CN103113960A - 一种加氢基础油的光稳定剂组合物及其应用 - Google Patents
一种加氢基础油的光稳定剂组合物及其应用 Download PDFInfo
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- CN103113960A CN103113960A CN2013100345479A CN201310034547A CN103113960A CN 103113960 A CN103113960 A CN 103113960A CN 2013100345479 A CN2013100345479 A CN 2013100345479A CN 201310034547 A CN201310034547 A CN 201310034547A CN 103113960 A CN103113960 A CN 103113960A
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- Prior art keywords
- light stabilizer
- antioxidant
- composition
- ester
- base oil
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004611 light stabiliser Substances 0.000 title claims abstract description 56
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 17
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 17
- 150000001412 amines Chemical class 0.000 claims abstract description 16
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 5
- 239000002199 base oil Substances 0.000 claims description 52
- 239000006096 absorbing agent Substances 0.000 claims description 35
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 22
- 150000002148 esters Chemical class 0.000 claims description 17
- 230000003647 oxidation Effects 0.000 claims description 16
- 238000007254 oxidation reaction Methods 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- 239000003112 inhibitor Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 11
- 150000002989 phenols Chemical class 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- NWHNXXMYEICZAT-UHFFFAOYSA-N 1,2,2,6,6-pentamethylpiperidin-4-ol Chemical compound CN1C(C)(C)CC(O)CC1(C)C NWHNXXMYEICZAT-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- VDVUCLWJZJHFAV-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1 VDVUCLWJZJHFAV-UHFFFAOYSA-N 0.000 claims description 7
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 7
- -1 phenylformic acid (2, 2, 6, 6-tetramethyl--4-hydroxy piperidine) ester Chemical class 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 5
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- 125000006487 butyl benzyl group Chemical group 0.000 claims description 3
- HCPOCMMGKBZWSJ-UHFFFAOYSA-N ethyl 3-hydrazinyl-3-oxopropanoate Chemical compound CCOC(=O)CC(=O)NN HCPOCMMGKBZWSJ-UHFFFAOYSA-N 0.000 claims description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- IKPVDNIZBYPODU-UHFFFAOYSA-N C(C1=CC=CC=C1)(=O)O.CC1(NC(CC(C1)O)(C)C)C Chemical compound C(C1=CC=CC=C1)(=O)O.CC1(NC(CC(C1)O)(C)C)C IKPVDNIZBYPODU-UHFFFAOYSA-N 0.000 claims description 2
- 239000002250 absorbent Substances 0.000 claims description 2
- 230000002745 absorbent Effects 0.000 claims description 2
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 2
- 230000006641 stabilisation Effects 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 abstract 1
- 239000010687 lubricating oil Substances 0.000 description 10
- 238000005984 hydrogenation reaction Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- 239000002131 composite material Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003352 sequestering agent Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000007539 photo-oxidation reaction Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- UTOPFCYIKGGRQK-UHFFFAOYSA-N 1-(2,2,6,6-tetramethylpiperidin-1-yl)hexane-1,1-diamine Chemical compound CCCCCC(N)(N)N1C(CCCC1(C)C)(C)C UTOPFCYIKGGRQK-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- BLBVLMPUSLFQNF-UHFFFAOYSA-N S.P(O)(O)(O)=O Chemical compound S.P(O)(O)(O)=O BLBVLMPUSLFQNF-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- VCAFTIGPOYBOIC-UHFFFAOYSA-N phenyl dihydrogen phosphite Chemical class OP(O)OC1=CC=CC=C1 VCAFTIGPOYBOIC-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Lubricants (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201310034547.9A CN103113960B (zh) | 2013-01-29 | 2013-01-29 | 一种加氢基础油的光稳定剂组合物及其应用 |
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CN201310034547.9A CN103113960B (zh) | 2013-01-29 | 2013-01-29 | 一种加氢基础油的光稳定剂组合物及其应用 |
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CN103113960A true CN103113960A (zh) | 2013-05-22 |
CN103113960B CN103113960B (zh) | 2015-02-18 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105087114A (zh) * | 2014-05-14 | 2015-11-25 | 吉坤日矿日石能源株式会社 | 润滑油组合物和生产线的管理方法 |
CN109652165A (zh) * | 2017-10-11 | 2019-04-19 | 中国石油化工股份有限公司 | 一种润滑油基础油光稳定剂组合物及其制备方法与应用 |
CN111333908A (zh) * | 2018-12-19 | 2020-06-26 | 天津利安隆新材料股份有限公司 | 一种稳定加氢精制基础油的抗老化组合物 |
CN113698980A (zh) * | 2021-09-23 | 2021-11-26 | 山东恒导石油化工股份有限公司 | 一种液压油油品光稳定剂及其制备工艺 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1715381A (zh) * | 2004-06-29 | 2006-01-04 | 中国石油化工股份有限公司 | 润滑油复合稳定剂及稳定的加氢润滑油组合物 |
CN102260573A (zh) * | 2010-06-07 | 2011-11-30 | 江苏双江石化制品有限公司 | 一种润滑基础油光安定性复合添加剂 |
CN102627994A (zh) * | 2012-03-21 | 2012-08-08 | 上海应用技术学院 | 一种高压加氢环烷基润滑油光稳定剂组合物及其应用 |
-
2013
- 2013-01-29 CN CN201310034547.9A patent/CN103113960B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1715381A (zh) * | 2004-06-29 | 2006-01-04 | 中国石油化工股份有限公司 | 润滑油复合稳定剂及稳定的加氢润滑油组合物 |
CN102260573A (zh) * | 2010-06-07 | 2011-11-30 | 江苏双江石化制品有限公司 | 一种润滑基础油光安定性复合添加剂 |
CN102627994A (zh) * | 2012-03-21 | 2012-08-08 | 上海应用技术学院 | 一种高压加氢环烷基润滑油光稳定剂组合物及其应用 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105087114A (zh) * | 2014-05-14 | 2015-11-25 | 吉坤日矿日石能源株式会社 | 润滑油组合物和生产线的管理方法 |
CN109652165A (zh) * | 2017-10-11 | 2019-04-19 | 中国石油化工股份有限公司 | 一种润滑油基础油光稳定剂组合物及其制备方法与应用 |
CN109652165B (zh) * | 2017-10-11 | 2021-09-14 | 中国石油化工股份有限公司 | 一种润滑油基础油光稳定剂组合物及其制备方法与应用 |
CN111333908A (zh) * | 2018-12-19 | 2020-06-26 | 天津利安隆新材料股份有限公司 | 一种稳定加氢精制基础油的抗老化组合物 |
CN111333908B (zh) * | 2018-12-19 | 2022-04-01 | 天津利安隆新材料股份有限公司 | 一种稳定加氢精制基础油的抗老化组合物 |
CN113698980A (zh) * | 2021-09-23 | 2021-11-26 | 山东恒导石油化工股份有限公司 | 一种液压油油品光稳定剂及其制备工艺 |
CN113698980B (zh) * | 2021-09-23 | 2023-07-11 | 山东恒导石油化工股份有限公司 | 一种液压油油品光稳定剂及其制备工艺 |
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CN103113960B (zh) | 2015-02-18 |
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Address after: 239300, No. four, No. 83, Tianchang Economic Zone, Chuzhou, Anhui Patentee after: ANHUI KION NEW ENERGY Corp. Address before: 239300 No. four, No. 83, Tianchang economic and Technological Development Zone, Chuzhou, Anhui Patentee before: ANHUI KAIAO LUBRICANT SCIENCE & TECHNOLOGY Co.,Ltd. |
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Denomination of invention: A light stabilizer composition of hydrogenated base oil and its application Effective date of registration: 20200812 Granted publication date: 20150218 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI KION NEW ENERGY Corp. Registration number: Y2020980004887 |
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Denomination of invention: A light stabilizer composition for hydrogenated base oil and its application Effective date of registration: 20210824 Granted publication date: 20150218 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI KION NEW ENERGY Corp. Registration number: Y2021980008169 |
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