CN103053868A - Compound acidity regulator for silage and use method thereof - Google Patents

Compound acidity regulator for silage and use method thereof Download PDF

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CN103053868A
CN103053868A CN2013100402077A CN201310040207A CN103053868A CN 103053868 A CN103053868 A CN 103053868A CN 2013100402077 A CN2013100402077 A CN 2013100402077A CN 201310040207 A CN201310040207 A CN 201310040207A CN 103053868 A CN103053868 A CN 103053868A
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ensilage
silage
conditioning agent
ensiling
fermentation
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王海东
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Shanghai Sanwei Tongli Bio Tech Co ltd
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Shanghai Sanwei Tongli Bio Tech Co ltd
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Abstract

The invention relates to a compound acidity regulator for silage and a using method thereof, which is characterized in that: the composite acidity regulator for silage comprises, by weight, 50-65% of propionic acid, 5-10% of formic acid, 20-30% of sodium benzoate and 0-25% of water. The composite acidity regulator is used for regulating the acidity of various silage, and the addition amount of the composite acidity regulator in the silage is 2-5L/ton. The product of the invention has the advantages of accelerating the silage acidification process, shortening the silage period, preventing the problems of poor fermentation and secondary fermentation of silage after opening the cellar, preserving silage nutrients to the maximum extent, improving the digestibility and improving the quality of the silage, and further promoting the improvement of milk yield of dairy cows and the fattening performance of beef cattle and mutton sheep.

Description

A kind of ensilage combined acidity conditioning agent and using method thereof
Technical field
The present invention relates to a kind of feed combined acidity conditioning agent, particularly disclose a kind of ensilage with combined acidity conditioning agent and using method thereof, belong to feed additive field.Preparation of the present invention can be used as silage additive and uses, can make ensilage not be subjected to the impact of type of feed, weather conditions, moisture content of raw material etc., have the ensiling of acceleration acidization and shorten the ensiling cycle, prevent the secondary fermentation problem after bad fermentation and ensilage are opened the cellar for storing things, preserve to greatest extent the ensilage nutriment, improve digestibility and improve the ensilage quality, and then promote the raising of milk production of cow and promote the finishing ability of beef cattle, mutton sheep.
Background technology
Successfully modulating high-quality and stable all kinds of herbages and cereal ensilage, is the decisive prerequisite that milk cow, beef cattle, mutton sheep aquaculture, dairy industry and animal husbandry are enhanced competitiveness.Although Sativa Silage Technology has had huge advance made at present, but still have the secondary fermentation problem after always also having bad fermentation and open the cellar for storing things in about 1/3rd all kinds of herbages and the cereal ensiling, these bad fermentations and secondary fermentation greatly reduce the feed value of ensiling, animal feed intake is reduced, the basal feed production capacity descends, and all kinds of mycotoxins that secondary fermentation produces also can cause potential security threat to human health by food chain.In addition, though tradition Silaging method or to add merely the lactobacillus preparation ensiling effective to the high raw material of solubility sugar content, and can't realize effective ensiling to all kinds of herbages and the cereal of low solubility sugar content and high protein because of its stronger buffer capacity, although artificially can effectively guarantee in theory the ensiling modulated process of low solubility sugar content and high protein raw material by the mode of mending pure interpolation molasses, but the situation of reality is the expection of the non-theory of additive effect of molasses, practical application is but effectively verified, and the interpolation of molasses not only needs high cost, in addition also comparatively inconvenience of its production operation needs extraordinary operating equipment and special expense expenditure.
Present stage all kinds of herbages and cereal ensilage Main Problems comprise following several aspect:
(1) the bad fermentation problem of herbage and cereal ensiling
The ensilage of all kinds of herbages and cereal is owing to being subjected to the wherein impact of butyric acid and the bad fermentation of butyric acid to pollute with the phenomenon of clostridial toxin very general, during ensiling, this bad fermentation is difficult to avoid the herbage that particularly sugar content is lower (such as alfalfa, Bai Sanye, rye grass etc.) in the higher situation of humidity.Owing to be subjected to soil pollution or be entrained with withered plant component, it is larger that clostridium enters the possibility of making raw material, and then the risk of this bad fermentation is higher.Clostridium can produce endospore through still in vivo survival behind the milk cow digestive system, and excretes by ight soil and to come back to the field.Constantly propagate whereby and circular regeneration.Shuttle shape gemma has the protection heavy wall, has heat-resisting, cold-resistant and chemically-resistant thing characteristic, can survive under adverse circumstances, and suitably germinate and continuation breeding growth under the environment.The ability tanacity because clostridium lives again, milk is infected after milking in (Room) even the picked-up of a small amount of dirt also is transferred to cow breast, causing lactation.Thereby cause the variety of issue in the processing of milk and dairy products.Because the clostridium route of transmission at first is to enter in the Contents in Cows through the grass silage material, so from start with at all, the measure that improves the ensilage health is indispensable.
(2) ensilage is opened the secondary fermentation problem behind the cellar for storing things
Successful silage fermentation can keep enough stability after opening the cellar for storing things, even serious heat production phenomenon does not occur yet in excess Temperature ensilage inside.The situation of reality is for owing to not having interpolation or only adding the ensilage that simplicity microorganism ensiling agent reduces pH-value rapidly, has the problem that can keep the stable acetic acid of ensiling to lack.Although such ensiling is well fermented, but may generate heat rapidly owing to entering heavily again of air after opening the cellar for storing things, if particularly have in the whole cellar for storing things residual " air-bed " (usually since shed inhomogeneous, prescind not or compacting not tight), air can take advantage of the occasion to invade, the harmfulness saccharomycete is bred rapidly, its aerobic respiration decomposing lactic acid, and the pH value raises heavily again in the ensiling container, mycotic spore begins rudiment, thus the ensilage moldy metamorphism.If in conjunction with slower feeding speed, lasting high temperature, a large amount of nutrient losss, the discarded waste of feed and the low-quality of feed then are inevitable.If highly polluted ensilage is then more dangerous as the mixing companion of complete mixed daily ration TMR, because it can be diffused into saccharomycete and mould in all the other mixed feeds again in mixing very soon.
(3) add merely the limitation of lactobacillus preparation ensiling
Though adding, lactobacillus preparation is the ensilage modulation, especially high to solubility sugar sugar content crop ensiling (such as corn etc.) provides the lactic acid bacteria that occupies predominance, and promote fermentation and acid and reduce rapidly ensilage pH, the risk that effectively stops bad fermentation, but all kinds of ensilages lack screening system and seed selection with the lactobacillus preparation bacterial classification in the market, bacterial classification is relatively backward, it is limited to produce acid and acid resistance, resistance is looked into, unstable properties, to low solubility sugar content, all kinds of herbages such as the alfalfa that are difficult for ensiling of high protein, Bai Sanye, the ensilings such as rye grass can't realize successfully modulating, and the poor stability behind the Yin Qikai cellar for storing things, especially can't effectively avoid the secondary fermentation problem of ensilage at high temperature season.
(4) herbage and cereal add the limitation of molasses ensiling
Ensilage artificially adds the non-theoretical expection of actual effect of molasses, has following limitation or problem:
1, the extra molasses that add have been proved to be intimate invalid in the ensilage.Because molasses also are of value to the breeding of the harmful bacteria that ferments, can excite butyric acid fermentation and cause fermentation bad.Simultaneously, molasses also can make ensilage " inoculation " infection saccharomycete, mould etc. cause secondary fermentation, and silage fermentation is caused negative effect;
2, the monose that contains in the molasses and disaccharide be not whole decomposition and inversion be lactic acid, add molasses and do not increase the ensiling energy content;
3, the theoretical addition of molasses is about ensilage 30kg per ton.Therefore, its interpolation is with high costs;
4, the dosage apparatus of molasses interpolation is complicated, costly, and the operation process sanitary condition is not good enough after molasses adding procedure and the interpolation.
(5) the domestic ensilage development and utilization situation of acidity regulator
Ensilage need be considered many complicated factors such as moisture characteristics (general 65-70%), type of feed (solubility sugar content, cushion effect etc.), weather conditions of ensiling raw material with acidity regulator exploitation, Current Domestic is almost developed without system research.Collaborative composite by between the organic acid such as propionic acid, formic acid, Sodium Benzoate and the salt thereof of the present invention, a kind of ensilage combined acidity conditioning agent that provides in conjunction with special processing technology, can effectively overcome all kinds of problems that exist in the above-mentioned present ensiling modulated process, make ensilage not be subjected to the impact of type of feed, weather conditions, moisture content of raw material etc., have the ensiling of acceleration acidization and shorten the ensiling cycle, avoid bad fermentation and the secondary fermentation problem of ensilage, guarantee fine quality and the aerobic stability of ensilage; In addition, can effectively solve the ensiling modulation difficult problem of low solubility sugar, high protein ensiling raw material (cushion effect is strong), and then promote the raising of milk production of cow and promote the finishing ability of beef cattle, mutton sheep, the economic benefit of promoting livestock-raising.
Summary of the invention
The objective of the invention is the problem for above-mentioned prior art existence, a kind of ensilage combined acidity conditioning agent and using method thereof are provided, preparation of the present invention can be used as silage additive and uses, can make ensilage not be subjected to type of feed, weather conditions, the impact of moisture content of raw material etc., have the ensiling of acceleration acidization and shorten the ensiling cycle, prevent the secondary fermentation problem after bad fermentation and ensilage are opened the cellar for storing things, preserve to greatest extent the ensilage nutriment, improve digestibility and improve the ensilage quality, and then promote the raising of milk production of cow and promote beef cattle, the finishing ability of mutton sheep.
The present invention is achieved in that a kind of ensilage combined acidity conditioning agent, it is characterized in that: described ensilage is that propionic acid 50-65%, formic acid 5-10%, Sodium Benzoate 20-30%, water are 0-25% with the composition of combined acidity conditioning agent and percentage by weight.
Form and part by weight by above-mentioned raw materials of the present invention, accurately take by weighing first in propionic acid, the water input Stainless steel 316 L reactor, at normal pressure, 80-90 0Slowly uniformly Sodium Benzoate is dropped under C and the reactor rotating shaft rotating speed 200rpm condition, through fully again formic acid being dropped into behind dissolving, the chemical reaction 1-1.5h, continue dissolving, chemical reaction 0.5-1h until mixed liquor becomes the homogeneity settled solution, namely make ensilage of the present invention combined acidity conditioning agent product.
Ensilage provided by the invention is the effective ensiling that realizes all kinds of herbages and cereal with the combined acidity conditioning agent, takes into full account and has satisfied following at least key point:
1. damping characteristics: the ensiling raw material is because of the 65-70% high moisture content, must guarantee good damping characteristics after adding acidity regulator, can not affect acidity regulator because of the change of raw material moisture to the regulation and control of pH stability, accelerate ensiling acidization and ensilage, reduce the fermentation loss of nutriment, avoid bad fermentation, improve Silage Quality;
2. slowly-releasing and antiseptic and inhibiting bacteria function characteristic: the sour environment of ensilage is conducive to the slow release of ensilage acidity regulator, with the secondary fermentation problem of effective prevention ensilage, continues to guarantee ensiling stability.
Described ensilage is when to be propionic acid 60%, formic acid 10%, Sodium Benzoate 30% and described ensilage with the composition of combined acidity conditioning agent and percentage by weight be propionic acid 65%, Sodium Benzoate 30%, formic acid 5% with the composition of combined acidity conditioning agent and percentage by weight, and ensilage of the present invention with the physicochemical characteristics of combined acidity conditioning agent is: a. density range is 1.05-1.16g/cm 3B. PHScope is 3.2-3.5; C. 1% aqueous solution PHBe 3.5 +0.2; 0.5% aqueous solution PHBe 3.6 +0.2.
When described ensilage was propionic acid 50%, Sodium Benzoate 25%, water 25% with the composition of combined acidity conditioning agent and percentage by weight, ensilage of the present invention with the physicochemical characteristics of combined acidity conditioning agent is: a. density range was 1.02-1.15g/cm 3B. PHScope is 4.1-4.5; C.1% the aqueous solution PHBe 4.0 +0.2; 0.5% aqueous solution PHBe 3.5 +0.2.
Ensilage of the present invention is supernatant liquid with the combined acidity conditioning agent, and it is 2-5L/ ton ensiling raw material as the addition that silage additive uses.Described ensiling raw material comprises all kinds of herbages and cereal, such as leguminous forage (alfalfa, Bai Sanye etc.), graminous pasture, maize straw etc.
The invention has the beneficial effects as follows:
1. after adding this product, the pH value can reduce rapidly in the ensiling, and the silage fermentation process can be subject to guiding energetically regulation and control, can improve correction under the undesirable situation of natural conditions, makes ensiling reach best yeastiness;
2. effectively solve low solubility sugar content and all kinds of herbages of high protein and cereal can't be realized effective ensiling because of its stronger buffer capacity reality, not only can save molasses and add, and can additionally not obtain than ensiling raw material the energy of 0.3-0.5 megajoule through the control group of any processing;
3. the science of propionic acid, formic acid, Sodium Benzoate etc. is composite, make it to have wide fungistatic effect by synergy, can extremely strong inhibition saccharomycete and mould, the secondary fermentation problem after effectively stoping the bad fermentation in the ensilage and opening the cellar for storing things guarantees fine quality and the stability of ensilage;
4. the best acylate buffer system of the composite formation such as propionic acid, formic acid, Sodium Benzoate makes its basic nonirritant and utmost point weak erosive and low volatility is only arranged, and can continue to keep effectiveness at whole duration of storage;
5. reduce the absorption to mycotoxin of milk cow, beef cattle and mutton sheep, alleviated immune burden, guaranteed the safe and sanitary of milk and beef and mutton.Because reduced the quantity that might invade the mycotoxin in the animal body when mould reduces, promote body to strengthen the concentrated of nutriment digested and assimilated, it is undisturbed to make self detoxification purify the adjusting process, has avoided the propagation of mycotoxin through food chain;
6. whether weatherproof makes the in good time harvesting possibility that becomes, and significantly shortens air-dry/airing time, need not to consider dry matter content immediately ensiling up to standard.
Second purpose of the present invention is to provide the using method of a kind of ensilage with the combined acidity conditioning agent, a kind of ensilage of the present invention is supernatant liquid with the combined acidity conditioning agent, and it is 2-5L/ ton ensiling raw material as the addition that silage additive uses.Described ensiling raw material comprises all kinds of herbages and cereal.
The specific embodiment
Introduce in detail the present invention below in conjunction with embodiment, described embodiment is used for understanding and also unrestricted the present invention.
Embodiment 1:
This experimental example uses the combined acidity conditioning agent on the impact of Alfalfa Silage Fermentation Quality for implementing a kind of ensilage, and the impact of aerobic stability.Ensilage is propionic acid 60%, formic acid 10% and Sodium Benzoate 30% with composition and the weight ratio of combined acidity conditioning agent.Form and part by weight by above-mentioned raw materials provided by the invention, accurately take by weighing first propionic acid and drop in the Stainless steel 316 L reactor, at normal pressure, 80-90 0Slowly uniformly Sodium Benzoate is dropped under C and the reactor rotating shaft rotating speed 200rpm condition, through fully again formic acid being dropped into behind dissolving, the chemical reaction 1-1.5h, continue dissolving, chemical reaction 0.5-1h until mixed liquor becomes the homogeneity settled solution, namely make ensilage of the present invention combined acidity conditioning agent product.
Prescind after this test cradles the initial bloom stage clover to the 3cm, test is divided into 5 processing at random, i.e. 1. negative control: alfalfa (not adding any additives for ensiling); 2. lactic acid bacteria is organized: alfalfa+50g lactic acid bacteria/ton; 3. formic acid group: alfalfa+5L formic acid/ton; 4. cane molasses group: alfalfa+20L cane molasses/ton; 5. combined acidity conditioning agent group: alfalfa+3L/ ton combined acidity conditioning agent, 6 repetitions of every processing, every repetition 10kg.
1, materials and methods
1.1 ensiling raw material
Tame alfalfa is the ensiling raw material, and initial bloom stage cradles, and prescinds to the 3cm.
1.2 additives for ensiling
Lactic acid bacteria, formic acid, cane molasses, and combined acidity conditioning agent (the invention provides).
1.3 experimental design
It is 4 processing that this test is divided into, 6 repetitions of every processing, and every repetition 10kg, test respectively is treated to:
1. negative control: alfalfa (not adding any additives for ensiling);
2. lactic acid bacteria is organized: alfalfa+50g lactic acid bacteria/ton;
3. formic acid group: alfalfa+5L formic acid/ton;
4. cane molasses group: alfalfa+20L cane molasses/ton;
5. combined acidity conditioning agent group: alfalfa+3L/ ton combined acidity conditioning agent.
1.4 test method
1.4.1 ensiling is made
The ensiling harvester cradles initial bloom stage alfalfa and moisture is naturally wilting to the rear about 1-2h of airing of 65-70%(harvesting), then with the special-purpose shredding machine of ensiling alfalfa is prescinded grass section to about 3cm, by the adding proportion of setting each additive evenly is sprayed to the Alfalfa Silage surface with spray system simultaneously, interior and the mechanical ramming of the silage barrel of packing into after mixing, every barrel of 10kg, sealed type storage fermentation after 45 days every processing get 3 and repeat out the cellar for storing things sampling and carry out subjective appreciation and physical and chemical index analysis, and the aerobic stability after the 90th day of silage fermentation got every processing the cellar for storing things is opened in 3 replication ensilings in addition.
1.4.2 mensuration project and method
1. subjective appreciation: according to the Ministry of Agriculture " ensilage quality standard ", carry out subjective appreciation from the smell of ensilage, color, quality etc.
2. PHPH-value determination pH: get at random the 10g ensilage behind the silage fermentation, add 90ml distilled water, homogenized 3-5min uses first 4 layers of Coarse Mesh Gauze coarse filtration, and then with measuring filtrate after the smart filter of qualitative filter paper PHValue.Filtrate palpus-20 0C seals preservation, organic acid to be measured and ammoniacal nitrogen;
3. lactic acid, acetic acid, propionic acid and butyric acid adopt high performance liquid chromatography (HPLC) to measure;
4. ammoniacal nitrogen (NH3-N): adopt phenol--hypochlorous acid colorimetric method for determining;
5. after 90 days, carry out the mensuration of aerobic stability in ensiling.Aerobic stability be defined as ensilage in air, expose after its central temperature exceed 2 than ambient temperature 0The needed hourage of C.Sample is placed on room temperature (25 0About C), temperature measuring utilizes thermocouple principle, adopts ZDR humiture recorder, and the thermocouple of each recorder is placed ensiling sample center, and per half an hour is the temperature of record ensilage center automatically.
1.4.3 data analysis
Test data adopts the SPSS16.0 statistical software to carry out variance analysis and multiple ratio.
2. results and analysis
2.1 the subjective appreciation of Alfalfa Silage
See Table 1.Table 1 is the subjective appreciation table of Alfalfa Silage.
Group Subjective appreciation
Negative control Stale flavor, crineous, the quality caking that rots to be clamminess, quality is of inferior quality
The lactic acid bacteria group Stale flavor, crineous, the quality caking that rots to be clamminess, quality is of inferior quality
The molasses group Stale flavor, crineous, the quality caking that rots to be clamminess, quality is of inferior quality
The formic acid group Pungent tart flavour, khaki, quality is viscosity slightly, and quality is general
Test group Comfort acid fragrance, glassy yellow, the loose softness of quality is tack-free, and blade and Stalk structure are complete, and clean mark is best in quality
According to Ministry of Agriculture's " ensilage quality standard " subjective appreciation, negative control, lactic acid bacteria group and molasses group Alfalfa Silage all are crineous, and quality is rotted and the caking that is clamminess, the remarkable stale flavor of tool, and fermentation quality is of inferior quality; The formic acid group is khaki, the tool tart flavour that is pungent, and quality is viscosity slightly, and fermentation quality is general; Combined acidity conditioning agent group ensilage provided by the invention is glassy yellow, and the loose softness of quality is tack-free, and blade and Stalk structure are complete, and clean mark shows that its fermentation quality is good.
2.2 the fermentation quality of Alfalfa Silage
See Table 2.Table 2 is the fermentation quality table of Alfalfa Silage.
Figure 2013100402077100002DEST_PATH_IMAGE002
Remarks: same column shoulder indicate same letter person's difference not significantly ( P>0.05), adjacent letters person's significant difference ( P<0.05), alternate alphabetical person's difference extremely significantly ( P<0.01).
Secondly result of the test shows that negative control group and molasses group pH value are the highest, and test group pH value is minimum, is the formic acid group, between the two significant difference ( P<0.05); The lactic acid content test group is the highest, secondly be the formic acid group ( P<0.05), test group and other each group difference extremely significantly ( P<0.01); Propionic acid content lactic acid bacteria group is the highest, secondly negative control group and molasses group, test group and formic acid group minimum ( P<0.01); Butyric acid content test group is minimum, itself and each group difference extremely significantly ( P<0.01), molasses group butyric acid content is the highest, negative contrast and lactic acid bacteria group secondly, both butyric acid content quite ( P>0.05); NH 3-N/TN negative control group apparently higher than other each group ( P<0.05) or ( P<0.01), test group is minimum, the formic acid group is taken second place, two group differences extremely significantly ( P<0.01).
2.3 the aerobic stability of Alfalfa Silage
See Table 3.Table 3 is the aerobic stability table of Alfalfa Silage.
Group Aerobic stability (h)
Negative control 48
The molasses group 52
The lactic acid bacteria group 55
The formic acid group 115
Test group 226
Result of the test shows, negative control group, molasses group and lactic acid bacteria group aerobic stability are approximate, are respectively 48h, 52h and 55h, between three groups without significant difference; Formic acid group aerobic stability is 115h, and test group stability is the highest, reaches 226h, is significantly higher than other each group.
3. conclusion
3.1 alfalfa is low as its solubility sugar content of main protide herbage, buffer capacity is strong, directly ensiling or add merely lactic acid bacteria or molasses are difficult to play the effect of fermentation assistant, and Alfalfa Silage Fermentation Quality is without obvious improvement.
3.2 the Medicago Sativa Silage process is added formic acid with respect to direct ensiling ferment or is added lactic acid bacteria, molasses ensiling, can improve to a certain extent the fermentation quality of Medicago Sativa Silage, but the improvement degree is limited, because acetic acid, butyric acid and NH that fermentation produces 3-N/TN content is higher, therefore, the alfalfa inferior quality of fermentation, stale flavor is heavier, and the nutriment loss is serious.
3.3 add the difficult problem that combined acidity conditioning agent of the present invention can effectively solve Medicago Sativa Silage, significantly improved the Medicago Sativa Silage fermentation quality, effectively avoided the bad sweat of ensiling to produce a large amount of acetic acid, butyric acid and NH 3-N/TN, fragrant odour be without corruption, the loose softness of quality, and blade and Stalk structure are complete, clean mark, good palatability, the nutriment loss is few.
Can effectively solve secondary fermentation problem after Medicago Sativa Silage is opened the cellar for storing things 3.4 add combined acidity conditioning agent of the present invention, have preferably aerobic stability, effectively stop Alfalfa Silage moldy metamorphism phenomenon in use.
The inventor to combined acidity conditioning agent provided by the invention simultaneously in Bai Sanye, red clover, rye grass, corn strain, and carried out single ensiling test on the herbage such as maize straw and the cereal, be applied to simultaneously the mixed silage ensilage of leguminous forage and other herbage or cereal, all obtain the result who is similar to.
Embodiment 2:
Ensilage of the present invention is propionic acid 65%, Sodium Benzoate 30%, formic acid 5% with composition and the percentage by weight of combined acidity conditioning agent.
The ensilage that embodiment 1 and embodiment 2 make with the physicochemical characteristics of combined acidity conditioning agent is: a. density range is 1.05-1.16g/cm 3B. PHScope is 3.2-3.5; C. 1% aqueous solution PHBe 3.5 +0.2; 0.5% aqueous solution PHBe 3.6 +0.2.
Embodiment 3:
Ensilage of the present invention is propionic acid 50%, Sodium Benzoate 25%, water 25% with composition and the percentage by weight of combined acidity conditioning agent, and the ensilage of acquisition with the physicochemical characteristics of combined acidity conditioning agent is: a. density range is 1.02-1.15g/cm 3B. PHScope is 4.1-4.5; C.1% the aqueous solution PHBe 4.0 +0.2; 0.5% aqueous solution PHBe 3.5 +0.2.

Claims (8)

1. ensilage combined acidity conditioning agent is characterized in that: described ensilage is that propionic acid 50-65%, formic acid 5-10%, Sodium Benzoate 20-30%, water are 0-25% with the composition of combined acidity conditioning agent and percentage by weight.
2. a kind of ensilage combined acidity conditioning agent according to claim 1, it is characterized in that: described ensilage is propionic acid 60%, formic acid 10%, Sodium Benzoate 30% with composition and the percentage by weight of combined acidity conditioning agent.
3. a kind of ensilage combined acidity conditioning agent according to claim 1, it is characterized in that: described ensilage is propionic acid 65%, Sodium Benzoate 30%, formic acid 5% with composition and the percentage by weight of combined acidity conditioning agent.
4. a kind of ensilage combined acidity conditioning agent according to claim 1, it is characterized in that: described ensilage is propionic acid 50%, Sodium Benzoate 25%, water 25% with composition and the percentage by weight of combined acidity conditioning agent.
5. according to claim 2 or 3 described a kind of ensilage combined acidity conditioning agents, its physicochemical characteristics:
Density 1.05-1.16g/cm 3
PH value 3.2-3.5.
6. a kind of ensilage combined acidity conditioning agent according to claim 4, its physicochemical characteristics:
Density 1.02-1.15g/cm 3
PH value 4.1-4.5.
7. the described ensilage of any one combined acidity conditioning agent according to claim 1~6, it is characterized in that: described ensilage is homogeneity liquid with the combined acidity conditioning agent.
8. one kind contains the described ensilage of any one in the claim 1~4 with the using method of combined acidity conditioning agent, it is characterized in that described combined acidity conditioning agent is used for all kinds of ensilage acidity adjustment, its addition in ensilage is 2~5L/ ton.
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CN104286604A (en) * 2014-10-11 2015-01-21 中国农业科学院草原研究所 Alfalfa fresh grass storage additive and preparation method thereof
CN104920811A (en) * 2015-05-11 2015-09-23 江苏奥迈生物科技有限公司 Feed acidity regulator and preparation method thereof
CN106562001A (en) * 2015-10-08 2017-04-19 中创云牧科技咨询(北京)股份有限公司 Medicago sativa silaging method and additive for medicago sativa silaging
CN109430539A (en) * 2018-12-28 2019-03-08 潍坊加易加生物科技有限公司 A kind of silage fermentation promotor and preparation method thereof and its application
CN109717302A (en) * 2019-01-30 2019-05-07 四川爱客信生物科技股份有限公司 The organic additive and its application method of ensilage and TMR anti-mildew fresh-keeping
CN110338357A (en) * 2019-08-13 2019-10-18 吴仲春 Maize acid method for making fried meat
CN110338282A (en) * 2019-08-13 2019-10-18 兰州大学 A kind of compound additive and its preparation method and application being used to prepare high-moisture ensilage
CN112335785A (en) * 2020-10-21 2021-02-09 宜宾学院 Acidifier and preparation method and application thereof
CN112617087A (en) * 2021-01-08 2021-04-09 中国农业科学院饲料研究所 Secondary fermentation inhibitor for silage

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CN104286604A (en) * 2014-10-11 2015-01-21 中国农业科学院草原研究所 Alfalfa fresh grass storage additive and preparation method thereof
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CN106562001A (en) * 2015-10-08 2017-04-19 中创云牧科技咨询(北京)股份有限公司 Medicago sativa silaging method and additive for medicago sativa silaging
CN109430539A (en) * 2018-12-28 2019-03-08 潍坊加易加生物科技有限公司 A kind of silage fermentation promotor and preparation method thereof and its application
CN109717302A (en) * 2019-01-30 2019-05-07 四川爱客信生物科技股份有限公司 The organic additive and its application method of ensilage and TMR anti-mildew fresh-keeping
CN110338357A (en) * 2019-08-13 2019-10-18 吴仲春 Maize acid method for making fried meat
CN110338282A (en) * 2019-08-13 2019-10-18 兰州大学 A kind of compound additive and its preparation method and application being used to prepare high-moisture ensilage
CN112335785A (en) * 2020-10-21 2021-02-09 宜宾学院 Acidifier and preparation method and application thereof
CN112335785B (en) * 2020-10-21 2024-01-05 宜宾学院 Acidulant and preparation method and application thereof
CN112617087A (en) * 2021-01-08 2021-04-09 中国农业科学院饲料研究所 Secondary fermentation inhibitor for silage

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