CN103131299A - Powder coating with nanometer titania - Google Patents
Powder coating with nanometer titania Download PDFInfo
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- CN103131299A CN103131299A CN2013100406415A CN201310040641A CN103131299A CN 103131299 A CN103131299 A CN 103131299A CN 2013100406415 A CN2013100406415 A CN 2013100406415A CN 201310040641 A CN201310040641 A CN 201310040641A CN 103131299 A CN103131299 A CN 103131299A
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- powder coating
- titanium oxide
- nano titanium
- powder
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000000843 powder Substances 0.000 title claims abstract description 30
- 239000011248 coating agent Substances 0.000 title claims abstract description 24
- 238000000576 coating method Methods 0.000 title claims abstract description 24
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 4
- 239000003822 epoxy resin Substances 0.000 claims abstract description 4
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 4
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 4
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 239000012764 mineral filler Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000002518 antifoaming agent Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 4
- 235000019738 Limestone Nutrition 0.000 claims description 3
- 239000004113 Sepiolite Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 239000001361 adipic acid Substances 0.000 claims description 3
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- -1 adipic acid ester Chemical class 0.000 claims description 3
- 229910001570 bauxite Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims description 3
- 238000013467 fragmentation Methods 0.000 claims description 3
- 238000006062 fragmentation reaction Methods 0.000 claims description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 3
- 230000036571 hydration Effects 0.000 claims description 3
- 238000006703 hydration reaction Methods 0.000 claims description 3
- 239000006028 limestone Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 229910052624 sepiolite Inorganic materials 0.000 claims description 3
- 235000019355 sepiolite Nutrition 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 abstract 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 abstract 1
- 229930185605 Bisphenol Natural products 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 244000028419 Styrax benzoin Species 0.000 abstract 1
- 235000000126 Styrax benzoin Nutrition 0.000 abstract 1
- 235000008411 Sumatra benzointree Nutrition 0.000 abstract 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 abstract 1
- 229960002130 benzoin Drugs 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 abstract 1
- 235000019382 gum benzoic Nutrition 0.000 abstract 1
- 239000011256 inorganic filler Substances 0.000 abstract 1
- 229910003475 inorganic filler Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229920001225 polyester resin Polymers 0.000 abstract 1
- 239000004645 polyester resin Substances 0.000 abstract 1
- 230000000979 retarding effect Effects 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- XUIMIQQOPSSXEZ-NJFSPNSNSA-N silicon-30 atom Chemical compound [30Si] XUIMIQQOPSSXEZ-NJFSPNSNSA-N 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses powder coating with nanometer titania. The powder coating with the nanometer titania is prepared from the following materials, by weight, 90-95 parts of bisphenols A type epoxy resin, 20-30 parts of polyester resin, 1-2 parts of aliphatic diisocyanate, 100-110 parts of inorganic filler, 3-5 parts of nanometer titania, 0.5-1.3 parts of sodium hexametaphosphate, 1-2 parts of organic silicon defoamer, 0.5-1.5 parts of benzoin, 1-2 parts of silane coupling agent KH570, 0.3-0.5 part of hydrated zinc borate, 30-50 parts of titanium dioxide and 1-2 parts of adipate. The powder coating with the nanometer titania is environment-friendly, high in mechanical strength, convenient to use, poison-free, harmless, inflaming retarding, and strong in weather resistance.
Description
Technical field
The present invention relates to paint field, is exactly a kind of powder coating that contains nano titanium oxide.
Background technology
Powder coating is a kind of novel solvent 100% solid powdery coating that do not contain.Have solvent-free, pollution-free, recyclable, environmental protection, the saving energy and resource, the physical strength high reduces labor intensity and films.Powder coating is and the diverse form of general coating, and it is that state with fines exists.Owing to not using solvent, so be called powder coating.The principal feature of powder coating has: the characteristics with nuisanceless, high-level efficiency, saving resource.
Summary of the invention
The object of the present invention is to provide a kind of powder coating that contains nano titanium oxide.
Above-mentioned purpose realizes by following scheme:
A kind of powder coating that contains nano titanium oxide is characterized in that, is that the raw material by following weight parts makes: bisphenol A type epoxy resin 90-95, vibrin 20-30, aliphatic diisocyanate 1-2, mineral filler 100-110, nano titanium oxide 3-5, Sodium hexametaphosphate 99 0.5-1.3, silicone antifoam agent 1-2, st-yrax 0.5-1.5, silane coupling agent KH570 1-2, hydration zinc borate 0.3-0.5, titanium dioxide 30-50, adipic acid ester 1-2.
Described a kind of powder coating that contains nano titanium oxide, it is characterized in that: described mineral filler is comprised of the raw material of following weight parts: nano silicon 20-30, nanometer sepiolite powder 10-12, red bauxite 50-52, limestone powder 40-50, modified Nano diatomite 10-15;
The diatomaceous preparation method of described modified Nano is: diatomite was calcined 4-6 hour under 700-800 ℃, cooling after, fragmentation, cross the 100-200 mesh sieve, then soak in the acetic acid solution of 8-10% after 5-7 hour, take out, deionized water wash is to neutral, add the dioctyl sebacate that is equivalent to diatomite weight 1-2%, the tetraethoxy of 1-2%, after mixing, oven dry, grind to form nanometer powder, and get final product.
Described a kind of powder coating that contains nano titanium oxide is characterized in that:
The preparation method comprises the following steps:
(1), by described each raw material of weight part accurate weighing, mix 3-4 minute under 500-600 rev/min, mix 8-10 minute under 2800-3000 rev/min, mix 1-2 minute afterwards under 400-500 rev/min, stop stirring, get mixture;
(2), mixture is extruded at the temperature of 100-115 ℃ with forcing machine, get extruded stock;
(3), extruded stock is crossed the 100-200 mesh sieve after pulverizing, and be get final product.
Described a kind of powder coating that contains nano titanium oxide is characterized in that:
Described silicone antifoam agent solid content is 22%.Described vibrin is the oh type polyester, acid number 30-40mk KOH/g, viscosity 5000-7000mPa.S, solidification value 180-200 ℃.
Beneficial effect of the present invention is: environmental protection of the present invention, and physical strength is high; Both easy to use, nontoxic fire-retardant again, weathering resistance is strong.
Embodiment
A kind of powder coating that contains nano titanium oxide is that the raw material by following weight parts (kg) makes: bisphenol A type epoxy resin 95, vibrin 23, aliphatic diisocyanate 2, mineral filler 110, nano titanium oxide 4, Sodium hexametaphosphate 99 1.3, solid content is 22% silicone antifoam agent 2, st-yrax 1.5, silane coupling agent KH570 2, hydration zinc borate 0.5, titanium dioxide 30, adipic acid ester 2.
Described mineral filler is comprised of the raw material of following weight parts (kg): nano silicon 30, nanometer sepiolite powder 12, red bauxite 52, limestone powder 50, modified Nano diatomite 15;
The diatomaceous preparation method of described modified Nano is: diatomite was calcined 6 hours under 800 ℃, cooling after, fragmentation, cross 200 mesh sieves, then soak in 10% acetic acid solution after 7 hours, take out, deionized water wash is to neutral, add the dioctyl sebacate that is equivalent to diatomite weight 1.3%, 2% tetraethoxy, after mixing, oven dry, grind to form nanometer powder, and get final product.
Described a kind of powder coating that contains nano titanium oxide,
The preparation method comprises the following steps:
(1), by described each raw material of weight part accurate weighing, mix 4 minutes under 600 rev/mins, mix 10 minutes under 3000 rev/mins, mix 2 minutes afterwards under 500 rev/mins, stop stirring, get mixture;
(2), mixture is extruded at the temperature of 100 ℃ with forcing machine, get extruded stock;
(3), extruded stock is crossed 100 mesh sieves after pulverizing, and be get final product.
Described vibrin is the oh type polyester, acid number 30-40mk KOH/g, viscosity 5000-7000mPa.S, solidification value 180-200 ℃.
Adopt high pressure electrostatic painting on foundry goods the present embodiment gained coating, voltage is 60KV, and average film thickness is the 65-75 micron, and condition of cure is 180 ℃ of bakings 20 minutes;
Performance index are as follows:
According to GB/T1732 test, shock resistance 〉=50kg.cm;
According to GB/T6739 test, pencil hardness 〉=H level;
480h QUV-B accelerated light ageing experimental test gets, and protects the light rate and reaches 91%.
The gained coatingsurface is smooth, without bubble, and particle, shrinkage cavity, pin hole.
Claims (4)
1. a powder coating that contains nano titanium oxide, is characterized in that, is that the raw material by following weight parts makes: bisphenol A type epoxy resin 90-95, vibrin 20-30, aliphatic diisocyanate 1-2, mineral filler 100-110, nano titanium oxide 3-5, Sodium hexametaphosphate 99 0.5-1.3, silicone antifoam agent 1-2, st-yrax 0.5-1.5, silane coupling agent KH570 1-2, hydration zinc borate 0.3-0.5, titanium dioxide 30-50, adipic acid ester 1-2.
2. a kind of powder coating that contains nano titanium oxide according to claim 1, it is characterized in that: described mineral filler is comprised of the raw material of following weight parts: nano silicon 20-30, nanometer sepiolite powder 10-12, red bauxite 50-52, limestone powder 40-50, modified Nano diatomite 10-15;
The diatomaceous preparation method of described modified Nano is: diatomite was calcined 4-6 hour under 700-800 ℃, cooling after, fragmentation, cross the 100-200 mesh sieve, then soak in the acetic acid solution of 8-10% after 5-7 hour, take out, deionized water wash is to neutral, add the dioctyl sebacate that is equivalent to diatomite weight 1-2%, the tetraethoxy of 1-2%, after mixing, oven dry, grind to form nanometer powder, and get final product.
3. a kind of powder coating that contains nano titanium oxide according to claim 1 is characterized in that:
The preparation method comprises the following steps:
(1), by described each raw material of weight part accurate weighing, mix 3-4 minute under 500-600 rev/min, mix 8-10 minute under 2800-3000 rev/min, mix 1-2 minute afterwards under 400-500 rev/min, stop stirring, get mixture;
(2), mixture is extruded at the temperature of 100-115 ℃ with forcing machine, get extruded stock;
(3), extruded stock is crossed the 100-200 mesh sieve after pulverizing, and be get final product.
4. a kind of powder coating that contains nano titanium oxide according to claim 1 is characterized in that:
Described silicone antifoam agent solid content is 22%, and described vibrin is the oh type polyester, acid number 30-40mk KOH/g, viscosity 5000-7000mPa.S, solidification value 180-200 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310040641.5A CN103131299B (en) | 2013-02-03 | 2013-02-03 | A kind of powder coating containing nano titanium oxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310040641.5A CN103131299B (en) | 2013-02-03 | 2013-02-03 | A kind of powder coating containing nano titanium oxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103131299A true CN103131299A (en) | 2013-06-05 |
| CN103131299B CN103131299B (en) | 2016-03-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310040641.5A Expired - Fee Related CN103131299B (en) | 2013-02-03 | 2013-02-03 | A kind of powder coating containing nano titanium oxide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103131299B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103319991A (en) * | 2013-06-18 | 2013-09-25 | 江苏华光粉末有限公司 | Nanometer powder coating and preparation method thereof |
| CN103483952A (en) * | 2013-09-03 | 2014-01-01 | 安徽精一机械设备有限公司 | Acrylic transparent powder paint |
| CN103497654A (en) * | 2013-09-24 | 2014-01-08 | 安徽锐视光电技术有限公司 | Low-temperature curing powder coating |
| CN103509446A (en) * | 2013-09-03 | 2014-01-15 | 安徽精一机械设备有限公司 | Nanometer polyester powder paint |
| CN105274840A (en) * | 2014-06-26 | 2016-01-27 | 香港理工大学 | Flame retardation finishing agent, fabric flame retardation finishing method and flame retardation fabric |
| CN107141844A (en) * | 2017-06-07 | 2017-09-08 | 合肥汇之新机械科技有限公司 | A kind of coating material and its production technology for high-temperature drier |
| CN108213872A (en) * | 2016-08-11 | 2018-06-29 | 海宁金茂五金有限公司 | The preparation method of the high intensity punching press sliding rail of improvement |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5378236A (en) * | 1976-12-22 | 1978-07-11 | Nippon Paint Co Ltd | Glittering powder coating composition |
| US5925698A (en) * | 1997-03-14 | 1999-07-20 | The Lubrizol Corporation | Powder coating composition and method for coating a substrate using said powder coating composition |
| CN101012350A (en) * | 2006-11-07 | 2007-08-08 | 苏州裕丰装饰门窗有限公司 | Special-purpose energy-saving environment-friendly type nano coating for aluminum alloy sections (door and window) and preparing method thereof |
| CN102277061A (en) * | 2011-06-30 | 2011-12-14 | 上海工程技术大学 | Powder coating containing nanowhisker materials and preparation method thereof |
| CN102766471A (en) * | 2012-03-29 | 2012-11-07 | 广东省宜华木业股份有限公司 | Preparation method of mesoporous silica nanometer composite flame retardant |
-
2013
- 2013-02-03 CN CN201310040641.5A patent/CN103131299B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5378236A (en) * | 1976-12-22 | 1978-07-11 | Nippon Paint Co Ltd | Glittering powder coating composition |
| US5925698A (en) * | 1997-03-14 | 1999-07-20 | The Lubrizol Corporation | Powder coating composition and method for coating a substrate using said powder coating composition |
| CN101012350A (en) * | 2006-11-07 | 2007-08-08 | 苏州裕丰装饰门窗有限公司 | Special-purpose energy-saving environment-friendly type nano coating for aluminum alloy sections (door and window) and preparing method thereof |
| CN102277061A (en) * | 2011-06-30 | 2011-12-14 | 上海工程技术大学 | Powder coating containing nanowhisker materials and preparation method thereof |
| CN102766471A (en) * | 2012-03-29 | 2012-11-07 | 广东省宜华木业股份有限公司 | Preparation method of mesoporous silica nanometer composite flame retardant |
Non-Patent Citations (2)
| Title |
|---|
| 于永忠等: "《阻燃材料手册》", 30 June 1991, 群众出版社 * |
| 郭彬等: "纳米TiO2对聚酯环氧粉末涂料性能的影响", 《涂料工业》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103319991A (en) * | 2013-06-18 | 2013-09-25 | 江苏华光粉末有限公司 | Nanometer powder coating and preparation method thereof |
| CN103483952A (en) * | 2013-09-03 | 2014-01-01 | 安徽精一机械设备有限公司 | Acrylic transparent powder paint |
| CN103509446A (en) * | 2013-09-03 | 2014-01-15 | 安徽精一机械设备有限公司 | Nanometer polyester powder paint |
| CN103483952B (en) * | 2013-09-03 | 2016-06-22 | 安徽精一机械设备有限公司 | A kind of Acrylic transparent powder paint |
| CN103497654A (en) * | 2013-09-24 | 2014-01-08 | 安徽锐视光电技术有限公司 | Low-temperature curing powder coating |
| CN105274840A (en) * | 2014-06-26 | 2016-01-27 | 香港理工大学 | Flame retardation finishing agent, fabric flame retardation finishing method and flame retardation fabric |
| CN108213872A (en) * | 2016-08-11 | 2018-06-29 | 海宁金茂五金有限公司 | The preparation method of the high intensity punching press sliding rail of improvement |
| CN107141844A (en) * | 2017-06-07 | 2017-09-08 | 合肥汇之新机械科技有限公司 | A kind of coating material and its production technology for high-temperature drier |
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| Publication number | Publication date |
|---|---|
| CN103131299B (en) | 2016-03-02 |
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Inventor after: Lin Wendong Inventor after: Pan Yanhua Inventor after: Lin Fasheng Inventor before: Ni Jinpei |
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| TR01 | Transfer of patent right |
Effective date of registration: 20170112 Address after: Minhou County of Fuzhou City, Fujian province 350000 Street Town Sand Village Limin No. 17 Patentee after: Fujian Cologne Mstar Technology Ltd Address before: The new town of Anhui province Wuhu City fan 241200 Fanchang County Economic Development Office Patentee before: Ni Jinpei |
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Granted publication date: 20160302 Termination date: 20180203 |
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