CN103038326A - 起泡清洁剂 - Google Patents

起泡清洁剂 Download PDF

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CN103038326A
CN103038326A CN2010800685530A CN201080068553A CN103038326A CN 103038326 A CN103038326 A CN 103038326A CN 2010800685530 A CN2010800685530 A CN 2010800685530A CN 201080068553 A CN201080068553 A CN 201080068553A CN 103038326 A CN103038326 A CN 103038326A
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K.波特钱
C.博伊克
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Colgate Palmolive Co
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Abstract

一种水性、可起泡的组合物，其包含蓖麻油马来酸酯、PEG-7甘油椰油酸酯、甘油、表面活性剂和任选地PEG-6辛酸/癸酸甘油酯。该组合物用作起泡清洁剂，该清洁剂分配具有增强的皮肤感觉和任选提高的泡沫支撑的泡沫，使得它较不过稀和难用。

Description

起泡清洁剂
背景
起泡手皂为一般具有极低粘度的清洁剂，因此它们得以通过起泡分配器分配以递送起泡的清洁剂给用户。一般地，所述泡沫不在长时期内支撑为泡沫。当泡沫破裂时，它可变得过稀(runny)和难用(messy)。期望提供带有提高的泡沫支撑的起泡清洁剂以改善泡沫的过稀性和难用性。还期望提供带有增强的皮肤感觉性质的起泡清洁剂。
摘要
一种水性、可起泡的组合物，其包含组合物0.1-1重量%的蓖麻油马来酸酯、组合物0.05-0.3重量%的PEG-7甘油椰油酸酯、组合物0.5-6重量%的甘油、表面活性剂和水，其中甘油存在的量大于蓖麻油马来酸酯或PEG-7甘油椰油酸酯的任一个，且组合物具有的粘度为1-100 mPas(cps)。组合物可提供增强的皮肤感觉。
在另一个实施方案中，组合物可进一步包括组合物0.05-1重量%的PEG-6辛酸/癸酸甘油酯。这种组合物可提供泡沫支撑，并较不过稀和难以使用。
详述
如全文所用，范围用作用于描述每个和所有在该范围内的值的简写。在该范围内的任何值可选作该范围的终点。另外，本文引用的所有参考文献在此通过引用将其全部并入。在本公开中的定义和引用的参考文献的定义冲突的情况下，以本公开为准。
除非另有说明，说明书中此处和别处表述的所有百分数和量应理解为指按重量计的百分数。给定的量基于材料的有效重量。
组合物包括蓖麻油马来酸酯、PEG-7甘油椰油酸酯、甘油、表面活性剂、水和任选地PEG-6辛酸/癸酸甘油酯。
蓖麻油马来酸酯(蓖麻油基马来酸酯)存在于组合物中的量为组合物的0.1-1重量%。在一个实施方案中，所述的量为约0.3-0.5重量%。在另一个实施方案中，所述的量为0.5重量%。蓖麻油马来酸酯可作为Ceraphyl™ RMT得自ISP Corp.。
PEG-7甘油椰油酸酯存在于组合物中的量为组合物的0.05-0.5重量%。在一个实施方案中，所述的量为0.2重量%。PEG-7甘油椰油酸酯可作为Cetiol™ HE得自Cognis。
甘油存在于组合物中的量为组合物的0.5-6重量%。甘油存在的量大于蓖麻油马来酸酯、PEG-7甘油椰油酸酯或PEG-6辛酸/癸酸甘油酯的任一个。在一个实施方案中，甘油存在约3.4重量%。虽然甘油可能已经包括在起泡清洁剂内，但一般量低，通常接近于0.1重量%或更低。由于甘油的量提高，预期是起泡将减少，且特别地当甘油的量超过3重量%时。
当包括在某些实施方案中时，PEG-6辛酸/癸酸甘油酯存在于组合物中的量为组合物的0.05-1重量%。在一个实施方案中，所述的量为约0.5重量%。PEG-6辛酸/癸酸甘油酯可作为Glycerox™ 767得自Croda。
任选地，组合物可含有PEG-120甲基葡萄糖二油酸酯。在一个实施方案中，PEG-120甲基葡萄糖二油酸酯的量为组合物的0.01-0.5重量%，且在另一个实施方案中所述的量为0.15重量%。PEG-120甲基葡萄糖二油酸酯可作为Glucamate™ DOE-120增稠剂得自Lubrizol Advanced Materials。包含PEG-120甲基葡萄糖二油酸酯可进一步提高泡沫支撑和皮肤感觉性质。
组合物包含至少一种表面活性剂。表面活性剂可为任何阴离子、非离子、阳离子、两性或两性离子表面活性剂。在一个实施方案中，表面活性剂包含月桂基醚(月桂醇聚醚)硫酸钠。在某些实施方案中，月桂醇聚醚硫酸盐中每摩尔的氧化乙烯部分的平均数为约2-约8。在一个实施方案中，平均数为约2。在另一个实施方案中，表面活性剂进一步包含椰油酰胺丙基甜菜碱。
表面活性剂可存在的量为组合物的1-40重量%。在其它实施方案中，表面活性剂的量为组合物的1-30、1-20、5-20、10-20、10-15或15-20重量%。
在一个实施方案中，表面活性剂包含存在的量为5-10重量%的月桂基醚硫酸钠。在另一个实施方案中，所述的量为7-8重量%。
在另一个实施方案中，表面活性剂包含月桂基醚硫酸钠和椰油酰胺丙基甜菜碱的组合。在此组合中月桂基醚硫酸钠的量与上文列举的相同，且椰油酰胺丙基甜菜碱的量为组合物的5-10或5.5-6.5重量%。在一个实施方案中，表面活性剂包含约7.6重量%月桂基醚硫酸钠和约6重量%椰油酰胺丙基甜菜碱。
本说明书和权利要求书中组合物的粘度为1-100 mPas(cps)，在Brookfield DVII粘度计上用转子3以100 rpm在25℃下测量。这允许组合物得以通过起泡分配器分配并产生泡沫。起泡分配器为任何吸入液体组合物然后作为泡沫分配该组合物的分配器。
当PEG-6辛酸/癸酸甘油酯包括在组合物中时，通过该组合物产生的泡沫具有较好的支撑并较不过稀和难以使用。在使用组合物后，蓖麻油马来酸酯、PEG-7甘油椰油酸酯、PEG-6辛酸/癸酸甘油酯和甘油的组合提供提高的支撑和更好的皮肤感觉。组合物可为起泡手皂或起泡沐浴露/淋浴凝胶。
在一些实施方案中组合物的pH为2-9。在一个实施方案中，组合物的pH为3-7。在其它实施方案中，组合物的pH为4-6。在另一个实施方案中组合物的pH为6-8。pH在25℃下测量。
另外，组合物可含有任何其它可包括在清洁组合物内的材料。另外的表面活性剂和其它材料的实例可见于美国专利公开号2007/0048235。
组合物可通过材料的混合而制备。
具体实施方案
在以下实施例中进一步描述本发明。实施例仅为说明性的，且不以任何方式限制所描述和请求保护的本发明的范围。
以下发明性组合物和比较性对照例使用下述程序制备。所述的量为所供材料的重量%。
材料 实施例1 对照例
水 足量 足量
月桂基醚硫酸钠(2EO)(70%) 10.9 10.9
防腐剂 0.7 0.7
椰油酰胺丙基甜菜碱 6 6
蓖麻油马来酸酯(Ceraphyl™ RMT) 0.3 0
甘油 3.4 0
PEG-6辛酸/癸酸甘油酯(Glycerox™ 767) 0.5 0
PEG-7甘油椰油酸酯(Cetiol™ HE) 0.2 0.01
EDTA四钠(39%) 0.26 0.26
PEG-120甲基葡萄糖二油酸酯(Glucamate™ DOE-120增稠剂) 0.15 0.15
柠檬酸溶液 0.055 0.055
香精 0.2-0.35 0.2-0.35
颜料 0.0001-0.0005 0.0001-0.0005
将蓖麻油马来酸酯预混物-Ceraphyl™ RMT蓖麻油马来酸酯添加至含有椰油酰胺丙基甜菜碱的烧杯，并以高速混合直到完全结合而液体澄清。把甘油添加至批料并混合直到均匀。然后把防腐剂(DMDM乙内酰脲)添加至批料并混合直到均匀。
DOE-120预混物-加水至烧杯并加热到35-50℃。添加PEG-120甲基葡萄糖二油酸酯至烧杯并以高速混合直到完全溶解。关闭加热。一旦温度低于40℃，添加防腐剂(DMDM乙内酰脲)并混合直到完全结合。
加水至装备有中部叶轮搅拌的容器并加热至50℃。一旦到50℃，缓慢地把月桂基醚硫酸钠添加至水，同时以中速混合。一旦全部月桂基醚硫酸钠溶解，关闭加热并开始冷却批料。当温度低于40℃时，添加防腐剂(DMDM乙内酰脲)并混合直到均匀。把椰油酰胺丙基甜菜碱和甘油连续地添加至批料，混合直到组分之间均匀。把蓖麻油马来酸酯预混物(见上文)缓慢地以高速添加至批料，并混合直到完全结合而批料澄清。把EDTA四钠溶液、PEG-6、DOE-120预混物(见上文)、PEG-7、香精和颜料连续地添加至批料，混合直到组分之间均匀。测量pH和粘度并调节(如有必要)。
本研究为顺序单一设计，据此每个受试者在本研究的过程中评价测试产品。征集和选择总共52位参与者参加本研究，所述参与者经常冲洗他们的手且不反对使用起泡皂。
每个试验阶段，每个受试者用每个测试产物冲洗一次。要求受试者每天两次(一次在上午，一次在下午)用产品冲洗他们的手并每个阶段评价一个测试产品。受试者使用他们的正常习惯分配产品，回答一些有关分配的问题，然后用产品正常冲洗他们的手并在一系列问题上评价产品。在试验阶段的过程中，每个受试者以均衡/随机的出现顺序评价所有产品。
以下表格列出由52位参与者提供的针对关于产品的问题的评分。
你多喜欢或不喜欢这个产品？
评分 实施例1 对照例
9：极喜欢 21.2% 1.9%
8：非常喜欢 23.1% 17.3%
7：中等喜欢 32.7% 26.9%
6：有点喜欢 9.6% 15.4%
5：既非喜欢也非不喜欢 7.7% 7.7%
4：有点不喜欢 5.8% 9.6%
3：中等不喜欢 0.0% 17.3%
2：非常不喜欢 0.0% 3.8%
1：极不喜欢 0.0% 0.0%
你将如何评价当你分配它时泡沫的稠度？
评分 实施例1 对照例
5：太过稠 0.0% 0.0%
4：有点过稠 11.5% 3.8%
3：差不多正好 84.6% 40.4%
2：有点过稀 3.8% 46.2%
1：太过稀 0.0% 9.6%
泡沫的稠度(差不多正好)：相比于对照例(40%)，实施例1具有显著更多的人评分泡沫的量为差不多正好。
具有吸引人的泡沫质地？
评分 实施例1 对照例
5：完美地描述 26.9% 9.6%
4：很好地描述 51.9% 34.6%
3：某种程度描述 13.5% 36.5%
2：不太好地描述 5.8% 17.3%
1：完全不好地描述 1.9% 1.9%
吸引人的泡沫质地：相比于对照例，实施例1具有显著更吸引人的泡沫质地。
不难以使用？
评分 实施例1 对照例
5：完美地描述 44.2% 19.2%
4：很好地描述 38.5% 34.6%
3：某种程度描述 15.4% 28.8%
2：不太好地描述 1.9% 11.5%
1：完全不好地描述 0.0% 5.8%
相比于对照例，实施例1对于整体喜好显著为更优选。相比于对照例，实施例1还显著地更不难以使用。

Claims (8)

1. 一种水性、可起泡的组合物，其包含：
a) 所述组合物0.1-1重量%的蓖麻油马来酸酯，
b) 所述组合物0.05-0.3重量%的PEG-7甘油椰油酸酯，
c) 所述组合物0.5-6重量%的甘油，和
d) 表面活性剂，
其中所述甘油存在的量大于蓖麻油马来酸酯或PEG-7甘油椰油酸酯的任一个，且
所述组合物具有的粘度为1-100 mPas(cps)。
2. 权利要求1的组合物，其进一步包含所述组合物0.05-1重量%的PEG-6辛酸/癸酸甘油酯。
3. 任一前述权利要求的组合物，其进一步包含PEG-120甲基葡萄糖二油酸酯。
4. 权利要求3的组合物，其中所述PEG-120甲基葡萄糖二油酸酯存在的量为所述组合物的0.01-0.5重量%，优选约0.15重量%。
5. 任一前述权利要求的组合物，其中所述表面活性剂包含月桂基醚硫酸钠和椰油酰胺丙基甜菜碱。
6. 权利要求4的组合物，其中所述月桂基醚硫酸钠每摩尔具有平均约2个氧化乙烯部分。
7. 权利要求1或3-6任一项的组合物，其中所述蓖麻油马来酸酯存在约0.5重量%，所述PEG-7甘油椰油酸酯存在约0.2重量%，且所述甘油存在约3.4重量%。
8. 权利要求2-7任一项的组合物，其中所述PEG-6辛酸/癸酸甘油酯存在约0.5重量%。
CN2010800685530A 2010-08-11 2010-08-11 起泡清洁剂 Pending CN103038326A (zh)

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CN110312504A (zh) * 2017-02-23 2019-10-08 德比Ip有限公司 可发泡清洁组合物
CN111526860A (zh) * 2017-12-30 2020-08-11 高露洁-棕榄公司 个人护理组合物

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CN106236640A (zh) * 2016-08-24 2016-12-21 马南行 一种天然洁牙摩丝泡沫组合物及其制备方法
CN110312504A (zh) * 2017-02-23 2019-10-08 德比Ip有限公司 可发泡清洁组合物
CN111526860A (zh) * 2017-12-30 2020-08-11 高露洁-棕榄公司 个人护理组合物
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CN107028775A (zh) 2017-08-11
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CA2805510C (en) 2014-09-30
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KR20130060288A (ko) 2013-06-07
ZA201300704B (en) 2018-12-19
WO2012021130A1 (en) 2012-02-16
EP2603574B1 (en) 2018-02-14
KR101442998B1 (ko) 2014-09-23
RU2543713C2 (ru) 2015-03-10
EP3348630B1 (en) 2022-03-02
MX349629B (es) 2017-08-07
US9700494B2 (en) 2017-07-11
US20130137619A1 (en) 2013-05-30
MX2013001212A (es) 2013-03-12
CA2805510A1 (en) 2012-02-16
AU2010359047A1 (en) 2013-02-21
BR112013003340A2 (pt) 2016-07-12
AU2010359047B2 (en) 2014-01-30
CN107028775B (zh) 2021-01-22
EP3348630A1 (en) 2018-07-18

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