备方法和应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103146292A CN103146292A (zh) | 2013-06-12 |
CN103146292B true CN103146292B (zh) | 2014-12-24 |
Family
ID=48544629
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310042733.7A Active CN103146292B (zh) | 2013-02-04 | 2013-02-04 | 一种耐水煮聚酯粉末涂料及其制备方法和应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103146292B (zh) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103694443B (zh) * | 2013-12-12 | 2016-03-02 | 苏州博纳化学科技有限公司 | 一种多元交联单体的合成方法 |
CN105273583B (zh) * | 2015-11-06 | 2018-05-11 | 广州擎天材料科技有限公司 | 一种铝材专用耐候性珠光粉末涂料及其制备方法 |
CN106497351A (zh) * | 2016-10-18 | 2017-03-15 | 浙江捷宇新材料科技股份有限公司 | 一种高耐水煮户外型粉末涂料及其制备方法 |
CN107383994B (zh) * | 2017-06-26 | 2020-08-04 | 天津翔盛新材料有限公司 | 一种用于提高粉末涂料耐水煮性的微囊化硫酸钡及其制备方法 |
CN109294415B (zh) * | 2018-10-26 | 2021-02-05 | 遵义春华新材料科技有限公司 | 一种室内用双组份粉末涂料及其制备方法 |
CN110396355A (zh) * | 2019-07-15 | 2019-11-01 | 江西睿智环保科技有限公司 | 超耐候3d木纹转印粉末涂料制备方法、涂料及用途 |
WO2021022389A1 (zh) * | 2019-08-02 | 2021-02-11 | 擎天材料科技有限公司 | 一种聚酯树脂组合物、粉末涂料及工件 |
CN112266711A (zh) * | 2020-10-20 | 2021-01-26 | 擎天材料科技有限公司 | 一种食品级粉末涂料及其制备方法 |
CN112708333A (zh) * | 2020-12-29 | 2021-04-27 | 老虎表面技术新材料(清远)有限公司 | 一种耐水煮粉末涂料组合物 |
CN114032012A (zh) * | 2021-12-20 | 2022-02-11 | 江南载福粉末涂料(张家港)有限公司 | 一种耐水煮粉末涂料及其制备方法和应用 |
CN115109500B (zh) * | 2022-07-19 | 2023-03-07 | 南通美怡彩新材料科技有限公司 | 一种用于建筑铝型材的耐候性粉末涂料 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5334631A (en) * | 1991-07-22 | 1994-08-02 | Akzo N.V. | Powder coating composition containing a resin, a curing agent and zinc |
CN101445591A (zh) * | 2008-12-26 | 2009-06-03 | 广州擎天实业有限公司 | 环保型干混低光粉末涂料用高低酸值聚酯树脂及其制备方法 |
-
2013
- 2013-02-04 CN CN201310042733.7A patent/CN103146292B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5334631A (en) * | 1991-07-22 | 1994-08-02 | Akzo N.V. | Powder coating composition containing a resin, a curing agent and zinc |
CN101445591A (zh) * | 2008-12-26 | 2009-06-03 | 广州擎天实业有限公司 | 环保型干混低光粉末涂料用高低酸值聚酯树脂及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN103146292A (zh) | 2013-06-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103146292B (zh) | 一种耐水煮聚酯粉末涂料及其制备方法和应用 | |
CN101985538A (zh) | 一种环保型低温固化纯聚酯粉末涂料及其制备方法 | |
CN101885943B (zh) | 纳米玻璃隔热涂料及其制备方法 | |
CN108165151B (zh) | 一种水性氟碳改性丙烯酸聚氨酯面漆及其制备方法 | |
CN103897571A (zh) | 一种水性双组份木器清漆及其用途 | |
CN101747826A (zh) | 一种低温固化环氧低光粉末涂料及其制备方法 | |
CN108409948B (zh) | 一种haa体系用低温固化聚酯树脂及其制备方法与应用 | |
CN109207030B (zh) | 一种高光泽粉末涂料用聚酯树脂及其制备方法与应用 | |
CN101659825A (zh) | 双组分水性纳米抗划伤木器涂料及其生产方法 | |
CN102676017A (zh) | 一种木器漆及其制备方法 | |
CN103131294A (zh) | 一种隔热超耐候粉末涂料及其制备方法和应用 | |
CN103468099A (zh) | 一种水性隔热保温防静电涂料及其制备方法 | |
CN103122205A (zh) | 低温固化超耐候性粉末涂料 | |
CN105969122A (zh) | 一种聚酯粉末家具涂料及其制备方法 | |
CN104387939A (zh) | 一种用于机车的可耐强酸碱的聚氨酯面漆及其制备方法 | |
CN103483942A (zh) | 一种具有纹理效果的氟碳粉末涂料及其制备方法 | |
CN108977061A (zh) | 一种耐候性高温粉末涂料及其生产工艺 | |
CN103205182A (zh) | 家用电器用耐候环保型粉末涂料 | |
CN109082184A (zh) | 一种高附着力的弹性乳胶漆 | |
CN101120062B (zh) | 适用于粉末涂料组合物的包含至少一种树脂和至少一种分散剂的组合物 | |
CN102070974A (zh) | 一种增强抗交叉污染能力的粉末涂料及其制备方法 | |
CN103122206A (zh) | 一种环保型超耐候粉末涂料组合物及制备方法 | |
CN102051114B (zh) | 橡胶底材底涂及其制备方法 | |
CN105670437A (zh) | 一种耐候涂料及其制备方法 | |
CN103571313A (zh) | 一种羟烷基酰胺型高流平粉末涂料、该涂料用的聚酯树脂及制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Boil-resistant polyester powder coating, and preparation method and application thereof Effective date of registration: 20171201 Granted publication date: 20141224 Pledgee: Bank of China, Limited by Share Ltd Fenghua branch Pledgor: Ningbo South-Sea Chemical Co., Ltd. Registration number: 2017330000223 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20191108 Granted publication date: 20141224 Pledgee: Bank of China, Limited by Share Ltd Fenghua branch Pledgor: Ningbo South-Sea Chemical Co., Ltd. Registration number: 2017330000223 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Boil-resistant polyester powder coating, and preparation method and application thereof Effective date of registration: 20191112 Granted publication date: 20141224 Pledgee: Bank of China, Limited by Share Ltd Fenghua branch Pledgor: Ningbo South-Sea Chemical Co., Ltd. Registration number: Y2019330000184 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20201027 Granted publication date: 20141224 Pledgee: Bank of China Limited by Share Ltd. Fenghua branch Pledgor: NINGBO SOUTH SEA CHEMICAL Co.,Ltd. Registration number: Y2019330000184 |