CN103052705B - A kind of sunitizing - Google Patents
A kind of sunitizing Download PDFInfo
- Publication number
- CN103052705B CN103052705B CN201180037794.3A CN201180037794A CN103052705B CN 103052705 B CN103052705 B CN 103052705B CN 201180037794 A CN201180037794 A CN 201180037794A CN 103052705 B CN103052705 B CN 103052705B
- Authority
- CN
- China
- Prior art keywords
- sunitizing
- sanitary ware
- weight
- active agent
- accounts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 239000007787 solid Substances 0.000 claims abstract description 10
- -1 polyoxyethylene Polymers 0.000 claims description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 230000001954 sterilising effect Effects 0.000 claims description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 7
- 239000013543 active substance Substances 0.000 claims description 5
- 238000004659 sterilization and disinfection Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 235000013599 spices Nutrition 0.000 claims description 3
- 239000003206 sterilizing agent Substances 0.000 claims description 3
- 241000282326 Felis catus Species 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 15
- 238000004140 cleaning Methods 0.000 abstract description 8
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 230000003319 supportive effect Effects 0.000 description 5
- 235000011613 Pinus brutia Nutrition 0.000 description 4
- 238000011010 flushing procedure Methods 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 3
- 241000018646 Pinus brutia Species 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229910017053 inorganic salt Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 150000003505 terpenes Chemical class 0.000 description 3
- 235000007586 terpenes Nutrition 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- QCYOIFVBYZNUNW-UHFFFAOYSA-N 2-(dimethylazaniumyl)propanoate Chemical class CN(C)C(C)C(O)=O QCYOIFVBYZNUNW-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000218631 Coniferophyta Species 0.000 description 1
- 206010016825 Flushing Diseases 0.000 description 1
- 241000218641 Pinaceae Species 0.000 description 1
- 235000017339 Pinus palustris Nutrition 0.000 description 1
- 241000204936 Pinus palustris Species 0.000 description 1
- 241000241413 Propolis Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 1
- NDTNEAIKTSZYCF-XWNHBAMRSA-N [(1R,4aR,4bR,10aR)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carbonyl] (1R,4aR,4bR,10aR)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound C([C@@H]1[C@@]2(C)CCC3)CC(C(C)C)=CC1=CC[C@H]2[C@]3(C)C(=O)OC(=O)[C@]1(C)CCC[C@@]2(C)[C@H]1CC=C1C=C(C(C)C)CC[C@@H]12 NDTNEAIKTSZYCF-XWNHBAMRSA-N 0.000 description 1
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 150000002085 enols Chemical class 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- ILHIHKRJJMKBEE-UHFFFAOYSA-N hydroperoxyethane Chemical compound CCOO ILHIHKRJJMKBEE-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229960001708 magnesium carbonate Drugs 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000010603 pastilles Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229940069949 propolis Drugs 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
- E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
- E03D9/032—Devices connected to or dispensing into the bowl
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
- E03D2009/024—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing using a solid substance
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Public Health (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epidemiology (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Detergent Compositions (AREA)
- Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
A kind of sunitizing for the treatment of sanitary ware, comprise a solid-state or semi-solid state active body, comprise a process mixture, described process mixture contains at least one active principle for the treatment of sanitary ware and at least one nonionic surface active agent, it is characterized in that, this process mixture comprises the adhesion key element of at least one derived from Gum Rosin, realizes active body to adhere on the wall of sanitary ware.In this way, sunitizing can be sticked in pending sanitary ware well, and energy high-efficiency cleaning sanitary ware, simultaneously, do not need at the end of its operational phase, go to the non-clean area of contact sanitary apparatus (water closet) to remove the residue of sunitizing with hand.
Description
Technical field
The present invention relates to a kind of sunitizing, clean for sanitary ware is carried out, sterilize and/or sweetening treatment.
The invention particularly relates to the sunitizing comprising an active body, it can be solid-state or semi-solid state (more or less in the pasty state), it can stick on the inwall of water closet or urinal, still can keep adhering to after very repeatedly water rinses, each dissolving wherein sub-fraction, until be consumed completely.
Background technology
Sanitary ware, such as, be fixed to the sanitary closestool on wall or urinal, all needs to carry out the operation of repetition cleaning and disinfection, thus can maintain enough sanitary conditions.
Prior art is included in each water closet where, hangs sunitizing by the hook feature be placed in toilet receptacle; Time in draining each time to toilet, sunitizing just discharges.
Known other sunitizing, is fixed on the surrounding edge of water closet by a upholder; These sunitizings are inserted in special device usually, and such as have the cage of supportive device as plastic stent, it also comprises crack and/or hole, thus such as enable part sunitizing discharge along with the flushing of each current.
When being subject to the water slug of flush toilet, above-mentioned sunitizing makes to be rich in the material be included in sunitizing in water, thus be provided for cleaning, scale removal, deodorizing and/or the key element needed for sterilizing water closet (element).
But above-mentioned health device exists some defects, such as, because supportive device is fragile, can not ensure sufficiently to anchor to water closet surrounding edge, cause sunitizing unexpectedly to fall in flushing toiler.
And these devices neither very actual and health; At artificial clean toilet bowls edge or with in inside toilet brush cleaning closestool, the supportive device being fixed on edge of closet may accidentally movement, therefore must retighten it.And, when replacing sunitizing due to consumption, need manual operation, thus operate and health problem, because device is placed in the place being inconvenient to touch usually, from sanitation point, in any case this is all undesirable for user brings.
And, be also difficult to by these device application to urinal, because urinal does not have obvious edge or part to fix supportive device usually.In urinal or bed pan, the fragrant ingot (pastilles) often used is fixed on the position of its lower water drain.But the fragrant ingot of part is also often washed away by current and causes unwanted splash.
Finding recently always and substituting solution, for removing the device having and need the supportive device being fixed to water closet surrounding edge.
Prior art comprises some schemes solved the problem, and wherein, sunitizing, especially solid-state or semi-solid state soap stably can stick to the inwall of WC pans or urinal, is subject to daily current rinses to make it.
The European patent EP 1086199 of Buck-Chemie GmbH describes a kind of sunitizing that can directly apply to sanitary ware surface, the viscosity of this sunitizing is at least 15000mPas, and comprise adhesion promotor, as polyoxy alkanol (poly oxy alcohol alkane), Mierocrystalline cellulose etc.But this excessive viscosity is difficult to ensure fully to remove incrusted deposit thing, be also difficult to ensure that the sanitising agent be included in sunitizing is evenly distributed.
And in use, sunitizing is out of shape, and causes its moiety to be dripped in incorrect mode downwards.Another disadvantage is, in order to apply it to the specific part of sanitary ware suitably, the sunitizing described in described patent application must use the feed proportioning system be usually made up of rigid plastics, causes a large amount of inessential use of plastic material.
Therefore must find a kind of surrogate, it can have good adhesive power, ensures that clean sanitary ware has satisfied effect simultaneously.
Such as, Johnson & Sons under one's name, publication number is the international patent application of WO2008/100393 (corresponding to U. S. application US2008/0190457), disclose a kind of solid soap, it can adhere to toilet surface, meanwhile, enough cleaning ability can be ensured; But this soap needs to comprise a large amount of solid state surface activators, especially benzene sulfonamide acid type (being called as LAS) anionic surfactant, accounts for the 75%-99% weight of soap weight, effectively adheres to toilet surface to make it.
So a high proportion of aniorfic surfactant causes high cost, and hostile environment impact, particularly when the material used is derived from benzene, and LAS tensio-active agent as mentioned above.
Even if in today, produce a kind of sunitizing comprising following feature and still there is technical problem: a) produce gratifying and lasting cleaning action and/or sweetening treatment and/or antiseptic hygiene apparatus, b) do not need a large amount of manual operation to remove the lingering section of the final adhesion existed at the end of sunitizing uses, c) part in use adhering to sanitary ware internal surface that is appropriate is had, and it is especially d) little to environmental influence, particularly when using the aniorfic surfactant of the relatively very low ratio existed in composition, strongly adherent effect can be realized.
Therefore the object of this invention is to provide a kind of sunitizing, for the treatment of sanitary ware, it forms the replacement scheme of the solution that above-mentioned prior art provides.
Object of the present invention especially provides a kind of sunitizing, for the treatment of sanitary ware, this sunitizing comprises at least one sticking ingredient, and at least one for the treatment of composition, this sticking ingredient can make sunitizing can keep sticking in the sanitary ware of any shape after very repeatedly current rinse, meanwhile, once for the treatment of the composition of sunitizing be consumed, it is easily dissolved in the current rinsed further.
Summary of the invention
First aspect, the present invention relates to a kind of sunitizing for clean, sterilization and/or sweetening treatment sanitary ware.
The applicant has found a kind of sunitizing for the treatment of sanitary ware, it comprises a solid-state or semi-solid active body, comprise a process mixture, this process mixture has at least one for the treatment of the active principle (element) of sanitary ware and at least one nonionic surface active agent, it is characterized in that process mixture comprises the adhesion key element of at least one derived from Gum Rosin (colophony resin) (pine resin) further, it is dispersed in active body material, sunitizing is realized to adhere in sanitary ware, still can continue to adhere to after making very repeatedly current rinse, sunitizing dissolves substantially completely at the end of its operational cycle, and disadvantageous effect can not be caused to environment.
In this context with in the claim of enclosing, term " sanitary ware " is understood to mean water closet, urinal, urinal, or any other rinses the similar devices maintaining clean and health usually with current.
In this context and in the appended claims, term " sanitary ware process " is understood to purification, clean, sterilization, sweetening treatment and removal incrustation scale, and other is applicable to the similar operations of sanitary ware.
In this context and in the appended claims, term " for the treatment of active principle " be understood to be exclusively used in that purification, clean, foaming, sweetening treatment, deodorizing, sterilization, feedwater are painted, polishing or other water soluble any for the treatment of the key element of sanitary ware.
In this context and in the appended claims, term " semi-solid state body " refers to have pasty state viscosity or can by the viscosity of artificial pressure distortion, even if but faint external force as current rinse or discharge effect after still can keep the main body of both shaped for a long time.
In this way, sunitizing no matter will be made to adhere on which kind of wall of sanitary ware, the shape of sunitizing can carry out suitable adjustment according to the shape of wall, thus ensures good adhesive power.This shape can keep for a long time, unless it dissolves due to current washing action thus cause Mass lost.
Sunitizing of the present invention suitably can be consumed gradually along with each bath of sanitary ware, and like this, first, the active principle for the treatment of sanitary ware is dissolved in current gradually.Thereafter, after a series of draining, the adhesion key element of sunitizing, together with the lingering section of process composition, starts to be exposed to current on, thus adhesion key element is removed completely.
In this way, when processing composition and running out, only have a fraction of adhesion key element still to contact the wall of treated sanitary ware, by the suitable burnisher for sanitary ware as brush etc., be easy to be removed.
The derivative of Gum Rosin preferably derived from the terpene (terpene) of rosin (resin), it is further preferred that this terpene is the rosin ester of straight chain, such as Bremasin 1205.
Rosin is yellow solid propolis (abietic anhydride), and it is transparent, is the residue (other pine tree of minute hand leaf pine resin (Pinus Palustris conifer resin) or Pinaceae) of turps distillation.
Derived from the amount of the adhesion key element of Gum Rosin relative to sunitizing gross weight, preferably account for 0.1-20% weight, more preferably account for 0.1-10% weight.
As mentioned above, sunitizing comprise have at least one for the treatment of the process mixture of active principle.
Active principle preferable detergent, spices (perfume) or sterilizing agent.
The amount of this at least one active principle, relative to the gross weight of sunitizing, preferably accounts for 1-75% weight.
Described at least one nonionic surface active agent, be preferably selected from long-chain alcohols (about 10 to about 20 carbon atoms), as the starch chain enol of polyoxyethylene (polyoxyethylene) derivative of lipid acid, lipid acid, alkyl glycoside (alkyl polyglucosides) (APG), naturally and/or ethoxy alcohol (etoxylated alchohols), the amine oxide of synthesis.
The amount of this at least one tensio-active agent, relative to sunitizing gross weight, preferably accounts for 25%-80% weight, more preferably accounts for 50-75% weight.
Process mixture is except comprising at least one nonionic surface active agent, and also preferably comprise another tensio-active agent of at least one, it is selected from aniorfic surfactant, cationic surfactant, amphoterics or their combination.
Aniorfic surfactant is preferably selected from the mixture with the carbon atom chain ended up with carboxyl (caroxylate) or sulfonic group (sulphanate), such as soap, alkyl sodium sulfate ether (LES/AES), alkyl sodium sulfate (alkyl sulphates) (LA/AS), sulfonated α-olefin (AOS), alkyl oxide carboxylate, sulfosuccinate, fragrant sulfonate.
Cationic surfactant is preferably selected from Long carbon chain (about 10 to about 20 the carbon atoms) material of quaternary amine base ending, such as alkyl hydroxyethyl alkyl dimethyl ammonium chloride, benzalkonium chloride (banzalconium chloride), cetyltrimethylammonium bromide or CTAB (cetyl-trimethyl ammonium bromide or chloride), cetyl trimethylammonium bromide or palmityl trimethyl ammonium chloride (hexadecyl-trimethyl ammonium bromide or chloride) etc.
Amphoterics is preferably selected from aminocarboxylic acid, alkyl betaine, such as 12 trimethyl-glycines, starch alkyl, CAB and both sexes acetate.
The amount of aniorfic surfactant is relatively very low, or even can ignore; It preferably accounts for 0.1-8% weight relative to the gross weight of sunitizing, more preferably accounts for 1-4% weight.
Treatment compositions preferably comprises at least one inorganic salt; It is further preferred that described at least one inorganic salt are selected from the monovalence in each stage of hydration or the vitriol of divalent metal, such as sodium sulfate or magnesium sulfate; The carbonate of monovalence or divalent metal and supercarbonate, such as sodium carbonate, magnesiumcarbonate and sodium bicarbonate; The muriate of monovalence and divalent metal, as sodium-chlor.
The amount of these at least one inorganic salt, relative to sunitizing gross weight, preferably accounts for 10-70% weight, more preferably accounts for 10-20% weight.
Process mixture preferably can comprise all ingredients, such as SYNTHETIC OPTICAL WHITNER, spices, sterilizing agent, tinting material, dispersion agent, softening agent further, and its amount accounts for 0.1-30% weight relative to the gross weight of sunitizing.
Second aspect, the present invention relates to a kind of method, for cleaning, sterilizing and/or sweetening treatment sanitary ware, it is characterized in that according to the description in the present invention first and second preferred embodiment, sunitizing such as those sunitizings above-described are applied directly on the wall of pending sanitary ware.
From the specific descriptions of non-exclusive preferred embodiment, by the mode of unrestricted example, can clearly understand further feature of the present invention and advantage.
Embodiment
example 1
sunitizing 1 (invention).
The first process mixture for sanitary ware is prepared as follows:
Mixture 1 is mixed with the laboratory double arm mixer that capacity is about 1Kg at ambient conditions by various composition, allows its stir about 30 minutes until obtain mashed prod that is uniform, plastic type, until obtain sunitizing 1.Sunitizing 1 shows as a kind of semi-solid state active body, substantially smooth cylindrical, and basal surface diameter is about 4cm, and highly (thickness) is about 0.4cm, and gross weight is about 12g.
Carrying out lavatory flushing and be pressed on pending sanitary ware wall after about 10 seconds, sunitizing 1 is adhered on the crust of toilet bowl interior wall, to ensure good adhesion.
Sunitizing 1 accepts 100 same water flushings, causes it progressively to discharge, until the completely consumed of process mixture, leave Gum Rosin residue, this residue is less than 3% of the rosin content be included at first in sunitizing; This resin residue thing toilet brush is easy to remove.
In this way, use sunitizing 1 of the present invention, even if it contains the aniorfic surfactant of relatively very low per-cent, also sunitizing can be sticked in pending sanitary ware well, and energy high-efficiency cleaning sanitary ware; , do not need at the end of operational phase meanwhile, go to the non-clean area of contact sanitary apparatus (water closet) to remove the residue of sunitizing 1 with hand.Finally, do not need in order to need not toilet bowl interior wall be contacted yet and use applicator object (applicator object) correctly to be placed by sunitizing.
sunitizing 2(contrast).
Similar with sunitizing 1, preparation sunitizing 2, the difference of itself and sunitizing 1 is that the formula for the treatment of compositions does not comprise the adhesion key element derived from Gum Rosin.
Process mixture 2 comprises:
The process that mixture preparation process and example 1 are reported is similar.
By with processing that mixture 2 obtains and there is the sunitizing 2 with sunitizing 1 same size, stand the process identical with sunitizing.
In this case, different from example 1, the adhesive power that sunitizing 2 adheres to pending surface is poor.In fact, after through minority, current rinse several times, sunitizing 2 comes off from the surface previously adhered to.
As can be seen from these examples, in process mixture, add Gum Rosin derivative can make sunitizing 1 of the present invention adhere on pending surface satisfactorily, even if be also like this when the aniorfic surfactant of relatively very low per-cent exists, this different from the situation that the sunitizing 2 compared is observed (it lacks Gum Rosin derivative).
Claims (6)
1. one kind for purifying, sterilizing and the sunitizing of sweetening treatment process sanitary ware, it comprises a solid-state or semi-solid state active body, comprise a process mixture, described process mixture contains at least one i) sanitising agent, spices and sterilizing agent be as the active principle for processing described in sanitary ware; Ii) at least one nonionic surface active agent, it is characterized in that, this sunitizing comprises at least one straight chain rosin ester and adheres to key element, described adhesion key element is dispersed in active body material, and realize active body to adhere on the wall of sanitary ware, and described at least one nonionic surface active agent is selected from the polyoxyethylene deriv of lipid acid; Wherein, relative to the gross weight of sunitizing, the weight of described straight chain rosin ester accounts for 0.1-20%; Wherein, relative to the weight of sunitizing, the weight of described nonionic surface active agent accounts for 25%-80%.
2. sunitizing according to claim 1, wherein, relative to the gross weight of sunitizing, the weight of described straight chain rosin ester accounts for 0.1-10%.
3. sunitizing according to claim 1, comprises other tensio-active agent further, and it is selected from the group of anion surfactant, cats product, amphoterics or their combination composition.
4. sunitizing according to claim 3, wherein said other tensio-active agent is anion surfactant.
5. sunitizing according to claim 4, wherein, relative to the weight of sunitizing, the amount of described aniorfic surfactant accounts for 0.1-8%.
6., for a method for clean, sterilization and sweetening treatment process sanitary ware, it is characterized in that, the sunitizing in claim 1-5 described in any one is applied on the wall of pending sanitary ware, and sunitizing is adhered on it.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITRE20100065 | 2010-08-06 | ||
| ITRE2010A000065 | 2010-08-06 | ||
| PCT/IB2011/001165 WO2012017278A1 (en) | 2010-08-06 | 2011-05-27 | A sanitary agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103052705A CN103052705A (en) | 2013-04-17 |
| CN103052705B true CN103052705B (en) | 2015-07-29 |
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| CN201180037794.3A Expired - Fee Related CN103052705B (en) | 2010-08-06 | 2011-05-27 | A kind of sunitizing |
Country Status (11)
| Country | Link |
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| US (1) | US20130125297A1 (en) |
| EP (2) | EP2601284B1 (en) |
| CN (1) | CN103052705B (en) |
| AU (1) | AU2011287328B2 (en) |
| CA (1) | CA2805335A1 (en) |
| EA (1) | EA022707B1 (en) |
| ES (2) | ES2528369T3 (en) |
| IL (1) | IL224340A (en) |
| IT (2) | ITRE20110042A1 (en) |
| MA (1) | MA34455B1 (en) |
| WO (2) | WO2012017277A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112015010471A2 (en) | 2012-11-09 | 2017-07-11 | Reckitt Benckiser Llc | single use folding dispenser for a toilet treatment adhesive composition |
| DE102013108019B3 (en) * | 2013-07-26 | 2014-08-28 | Buck-Chemie Gmbh | Adhesive agent for application to a sanitary article |
| GB201812647D0 (en) | 2018-08-03 | 2018-09-19 | Chancellor Masters And Scholars Of The Univ Of Oxford | Viral vectors and methods for the prevention or treatment of cancer |
| CN117120586A (en) * | 2021-03-08 | 2023-11-24 | 联合利华知识产权控股有限公司 | Shaped toilet cleaning block |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1213395A (en) * | 1996-01-12 | 1999-04-07 | 普罗格特-甘布尔公司 | Stable perfumed bleaching compositions |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3257478A (en) * | 1965-02-12 | 1966-06-21 | Nat Starch Chem Corp | Pressure sensitive adhesive compositions |
| US4373219A (en) * | 1980-04-07 | 1983-02-15 | Gruber Systems, Inc. | Cast toilet base structure |
| DE19826293A1 (en) | 1998-06-12 | 2000-03-23 | Buck Chemie Gmbh | Sanitary ware |
| DE102004056554A1 (en) * | 2004-11-23 | 2006-05-24 | Buck-Chemie Gmbh | Adhesive sanitary cleaning and scenting agent |
| US20060260031A1 (en) * | 2005-05-20 | 2006-11-23 | Conrad Joseph M Iii | Potty training device |
| CA2657984C (en) * | 2006-06-20 | 2014-07-29 | Reckitt Benckiser Inc. | Improved solid treatment blocks for sanitary appliances |
| US7709433B2 (en) | 2007-02-12 | 2010-05-04 | S.C. Johnson & Son, Inc. | Self-sticking disintegrating block for toilet or urinal |
| EP2137290B1 (en) * | 2007-04-16 | 2013-07-17 | Unilever N.V. | Self adhesive hard surface cleaning composition |
| CN101945987B (en) * | 2008-02-21 | 2014-01-22 | 约翰逊父子公司 | Cleaning composition having high self-adhesion and providing residual benefits |
| ITMI20081202A1 (en) | 2008-06-30 | 2010-01-01 | Bolton Manitoba S P A | PRODUCT ADHESIVE DETERGENT AND DEVICE CONTAINER AND APPLICATOR FOR THIS PRODUCT |
-
2011
- 2011-05-27 AU AU2011287328A patent/AU2011287328B2/en not_active Ceased
- 2011-05-27 CA CA2805335A patent/CA2805335A1/en not_active Abandoned
- 2011-05-27 EP EP11729169.0A patent/EP2601284B1/en active Active
- 2011-05-27 US US13/814,467 patent/US20130125297A1/en not_active Abandoned
- 2011-05-27 EP EP11727520.6A patent/EP2601283B1/en active Active
- 2011-05-27 EA EA201390062A patent/EA022707B1/en not_active IP Right Cessation
- 2011-05-27 MA MA35643A patent/MA34455B1/en unknown
- 2011-05-27 WO PCT/IB2011/001164 patent/WO2012017277A1/en active Application Filing
- 2011-05-27 ES ES11727520.6T patent/ES2528369T3/en active Active
- 2011-05-27 WO PCT/IB2011/001165 patent/WO2012017278A1/en active Application Filing
- 2011-05-27 CN CN201180037794.3A patent/CN103052705B/en not_active Expired - Fee Related
- 2011-05-27 ES ES11729169.0T patent/ES2561529T3/en active Active
- 2011-06-08 IT IT000042A patent/ITRE20110042A1/en unknown
- 2011-06-08 IT IT000041A patent/ITRE20110041A1/en unknown
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2013
- 2013-01-21 IL IL224340A patent/IL224340A/en active IP Right Grant
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1213395A (en) * | 1996-01-12 | 1999-04-07 | 普罗格特-甘布尔公司 | Stable perfumed bleaching compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103052705A (en) | 2013-04-17 |
| EP2601284B1 (en) | 2016-01-13 |
| CA2805335A1 (en) | 2012-02-09 |
| EP2601284A1 (en) | 2013-06-12 |
| EA022707B1 (en) | 2016-02-29 |
| AU2011287328A1 (en) | 2013-02-28 |
| ES2528369T3 (en) | 2015-02-09 |
| WO2012017277A1 (en) | 2012-02-09 |
| IL224340A (en) | 2015-10-29 |
| ITRE20110041A1 (en) | 2012-02-07 |
| EP2601283A1 (en) | 2013-06-12 |
| EP2601283B1 (en) | 2014-11-19 |
| EA201390062A1 (en) | 2013-06-28 |
| ES2561529T3 (en) | 2016-02-26 |
| AU2011287328B2 (en) | 2013-09-12 |
| WO2012017278A1 (en) | 2012-02-09 |
| MA34455B1 (en) | 2013-08-01 |
| ITRE20110042A1 (en) | 2012-02-07 |
| US20130125297A1 (en) | 2013-05-23 |
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