CN103122083A - Preparation method of potato starch biodegradable plastic - Google Patents
Preparation method of potato starch biodegradable plastic Download PDFInfo
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- CN103122083A CN103122083A CN2013100745503A CN201310074550A CN103122083A CN 103122083 A CN103122083 A CN 103122083A CN 2013100745503 A CN2013100745503 A CN 2013100745503A CN 201310074550 A CN201310074550 A CN 201310074550A CN 103122083 A CN103122083 A CN 103122083A
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- potato starch
- biodegradable plastic
- preparation
- class biodegradable
- floss
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Abstract
The invention discloses a preparation method of potato starch biodegradable plastic, which comprises the following steps of: mixing and stirring 3-chloro-2-hydroxypropyltrimethylammonium chloride and a sodium hydroxide aqueous solution; spraying the mixture onto potato starch and continuing heating and stirring to obtain a potato starch floccule; mixing the potato starch floccule, cellulose and phthalate for reaction; performing tape casting of the obtained mixed solution onto a polytetrafluoroethylene square disc by a tape casting machine to form a film; and drying to obtain the potato starch biodegradable plastic. According to the preparation method of potato starch biodegradable plastic disclosed by the invention, the preparation technology is simple, the whole production process is non-toxic and harmless, a worker can work in a good working environment, the obtained potato starch biodegradable plastic can be degraded by microorganisms after use, and environmental pollution caused by plastic is effectively reduced.
Description
Technical field
The present invention relates to field of plastics processing, particularly relate to a kind of preparation method of potato starch class biodegradable plastic.
Background technology
Plastics are compared with traditional metal products, have lightweight, corrosion-resistant, moulding is easy, processing elegant in appearance, easy, low cost and other advantages, generally be applied in our life, be indispensable simultaneously.But along with increasing rapidly of plastics output, waste plastic can not in time be processed, thereby causes the pollution of environment more and more serious.The plastic garbage appropriation of land blocks rivers, hinders health, affect view, the growth that harms the crops and HUMAN HEALTH, plastic garbage have become the important factor of polluting human habitat, and therefore the biodegradable plastics goods are used more and more on a large scale now.But traditional biodegradable plastics product producing process is complicated, and preparation process can cause environmental pollution, and Working environment is unfavorable for that the workman's is healthy.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of preparation method of potato starch class biodegradable plastic, and the method preparation technology is simple, and technological process and product are pollution-free.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of preparation method of potato starch class biodegradable plastic is provided, comprises that step is:
(1) with 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride and aqueous sodium hydroxide solution mix and blend, spray mixture on potato starch and continue heated and stirred, obtain the potato starch floss;
(2) with described potato starch floss, Mierocrystalline cellulose and phthalic ester hybrid reaction, the mixing solutions that obtains is by casting machine curtain coating film forming on the polytetrafluoro alkene square plate, and oven dry obtains potato starch class biodegradable plastic.
In a preferred embodiment of the present invention, described in step (1), Heating temperature is 120-130 ℃.
In a preferred embodiment of the present invention, described in step (2), the hybrid reaction temperature is 70-90 ℃.
In a preferred embodiment of the present invention, described in step (2), drying course is to use oven for drying.
The invention has the beneficial effects as follows: the preparation method of potato starch class biodegradable plastic of the present invention, the method preparation technology is simple, whole production process is nontoxic, the workman is worked under good Working environment, the potato starch class biodegradable plastic that obtains can be degraded by microorganisms after use, has effectively reduced the pollution of plastics to environment.
Embodiment
The below is described in detail preferred embodiment of the present invention, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made more explicit defining.
Embodiment one:
(1) with 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride and aqueous sodium hydroxide solution mix and blend, mixture is sprayed on potato starch and continues 128 ℃ of lower heated and stirred, obtain the potato starch floss;
(2) with described potato starch floss, Mierocrystalline cellulose and phthalic ester 74 ℃ of lower hybrid reactions, the mixing solutions that obtains obtains potato starch class biodegradable plastic by casting machine curtain coating film forming on the polytetrafluoro alkene square plate with oven for drying.
Embodiment two:
(1) with 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride and aqueous sodium hydroxide solution mix and blend, mixture is sprayed on potato starch and continues 125 ℃ of lower heated and stirred, obtain the potato starch floss;
(2) with described potato starch floss, Mierocrystalline cellulose and phthalic ester 80 ℃ of lower hybrid reactions, the mixing solutions that obtains obtains potato starch class biodegradable plastic by casting machine curtain coating film forming on the polytetrafluoro alkene square plate with oven for drying.
Embodiment three:
(1) with 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride and aqueous sodium hydroxide solution mix and blend, mixture is sprayed on potato starch and continues 120 ℃ of lower heated and stirred, obtain the potato starch floss;
(2) with described potato starch floss, Mierocrystalline cellulose and phthalic ester 90 ℃ of lower hybrid reactions, the mixing solutions that obtains obtains potato starch class biodegradable plastic by casting machine curtain coating film forming on the polytetrafluoro alkene square plate with oven for drying.
The above is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or equivalent flow process conversion that utilizes specification sheets of the present invention to do, or directly or indirectly be used in other relevant technical fields, all in like manner be included in scope of patent protection of the present invention.
Claims (4)
1. the preparation method of a potato starch class biodegradable plastic, is characterized in that, comprises that step is:
(1) with 3-chloro-2-hydroxypropyl-trimethyl ammonium chloride and aqueous sodium hydroxide solution mix and blend, spray mixture on potato starch and continue heated and stirred, obtain the potato starch floss;
(2) with described potato starch floss, Mierocrystalline cellulose and phthalic ester hybrid reaction, the mixing solutions that obtains is by casting machine curtain coating film forming on the polytetrafluoro alkene square plate, and oven dry obtains potato starch class biodegradable plastic.
2. the preparation method of potato starch class biodegradable plastic according to claim 1, is characterized in that, described in step (1), Heating temperature is 120-130 ℃.
3. the preparation method of potato starch class biodegradable plastic according to claim 1, is characterized in that, described in step (2), the hybrid reaction temperature is 70-90 ℃.
4. the preparation method of potato starch class biodegradable plastic according to claim 1, is characterized in that, described in step (2), drying course is to use oven for drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100745503A CN103122083A (en) | 2013-03-11 | 2013-03-11 | Preparation method of potato starch biodegradable plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100745503A CN103122083A (en) | 2013-03-11 | 2013-03-11 | Preparation method of potato starch biodegradable plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103122083A true CN103122083A (en) | 2013-05-29 |
Family
ID=48453248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013100745503A Pending CN103122083A (en) | 2013-03-11 | 2013-03-11 | Preparation method of potato starch biodegradable plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103122083A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1088226A (en) * | 1992-11-06 | 1994-06-22 | 弗伦特拉有限公司 | Biodegradable polyblend |
| CN1420139A (en) * | 2001-11-15 | 2003-05-28 | 晓威国际有限公司 | Ecological environment material nd mfg. method thereof |
| CN1693348A (en) * | 2005-06-09 | 2005-11-09 | 张雷 | Natural high molecular composite material and its preparation process and application |
| CN1935882A (en) * | 2005-09-21 | 2007-03-28 | 李小鲁 | Water-soluble biodegradable material, and its preparing method and sheet-like shaped product |
-
2013
- 2013-03-11 CN CN2013100745503A patent/CN103122083A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1088226A (en) * | 1992-11-06 | 1994-06-22 | 弗伦特拉有限公司 | Biodegradable polyblend |
| CN1420139A (en) * | 2001-11-15 | 2003-05-28 | 晓威国际有限公司 | Ecological environment material nd mfg. method thereof |
| CN1693348A (en) * | 2005-06-09 | 2005-11-09 | 张雷 | Natural high molecular composite material and its preparation process and application |
| CN1935882A (en) * | 2005-09-21 | 2007-03-28 | 李小鲁 | Water-soluble biodegradable material, and its preparing method and sheet-like shaped product |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130529 |