CN103058584B - Epoxy resin coating for exterior wall of building - Google Patents

Epoxy resin coating for exterior wall of building Download PDF

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CN103058584B
CN103058584B CN201310049134.8A CN201310049134A CN103058584B CN 103058584 B CN103058584 B CN 103058584B CN 201310049134 A CN201310049134 A CN 201310049134A CN 103058584 B CN103058584 B CN 103058584B
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component
parts
weight
epoxy resin
epoxypaint
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CN103058584A (en
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张国刚
黎世龙
吴玉泉
何永财
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CHINA NUCLEAR INDUSTRY HUATAI CONSTRUCTION CO., LTD.
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CHINA NUCLEAR INDUSTRY HUATAI CONSTRUCTION Co Ltd
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Priority to CN201410135157.5A priority Critical patent/CN103880334B/en
Priority to CN201310049134.8A priority patent/CN103058584B/en
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Abstract

The invention belongs to the technical field of coatings, and particularly relates to an epoxy resin coating for an exterior wall of a building. The epoxy resin coating is characterized by comprising a component A, a component B and a component C in proportion of (900-1800):(30-50):1 in parts by weight, wherein the component A comprises the components in parts by weight as follows: 8-12 parts of epoxy resin, 12-18 parts of acetone, 3-8 parts of ethylene glycol monobutyl ether, 1-3 parts of commercial OP-10 emulsifier, 0.1-0.3 part of sodium hydroxide, 30-50 parts of ethanol, 70-100 parts of de-ionized water, 140-180 parts of titanium dioxide and 35-45 parts of lithopone; the component B comprises a paint curing agent and tetrachloroisophthalonitrile; and the component C is a pigment. The epoxy resin coating mainly has the beneficial effects that the fluidity is good, the anti-mildew and anticorrosive property is perfect, the coating drying and solidification speed is fast, the color harmonization is flexible, the fast construction is convenient, a preparation method is simple, the operation is easy, and a needed device is simple.

Description

A kind of skin epoxypaint
Technical field
the invention belongs to technical field of coatings, especially relate to a kind of skin epoxypaint.
Background technology
in prior art, epoxypaint is widely used, but the epoxypaint rate of drying regrettably using in prior art is slow, can not meet the requirement of rapid construction.
Summary of the invention
in order to address the above problem, the present invention discloses a kind of skin epoxypaint, and it can be dried quickly and be bonded in securely skin surface, and it is realized by the following technical solutions.
a kind of skin epoxypaint, is characterized in that it is made up of A component, B component and component C, in parts by weight, meets: component A: component B: component C=(900~1800): (30~50): 1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 8~12 parts, acetone: 12~18 parts, ethylene glycol monobutyl ether: 3~8 parts, commercially available OP-10 type emulsifying agent: 1~3 part, sodium hydroxide: 0.1~0.3 part, ethanol: 30~50 parts, deionized water: 70~100 parts, titanium dioxide: 140~180 parts, zinc sulfide white: 35~45 parts; Component B, by by weight, includes following material and content: coating curing agent: 3~5 parts, daconil M: 2~4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein viridescent or phthalein are blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
the first step: make component A: first ratio takes epoxy resin by weight: 8~12 parts, acetone: 12~18 parts, ethylene glycol monobutyl ether: 3~8 parts, commercially available OP-10 type emulsifying agent: 1~3 part, sodium hydroxide: 0.1~0.3 part, ethanol: 30~50 parts, deionized water: 70~100 parts, titanium dioxide: 140~180 parts, zinc sulfide white: 35~45 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75~85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 140~180 parts, zinc sulfide white: 35~45 parts add initial latex to stir to obtain A component emulsion together; Pack A component emulsion into the component A that gets product in packaging vessel;
second step: make component B: ratio takes the various raw materials of component B mixing and stirring and packs container into and obtain finished product component B by weight;
the 3rd step: according to component A: component B: component C=(900~1800): (30~50): 1 weight ratio takes component C and inserts the component C that gets product in container; And rationally take in proportion component A and component B;
the 4th step: by the 3rd step, claim finished product component C insert in finished product component B, fully stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
skin epoxypaint described above, empirical tests, wherein in parts by weight, meets: component A: component B: component C=1125:35:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 10 parts, acetone: 15 parts, ethylene glycol monobutyl ether: 5 parts, commercially available OP-10 type emulsifying agent: 2 parts, sodium hydroxide: 0.2 part, ethanol: 40 parts, deionized water: 90 parts, titanium dioxide: 160 parts, zinc sulfide white: 40 parts; Component B, by by weight, includes following material and content: coating curing agent: 4 parts, daconil M: 3 parts; Component C is ultramarine or phthalocyanine blue or phthalein viridescent or the blue or green red or bright red formula of phthalein, the best results that can reach.
skin epoxypaint described above, is characterized in that described coating curing agent is the epoxy curing agent D-230 of DSM Di Suo company production or the solidifying agent EC-301 of D-400 or the production of BASF Chemical Co., Ltd..
in the present invention, owing to thering is the existence of the volatile materials such as acetone, ethylene glycol monobutyl ether, ethanol in component A, therefore when coating is coated in to building surface, be dried very rapidly and solidify, be convenient to very much rapid construction, in addition, making method of the present invention is simple, easy to operate, required equipment is simple and easy, do not need the input of a large amount of equipment aspects; Good fluidity of the present invention, is not only applicable to artificial coating, and also the utmost point is suitable for machine spraying; In the present invention, due to the existence of daconil M, product is had good anti-ly go mouldy, anti-corrosion performance.
certainly, improve as of the present invention another, can not use component C completely, the content of component C is zero, and through test, product can use as usual, and only product does not have the color of other requirement, but presents white.
when this product export, the mode of packing separately by component A, component B, component C is supplied, and before coating, component C is mixed with B, and then adds mixing in component A; Certainly,, when component C does not exist, only component B need to be added component A to mix; The existence of component C, can configure the color of coating neatly, is applied in the occasion of various needs; Certainly, the present invention should be finished after mixing in 8 hours, in order to avoid solidify.
therefore, the present invention has following main beneficial effect: good fluidity, anti-go mouldy and anti-corrosion performance is good, dry, the color matching fast with setting rate of coating flexibly, be convenient to rapid construction, making method is simple, easy to operate, required equipment is simple and easy, do not need the input of a large amount of equipment aspects.
Embodiment
below in conjunction with embodiment, the present invention is further described in detail, but is not limited to this.
embodiment 1
a kind of skin epoxypaint, is characterized in that it is made up of A component, B component and component C, in parts by weight, meets: component A: component B: component C=900:30:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 12 parts, acetone: 18 parts, ethylene glycol monobutyl ether: 8 parts, commercially available OP-10 type emulsifying agent: 3 parts, sodium hydroxide: 0.3 part, ethanol: 50 parts, deionized water: 100 parts, titanium dioxide: 180 parts, zinc sulfide white: 45 parts; Component B, by by weight, includes following material and content: coating curing agent: 3~5 parts, daconil M: 2~4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein viridescent or phthalein are blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
the first step: make component A: first ratio epoxy resin by weight: 12 parts, acetone: 18 parts, ethylene glycol monobutyl ether: 8 parts, commercially available OP-10 type emulsifying agent: 3 parts, sodium hydroxide: 0.3 part, ethanol: 50 parts, deionized water: 100 parts, titanium dioxide: 180 parts, zinc sulfide white: 45 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75~85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 180 parts, zinc sulfide white: 45 parts add initial latex to stir to obtain A component emulsion together; Pack A component emulsion into the component A that gets product in packaging vessel;
second step: make component B: ratio takes the various raw materials of component B mixing and stirring and packs container into and obtain finished product component B by weight;
the 3rd step: according to component A: the weight ratio of component B: component C=900:30:1 takes component C and inserts the component C that gets product in container; And rationally take in proportion component A and component B;
the 4th step: by the 3rd step, claim finished product component C insert in finished product component B, fully stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
embodiment 2
a kind of skin epoxypaint, is characterized in that it is made up of A component, B component and component C, in parts by weight, meets: component A: component B: component C=1800:50:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 8 parts, acetone: 12 parts, ethylene glycol monobutyl ether: 3 parts, commercially available OP-10 type emulsifying agent: 1 part, sodium hydroxide: 0.1 part, ethanol: 30 parts, deionized water: 70 parts, titanium dioxide: 140 parts, zinc sulfide white: 35 parts; Component B, by by weight, includes following material and content: coating curing agent: 3~5 parts, daconil M: 2~4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein viridescent or phthalein are blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
the first step: make component A: first ratio epoxy resin by weight: 8 parts, acetone: 12 parts, ethylene glycol monobutyl ether: 3 parts, commercially available OP-10 type emulsifying agent: 1 part, sodium hydroxide: 0.1 part, ethanol: 30 parts, deionized water: 70 parts, titanium dioxide: 140 parts, zinc sulfide white: 35 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75~85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 140 parts, zinc sulfide white: 35 parts add initial latex to stir to obtain A component emulsion together; Pack A component emulsion into the component A that gets product in packaging vessel;
second step: make component B: ratio takes the various raw materials of component B mixing and stirring and packs container into and obtain finished product component B by weight;
the 3rd step: according to component A: the weight ratio of component B: component C=1800:30:1 takes component C and inserts the component C that gets product in container; And rationally take in proportion component A and component B;
the 4th step: by the 3rd step, claim finished product component C insert in finished product component B, fully stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
embodiment 3
a kind of skin epoxypaint, is characterized in that it is made up of A component, B component and component C, in parts by weight, meets: component A: component B: component C=1125:35:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 10 parts, acetone: 15 parts, ethylene glycol monobutyl ether: 5 parts, commercially available OP-10 type emulsifying agent: 2 parts, sodium hydroxide: 0.2 part, ethanol: 40 parts, deionized water: 90 parts, titanium dioxide: 160 parts, zinc sulfide white: 40 parts; Component B, by by weight, includes following material and content: coating curing agent: 3~5 parts, daconil M: 2~4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein viridescent or phthalein are blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
the first step: make component A: first ratio epoxy resin by weight: 10 parts, acetone: 15 parts, ethylene glycol monobutyl ether: 5 parts, commercially available OP-10 type emulsifying agent: 2 parts, sodium hydroxide: 0.2 part, ethanol: 40 parts, deionized water: 90 parts, titanium dioxide: 160 parts, zinc sulfide white: 40 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75~85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 160 parts, zinc sulfide white: 40 parts add initial latex to stir to obtain A component emulsion together; Pack A component emulsion into the component A that gets product in packaging vessel;
second step: make component B: ratio takes the various raw materials of component B mixing and stirring and packs container into and obtain finished product component B by weight;
the 3rd step: according to component A: the weight ratio of component B: component C=1125:35:1 takes component C and inserts the component C that gets product in container; And rationally take in proportion component A and component B;
the 4th step: by the 3rd step, claim finished product component C insert in finished product component B, fully stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
through contriver's repetition test, in above-mentioned arbitrary embodiment, the coating that adopts following ratio and method to realize can reach object of the present invention:
a kind of skin epoxypaint, is characterized in that it is made up of A component, B component and component C, in parts by weight, meets: component A: component B: component C=(900~1800): (30~50): 1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 8~12 parts, acetone: 12~18 parts, ethylene glycol monobutyl ether: 3~8 parts, commercially available OP-10 type emulsifying agent: 1~3 part, sodium hydroxide: 0.1~0.3 part, ethanol: 30~50 parts, deionized water: 70~100 parts, titanium dioxide: 140~180 parts, zinc sulfide white: 35~45 parts; Component B, by by weight, includes following material and content: coating curing agent: 3~5 parts, daconil M: 2~4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein viridescent or phthalein are blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
the first step: make component A: first ratio takes epoxy resin by weight: 8~12 parts, acetone: 12~18 parts, ethylene glycol monobutyl ether: 3~8 parts, commercially available OP-10 type emulsifying agent: 1~3 part, sodium hydroxide: 0.1~0.3 part, ethanol: 30~50 parts, deionized water: 70~100 parts, titanium dioxide: 140~180 parts, zinc sulfide white: 35~45 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75~85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 140~180 parts, zinc sulfide white: 35~45 parts add initial latex to stir to obtain A component emulsion together; Pack A component emulsion into the component A that gets product in packaging vessel;
second step: make component B: ratio takes the various raw materials of component B mixing and stirring and packs container into and obtain finished product component B by weight;
the 3rd step: according to component A: component B: component C=(900~1800): (30~50): 1 weight ratio takes component C and inserts the component C that gets product in container; And rationally take in proportion component A and component B;
the 4th step: by the 3rd step, claim finished product component C insert in finished product component B, fully stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
skin epoxypaint described above, empirical tests, wherein in parts by weight, meets: component A: component B: component C :=1125:35:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 10 parts, acetone: 15 parts, ethylene glycol monobutyl ether: 5 parts, commercially available OP-10 type emulsifying agent: 2 parts, sodium hydroxide: 0.2 part, ethanol: 40 parts, deionized water: 90 parts, titanium dioxide: 160 parts, zinc sulfide white: 40 parts; Component B, by by weight, includes following material and content: coating curing agent: 4 parts, daconil M: 3 parts; Component C is ultramarine or phthalocyanine blue or phthalein viridescent or the blue or green red or bright red formula of phthalein, the best results that can reach.
skin epoxypaint described above, is characterized in that described coating curing agent is the epoxy curing agent D-230 of DSM Di Suo company production or the solidifying agent EC-301 of D-400 or the production of BASF Chemical Co., Ltd..
in the present invention, owing to thering is the existence of the volatile materials such as acetone, ethylene glycol monobutyl ether, ethanol in component A, therefore when coating is coated in to building surface, be dried very rapidly and solidify, be convenient to very much rapid construction, in addition, making method of the present invention is simple, easy to operate, required equipment is simple and easy, do not need the input of a large amount of equipment aspects; Good fluidity of the present invention, is not only applicable to artificial coating, and also the utmost point is suitable for machine spraying; In the present invention, due to the existence of daconil M, product is had good anti-ly go mouldy, anti-corrosion performance.
certainly, improve as of the present invention another, can not use component C completely, the content of component C is zero, and through test, product can use as usual, and only product does not have the color of other requirement, but presents white.
when this product export, the mode of packing separately by component A, component B, component C is supplied, and before coating, component C is mixed with B, and then adds mixing in component A; Certainly,, when component C does not exist, only component B need to be added component A to mix; The existence of component C, can configure the color of coating neatly, is applied in the occasion of various needs; Certainly, the present invention should be finished after mixing in 8 hours, in order to avoid solidify.
therefore, the present invention has following main beneficial effect: good fluidity, anti-go mouldy and anti-corrosion performance is good, dry, the color matching fast with setting rate of coating flexibly, be convenient to rapid construction, making method is simple, easy to operate, required equipment is simple and easy, do not need the input of a large amount of equipment aspects.
the present invention has passed through following Performance Detection:
Sequence number Interventions Requested Technical requirements Assay Conclusion
1 Condition in container Without lump, after stirring, be uniform state Meet the requirements Qualified
2 Application property Brush two roads accessible Meet the requirements Qualified
3 Low-temperature stability (20 DEG C) Never degenerate Meet the requirements Qualified
4 25 DEG C of set times ≤144h 8h Qualified
5 Appearance of film Normally Meet the requirements Qualified
6 Water-fastness 96h is without extremely Meet the requirements Qualified
7 Acid resistance 48h is without extremely Meet the requirements Qualified
8 Abrasion resistance (inferior) ≥500 3000 Qualified
9 Midew proof When humidity 40%, continuous 60 days without mildew Without mildew Qualified
and the products solidifying time of the prior art generally about 72 hours, therefore, greatly improved set time; In addition, midew proof has also improvement greatly.
the present invention is not limited to above-mentioned preferred forms, should be appreciated that design of the present invention can be by other various forms enforcement utilizations, and they drop in protection scope of the present invention equally.

Claims (3)

1. a skin epoxypaint, is characterized in that it is made up of A component, B component and component C, in parts by weight, meets: component A: component B: component C=(900~1800): (30~50): 1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 8~12 parts, acetone: 12~18 parts, ethylene glycol monobutyl ether: 3~8 parts, commercially available OP-10 type emulsifying agent: 1~3 part, sodium hydroxide: 0.1~0.3 part, ethanol: 30~50 parts, deionized water: 70~100 parts, titanium dioxide: 140~180 parts, zinc sulfide white: 35~45 parts; Component B counts by weight, includes following material and content: coating curing agent: 3~5 parts, daconil M: 2~4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein viridescent or phthalein are blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
The first step: make component A: first ratio takes epoxy resin by weight: 8~12 parts, acetone: 12~18 parts, ethylene glycol monobutyl ether: 3~8 parts, commercially available OP-10 type emulsifying agent: 1~3 part, sodium hydroxide: 0.1~0.3 part, ethanol: 30~50 parts, deionized water: 70~100 parts, titanium dioxide: 140~180 parts, zinc sulfide white: 35~45 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75~85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 140~180 parts, zinc sulfide white: 35~45 parts add initial latex to stir to obtain A component emulsion together; Pack A component emulsion into the component A that gets product in packaging vessel;
Second step: make component B: ratio takes the various raw materials of component B mixing and stirring and packs container into and obtain finished product component B by weight;
The 3rd step: according to component A: component B: component C=(900~1800): (30~50): 1 weight ratio takes component C and inserts the component C that gets product in container; And rationally take in proportion component A and component B;
The 4th step: by the 3rd step, claim finished product component C insert in finished product component B, fully stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
2. a skin epoxypaint, is characterized in that it is made up of A component, B component and component C, in parts by weight, meets: component A: component B: component C=1125:35:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 10 parts, acetone: 15 parts, ethylene glycol monobutyl ether: 5 parts, commercially available OP-10 type emulsifying agent: 2 parts, sodium hydroxide: 0.2 part, ethanol: 40 parts, deionized water: 90 parts, titanium dioxide: 160 parts, zinc sulfide white: 40 parts; Component B counts by weight, includes following material and content: coating curing agent: 4 parts, daconil M: 3 parts; Component C is ultramarine or phthalocyanine blue or phthalein viridescent or the blue or green red or bright red formula of phthalein; Skin epoxypaint described above, it prepares by the following method:
The first step: make component A: first ratio takes epoxy resin by weight: 10 parts, acetone: 15 parts, ethylene glycol monobutyl ether: 5 parts, commercially available OP-10 type emulsifying agent: 2 parts, sodium hydroxide: 0.2 part, ethanol: 40 parts, deionized water: 90 parts, titanium dioxide: 160 parts, zinc sulfide white: 40 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75~85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 160 parts, zinc sulfide white: 40 parts add initial latex to stir to obtain A component emulsion together; Pack A component emulsion into the component A that gets product in packaging vessel;
Second step: make component B: ratio takes the various raw materials of component B mixing and stirring and packs container into and obtain finished product component B by weight;
The 3rd step: according to component A: the weight ratio of component B: component C=1125:35:1 takes component C and inserts the component C that gets product in container; And rationally take in proportion component A and component B;
The 4th step: by the 3rd step, claim finished product component C insert in finished product component B, fully stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
3. according to claim 1 or a kind of skin epoxypaint claimed in claim 2, it is characterized in that described coating curing agent is the epoxy curing agent D-230 of DSM Di Suo company production or the solidifying agent EC-301 of D-400 or the production of BASF Chemical Co., Ltd..
CN201310049134.8A 2013-02-07 2013-02-07 Epoxy resin coating for exterior wall of building Active CN103058584B (en)

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CN201410135157.5A CN103880334B (en) 2013-02-07 2013-02-07 A kind of skin epoxypaint
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CN103555103A (en) * 2013-10-16 2014-02-05 苏州瑞邦塑胶有限公司 Novel environment-friendly thermal insulation anti-corrosive coating
CN104559484A (en) * 2015-01-05 2015-04-29 王红玉 Coating for external wall of building
CN106082880A (en) * 2016-06-27 2016-11-09 青岛华联装饰工程有限公司 A kind of environmental protection flame retardant architectural decoration coating material and preparation method thereof

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CN102850878A (en) * 2012-08-31 2013-01-02 芜湖县双宝建材有限公司 Weather-resistant exterior wall paint and preparation method thereof

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Publication number Priority date Publication date Assignee Title
WO2005063880A1 (en) * 2003-12-30 2005-07-14 Sang Yang Kim Epoxy resin mortar composition and a method of coating the same on concrete surface
CN102352161A (en) * 2011-08-25 2012-02-15 杭州传化涂料有限公司 Water-based primer-topcoat in one type paint
CN102702920A (en) * 2012-06-12 2012-10-03 中国科学院长春应用化学研究所 Aqueous polyaniline anti-corrosive paint and preparation method thereof
CN102850878A (en) * 2012-08-31 2013-01-02 芜湖县双宝建材有限公司 Weather-resistant exterior wall paint and preparation method thereof

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