CN103031117A - Oilfield drilling accelerant - Google Patents

Oilfield drilling accelerant Download PDF

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Publication number
CN103031117A
CN103031117A CN2011102998358A CN201110299835A CN103031117A CN 103031117 A CN103031117 A CN 103031117A CN 2011102998358 A CN2011102998358 A CN 2011102998358A CN 201110299835 A CN201110299835 A CN 201110299835A CN 103031117 A CN103031117 A CN 103031117A
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China
Prior art keywords
speed
raising agent
drilling
accelerant
fatty alcohol
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Application number
CN2011102998358A
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Chinese (zh)
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CN103031117B (en
Inventor
刘书杰
岳前升
周建良
王平双
胡友林
李玉光
邢希金
曹砚锋
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China National Offshore Oil Corp CNOOC
CNOOC Research Institute Co Ltd
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Yangtze University
China National Offshore Oil Corp CNOOC
CNOOC Research Center
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Application filed by Yangtze University, China National Offshore Oil Corp CNOOC, CNOOC Research Center filed Critical Yangtze University
Priority to CN201110299835.8A priority Critical patent/CN103031117B/en
Publication of CN103031117A publication Critical patent/CN103031117A/en
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Abstract

The invention discloses an oilfield drilling accelerant, consisting of the following components, by weight percent, 5-10% of glycol, 5-10% of tributyl phosphate, 5-15% of sulfonated caster oil, 5-10% of fatty alcohol-polyoxyethylene ether, 10-20% of polyglycerol and the balance of water. The oilfield drilling accelerant provided by the invention is friendly to the environment, overcomes the problem of environmental pollution caused by a fact that the past similar products contain oils, and has a stronger capability of preventing bit balling, a good interfacial activity and a better lubricating capacity.

Description

A kind of oil drilling speed-raising agent
Technical field
The present invention relates to a kind of oil drilling speed-raising agent, belong to petroleum drilling engineering chemical agent technical field.
Background technology
Drilling speed is directly connected to the cost of oil/gas drilling, and improve rate of penetration is one of target of oil/gas drilling operation pursuit always.The approach that improves drilling speed has 3 kinds: the one, and development of new fast drilling fluid technology; The 2nd, design high efficiency drill, optimization drilling tool structure; The 3rd, use the drilling well optimization technique.At present, normal optimization design with novel fast drilling drilling fluid and high efficiency drill combines the raising drilling speed.Most important progress is to have researched and developed the PDC drill bit in the optimization design of high efficiency drill, and polishing gear wheel PDC drill bit occurred.When the PDC drill bit is combined with the sludge shale formation with oil base, synthetic base drilling fluid, because oil base or synthetic base drilling fluid can reduce moment of torsion, weakens drill string and adhere to, prevent bit balling, keep wellbore stability, improved drilling speed.But the oils compound concentration that adds surpasses 10%, easily causes environmental pollution and its application is restricted.When the PDC drill bit is combined with water-base drilling fluid, when particularly boring the deep layer mud shale stratum, though do not cause environmental pollution, but exist slump in, bit balling, bit freezing, drilling speed to wait slowly problem, can significantly improve drilling speed though add subsequently oiliness compound, but easily enrichment and contaminate environment are so its application also is restricted.For this reason, in the urgent need to research and development environment-friendly type creep into fast drilling liquid technology, wherein most critical be develop have good compatibleness, biodegradable speed-raising agent.
Summary of the invention
The purpose of this invention is to provide a kind of oil drilling speed-raising agent, it has environmental friendliness, anti-drill bit mud drum ability strong and interfacial activity and the more excellent characteristics of lubricity.
A kind of oil drilling speed-raising agent provided by the invention, according to weight percent meter, described speed-raising agent is comprised of following component:
Ethylene glycol: 5~10%;
Tributyl phosphate: 5~10%;
Alizarin assistant: 5~15%;
Fatty alcohol-polyoxyethylene ether: 5~10%;
Polyglycerine: 10~20%; With
The water of surplus.
Above-mentioned speed-raising agent is comprised of following component, all by weight percentage: 5% ethylene glycol, 10% tributyl phosphate, 10% alizarin assistant, 5% fatty alcohol-polyoxyethylene ether, 10% Polyglycerine and the water of surplus; 5% ethylene glycol, 5% tributyl phosphate, 15% alizarin assistant, 10% fatty alcohol-polyoxyethylene ether, 15% Polyglycerine and the water of surplus; Or 10% ethylene glycol, 5% tributyl phosphate, 10% alizarin assistant, 7% fatty alcohol-polyoxyethylene ether, 18% Polyglycerine and the water of surplus.
In the above-mentioned speed-raising agent, the polyoxyethylene EO number of described fatty alcohol-polyoxyethylene ether can be 4 or 5.
In the above-mentioned speed-raising agent, described fatty alcohol-polyoxyethylene ether can be the alkyl alcohol Soxylat A 25-7 of carbonatoms 8-10.
In the above-mentioned speed-raising agent, the polymerization degree of described Polyglycerine can be 3~10, specifically can be 4,6 or 10.
In the above-mentioned speed-raising agent, described alizarin assistant is ricinoleate acid sulfuric ester sodium salt, and its molecular formula is C18H12O6Na2.
Can dispose by the following method above-mentioned oil drilling speed-raising agent, at normal temperatures with described each component through shearing pump or colloidal mill strong shear or stir and got final product in 1~2 hour.
The present invention has following beneficial effect compared with prior art:
1, oil drilling provided by the invention speed-raising agent is environmentally friendly, has overcome in the past like product because containing the oils environmental pollution problem.
2, oil drilling speed-raising agent provided by the invention has stronger anti-drill bit mud drum ability.
3, oil drilling speed-raising agent provided by the invention has good interfacial activity, more excellent lubricity.
Embodiment
Employed experimental technique is ordinary method if no special instructions among the following embodiment.
Used material, reagent etc. if no special instructions, all can obtain from commercial channels among the following embodiment.
The preparation of embodiment 1, No. 1 oil drilling speed-raising agent
Quality proportioning preparating mixture according to following each component: ethylene glycol: 5%, tributyl phosphate: 10%, alizarin assistant: 10%, octanol Soxylat A 25-7 (wherein polyoxyethylene EO number is 5): 5%, Polyglycerine (polymerization degree is 10): 10% and water: surplus; The mixture that above-mentioned preparation is obtained namely got No. 1 oil drilling speed-raising agent in 2 hours through the shearing pump shearing at normal temperatures.
Each performance perameter of No. 1 speed-raising agent of present embodiment preparation is as shown in table 1:
The performance perameter of table No. 11 speed-raising agent
Figure BDA0000096352930000031
By data in the table 1 as can be known, the speed-raising agent of the present invention's preparation can be used for the drilling speed of drilling fluid in the oil field.
The preparation of embodiment 2, No. 2 oil drilling speed-raising agent
Quality proportioning preparating mixture according to following each component: ethylene glycol: 5%, tributyl phosphate: 5%, alizarin assistant: 15%, certain herbaceous plants with big flowers polyoxyethylenated alcohol (wherein polyoxyethylene EO number is 4): 10%, Polyglycerine (polymerization degree is 4): 15% and water: surplus; The mixture that above-mentioned preparation is obtained namely got No. 2 oil drillings speed-raising agent in 1 hour through the shearing pump shearing at normal temperatures.
Each performance perameter of No. 2 speed-raising agent of present embodiment preparation is as shown in table 2:
The performance perameter of table No. 22 speed-raising agent
Figure BDA0000096352930000032
By data in the table 2 as can be known, the speed-raising agent of the present invention's preparation can be used for the drilling speed of drilling fluid in the oil field.
The preparation of embodiment 3, No. 3 oil drilling speed-raising agent
Quality proportioning preparating mixture according to following each component: ethylene glycol: 10%, tributyl phosphate: 5%, alizarin assistant: 10%, nonyl alcohol Soxylat A 25-7 (wherein polyoxyethylene EO number is 5): 7%, Polyglycerine (polymerization degree is 6): 18% and water: surplus; The mixture that above-mentioned preparation is obtained namely got No. 3 oil drillings speed-raising agent in 1 hour through the shearing pump shearing at normal temperatures.
Each performance perameter of No. 3 speed-raising agent of present embodiment preparation is as shown in table 3:
The performance perameter of table No. 33 speed-raising agent
Figure BDA0000096352930000041
By data in the table 3 as can be known, the speed-raising agent of the present invention's preparation can be used for the drilling speed of drilling fluid in the oil field.

Claims (4)

1. oil drilling speed-raising agent, according to weight percent meter, described speed-raising agent is comprised of following component:
Ethylene glycol: 5~10%;
Tributyl phosphate: 5~10%;
Alizarin assistant: 5~15%;
Fatty alcohol-polyoxyethylene ether: 5~10%;
Polyglycerine: 10~20%; With
The water of surplus.
2. speed-raising agent according to claim 1 is characterized in that: the polyoxyethylene number of described fatty alcohol-polyoxyethylene ether is 4 or 5.
3. speed-raising agent according to claim 1 and 2 is characterized in that: described fatty alcohol-polyoxyethylene ether is that carbonatoms is 8~10 alkyl alcohol Soxylat A 25-7.
4. arbitrary described speed-raising agent according to claim 1-3, it is characterized in that: the polymerization degree of described Polyglycerine is 3~10.
CN201110299835.8A 2011-09-29 2011-09-29 Oilfield drilling accelerant Active CN103031117B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Publications (2)

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CN103031117A true CN103031117A (en) 2013-04-10
CN103031117B CN103031117B (en) 2014-07-16

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107474805A (en) * 2017-09-20 2017-12-15 中国石油大学(北京) Suitable for the speed-raising agent of drilling fluid and water-base drilling fluid and its application

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101186813A (en) * 2007-12-28 2008-05-28 中国石油集团钻井工程技术研究院 Fast drilling fluid and preparation technique thereof
EP2028247A1 (en) * 2007-08-06 2009-02-25 Clariant International Ltd. Use of 1-alkyl-5-oxo-pyrrolidine-3-carbolic acid esters as gas hydrate inhibitors with improved biological degradability
WO2010071784A1 (en) * 2008-12-16 2010-06-24 Pq Corporation Friction modifier for drilling fluids
WO2011109014A1 (en) * 2010-03-02 2011-09-09 David John Kusko Borehole flow modulator and inverted seismic source generating system

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EP2028247A1 (en) * 2007-08-06 2009-02-25 Clariant International Ltd. Use of 1-alkyl-5-oxo-pyrrolidine-3-carbolic acid esters as gas hydrate inhibitors with improved biological degradability
CN101186813A (en) * 2007-12-28 2008-05-28 中国石油集团钻井工程技术研究院 Fast drilling fluid and preparation technique thereof
WO2010071784A1 (en) * 2008-12-16 2010-06-24 Pq Corporation Friction modifier for drilling fluids
WO2011109014A1 (en) * 2010-03-02 2011-09-09 David John Kusko Borehole flow modulator and inverted seismic source generating system

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余丽彬等: "快速钻进钻井液的研究及其在吐哈油田的应用", 《钻井液与完井液》, vol. 24, no. 05, 30 September 2007 (2007-09-30) *
徐生江等: "快钻剂KZ-1在钻井液中应用的实验室评价", 《精细石油化工进展》, vol. 8, no. 04, 25 April 2007 (2007-04-25) *
金潮苏: "KRH1快钻剂的研究与应用", 《石油钻探技术》, vol. 37, no. 02, 25 March 2009 (2009-03-25) *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107474805A (en) * 2017-09-20 2017-12-15 中国石油大学(北京) Suitable for the speed-raising agent of drilling fluid and water-base drilling fluid and its application
CN107474805B (en) * 2017-09-20 2018-06-12 中国石油大学(北京) Suitable for the speed-raising agent of drilling fluid and water-base drilling fluid and its application
US10266744B2 (en) 2017-09-20 2019-04-23 China University Of Petroleum (Beijing) Accelerator used for drilling fluids, water-based drilling fluid and usage thereof

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Address after: 100010 Beijing, Chaoyangmen, North Street, No. 25, No.

Applicant after: China National Offshore Oil Corporation

Applicant after: CNOOC Research Institute

Applicant after: Yangtze University

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Applicant before: Yangtze University

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Address after: 100010 Beijing, Chaoyangmen, North Street, No. 25, No.

Co-patentee after: CNOOC research institute limited liability company

Patentee after: China Offshore Oil Group Co., Ltd.

Co-patentee after: Yangtze University

Address before: 100010 Beijing, Chaoyangmen, North Street, No. 25, No.

Co-patentee before: CNOOC Research Institute

Patentee before: China National Offshore Oil Corporation

Co-patentee before: Yangtze University

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TR01 Transfer of patent right

Effective date of registration: 20191209

Address after: 100010 Beijing, Chaoyangmen, North Street, No. 25, No.

Co-patentee after: CNOOC research institute limited liability company

Patentee after: China Offshore Oil Group Co., Ltd.

Address before: 100010 Beijing, Chaoyangmen, North Street, No. 25, No.

Co-patentee before: CNOOC research institute limited liability company

Patentee before: China Offshore Oil Group Co., Ltd.

Co-patentee before: Yangtze University