CN103127646A - Spraying reagent for purifying formaldehyde - Google Patents

Spraying reagent for purifying formaldehyde Download PDF

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Publication number
CN103127646A
CN103127646A CN2011103841522A CN201110384152A CN103127646A CN 103127646 A CN103127646 A CN 103127646A CN 2011103841522 A CN2011103841522 A CN 2011103841522A CN 201110384152 A CN201110384152 A CN 201110384152A CN 103127646 A CN103127646 A CN 103127646A
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China
Prior art keywords
formaldehyde
spraying reagent
nano titanium
purifying
titanium oxide
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CN2011103841522A
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Chinese (zh)
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CN103127646B (en
Inventor
王欣欣
杨华
刘清珺
刘艳菊
孙凌刚
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Beijing Physichemistry Analysis & Measurment Centre
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Beijing Physichemistry Analysis & Measurment Centre
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Abstract

The invention provides a spraying reagent for purifying formaldehyde. Components of the spraying reagent in weight percent include 90-94% of deionized water, 0.2-0.5% of nano titanium dioxide, 5-8% of imidazolidone derivatives and 0.2-0.5% of glycerin, and the remaining is triethanolamine. The spraying reagent for purifying the formaldehyde is simple and convenient to use, remarkable in effects, lasting in functions and free of environmental pollution, and is an ideal product for controlling formaldehyde pollution in the air indoors.

Description

A kind of spraying reagent of purifying formaldehyde
Technical field
The invention belongs to chemical field, specifically, relate to a kind of spraying reagent of purifying formaldehyde.
Background technology
Formaldehyde can absorb by respiration and skin and enter human body, and health is damaged, and is delimited by the World Health Organization (WHO) to be potential dangerous carcinogenic substance.Formaldehyde pollution is the indoor ubiquitous problem of China.Formaldehyde is prevalent in building, finishing and ornament materials.At present, formaldehyde is the raw material of making synthetic resin, paint, plastics and staple fibre, is also the important source material of making urea-formaldehyde resin adhesive, melamine resin glue, polyacetal resin, penta tetrol urea formaldehyde and phenolic resin glue in wood-based panel industry.The material that uses in interior decoration or furniture, such as glued board, core-board, medium density fibre board (MDF), particieboard, wall covering fabric, wallpaper, chemical fibre carpet, paint, coating, adhesive etc. all contained the chemical substance that formaldehyde or hydrolyzable are formaldehyde to some extent.These formaldehyde residual or that decompose out can discharge in environment gradually towards periphery, and the longest release period can reach the more than ten years.
Severe contamination problem in the face of room air how effectively to control the focus that room air pollution becomes public attention, and convenient, efficient, lasting improvement technology is the target that people pursue all the time.
Summary of the invention
The purpose of this invention is to provide a kind of easy to use, effect significantly and act on the spraying reagent of lasting purifying formaldehyde.
In order to realize the object of the invention, the spraying reagent of a kind of purifying formaldehyde of the present invention, its component by following percetage by weight forms: deionized water 90-94%, nano titanium oxide 0.2-0.5%, imidazolidinone derivatives 5-8%, glycerine 0.2-0.5%, surplus is triethanolamine.
Preferably, the spraying reagent of purifying formaldehyde of the present invention is comprised of the component of following percetage by weight: deionized water 91-93%, nano titanium oxide 0.2-0.4%, imidazolidinone derivatives 5-7%, glycerine 0.2-0.4%, surplus is triethanolamine.
More preferably, the spraying reagent of purifying formaldehyde of the present invention is comprised of the component of following percetage by weight: deionized water 93%, nano titanium oxide 0.2%, imidazolidinone derivatives 5%, glycerine 0.2% and triethanolamine 1.6%.
The spraying reagent of aforesaid purifying formaldehyde, wherein said imidazolidinone derivatives are the hydroxyl imidazolidinone.
The spraying reagent of aforesaid purifying formaldehyde, the particle diameter of wherein said nano titanium oxide are 7-15nm.
The present invention also provides the preparation method of the spraying reagent of above-mentioned purifying formaldehyde, and it is to add successively nano titanium oxide, imidazolidinone derivatives, glycerine and the triethanolamine that measures by formula ratio in deionized water, mixes.
The present invention further provides the application of spraying reagent in indoor air purification of above-mentioned purifying formaldehyde, be specially: this product evenly is sprayed at metope, furniture surface and cabinet-wood exposed section, can prevent effectively that formaldehyde from discharging, and the formaldehyde in the room air that constantly absorbs, degrades.
The present invention has following advantages:
(1) the spraying reagent of purifying formaldehyde provided by the invention is easy to use, effect remarkable, effect is lasting and environmentally safe, is to administer the ideal product that formaldehyde in indoor air is polluted.
(2) the present invention utilizes the quick addition reaction of imidazolidinone and formaldehyde, combines simultaneously the persistence of nano titanium oxide catalytic reaction, thereby makes spraying reagent can bring into play preferably the effect of removing formaldehyde.
(3) this product also has removal effect preferably to other organic pollution except formaldehyde.
(4) this product is water-based system, and character is gentle, and acid-base value is moderate, can not produce any infringement to furniture material.
The specific embodiment
Following examples are used for explanation the present invention, but are not used for limiting the scope of the invention.If do not specialize, the percentage sign that relates in embodiment " % " refers to mass percent, the raw materials used commercial goods that is.
The preparation of the spraying reagent of embodiment 1 purifying formaldehyde
Under room temperature, add 93% deionized water in the glass container with agitating device, then add successively nano titanium oxide 0.2%, hydroxyl imidazolidinone 5%, glycerine 0.2% and triethanolamine 1.6%, after stirring and get final product.
During use, this product evenly is sprayed at metope, furniture surface and cabinet-wood exposed section, in 24 hours, the formaldehyde in indoor air clearance can reach 43%.
The preparation of the spraying reagent of embodiment 2 purifying formaldehydes
The preparation method is with embodiment 1, and the percentage of each component is: deionized water 91%, nano titanium oxide 0.4%, hydroxyl imidazolidinone 7%, glycerine 0.4% and triethanolamine 1.2%.
During use, this product evenly is sprayed at metope, furniture surface and cabinet-wood exposed section, in 24 hours, the formaldehyde in indoor air clearance can reach 40%.
The preparation of the spraying reagent of embodiment 3 purifying formaldehydes
The preparation method is with embodiment 1, and the percentage of each component is: deionized water 92%, nano titanium oxide 0.2%, hydroxyl imidazolidinone 5%, glycerine 0.2% and triethanolamine 2.6%.
During use, this product evenly is sprayed at metope, furniture surface and cabinet-wood exposed section, in 24 hours, the formaldehyde in indoor air clearance can reach 41%.
The preparation of the spraying reagent of embodiment 4 purifying formaldehydes
The preparation method is with embodiment 1, and the percentage of each component is: deionized water 90%, nano titanium oxide 0.4%, hydroxyl imidazolidinone 6%, glycerine 0.5% and triethanolamine 3.1%.
During use, this product evenly is sprayed at metope, furniture surface and cabinet-wood exposed section, in 24 hours, the formaldehyde in indoor air clearance can reach 42%.
The preparation of the spraying reagent of embodiment 5 purifying formaldehydes
The preparation method is with embodiment 1, and the percentage of each component is: deionized water 94%, nano titanium oxide 0.3%, hydroxyl imidazolidinone 5%, glycerine 0.3% and triethanolamine 0.4%.
During use, this product evenly is sprayed at metope, furniture surface and cabinet-wood exposed section, in 24 hours, the formaldehyde in indoor air clearance can reach 40%.
The preparation of the spraying reagent of embodiment 6 purifying formaldehydes
The preparation method is with embodiment 1, and the percentage of each component is: deionized water 90%, nano titanium oxide 0.3%, hydroxyl imidazolidinone 8%, glycerine 0.3% and triethanolamine 1.4%.
During use, this product evenly is sprayed at metope, furniture surface and cabinet-wood exposed section, in 24 hours, the formaldehyde in indoor air clearance can reach 41%.
Although above the present invention is described in detail with a general description of the specific embodiments, on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements, all belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.

Claims (7)

1. the spraying reagent of a purifying formaldehyde, is characterized in that, be comprised of the component of following percetage by weight: deionized water 90-94%, nano titanium oxide 0.2-0.5%, imidazolidinone derivatives 5-8%, glycerine 0.2-0.5%, surplus is triethanolamine.
2. the spraying reagent of purifying formaldehyde according to claim 1, it is characterized in that, component by following percetage by weight forms: deionized water 91-93%, nano titanium oxide 0.2-0.4%, imidazolidinone derivatives 5-7%, glycerine 0.2-0.4%, surplus is triethanolamine.
3. the spraying reagent of purifying formaldehyde according to claim 2, is characterized in that, is comprised of the component of following percetage by weight: deionized water 93%, nano titanium oxide 0.2%, imidazolidinone derivatives 5%, glycerine 0.2% and triethanolamine 1.6%.
4. the spraying reagent of according to claim 1-3 described purifying formaldehydes of any one, is characterized in that, described imidazolidinone derivatives is the hydroxyl imidazolidinone.
5. the spraying reagent of according to claim 1-3 described purifying formaldehydes of any one, is characterized in that, the particle diameter of described nano titanium oxide is 7-15nm.
6. the preparation method of the spraying reagent of the described purifying formaldehyde of claim 1-5 any one, it is to add successively nano titanium oxide, imidazolidinone derivatives, glycerine and the triethanolamine that measures by formula ratio in deionized water, mixes.
7. the application of spraying reagent in indoor air purification of the described purifying formaldehyde of claim 1-5 any one.
CN201110384152.2A 2011-11-28 2011-11-28 Spraying reagent for purifying formaldehyde Active CN103127646B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN103127646B CN103127646B (en) 2015-02-18

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104645800A (en) * 2013-11-25 2015-05-27 北京市理化分析测试中心 Formaldehyde catching agent and preparation method thereof
CN104874257A (en) * 2015-05-20 2015-09-02 上海韬鸿化工科技有限公司 Formaldehyde removing agent
CN104998370A (en) * 2015-07-11 2015-10-28 卞洪锋 Preparation method of formaldehyde eliminating agent and application
CN105013127A (en) * 2015-07-11 2015-11-04 卞洪锋 Formaldehyde elimination agent and application thereof
CN105056460A (en) * 2015-07-17 2015-11-18 卞洪锋 Environment-friendly dispelling agent used for eliminating formaldehyde
CN105148448A (en) * 2015-07-17 2015-12-16 卞洪锋 Method for removing hazardous substance formaldehyde on furniture
CN105771606A (en) * 2016-05-11 2016-07-20 山东惠净居环保科技有限公司 Environment-friendly decoration pollution deodorant and preparation method thereof
CN106474868A (en) * 2016-09-28 2017-03-08 上海杉盛空气净化技术有限公司 A kind of air cleaning liquid and preparation method thereof
CN106512951A (en) * 2016-11-23 2017-03-22 郑州莉迪亚医药科技有限公司 Formaldehyde adsorbent for purification and its preparation method and application
CN106582270A (en) * 2016-11-29 2017-04-26 青岛海之星生物科技有限公司 Sterilization and aldehyde-removal spray and preparation method thereof
CN106732382A (en) * 2016-11-23 2017-05-31 郑州莉迪亚医药科技有限公司 A kind of purification of air formaldehyde adsorbent and preparation method and application
CN106823237A (en) * 2017-01-26 2017-06-13 南京双全科技有限公司 Except formaldehyde smoke agent and preparation method thereof
CN106861110A (en) * 2017-02-16 2017-06-20 杭州蓝山环保科技有限公司 A kind of long-acting elimination method of formaldehyde
CN107126823A (en) * 2017-04-05 2017-09-05 介休市博创纳米材料科技有限公司 It is a kind of long-acting except aldehyde, antibacterial, mould proof furniture spray and its manufacture method
CN108434980A (en) * 2018-04-16 2018-08-24 水夫人(福建)环保科技股份有限公司 A kind of formaldehyde treated agent and preparation method thereof
CN110157334A (en) * 2018-01-26 2019-08-23 北京欧美中科学技术研究院 It is a kind of can purifying formaldehyde graphene mineral coating preparation method
CN110624388A (en) * 2019-10-28 2019-12-31 深圳市爱康泉水处理服务有限公司 Deodorant composition, deodorant and application thereof
CN112441656A (en) * 2020-11-06 2021-03-05 福建绿航环保科技有限公司 Formaldehyde removal method and formaldehyde removal reagent for medium-density fiberboard production wastewater
CN114768502A (en) * 2022-03-18 2022-07-22 河北登尚科技有限公司 Aldehyde removing agent

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CN101011623A (en) * 2007-02-06 2007-08-08 江苏飞翔化工股份有限公司 Formaldehyde removing agent composition
CN101437552A (en) * 2006-03-01 2009-05-20 罗伯特·斯维德扎克 Method for the absorption of harmful substances and odors
CN101703832A (en) * 2009-11-30 2010-05-12 长沙灏阳环保科技有限责任公司 Formaldehyde scavenging agent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101437552A (en) * 2006-03-01 2009-05-20 罗伯特·斯维德扎克 Method for the absorption of harmful substances and odors
CN101011623A (en) * 2007-02-06 2007-08-08 江苏飞翔化工股份有限公司 Formaldehyde removing agent composition
CN101703832A (en) * 2009-11-30 2010-05-12 长沙灏阳环保科技有限责任公司 Formaldehyde scavenging agent and preparation method thereof

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104645800A (en) * 2013-11-25 2015-05-27 北京市理化分析测试中心 Formaldehyde catching agent and preparation method thereof
CN104645800B (en) * 2013-11-25 2016-08-17 北京市理化分析测试中心 formaldehyde catching agent and preparation method thereof
CN104874257A (en) * 2015-05-20 2015-09-02 上海韬鸿化工科技有限公司 Formaldehyde removing agent
CN105013127B (en) * 2015-07-11 2017-12-29 亳州市爱开发网络科技有限公司 A kind of formaldehyde eliminating agent and its application
CN104998370A (en) * 2015-07-11 2015-10-28 卞洪锋 Preparation method of formaldehyde eliminating agent and application
CN105013127A (en) * 2015-07-11 2015-11-04 卞洪锋 Formaldehyde elimination agent and application thereof
CN104998370B (en) * 2015-07-11 2017-12-29 卞洪锋 A kind of preparation method and application of formaldehyde eliminating agent
CN105056460A (en) * 2015-07-17 2015-11-18 卞洪锋 Environment-friendly dispelling agent used for eliminating formaldehyde
CN105148448A (en) * 2015-07-17 2015-12-16 卞洪锋 Method for removing hazardous substance formaldehyde on furniture
CN105148448B (en) * 2015-07-17 2018-06-26 广州佳伲思抗菌材料有限公司 A kind of method for dispelling harmful substance formaldehyde on furniture
CN105056460B (en) * 2015-07-17 2017-12-29 卞洪锋 A kind of environment-friendly type remover for being used to eliminate formaldehyde
CN105771606A (en) * 2016-05-11 2016-07-20 山东惠净居环保科技有限公司 Environment-friendly decoration pollution deodorant and preparation method thereof
CN106474868A (en) * 2016-09-28 2017-03-08 上海杉盛空气净化技术有限公司 A kind of air cleaning liquid and preparation method thereof
CN106474868B (en) * 2016-09-28 2019-01-22 上海杉盛空气净化技术有限公司 A kind of air cleaning liquid and preparation method thereof
CN106732382A (en) * 2016-11-23 2017-05-31 郑州莉迪亚医药科技有限公司 A kind of purification of air formaldehyde adsorbent and preparation method and application
CN106512951A (en) * 2016-11-23 2017-03-22 郑州莉迪亚医药科技有限公司 Formaldehyde adsorbent for purification and its preparation method and application
CN106582270A (en) * 2016-11-29 2017-04-26 青岛海之星生物科技有限公司 Sterilization and aldehyde-removal spray and preparation method thereof
CN106823237A (en) * 2017-01-26 2017-06-13 南京双全科技有限公司 Except formaldehyde smoke agent and preparation method thereof
CN106861110A (en) * 2017-02-16 2017-06-20 杭州蓝山环保科技有限公司 A kind of long-acting elimination method of formaldehyde
CN107126823A (en) * 2017-04-05 2017-09-05 介休市博创纳米材料科技有限公司 It is a kind of long-acting except aldehyde, antibacterial, mould proof furniture spray and its manufacture method
CN110157334A (en) * 2018-01-26 2019-08-23 北京欧美中科学技术研究院 It is a kind of can purifying formaldehyde graphene mineral coating preparation method
CN108434980A (en) * 2018-04-16 2018-08-24 水夫人(福建)环保科技股份有限公司 A kind of formaldehyde treated agent and preparation method thereof
CN110624388A (en) * 2019-10-28 2019-12-31 深圳市爱康泉水处理服务有限公司 Deodorant composition, deodorant and application thereof
CN110624388B (en) * 2019-10-28 2022-04-15 深圳市爱康泉水处理服务有限公司 Deodorant composition, deodorant and application thereof
CN112441656A (en) * 2020-11-06 2021-03-05 福建绿航环保科技有限公司 Formaldehyde removal method and formaldehyde removal reagent for medium-density fiberboard production wastewater
CN114768502A (en) * 2022-03-18 2022-07-22 河北登尚科技有限公司 Aldehyde removing agent

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