CN103081905A - Preparation method of pesticide residue toxinicide for agricultural products - Google Patents
Preparation method of pesticide residue toxinicide for agricultural products Download PDFInfo
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- CN103081905A CN103081905A CN2012103965568A CN201210396556A CN103081905A CN 103081905 A CN103081905 A CN 103081905A CN 2012103965568 A CN2012103965568 A CN 2012103965568A CN 201210396556 A CN201210396556 A CN 201210396556A CN 103081905 A CN103081905 A CN 103081905A
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Abstract
The invention relates to a preparation method of a pesticide residue toxinicide for agricultural products, which comprises the following steps: (1) mixing 0.6-2.1% of nano zinc oxide, 40-50% of percarbonate, 0.4-1.6% of potassium selenite and right amounts of pure water, and continuously stirring until all the components are completely dissolved; and (2) continuing adding pure water to the total weight percentage of 100%, and stirring uniformly. The toxinicide prepared by the method provided by the invention can effectively reduce the pesticide residue by more than 70%, and can degrade the pesticide residue on the agricultural product and lower the pesticide residue in the agricultural product.
Description
Technical field
The present invention relates to the preparation method of Practice for Pesticide Residue in Agricultural Products antipoison.
Background technology
Residue of pesticide refer to because pesticides application remains in the agricultural chemicals parent in organism, agricultural product and environment and has the general name of impurity, metabolite and the reaction of toxicology meaning.China is world pesticide production and uses big country.A large amount of residue of pesticide can cause acute toxicity.Remains of pesticide also can be accumulated in human body, can cause some diseases over after a certain amount of, as angiocardiopathy, diabetes, hepatopathy, cancer etc.; Agricultural chemicals accumulating also in human body can be passed to the next generation by pregnant and lactation, brings disaster to descendants's health.Bread is the staff of life, and food is with An Weixian.When food industry had developed into the large industry of the first in the world, food security also was subject to extensive concern.Therefore, the residue of pesticide of reduction agricultural product are trends of the times.Product in the market belongs to types of detergents mostly, real degrading pesticide, and can cause secondary pollution to water quality.
Summary of the invention
The preparation method who the purpose of this invention is to provide a kind of Practice for Pesticide Residue in Agricultural Products antipoison makes both can the degrade residue of pesticide on crops surfaces of antipoison and can also reduce the agricultural chemicals that infiltrates through crops inside, drops into low and effect is remarkable.
Residue of pesticide antipoison of the present invention is comprised of the component of following percentage by weight:
Nano zine oxide 0.6-2.1%
Percarbonate 40-50%
Potassium selenite 0.4-1.6%
Surplus is pure water.
Wherein nano zine oxide has good photocatalysis performance, and it can absorb luminous energy, produces the material with strong oxidizing property and comes chemical bond in degrading pesticide.Percarbonate can be SODIUM PERCARBONATE, potassium percarbonate, is the strong oxidizing property material.Selenium in potassium selenite can enter rapidly plant cell in photosynthesis, add the foreign substance removing function of cell, accelerates simultaneously the aging of pesticide molecule chain and fracture, greatly reduces the residue of pesticide in crops.
The preparation method of above-mentioned antipoison comprises the following steps:
(1) 0.6-2.1% nano zine oxide, 40-50% percarbonate, 0.4-1.6% potassium selenite and appropriate pure water are mixed, constantly stir until all components dissolves fully;
(2) continuing to add pure water to make total weight percent is 100%, stirs.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.But the invention is not restricted to given example.
Embodiment 1
The component of the following percentage by weight of residue of pesticide antipoison of the present embodiment forms:
Nano zine oxide 0.6%
SODIUM PERCARBONATE 40%
Potassium selenite 0.4%
Surplus is pure water.
The preparation method of the residue of pesticide antipoison of the present embodiment comprises the following steps:
(1) 0.6 nano zine oxide, 40% SODIUM PERCARBONATE, 0.4% potassium selenite and appropriate pure water are mixed, constantly stir until all components dissolves fully;
(2) continuing to add pure water to make total weight percent is 100%, stirs.
Embodiment 2
The component of the following percentage by weight of residue of pesticide antipoison of the present embodiment forms:
Nano zine oxide 1.0%
Potassium percarbonate 45%
Potassium selenite 1.0%
Surplus is pure water.
The preparation method of the residue of pesticide antipoison of the present embodiment comprises the following steps:
(1) 1.0 nano zine oxides, 45% potassium percarbonate, 1.0% potassium selenite and appropriate pure water are mixed, constantly stir until all components dissolves fully;
(2) continuing to add pure water to make total weight percent is 100%, stirs.
Embodiment 3
The component of the following percentage by weight of residue of pesticide antipoison of the present embodiment forms:
Nano zine oxide 2.1%
Potassium percarbonate 50%
Potassium selenite 1.6%
Surplus is pure water.
The preparation method of the residue of pesticide antipoison of the present embodiment comprises the following steps:
(1) 2.1% nano zine oxide, 50% potassium percarbonate, 1.6% potassium selenite and appropriate pure water are mixed, constantly stir until all components dissolves fully;
(2) continuing to add pure water to make total weight percent is 100%, stirs.
The method that adopts the various embodiments described above residue of pesticide antipoison to process crops comprises the following steps:
(1) with 20 times of above-described embodiment residue of pesticide antipoison dilutions;
(2) reach 24 hours after pesticide spraying, before the 1-2 before crops are gathered days, the antipoison that dilutes is sprayed at crop surface;
(3) expose at least 10 hours under sunlight or artificial light source.
Processing crops with above-described embodiment residue of pesticide antipoison can effectively reduce residue of pesticide more than 70%, and the residue of pesticide of the surface of agricultural products of can degrading, and can reduce again the persticide residue of agricultural product inside.
Claims (1)
1. the preparation method of a residue of pesticide antipoison, is characterized in that, comprises the following steps:
(1) 0.6-2.1% nano zine oxide, 40-50% percarbonate, 0.4-1.6% potassium selenite and appropriate pure water are mixed, constantly stir until all components dissolves fully;
(2) continuing to add pure water to make total weight percent is 100%, stirs.
Priority Applications (1)
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CN2012103965568A CN103081905A (en) | 2012-10-17 | 2012-10-17 | Preparation method of pesticide residue toxinicide for agricultural products |
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CN2012103965568A CN103081905A (en) | 2012-10-17 | 2012-10-17 | Preparation method of pesticide residue toxinicide for agricultural products |
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CN103081905A true CN103081905A (en) | 2013-05-08 |
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CN2012103965568A Pending CN103081905A (en) | 2012-10-17 | 2012-10-17 | Preparation method of pesticide residue toxinicide for agricultural products |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1468937A (en) * | 2002-07-18 | 2004-01-21 | 青岛海洋大学 | Residual pesticide degrading agent |
CN1524595A (en) * | 2003-09-12 | 2004-09-01 | 淮阴师范学院 | Oxidation type antidote for pesticide residue on fruits and vegetables |
GR1005523B (en) * | 2005-12-19 | 2007-05-25 | Εθνικο Κεντρο Ερευνας Φυσικων Επιστημων (Εκεφε) -"Δημοκριτος" | Multifunctional aqueous pastes and thin films of nanostructured titania |
WO2009011842A1 (en) * | 2007-07-16 | 2009-01-22 | Accelegrow Technologies, Inc. | Dry fertilizer with growth hormone-containing formulation and methods of use and making |
CN101531541A (en) * | 2008-03-10 | 2009-09-16 | 孔宪中 | Potassium-containing selenium fertilizer for promoting plant growth and deteriorating pesticide residue |
CN101863697A (en) * | 2010-07-11 | 2010-10-20 | 于百涛 | Potassium-boron-selenium fertilizer capable of promoting growth of fruit trees and degrading residual pesticide |
-
2012
- 2012-10-17 CN CN2012103965568A patent/CN103081905A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1468937A (en) * | 2002-07-18 | 2004-01-21 | 青岛海洋大学 | Residual pesticide degrading agent |
CN1524595A (en) * | 2003-09-12 | 2004-09-01 | 淮阴师范学院 | Oxidation type antidote for pesticide residue on fruits and vegetables |
GR1005523B (en) * | 2005-12-19 | 2007-05-25 | Εθνικο Κεντρο Ερευνας Φυσικων Επιστημων (Εκεφε) -"Δημοκριτος" | Multifunctional aqueous pastes and thin films of nanostructured titania |
WO2009011842A1 (en) * | 2007-07-16 | 2009-01-22 | Accelegrow Technologies, Inc. | Dry fertilizer with growth hormone-containing formulation and methods of use and making |
CN101531541A (en) * | 2008-03-10 | 2009-09-16 | 孔宪中 | Potassium-containing selenium fertilizer for promoting plant growth and deteriorating pesticide residue |
CN101863697A (en) * | 2010-07-11 | 2010-10-20 | 于百涛 | Potassium-boron-selenium fertilizer capable of promoting growth of fruit trees and degrading residual pesticide |
Non-Patent Citations (5)
Title |
---|
M.H.PÉREZ 等: "Degradation of pesticides in water using solar advanced oxidation processes", 《APPLIED CATALYSIS B: ENVIRONMENTAL》, vol. 64, 25 January 2006 (2006-01-25), pages 272 - 281, XP 028001001, DOI: doi:10.1016/j.apcatb.2005.11.013 * |
*** 等: "ZnO/TiO2光催化降解烟草中的农药残留及有害成分", 《功能材料》, vol. 43, no. 16, 31 August 2012 (2012-08-31), pages 2146 - 2148 * |
王玲玲 等: "过碳酸盐对菊酯类农药降解作用的研究", 《化工时刊》, vol. 23, no. 2, 28 February 2009 (2009-02-28), pages 10 - 14 * |
赵硕伟: "ZnO纳米粒子光催化降解失效农药草甘膦的研究", 《农业环境科学学报》, vol. 31, no. 1, 31 January 2012 (2012-01-31), pages 54 - 59 * |
陈宗保 等: "纳米ZnO 光催化有机磷农药降解的研究", 《上海师范学院学报》, vol. 27, no. 6, 31 December 2007 (2007-12-31), pages 52 - 54 * |
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Application publication date: 20130508 |