CN103053587B - Insecticide/bactericide composition containing dinotefuran and azoxystrobin and application thereof - Google Patents
Insecticide/bactericide composition containing dinotefuran and azoxystrobin and application thereof Download PDFInfo
- Publication number
- CN103053587B CN103053587B CN201110321791.4A CN201110321791A CN103053587B CN 103053587 B CN103053587 B CN 103053587B CN 201110321791 A CN201110321791 A CN 201110321791A CN 103053587 B CN103053587 B CN 103053587B
- Authority
- CN
- China
- Prior art keywords
- mti
- fluoxastrobin
- insecticide
- bactericidal composition
- composition containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an insecticide/bactericide composition containing dinotefuran and azoxystrobin and application thereof. The insecticide/bactericide composition takes dinotefuran and azoxystrobin as main active ingredients, wherein the weight ratio of dinotefuran to azoxystrobin is (0.1-85):(0.5-75). The insecticide/bactericide composition has the beneficial effects that the insecticide/bactericide composition can have higher synergy and is especially suitable for controlling diseases caused by crop pests and various fungi; the dosage of the mixture is greatly reduced compared with that of the independent active compound; the drug dosage is reduced in practical application and then the drug cost is reduced; the insecticide/bactericide composition can control the diseases caused by hemiptera, lepidoptera and coleoptera pests on the crops and fungi; and besides, the composition is also especially suitable for treating seeds and protecting the seeds from the diseases after germination.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of composite insecticidal bactericidal composition containing MTI-446 and Fluoxastrobin and uses thereof.
Background technology
MTI-446 (dinotefuran) is the third generation nicotinic insecticide of Mitsui chemical company exploitation.The chemical constitution of itself and existing nicotinic insecticide is far from each other, and chloro-pyridine base, chloro thiazolyl before its tetrahydrofuran base has replaced, containing halogen.Meanwhile, also different with nicotine at aspect of performance.So people are referred to as " furans nicotine " at present.MTI-446 chemical name: 1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine.
A new generation's anabasine insecticide MTI-446 Main Function, in insect neurotransmission system, makes insect paralysis dead.This medicament insecticidal spectrum is wide, has remarkable interior suction osmosis, and has shown very high insecticidal activity at very low dosage.This medicament is fool proof to mammal, birds and aquatile, and crop, without poisoning, be can be used for to numerous crops such as paddy rice, fruit tree, vegetables.To rice grub brown planthopper, white-backed planthopper, small brown rice planthopper, rice leafhopper, rice spider rafter stinkbug, star stinkbug, green rice bug resemble, red must fleahopper, the negative mixed worm of rice, rice cylinder water snout moth's larva be efficient.Effective to striped rice borer, oryza chinensis class.Efficient to vegetables, fruit insect Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving.The cured a red-spotted lizard in diagonal angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza are effective.MTI-446 has very wide insecticidal spectrum, and fool proof again to crop, people and animals and environment, then is equipped with the using method of various uses, this agricultural chemicals large-tonnage agricultural chemicals that is expected to become international.
Fluoxastrobin (Azoxystrobin), Chinese: (E)-[2-[6-(2-cyano-benzene oxygen) pyrimidine-4-yl oxygen] phenyl]-3-methoxy-methyl acrylate, be first commercial methoxy acrylic bactericide that Syngenta Co.,Ltd succeeds in developing, structural formula is as follows:
The mechanism of action: mitochondrial respiratory inhibitor, is shifted and is suppressed mitochondrial breathing by electronics between cytochrome b and C1.Extranuclear mitochondria mainly by respiration for cell provides energy ATP, if mitochondrial respiratory is obstructed, can not produce ATP, can cause cell death.The bacterial strain that 14-demethylation enzyme inhibitor, benzamides, three carboxyl acylamides and benzimidazole is produced to resistance is effective.Use crop: cereal crop, paddy rice, peanut, grape, potato, vegetables, coffee, fruit tree (oranges and tangerines, apple, banana, pears etc.), lawn etc.Under recommended dose, to crop safety, without key, but some apple variety is had to poisoning.To underground water, Environmental security.Controlling object: Fluoxastrobin has the bactericidal activity of wide spectrum, all has good activity to nearly all Mycophytes (Ascomycetes, Basidiomycetes, Oomycete and deuteromycetes) disease as tens of kinds of diseases such as powdery mildew, rust, glume blight, net blotch, scab, downy mildew, rice blast.Can be used for cauline leaf spraying, seed treatment, also can carry out the processing of scholar's earth.
Under the condition of long-term single drug, target increases gradually to the resistance of medicament, and agricultural chemicals single dose can decline gradually to the effect of control of insect, greatly shortens the service life of a good medicament.Inventor finds after deliberation, and the Synergistic of agricultural chemicals is composite to be expanding prevention spectrum and to improve the effective measures that preventive effect extends the medicament pot life, and not yet finds up to now the insecticidal and bactericidal composition patent of relevant MTI-446 and Fluoxastrobin.
Summary of the invention
The object of this invention is to provide a kind of high-efficiency low-toxicity composite insecticidal bactericidal composition containing MTI-446 and Fluoxastrobin, this Pesticidal combination be control Semiptera, coleoptera, lepidoptera pest and fungal disease multifunctional insecticide bactericidal composition.
Another object of the present invention is to provide this insecticidal and bactericidal composition and prevents and treats the application on resistance Semiptera, coleoptera, lepidoptera pest and various fungal disease pesticide-germicide medicine in preparation, particularly the application on the pesticide-germicide medicine of preparation control rice fulgorid, leafhopper, stinkbug, aleyrodid, aphid and powdery mildew, rust, glume blight, net blotch, downy mildew, rice blast.
The object of the invention is to be achieved through the following technical solutions:
Containing a high-efficiency low-toxicity composite insecticidal bactericidal composition for MTI-446 and Fluoxastrobin, it is main active ingredient that this insecticidal and bactericidal composition be take MTI-446 and Fluoxastrobin, and wherein, the weight ratio of MTI-446 and Fluoxastrobin is 0.1～85: 0.5～75.In this insecticidal and bactericidal composition, effective ingredient is present in composition with synergy effective dose.
In this potentiating pesticidal bactericidal composition, the weight ratio of MTI-446 and Fluoxastrobin preferably 0.5～50: 2～50, and more preferably 0.5～10: 4～30, most preferably be 1～10: 20～30.
In the present composition, the two percentage by weight that accounts for composition of MTI-446 and Fluoxastrobin is 3～80%.Be preferably 5～50%, most preferably 10～40%.
Insecticidal and bactericidal composition of the present invention be take MTI-446 and Fluoxastrobin and is mixed with any one formulation allowing on agricultural chemicals, the preferred emulsion of described formulation, suspending agent, wetting powder, aqueous emulsion, microemulsion and water dispersion granule as main active ingredient and insecticides adjuvant and excipient.
Auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), the one or more combinations in polyoxyethylene nonylphenol ether, excipient comprises isopropyl alcohol, solvent naphtha, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and use.
This insecticidal and bactericidal composition can produce higher synergistic function, be specially adapted to prevent and treat crop pest and various fungus-caused disease, and the consumption of the independent reactive compound of amount ratio of this mixture reduces greatly, be the activity that the activity of mixture is greater than independent component, can suppress the drug-fast generation to unitary agent (MTI-446 and Fluoxastrobin are arbitrary) of insect or fungi.In practical application, reduce dosage, and then reduced drug cost.The present invention can prevent and treat Semiptera, Lepidoptera, coleopteran pest or the fungal disease occurring on crops, especially can be used for preventing and treating rice fulgorid, leafhopper, aphid, stinkbug, aleyrodid and powdery mildew, rust, glume blight, net blotch, downy mildew, rice blast etc., its successful is used higher than its single dose." % " of the present invention is mass percent.Therefore, the present composition is prevented and treated in preparation on the pesticide-germicide medicine of resistance Semiptera evil, Lepidoptera, coleopteran pest or fungal disease and is applied, and particularly in preparation, anti-ly eliminates aphis, applies on the pesticide-germicide medicine of aleyrodid, leafhopper, stinkbug, plant hopper or powdery mildew, rust, glume blight, net blotch, downy mildew, rice blast.
Beneficial effect of the present invention compared with prior art: (1) is compared with single dose, said composition antagonism Semiptera, coleoptera, lepidoptera pest have obvious synergistic function as fungal diseases such as powdery mildew, rust, glume blight, net blotch, downy mildew, rice blast as rice fulgorid, leafhopper, aphid and fungal disease, overcome and delayed pesticide resistance, expanding prevention spectrum, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative high-toxic pesticide; (4) have the effect of controlling worm and diseases prevention concurrently; (5) compare with Fluoxastrobin single dose with MTI-446, produce and use cost reduction; (6) suppress Semiptera, coleoptera, the resistance enhancing of lepidoptera pest to agricultural chemicals, the drug-fast generation of Antifungi, its successful is used higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
The expection activity of two kinds of active agent combinations can calculate as follows (referring to colby, S.R.; Weed 15, page 20-22,1967)
If
The lethality of X=when rate of application with m ppm is used reactive compound A, is expressed as the percentage of untreated control group.
The lethality of Y=when rate of application with n ppm is used reactive compound B, is expressed as the percentage of untreated control group.
The lethality of E=when rate of application with m and n ppm is used reactive compound A and B, is expressed as the percentage of untreated control group.
:
E＝X+Y-(XY/100)
If actual insect mortality surpasses calculated value, the lethality of bond has additive property, has syneryistic effect.
Embodiment:
Adopt rice stem infusion process to carry out indoor bioassay, selecting resistant rice plant hopper is target pest, and every processing repeats 3 times, and every concentration is processed 60, the results are shown in Table 1.
Table 1: the toxicity of MTI-446-azoxystrobin compound to Brown Planthopper
Embodiment:
Employing is soaked leaf dip method and is carried out indoor synergy biologicall test, and selecting resistance wheat aphid is target pest, and every processing repeats 3 times, and every concentration is processed 60 and be the results are shown in Table 2:
Table 2: the toxicity of MTI-446-azoxystrobin compound to aphid
Embodiment:
Employing is soaked leaf dip method and is carried out indoor synergy biologicall test, and selecting resistant rice stinkbug is target pest, and every processing repeats 3 times, and every concentration is processed 60 and be the results are shown in Table 3:
Table 3: the toxicity of MTI-446-azoxystrobin compound to rice stinkbug
Embodiment
Take rice blast pathogen as subjects, adopt colony diameter method to calculate the activity of the many germs of medicament, the results are shown in Table 4.
Table 4: the indoor bacteriostatic activity of MTI-446-azoxystrobin compound to rice blast
By this Fungicidal insecticidal composition, for field control effectiveness test, the synergetic that liquid 30L further verifies said composition is used on every mu of ground, the results are shown in Table 5.
Table 5: the field test results of MTI-446-azoxystrobin compound to Brown Planthopper, rice blast
Indoor biometrics and field efficacy result show, MTI-446 azoxystrobin composite antagonism brown plant-hopper, stinkbug, aphid and rice blast have good control efficiency, control efficiency is all better than the effect of single dose kind, so Fluoxastrobin and MTI-446 have obvious synergistic function after composite.
Two kinds of reactive compounds can be processed into any one formulation of permission, and below with two kinds of preparations that active ingredient is processed into of specific embodiment explanation, but the preparation that these two kinds of active components can be processed is not limited only to following listed.
Embodiment 2:
Take 5g MTI-446,50g Fluoxastrobin, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, and making main active ingredient weight percentage is 55% MTI-446-azoxystrobin water emulsion.
Embodiment 3:
Take 2g MTI-446,30g Fluoxastrobin, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 32% MTI-446-Fluoxastrobin microemulsion.
Embodiment 4:
Take 1g MTI-446,5g Fluoxastrobin, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, and making main active ingredient weight percentage is 55% MTI-446-azoxystrobin water emulsion.
Embodiment 5: take 50g MTI-446,20g Fluoxastrobin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 70% MTI-446-Fluoxastrobin missible oil.
Embodiment 6: take 2g MTI-446,40g Fluoxastrobin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 42% MTI-446-Fluoxastrobin missible oil.
Embodiment 7: take 5g MTI-446,20g Fluoxastrobin, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33
#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 32% MTI-446-Fluoxastrobin microemulsion.
Embodiment 8: take 5g MTI-446,0.5g Fluoxastrobin, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 5.5% MTI-446-Fluoxastrobin missible oil.
Embodiment 9: take 5g MTI-446,30g Fluoxastrobin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 35% MTI-446-Fluoxastrobin missible oil.
Embodiment 10: take 10g MTI-446,10g Fluoxastrobin, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 42% MTI-446-Fluoxastrobin suspending agent.
Embodiment 11: take 30g MTI-446,12g Fluoxastrobin, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 42% MTI-446-Fluoxastrobin suspending agent.
Embodiment 12: take 2g MTI-446,5g Fluoxastrobin, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite complements to 100g, and it is 7% MTI-446-Fluoxastrobin water dispersion granule that above raw material is made to main active ingredient weight percentage by water dispersible granular agent method.
Embodiment 13: take 2g MTI-446,18g Fluoxastrobin, lignin 10g, Negel 2g, with diatomite, add to 100g, above raw material is mixed in micronizer, and making main active ingredient weight percentage is 20% MTI-446 and Fluoxastrobin wetting powder.
Embodiment 14: take 7g MTI-446,70g Fluoxastrobin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 77% MTI-446-Fluoxastrobin missible oil.
Claims (7)
1. containing a composite insecticidal bactericidal composition for MTI-446 and Fluoxastrobin, it is characterized in that it is active ingredient that this insecticidal and bactericidal composition be take MTI-446 and Fluoxastrobin, wherein, the weight ratio of MTI-446 and Fluoxastrobin is 1:30 or 1:20.
2. the composite insecticidal bactericidal composition containing MTI-446 and Fluoxastrobin according to claim 1, is characterized in that the two weight percentage that accounts for composition of MTI-446 and Fluoxastrobin is 3 ~ 80%.
3. the composite insecticidal bactericidal composition containing MTI-446 and Fluoxastrobin according to claim 2, is characterized in that the two weight percentage that accounts for composition of MTI-446 and Fluoxastrobin is 5 ~ 50%.
4. the composite insecticidal bactericidal composition containing MTI-446 and Fluoxastrobin according to claim 3, is characterized in that the two weight percentage that accounts for composition of MTI-446 and Fluoxastrobin is 10 ~ 40%.
5. the composite insecticidal bactericidal composition containing MTI-446 and Fluoxastrobin according to claim 1, is characterized in that it take MTI-446 and Fluoxastrobin and be mixed with any one formulation allowing on agricultural chemicals as active ingredient and insecticides adjuvant, excipients.
6. the composite insecticidal bactericidal composition containing MTI-446 and Fluoxastrobin according to claim 5, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
7. the application of the composite insecticidal bactericidal composition containing MTI-446 and Fluoxastrobin claimed in claim 1 on the pesticide-germicide medicine of preparing pest control Brown Planthopper, aphid, rice stinkbug and disease rice blast.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110321791.4A CN103053587B (en) | 2011-10-20 | 2011-10-20 | Insecticide/bactericide composition containing dinotefuran and azoxystrobin and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110321791.4A CN103053587B (en) | 2011-10-20 | 2011-10-20 | Insecticide/bactericide composition containing dinotefuran and azoxystrobin and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103053587A CN103053587A (en) | 2013-04-24 |
| CN103053587B true CN103053587B (en) | 2014-10-29 |
Family
ID=48096733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110321791.4A Active CN103053587B (en) | 2011-10-20 | 2011-10-20 | Insecticide/bactericide composition containing dinotefuran and azoxystrobin and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103053587B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111387196B (en) * | 2020-03-26 | 2021-10-22 | 南通联农佳田作物科技有限公司 | Multi-phase preparation for treating diseases and pests and treating seeds |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101242739A (en) * | 2005-06-29 | 2008-08-13 | 先正达参股股份有限公司 | Liquid compositions for treating plant propagation materials |
| WO2009098228A2 (en) * | 2008-02-05 | 2009-08-13 | Basf Se | Pesticidal mixtures |
| WO2009098210A2 (en) * | 2008-02-05 | 2009-08-13 | Basf Se | Pesticidal mixtures |
-
2011
- 2011-10-20 CN CN201110321791.4A patent/CN103053587B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101242739A (en) * | 2005-06-29 | 2008-08-13 | 先正达参股股份有限公司 | Liquid compositions for treating plant propagation materials |
| WO2009098228A2 (en) * | 2008-02-05 | 2009-08-13 | Basf Se | Pesticidal mixtures |
| WO2009098210A2 (en) * | 2008-02-05 | 2009-08-13 | Basf Se | Pesticidal mixtures |
Non-Patent Citations (2)
| Title |
|---|
| 新型烟碱类农药呋虫胺的开发沿革;朱丽华;《世界农药》;20040425;第26卷(第02期);第16页 * |
| 朱丽华.新型烟碱类农药呋虫胺的开发沿革.《世界农药》.2004,第26卷(第02期),第16页. |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103053587A (en) | 2013-04-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102640748A (en) | Ultra-low-volume liquid containing prothioconazole | |
| CN101946775B (en) | Sterilization compound containing triazole fungicide and azoxystrobin | |
| CN102239853A (en) | Thifluzamide-containing composite bacteriacide | |
| CN102415400A (en) | Composite pesticidal composition containing dinotefuran and abamectin and application thereof | |
| CN105010357A (en) | Sterilization composition and application thereof | |
| CN102415398A (en) | Composite insecticide composition containing dinotefuran and emamectin benzoate and purpose thereof | |
| CN103053584A (en) | Compound insecticidal and bactericidal composition containing dinotefuran and kresoxim-methyl, and application thereof | |
| CN103053588B (en) | Insecticide/bactericide composition containing dinotefuran and prochloraz and application thereof | |
| CN103053587B (en) | Insecticide/bactericide composition containing dinotefuran and azoxystrobin and application thereof | |
| CN103563938A (en) | Bactericidal composition containing pyraclostrobin and difenoconazole and application thereof | |
| CN101984817B (en) | Bactericidal composition containing azoxystrobin and fluazinam and use thereof | |
| CN101984821B (en) | Bactericidal composition containing fluazinam and tebuconazole and application thereof | |
| CN103891723A (en) | Bactericidal composition containing isopyrazam and picoxystrobin and application thereof | |
| CN103598194A (en) | Picoxystrobin and prochloraz containing sterilization composition and application thereof | |
| CN104472493A (en) | Compound preparation of plant growth regulator namely compound sodium nitrophenolate and bactericide | |
| CN105265441B (en) | Herbicidal combinations containing KIH 6127 and Oxyfluorfen and pretilachlor | |
| CN101984816A (en) | Bactericidal composition containing azoxystrobin and flutolanil and use thereof | |
| CN104472525B (en) | The mixed pesticide synergistic formula of a kind of field bucket for the fringe such as rice green smut and panicle blast phase disease and spraying method thereof | |
| CN102349522B (en) | Synergy sterilizing composition containing tetraconazole and tricyclazole | |
| CN103109815A (en) | Pesticide composition of dimoxystrobin and azoxystrobin | |
| CN103053583A (en) | Synergistic insecticidal composition containing dinotefuran and flonicamid and application thereof | |
| CN103563920B (en) | Bactericidal composition containing thifluzamide and picoxystrobin and application thereof | |
| CN103891724B (en) | A kind of composite synergistic bactericidal composition and application thereof containing isopyrazam and oxime bacterium ester | |
| CN106879639A (en) | A kind of composition pesticide of the flavones of fruit containing ground | |
| CN105284863A (en) | Pesticide composition containing thiamethoxam and fluoxastrobin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180524 Address after: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Co-patentee after: Nanjing Redsun Co., Ltd. Patentee after: Nanjing Huazhou Pharmaceutical Co., Ltd. Address before: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Patentee before: Nanjing Huazhou Pharmaceutical Co., Ltd. |