CN103130568A - Thiamethoxam insecticide-fertilizer mixture and preparing method thereof - Google Patents
Thiamethoxam insecticide-fertilizer mixture and preparing method thereof Download PDFInfo
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- CN103130568A CN103130568A CN2013100291036A CN201310029103A CN103130568A CN 103130568 A CN103130568 A CN 103130568A CN 2013100291036 A CN2013100291036 A CN 2013100291036A CN 201310029103 A CN201310029103 A CN 201310029103A CN 103130568 A CN103130568 A CN 103130568A
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Abstract
The invention discloses a thiamethoxam insecticide-fertilizer mixture and a preparing method thereof. The active ingredient of the thiamethoxam insecticide-fertilizer mixture is thiamethoxam. The thiamethoxam insecticide-fertilizer mixture comprises, by weight, 0.01%-1% of thiamethoxam, 10%-60% of fertilizer, 0.1%-2% of sustained release preparation, 0.1%-10% of binder, 0.1%-0.5% of film agents, and the balance fillers. The materials are evenly mixed in proportion, granulated with the enveloping method, dried and sieved to produce the thiamethoxam insecticide-fertilizer mixture. The thiamethoxam insecticide-fertilizer mixture is capable of preventing pests and fertilizing at the same time in agricultural production and overcomes the defect that a user needs to use insecticide and the fertilizer independently and repeatedly in the prior art.
Description
Technical field
The present invention relates to a kind of Diacloden medicament-fertilizer mixture and preparation method thereof.
Background technology
Diacloden, chemical formula:
Chemical name: 3-(2-chloro-1,3-thiazoles-5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazine-4-base fork (nitro) amine, English name: thiamethoxam.Diacloden is a kind of novel high-efficiency low-toxicity broad spectrum pesticide.Be s-generation anabasine insecticide, the mechanism of action is similar to first-generation anabasine insecticides such as Provados, but has higher activity.To insect have stomach toxicity, tag, systemic action, the characteristics such as speed of action is fast, the lasting period is long.Better to preventive effects such as sucking pest such as aphid, plant hopper, leafhopper, aleyrodids.
But existing Diacloden formulation has water dispersible granules, microcapsule suspending agent, suspension seed-coating agent, seed treatment dispersion powder, be and be watered spraying and the Agricultural pests such as seed treatment prevents eliminating aphis, planthopper, thrips, scale insect, Diacloden and Fertilizer application separate.
The inventor is to the Diacloden formulation and use further investigation, with itself and Fertilizer combination, is developed to the Diacloden medicament-fertilizer mixture.The Diacloden medicament-fertilizer mixture is used for control farm crop sucking pest, completes simultaneously desinsection and the two procedures of topdressing, and the situation of having avoided dispenser in the past and having topdressed and can not take into account is saved time and manually, improved production efficiency.
The fertile preparation method of application for a patent for invention number 201010239865.5 disclosed medicine fertilizer and application thereof, particle formulation medicine fertilizer and powder-type medicine, to be used for control subterranean pest-insect or nematode by Avrmectin, Provado/acetamiprid/Diacloden and Fertilizer Combination, with the present invention's same technology of symbolic animal of the birth year not.
Summary of the invention
Technical problem to be solved: the present invention is directed to the prior art deficiency provides Diacloden to be combined with fertilizer science and the Diacloden medicament-fertilizer mixture developed, applied once both can be prevented and treated Agricultural pests in agriculture production, can topdress again, overcome that user under the prior art condition wants twice or the way of use of insecticide and fertilizer repeatedly.
The present invention also provides the preparation method of above-mentioned Diacloden medicament-fertilizer mixture.
Technical scheme: Diacloden medicament-fertilizer mixture of the present invention is by Diacloden, fertilizer, sustained release dosage, binding agent, coating agent, media assemblage.
In the medicament-fertilizer mixture gross weight, wherein: Diacloden 0.01%～1%, fertilizer 10%～60%, sustained release dosage 0.1%～2%, binding agent 0.1%～10%, coating agent 0.1～0.5%, all the other are filler.
Described fertilizer is the one or more combination in ammonium chloride, ammonium sulfate, urea, Repone K, vitriolate of tartar, monoammonium phosphate etc., its N element nutrient content is 5%～30% of Diacloden medicament-fertilizer mixture gross weight, the P constituent content is 0～20% of Diacloden medicament-fertilizer mixture gross weight, the K constituent content is 0～20% of Diacloden medicament-fertilizer mixture gross weight, and micronutrient levels is 0.01～5% of Diacloden medicament-fertilizer mixture gross weight.
Described trace element is one or more the combination in the trace elements such as zinc, boron, calcium, magnesium, manganese, copper, molybdenum.
Described sustained release dosage is one or more the combination in polyvinyl alcohol or gum arabic etc.
Described binding agent is one or more the combination in attapulgite, paraffin, rosin, pasted starch, xanthan gum, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose gum etc.
Described coating agent is one or more the combination in polyvinyl alcohol, polyvinylpyrrolidone, vibrin, vinylformic acid synthetic polymer, acrylic resin membrane-forming agent, butadiene resin membrane-forming agent, polyurethane finishing agent, cellulose nitrate membrane-forming agent etc.
Described filler is one or more the combination in kaolin, diatomite, white carbon black, starch, stone flour, quartz sand, brick slag etc.
The preparation method of Diacloden medicament-fertilizer mixture of the present invention: after 0.01%～1% former medicine of Diacloden, 10%～60% fertilizer, 0.1%～2% sustained release dosage, 0.1%～10% binding agent, 0.1%～0.5% coating agent, appropriate filler are mixed in airtight stirred pot, add and carry out the granulation of coating method in granulating equipment, be dried to the particle water content less than 3% under 80 ℃～100 ℃ conditions, screening, size range 2000um～4000um, through after the assay was approved, namely obtain required Diacloden fertilizer granules; The powder sieving thing is back to stirred pot after crushed to be mixed again; Unacceptable product is back to stirred pot after the check analysis reason mixes again, mix and adopt the method for fractional steps, the starting material that component concentration is lower first mix the fertilizer of certain mass or filler again with other mixing of materials, to guarantee the homogeneity of product content, drying temperature is at 80 ℃～100 ℃, strict variation and the fluctuation of controlling temperature is in order to avoid decomposition and the loss of agricultural chemicals, fertilizer composition.
Compared with prior art, the present invention has following unusual effect.
Diacloden medicament-fertilizer mixture of the present invention, the Diacloden medicament-fertilizer mixture that combination of sciences exploitation by insecticidal active ingredient Diacloden and fertilizer forms, the dual function that applied once can reach desinsection and topdress, peasant's labour intensity and work number of times have been alleviated, save time and manually, improved production efficiency.
The present invention adopts the modern mechanical complete processing, and effective constituent is evenly distributed in product, and the preparation method easily operates.Product directly spreads fertilizer over the fields and can be distributed in uniformly the field, is conducive to absorbing of effective constituent, has overcome existing operation technique and has been watered spraying and causes drift contaminate environment phenomenon.
Adopt slow release method, effectively guarantee the slow release of agricultural chemicals, fertilizer, extend the lasting period of product, improve drug effect and agricultural chemicals utilization ratio, reduce the waste of agricultural chemicals, fertilizer, guarantee pest control, double effects topdresses.
The medicament-fertilizer mixture product has been saved auxiliary agent cost and circulation cost in a cover packing material and agricultural chemicals with respect to twice use of agricultural chemicals and fertilizer.
Diacloden medicament-fertilizer mixture of the present invention is used for control Agricultural pests, especially sucking pest prevention effect preferably.
Safety, low toxicity, low risk are used conveniently in Diacloden medicament-fertilizer mixture formulation of the present invention environmental protection.
Description of drawings
Fig. 1 is production technological process of the present invention.
Embodiment
Embodiment one: Diacloden medicament-fertilizer mixture of the present invention is by Diacloden, fertilizer, and sustained release dosage, binding agent, the coating agent, filler material forms.In the medicament-fertilizer mixture gross weight, wherein: Diacloden 0.01%～1%, fertilizer 10%～60%, sustained release dosage 0.1%～2%, binding agent 0.1%～10%, coating agent 0.1～0.5%, all the other are filler.
As shown in Figure 1, according to Diacloden medicament-fertilizer mixture preparation method of the present invention, after 0.01%～1% former medicine of Diacloden, 10%～60% fertilizer, 0.1%～2% sustained release dosage, 0.1%～10% binding agent, 0.1%～0.5% coating agent, appropriate filler are mixed in airtight stirred pot, add and carry out the granulation of coating method in granulating equipment, be dried to the particle water content less than 3% under 80 ℃～100 ℃ conditions, screening (size range 2000um～4000um), through after the assay was approved, namely obtain required Diacloden medicament-fertilizer mixture.The powder sieving thing is back to stirred pot after crushed to be mixed again.Unacceptable product is back to stirred pot after the check analysis reason mixes again.Mix and adopt the method for fractional steps, the starting material that component concentration is lower first mix the fertilizer of certain mass or filler again with other mixing of materials, to guarantee the homogeneity of product content, drying temperature is at 80 ℃～100 ℃, strict variation and the fluctuation of controlling temperature is in order to avoid decomposition and the loss of agricultural chemicals, fertilizer composition.
Can be made into the different Diacloden medicament-fertilizer mixture of active constituent content, gross weight by medicament-fertilizer mixture, activeconstituents Diacloden 0.01%～1%, fertilizer component macroelement N element nutrient 5%～30%, P element nutrient 0%～20%, K element nutrient 0%～20%, trace element sum total 0.01～5%.
Diacloden medicament-fertilizer mixture production technique of the present invention is ripe, can produce according to product standard up-to-standard, the Diacloden medicament-fertilizer mixture of effect stability.Be the checking constant product quality, we have carried out the heat storage stability test of product: stored 14 days the rate of decomposition of mensuration effective constituent, moisture, pH value etc. under 54 ℃ ± 2 ℃ conditions.Test-results table 1 shows, constant product quality is good, the requirement of indices conformance with standard.
Table 1,0.04% Diacloden medicament-fertilizer mixture heat storage stability test-results.
Embodiment two: in order better to verify practical application effect of the present invention, the below illustrates that with the field efficacy example Diacloden medicament-fertilizer mixture of the present invention is used for control tomato white powder reagent effect test effect.
Test site is positioned at Lao Keng village, Ren Shan town, Huizhou Huidong County, test period is in April, 2012,0.04% Diacloden medicament-fertilizer mixture spreads fertilizer over the fields before the tomato field planting, be watered the filling root before reference product 25% Diacloden water dispersible granules field planting, 4 chemicals treatment are established in test altogether, and each is processed 4 times and repeats, and after dispenser, each investigation in 10 days, 20 days once, calculate prevention effect, test-results is as shown in table 2.
As can be seen from Table 2, after 0.04% 36～56 g/has of Diacloden medicament-fertilizer mixture effective ingredient consumptions control tomato trialeurodes vaporariorum medicine, the 20d preventive effect is 80.12%～88.36%, effectively prevents and treats trialeurodes vaporariorum and causes harm.Identical effective ingredient consumption 0.04% Diacloden medicament-fertilizer mixture control tomato trialeurodes vaporariorum effect is better than 25% Diacloden water dispersible granules.
Table 2,0.04% Diacloden medicament-fertilizer mixture control tomato trialeurodes vaporariorum test-results.
Claims (8)
1. Diacloden medicament-fertilizer mixture, it is characterized in that: activeconstituents is Diacloden, in the fertile gross weight of medicine, wherein: Diacloden 0.01%～1%, fertilizer 10%～60%, sustained release dosage 0.1%～2%, binding agent 0.1%～10%, coating agent 0.1～0.5%, all the other are filler.
2. Diacloden medicament-fertilizer mixture according to claim 1, it is characterized in that: described fertilizer is the one or more combination in ammonium chloride, ammonium sulfate, urea, Repone K, vitriolate of tartar, monoammonium phosphate etc., its N element nutrient content is 5%～30% of Diacloden medicament-fertilizer mixture gross weight, the P constituent content is 0～20% of Diacloden medicament-fertilizer mixture gross weight, the K constituent content is 0～20% of Diacloden medicament-fertilizer mixture gross weight, and micronutrient levels is 0.01～5% of Diacloden medicament-fertilizer mixture gross weight.
3. Diacloden medicament-fertilizer mixture according to claim 2 is characterized in that: described trace element is one or more the combination in the trace elements such as zinc, boron, calcium, magnesium, manganese, copper, molybdenum.
4. a kind of Diacloden medicament-fertilizer mixture according to claim 1 is characterized in that: described sustained release dosage is one or more the combination in polyvinyl alcohol or gum arabic etc.
5. Diacloden medicament-fertilizer mixture according to claim 1 is characterized in that: described binding agent is one or more the combination in attapulgite, paraffin, rosin, pasted starch, xanthan gum, carboxymethyl cellulose, carboxyethyl cellulose, methylcellulose gum etc.
6. Diacloden medicament-fertilizer mixture according to claim 1 is characterized in that: described coating agent is one or more the combination in polyvinyl alcohol, polyvinylpyrrolidone, vibrin, vinylformic acid synthetic polymer, acrylic resin membrane-forming agent, butadiene resin membrane-forming agent, polyurethane finishing agent, cellulose nitrate membrane-forming agent etc.
7. Diacloden medicament-fertilizer mixture according to claim 1 is characterized in that: described filler is one or more the combination in kaolin, diatomite, white carbon black, starch, stone flour, quartz sand, brick slag etc.
8. the preparation method of a kind of Diacloden medicament-fertilizer mixture according to claim 1, it is characterized in that: after 0.01%～1% former medicine of Diacloden, 10%～60% fertilizer, 0.1%～2% sustained release dosage, 0.1%～10% binding agent, 0.1%～0.5% coating agent, appropriate filler are mixed in airtight stirred pot, add and carry out the granulation of coating method in granulating equipment, be dried to the particle water content less than 3% under 80 ℃～100 ℃ conditions, screening, size range 2000um～4000um, through after the assay was approved, namely obtain required Diacloden fertilizer granules; The powder sieving thing is back to stirred pot after crushed to be mixed again; Unacceptable product is back to stirred pot after the check analysis reason mixes again, mix and adopt the method for fractional steps, the starting material that component concentration is lower first mix the fertilizer of certain mass or filler again with other mixing of materials, to guarantee the homogeneity of product content, drying temperature is at 80 ℃～100 ℃, strict variation and the fluctuation of controlling temperature is in order to avoid decomposition and the loss of agricultural chemicals, fertilizer composition.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103360162A (en) * | 2013-07-17 | 2013-10-23 | 广州甘蔗糖业研究所湛江甘蔗研究中心 | Sugarcane sustained-release granular medicinal fertilizer |
| CN104151088A (en) * | 2014-09-02 | 2014-11-19 | 联保作物科技有限公司 | Pesticide fertilizer slow release preparation, as well as preparation method and application method thereof |
| CN104163726A (en) * | 2014-09-02 | 2014-11-26 | 联保作物科技有限公司 | Pesticide fertilizer slow-release preparation, and preparation method and application method thereof |
| CN104447096A (en) * | 2014-12-15 | 2015-03-25 | 广西乐土生物科技有限公司 | Compound fertilizer for controlling fast-growing eucalypt pest inchworms and production method of compound fertilizer |
| CN104609988A (en) * | 2014-04-29 | 2015-05-13 | 河南远见农业科技有限公司 | Paddy rice insecticide-fertilizer mixed formulation containing thiamethoxam.cartap and production method thereof |
| CN104839195A (en) * | 2015-05-08 | 2015-08-19 | 青岛海纳生物科技有限公司 | Pesticide sustained release granule containing thiamethoxam and preparation method thereof |
| CN105347959A (en) * | 2015-12-06 | 2016-02-24 | 张友兰 | Plant pesticide fertilizer granule |
| CN105439758A (en) * | 2014-08-21 | 2016-03-30 | 天津市汇源化学品有限公司 | Novel slow-release granules containing thiamethoxam and preparation method thereof |
| CN106045661A (en) * | 2016-05-25 | 2016-10-26 | 广西金穗农药有限公司 | Pesticide-fertilizer granules comprising thiamethoxam |
| CN107258808A (en) * | 2017-07-06 | 2017-10-20 | 王章修 | A kind of fertilizer granules and its application containing Diacloden and cyfloxylate |
| CN107821403A (en) * | 2017-11-23 | 2018-03-23 | 陕西嘉益蓝德生物工程有限公司 | A kind of sterilization and disinsection fertilizer granules |
| CN112521213A (en) * | 2020-12-04 | 2021-03-19 | 广西联和裕隆药肥有限公司 | Pesticide fertilizer for delaying pesticide release |
| CN112707761A (en) * | 2021-01-12 | 2021-04-27 | 广西联和裕隆药肥有限公司 | Drought-resistant soil moisture conservation pesticide fertilizer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103360162A (en) * | 2013-07-17 | 2013-10-23 | 广州甘蔗糖业研究所湛江甘蔗研究中心 | Sugarcane sustained-release granular medicinal fertilizer |
| CN103360162B (en) * | 2013-07-17 | 2015-08-19 | 广州甘蔗糖业研究所湛江甘蔗研究中心 | A kind of Sugarcane sustained-release granular medicinal fertilizer |
| CN104609988A (en) * | 2014-04-29 | 2015-05-13 | 河南远见农业科技有限公司 | Paddy rice insecticide-fertilizer mixed formulation containing thiamethoxam.cartap and production method thereof |
| CN105439758A (en) * | 2014-08-21 | 2016-03-30 | 天津市汇源化学品有限公司 | Novel slow-release granules containing thiamethoxam and preparation method thereof |
| CN104163726A (en) * | 2014-09-02 | 2014-11-26 | 联保作物科技有限公司 | Pesticide fertilizer slow-release preparation, and preparation method and application method thereof |
| CN104151088A (en) * | 2014-09-02 | 2014-11-19 | 联保作物科技有限公司 | Pesticide fertilizer slow release preparation, as well as preparation method and application method thereof |
| CN104151088B (en) * | 2014-09-02 | 2016-12-07 | 联保作物科技有限公司 | A kind of medicine fertilizer slow-release preparation, its preparation method and application process |
| CN104447096A (en) * | 2014-12-15 | 2015-03-25 | 广西乐土生物科技有限公司 | Compound fertilizer for controlling fast-growing eucalypt pest inchworms and production method of compound fertilizer |
| CN104839195A (en) * | 2015-05-08 | 2015-08-19 | 青岛海纳生物科技有限公司 | Pesticide sustained release granule containing thiamethoxam and preparation method thereof |
| CN104839195B (en) * | 2015-05-08 | 2017-08-29 | 青岛海纳生物科技有限公司 | A kind of pesticide slow-release particle containing Diacloden and preparation method thereof |
| CN105347959A (en) * | 2015-12-06 | 2016-02-24 | 张友兰 | Plant pesticide fertilizer granule |
| CN106045661A (en) * | 2016-05-25 | 2016-10-26 | 广西金穗农药有限公司 | Pesticide-fertilizer granules comprising thiamethoxam |
| CN107258808A (en) * | 2017-07-06 | 2017-10-20 | 王章修 | A kind of fertilizer granules and its application containing Diacloden and cyfloxylate |
| CN107821403A (en) * | 2017-11-23 | 2018-03-23 | 陕西嘉益蓝德生物工程有限公司 | A kind of sterilization and disinsection fertilizer granules |
| CN112521213A (en) * | 2020-12-04 | 2021-03-19 | 广西联和裕隆药肥有限公司 | Pesticide fertilizer for delaying pesticide release |
| CN112707761A (en) * | 2021-01-12 | 2021-04-27 | 广西联和裕隆药肥有限公司 | Drought-resistant soil moisture conservation pesticide fertilizer |
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Application publication date: 20130605 |