CN103015224B - Method for dyeing fabric with natural mineral dye - Google Patents
Method for dyeing fabric with natural mineral dye Download PDFInfo
- Publication number
- CN103015224B CN103015224B CN201210552968.6A CN201210552968A CN103015224B CN 103015224 B CN103015224 B CN 103015224B CN 201210552968 A CN201210552968 A CN 201210552968A CN 103015224 B CN103015224 B CN 103015224B
- Authority
- CN
- China
- Prior art keywords
- fabric
- dye
- natural minerals
- alkyl
- colouring method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 0 CC(C)(*(*)O[N+](*)[O-])C(C)(C)N Chemical compound CC(C)(*(*)O[N+](*)[O-])C(C)(C)N 0.000 description 2
Landscapes
- Coloring (AREA)
Abstract
The invention relates to a method for dyeing fabric with a natural mineral dye. The method comprises the following steps: (1) modifying fabric with a modifying agent by a dipping or padding method for use; and (2) nanocrystallizing the natural mineral dye with a dispersing agent, preparing the nanocrystallized mineral dye into a dye solution, dyeing the modified fabric by a double-dipping and double-padding method, and drying, baking, soaping, rinsing and drying the fabric. The method for dyeing the fabric with the natural mineral dye is simple and feasible; and by the method, the color fastness of the natural dye is improved, the functionality of the natural dye is improved, and dual purposes of high-color fastness ecological dyeing and functional finishing of the natural dye are achieved.
Description
Technical field
The invention belongs to fabric dyeing method field, particularly the colouring method of natural minerals dyestuff on fabric.
Background technology
Textiles, after the dyeing of a part of chemical synthesis, easily causes stimulation to the skin of human body, and on the other hand, the dyestuff of chemical synthesis can cause certain influence to environment in production and use procedure.Along with the enhancing of ecological, environmental protective consciousness, increasing consumers, in the textiles of green safety, pays close attention to the security of textile dye.
In natural dye dying, along with the part kind in synthetic dyestuffs is forbidden, people are to the interest of natural dye enrichment again.Main cause is natural dye is obtain from the microorganisms such as plant, animal, mineral or bacterium, fungi, mould and some other natural material, seldom or not through the dyestuff of chemical process.Most of natural dye and environmental ecology compatibility good, biodegradable, and toxicity is lower.Add that the consumption of petroleum resources has shown synthetic dyestuffs insufficient raw material, also promote that exploitation natural dye carrys out supplementary synthetic dyestuffs.Although natural dye self also also exists many deficiencies, incomplete, the most kind price of as poor in dyefastness, chromatogram is more expensive, synthetic dyestuffs can not be substituted completely, but as synthetic dyestuffs Some substitute or to supplement be valuable, especially have more vast potential for future development with the textiles that some high added values developed by natural dye.
Natural minerals dyestuff, as natural inorganic dyestuff, has long applicating history.Natural minerals dyestuff is a kind of naturally inorganic dyestuff, has different colors, as brownish red, green, grey, yellow, white etc.Wherein: green ore mainly contains: malachite [Cu
2(CO
3) (OH)
2], dioptase [Cu
2(OH)
3cl], warringtonite [Cu
4(OH)
4sO
4] and brown ore (mainly containing the oxide of iron and manganese).Blue ore has: chessy copper [Cu
2(CO
3)
2(OH)
2], lapis lazuli [(Na, Ca)
3(AlSiO
4) (SO
4, S, Cl)
2], asbolane [m (Co, Ni) OMnO
2nH
2o].Red ore has: bloodstone (Fe
2o
3) and speculum iron, the red earthy material containing iron oxide of various tone.Yellow ore has: orpiment (As
2s
3), lead and yellow-collation (PbO), phlogopite, the various yellow earthy material containing iron hydroxide.These natural mineral dyes do not have affinity to fiber, and therefore its dyeing is different from dyeing.By research, natural minerals dyestuff can be carried out nanometer in the presence of dispersants, when fiber is swelling, mineral dye reaches the object of dyeing with tiny particulate infiltrated fiber inside on the one hand; On the other hand, mineral dye the padding by fabric after nanometer, is carried to fiber surface, is deposited in fiber capillary space or tissue space.Along with fabric is in oven dry with bake in process and be heated, the spacing of dispersant molecule aggregation reduces and forms strong wear-resisting, water white linear polymeric film, is bonded in fiber surface tightly.In addition, under high temperature bakes, " dye seat " on fabric and the active function groups in dispersant molecule again between fiber and dispersant, formed between dispersant molecule crosslinked, in three-dimensional network structure, make mineral dye embedding and be attached to securely on fabric by dispersant epithelium bag, thus reach the object of " upper dye ".Therefore, complete the dyeing of natural minerals dyestuff on fabric, " dye seat " on the structure of dispersant and fabric is the key improving dyefastness.
In addition, because some mineral dyes have, some are specifically functional, as uvioresistant, far infrared, promoting blood circulation and removing blood stasis etc., by to the dyeing of natural minerals dyestuff on fabric, the added value of textiles can be improved, thus reach improve natural dye dying COLOR FASTNESS, increase its dual purpose that is functional, that realize natural dye high color fastness ecological dyeing and functional treatment.
Summary of the invention
Technical problem to be solved by this invention is to provide the colouring method of a kind of natural minerals dyestuff on fabric, colouring method simple possible of the present invention, can improve the COLOR FASTNESS of natural dye dying, increase its dual purpose that is functional, that realize natural dye high color fastness ecological dyeing and functional treatment.
The colouring method of a kind of natural minerals dyestuff of the present invention on fabric, comprising:
(1) by dipping or pad method, with fabric-modifying agent, modification is carried out to fabric;
(2) with dispersant by after natural minerals dyestuff nanometer, nano-mineral dyestuff is mixed with dye liquor, adopts two colouring methods that roll of leaching two to dye to above-mentioned modified fabric, carry out after dyeing drying, bake, soap, wash post-drying.
In described step (1) in fabric-modifying agent molecule structure containing at least double functional group, for epoxychloropropane, glyoxal, glutaraldehyde, ethylenediamine or vulcabond.
Fabric in described step (1) is the one in COTTON FABRIC, linen, dacron, cotton ramie blended spinning fabric, cotton-polyester blend fabric, wool fabric, rabbit hair fabric.
Dispersant structure formula in described step (2) is:
Wherein, R
1for H or CH
3; R
2for C
1~ C
10alkyl, hydroxyl C
1~ C
10alkyl in one or more; R
3for H or CH
3; R
4for H or CH
3; R
5for C
1~ C
10alkyl, hydroxyl C
1~ C
10alkyl in one or more; A:b:c:d=0.3 ~ 0.5:0 ~ 0.4:0.4 ~ 0.7:0 ~ 0.2, the weight average molecular weight of dispersant is 8000-30000 gram/mol.
The preparation method of described dispersant is: under room temperature, reaction monomers is added in reaction vessel, solvent, logical nitrogen 20 ~ 60min, warming while stirring is to 60-85 DEG C, drip insulation reaction 0.5 ~ 4h after a part of initator, drip residue initator again, then insulation reaction 5 ~ 12h, after product cooling, crude product is added drop-wise in the poor solvent of copolymer and precipitates again, then wash, dry to obtain copolymer, by gained copolymer with after sodium hydroxide solution mixing, saponification 1 ~ 3h at 30 ~ 50 DEG C, then products therefrom is added dropwise in acetone and precipitates again, suction filtration, washing, dry to obtain dispersant.
Described reaction monomers is maleic anhydride, R
2cOOC (R
1) CH
2, CH
2c (R
4) COOR
5in one or more, wherein R
2cOOC (R
1) CH
2middle R
1for H or CH
3, R
2for C
1~ C
10alkyl, hydroxyl C
1~ C
10alkyl in one or more; CH
2c (R
4) COOR
5middle R
4for H or CH
3, R
5for C
1~ C
10alkyl, hydroxyl C
1~ C
10alkyl in one or more.
Described solvent is methyl alcohol, ethanol, acetone, butanone, ethyl acetate, dimethyl sulfoxide (DMSO) or carbon tetrachloride; Initator is azoic compound initiator or organic peroxide evocating agent; The poor solvent of copolymer is acetone, chloroform, carrene, methyl alcohol or benzinum, and the poor solvent of copolymer depends on the solvent that reaction system is used and reaction monomers.
Described azoic compound initiator is azodiisobutyronitrile or 2,2'-Azobis(2,4-dimethylvaleronitrile), and organic peroxide evocating agent is benzoyl peroxide, cumyl peroxide, dilauroyl peroxide or di-isopropyl peroxydicarbonate.
Adopt the method for titration, the actual molar content of maleic anhydride is 20 ~ 45%.
According to the amount of added NaOH, measuring actual saponification degree is 15 ~ 80%.
Mineral dye in described step (2) is green ore, brown ore, blue ore, red ore or yellow ore.
Such as: green ore mainly contains: malachite [Cu
2(CO
3) (OH)
2], dioptase [Cu
2(OH)
3cl], warringtonite [Cu
4(OH)
4sO
4] and brown ore (mainly containing the oxide of iron and manganese).Blue ore has: chessy copper [Cu
2(CO
3)
2(OH)
2], lapis lazuli [(Na, Ca)
3(AlSiO
4) (SO
4, S, Cl)
2], asbolane [m (Co, Ni) OMnO
2nH
2o].Red ore has: bloodstone (Fe
2o
3) and speculum iron, the red earthy material containing iron oxide of various tone.Yellow ore has: orpiment (As
2s
3), lead and yellow-collation (PbO), phlogopite, the various yellow earthy material containing iron hydroxide.
Natural minerals dyestuff has certain functional, uvioresistant performance, far infrared performance, performance promoting blood circulation and removing blood stasis.
By adopting mechanical means by its nanometer in described step (2), refer in particular to the method adopting and pulverize and grind, the particle diameter of the natural minerals dyestuff after grinding is 90 ~ 300nm.
In described step (2), bake out temperature is 80 ~ 100 DEG C, and drying time is 1 ~ 3min, and baking temperature is 130 ~ 150 DEG C, and the time of baking is 3min.
Measure the K/S value of front and back DYED FABRICS of soaping, for calculating the dyefastness of DYED FABRICS, this dyefastness computing formula is:
In formula, K/S
beforefor DYED FABRICS soap before the color depth of DYED FABRICS, K/S
afterfor DYED FABRICS soap before the color depth of DYED FABRICS.
Measure the K/S value of front and back DYED FABRICS of soaping, measure the K/S value of 13 differences, for calculating the Dry Sack irregularity of DYED FABRICS, this Dry Sack irregularity computing formula is:
In formula, K/S
iget by DYED FABRICS front the color depth of 13 middle each points,
be the mean value of 13 K/S.
The colouring method of natural minerals dyestuff of the present invention on fabric, first the method relates to a kind of fabric-modifying agent, by fabric-modifying, introduces abundant " dye seat " in fabric.Secondly, natural minerals dyestuff has nanometer under ad hoc structure dispersant, and by adding this dispersant, natural minerals dyestuff can soak very fast, disperse in water-based system, shorten sand milling or Ball-milling Time, and this dispersant there is good dispersion stabilization to natural minerals dye.Again, adopt the method for padding to dye to fabric, DYED FABRICS is when 130 ~ 150 DEG C × 3min bakes, and " dye seat " on dispersant and fabric occurs to react, improve the dyefastness after dyeing, thus improve the dyefastness of natural minerals dyestuff on fabric.
beneficial effect
(1) colouring method simple possible of the present invention;
(2) colouring method of the present invention improve natural dye dying COLOR FASTNESS, increase its dual purpose that is functional, that realize natural dye high color fastness ecological dyeing and functional treatment.
Accompanying drawing explanation
Fig. 1 is the SEM figure in embodiment 1 before pure cotton fabric dyeing;
Fig. 2 is that in embodiment 1, natural minerals dyestuff is schemed the SEM after modified pure cotton fabric dyeing.
Detailed description of the invention
Below in conjunction with specific embodiment, set forth the present invention further.Should be understood that these embodiments are only not used in for illustration of the present invention to limit the scope of the invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention, and these equivalent form of values fall within the application's appended claims limited range equally after the content of having read the present invention's instruction.
Embodiment 1
(1) modification of pure cotton fabric: 0.5g anion emulsifier lauryl sodium sulfate powder is joined in 200g water, stir, after lauryl sodium sulfate is dissolved completely, 4g epoxychloropropane (fabric-modifying agent) is dripped in the solution of above-mentioned 0.25%, dropping limit, limit is stirred, until be mixed with stable, homogeneous epoxychloropropane emulsion.
Adopt two method of modifying that roll of leaching two to process pure cotton fabric (filling yarn density 14.575tex × 14.575tex, through close 133/10cm, filling density 72/10cm), pick-up is 70%, then dries at 110 DEG C; Fabric after oven dry processes 30min at 60 DEG C in the NaOH solution of 12g/L, takes out fully washing afterwards, makes cloth cover pH value be 7, after oven dry, measure the epoxide number in COTTON FABRIC, stand-by.
The assay method of epoxide number is: configure certain density HClO
4and NaOH solution, the concentration 0.2456mol/L of the NaOH demarcated.Then modified pure cotton fabric is cut into the fragment of about 2mm × 2mm size, get 0.5g shred after COTTON FABRIC in round-bottomed flask, add the HClO that 10ml demarcates
4, and add 40ml deionized water, stir process 1h at 30 DEG C, then with the concentration titrations of the NaOH demarcated, titration is simultaneously blank, the epoxide number by following formulae discovery COTTON FABRIC:
In formula, V
0for the NaOH volume that blank sample consumes, mL; V
tfor the NaOH volume that sample sample consumes, mL; C
naOHfor NaOH concentration, mol/L; m
fabricfor the quality of COTTON FABRIC, g.
By the mensuration to the epoxide number on modified fabric, the epoxide number on fabric is 0.007mol/g fabric.
(2) preparation of mineral dye nanometer dispersant:
Under room temperature, monomer vinylacetate (12.09g is added in the four-hole boiling flask of 250mL, 0.14mol) with maleic anhydride (5.882g, 0.06mol), and add solvent ethyl acetate (100g), pass into nitrogen and be about 30min, then mechanical agitation under 300r/min, warming while stirring to 70 ~ 72 DEG C, then the initator azodiisobutyronitrile (0.085g of a part is dripped, 0.517mmol), after initator drips at 70 ~ 72 DEG C insulation reaction 2h, drip residue initator azodiisobutyronitrile (0.085g afterwards again, 0.517mmol), then be incubated in 70-72 DEG C, reaction is stopped after sustained response 10h.After product cooling, crude product is added drop-wise in chloroform and precipitates again, suction filtration, and wash repeatedly with chloroform, then in 40 DEG C of vacuum drying ovens, dry 10h, obtain copolymer.In copolymer, the actual mol ratio of maleic anhydride is 30.6%, and productive rate is 70%.
Get 10g copolymer in three mouthfuls of burning product of 100mL, take a certain amount of NaOH(8.89g, 0.22mol) be added in 60mL water, then the NaOH aqueous solution is joined in there-necked flask, stirring reaction 2h at 30 DEG C, product is added dropwise in acetone and precipitates, suction filtration after stopping by reaction, and washing repeatedly, in 40 DEG C of vacuum drying ovens, dry 10h afterwards, obtain final dispersant product, saponification degree is 40.9%.
(3) nanometer of mineral dye
Get 2g mineral dye iron oxide yellow, add 60ml water in row sand milling instrument, and add the zirconium pearl 250g that particle diameter is 2mm and 0.5mm, zirconium pearl compound proportion is 2mm:0.5mm=30:20, the consumption of the dispersant of preparation is 0.5g/g iron oxide yellow, after all preparation is ready, at room temperature open sand milling instrument, grinding 3h.The particle diameter of the iron oxide yellow obtained under this condition is 150nm, Zata is-35.2mV, use to be dyed.
(4) dyeing of mineral dye on fabric
Be that the iron oxide yellow of 150nm is mixed with the dye liquor that concentration is 10g/L by particle diameter, the pure cotton fabric of colouring method to modification adopting two leachings two to roll dyes, pick-up is 80%, after dyeing, fabric is dried under 80 DEG C × 3min condition, bakes at 130 ~ 150 DEG C × 3min, is then containing 95 DEG C of 10min that soap under the soap powder of 3%, washing, dries.
Coloration result is as shown in table 1:
Iron oxide yellow after table 1 grinds is to the coloration result of fabric
As can be seen from Table 1, relatively high by the color depth K/S value of iron oxide yellow to fabric after the cotton fabric dyeing process of embodiment 1 modification after grinding, and after dyeing after soaping, color depth K/S value is still higher, namely dyefastness is higher; And the dye level of modified fabric is significantly higher than the dye level of unmodified fabric, and the Dry Sack irregularity of modified fabric is less than 10, meets standard.
Embodiment 2
(1) modification of pure cotton fabric: 0.5g anion emulsifier lauryl sodium sulfate powder is joined in 200g water, stir, after lauryl sodium sulfate is dissolved completely, 4g epoxychloropropane (fabric-modifying agent) is dripped in the solution of above-mentioned 0.25%, dropping limit, limit is stirred, until be mixed with stable, homogeneous epoxychloropropane emulsion.
Adopt the method for modifying of dipping to pure cotton fabric (filling yarn density 14.575tex × 14.575tex, through close 133/10cm, filling density 72/10cm) modification, at 60 DEG C after impregnation process 30min, 30min is processed at 60 DEG C again in the NaOH solution of 12g/L, take out fully washing afterwards, make cloth cover pH value be 7, stand-by after drying.By the mensuration to the epoxide number on modified fabric, the epoxide number on fabric is 0.009mol/g fabric.
(2) dyeing of mineral dye on fabric
The iron oxide yellow being 150nm by particle diameter in embodiment 1 is mixed with the dye liquor that concentration is 10g/L, the pure cotton fabric of colouring method to above-mentioned modification adopting two leachings two to roll dyes, pick-up is 80%, after dyeing, fabric is dried under 80 DEG C × 3min condition, bakes at 130 ~ 150 DEG C × 3min, is then containing 95 DEG C of 10min that soap under the soap powder of 3%, washing, dries.
Coloration result is as shown in table 2:
Iron oxide yellow after table 2 grinds is to the coloration result of fabric
As can be seen from Table 2, relatively high by the color depth K/S value of iron oxide yellow to the cotton fabric dyeing process fabric of embodiment 2 modification after grinding, but the Dry Sack irregularity of modified fabric is higher.
Embodiment 3
(1) modification of pure cotton fabric: by 0.5g nonionic emulsifier AEO
10join in 200g water, stir, in the solution of above-mentioned 0.25%, then drip 4g epoxychloropropane (fabric-modifying agent), dropping limit, limit is stirred, until be mixed with stable, homogeneous epoxychloropropane emulsion.
Adopt two method of modifying that roll of leaching two to process pure cotton fabric (filling yarn density 14.575tex × 14.575tex, through close 133/10cm, filling density 72/10cm), pick-up is 70%, then dries at 110 DEG C; Fabric after oven dry processes 30min at 60 DEG C in the NaOH solution of 12g/L, takes out fully washing afterwards, makes cloth cover pH value be 7, after oven dry, measure the epoxide number in COTTON FABRIC, stand-by.
By the mensuration to the epoxide number on modified fabric, the epoxide number on fabric is 0.004mol/g fabric.
(2) dyeing of mineral dye on fabric
The iron oxide yellow being 150nm by particle diameter in embodiment 1 is mixed with the dye liquor that concentration is 10g/L, the pure cotton fabric of colouring method to above-mentioned modification adopting two leachings two to roll dyes, pick-up is 80%, after dyeing, fabric is dried under 80 DEG C × 3min condition, bakes at 130 ~ 150 DEG C × 3min, is then containing 95 DEG C of 10min that soap under the soap powder of 3%, washing, dries.
Coloration result is as shown in table 3:
Iron oxide yellow after table 3 grinds is to the coloration result of fabric
As can be seen from Table 3, relatively high by the color depth K/S value of iron oxide yellow to the cotton fabric dyeing process fabric of embodiment 3 modification after grinding, and the dye level of modified fabric is higher than the dye level of unmodified fabric, the Dry Sack irregularity of modified fabric is less than 10, meets standard.
Dyefastness in comparison sheet 1 and table 2 after embodiment 1 and the dyeing of embodiment 2 modified fabric and Dry Sack irregularity known, adopt the modified effect padding modification method relatively good for modifier epoxychloropropane; Dyefastness in comparison sheet 1 and table 3 after embodiment 1 and the dyeing of embodiment 3 modified fabric and Dry Sack irregularity known, adopt the modified effect of anion emulsifier emulsified epoxy chloropropane relatively good.
Claims (9)
1. the colouring method of natural minerals dyestuff on fabric, comprising:
(1) by dipping or pad method, with fabric-modifying agent, modification is carried out to fabric; Wherein in fabric-modifying agent molecule structure containing at least double functional group, for epoxychloropropane, glyoxal, glutaraldehyde, ethylenediamine or vulcabond;
(2) with dispersant by after natural minerals dyestuff nanometer, nano-mineral dyestuff is mixed with dye liquor, adopts two colouring methods that roll of leaching two to dye to above-mentioned modified fabric, carry out after dyeing drying, bake, soap, wash post-drying; Wherein dispersant structure formula is:
wherein, R
1for H or CH
3; R
2for C
1~ C
10alkyl, hydroxyl C
1~ C
10alkyl in one or more; R
3for H or CH
3; R
4for H or CH
3; R
5for C
1~ C
10alkyl, hydroxyl C
1~ C
10alkyl in one or more; A:b:c:d=0.3 ~ 0.5:0 ~ 0.4:0.4 ~ 0.7:0 ~ 0.2, the weight average molecular weight of dispersant is 8000-30000 gram/mol.
2. the colouring method of a kind of natural minerals dyestuff according to claim 1 on fabric, is characterized in that: the fabric in described step (1) is the one in COTTON FABRIC, linen, dacron, cotton ramie blended spinning fabric, cotton-polyester blend fabric, wool fabric, rabbit hair fabric.
3. the colouring method of a kind of natural minerals dyestuff according to claim 1 on fabric, it is characterized in that: the preparation method of described dispersant is: under room temperature, reaction monomers is added in reaction vessel, solvent, logical nitrogen 20 ~ 60min, warming while stirring is to 60-85 DEG C, drip insulation reaction 0.5 ~ 4h after a part of initator, drip residue initator again, then insulation reaction 5 ~ 12h, after product cooling, crude product is added drop-wise in the poor solvent of copolymer and precipitates again, then wash, dry to obtain copolymer, by gained copolymer with after sodium hydroxide solution mixing, saponification 1 ~ 3h at 30 ~ 50 DEG C, then products therefrom is added dropwise in acetone and precipitates again, suction filtration, washing, dry to obtain dispersant.
4. the colouring method of a kind of natural minerals dyestuff according to claim 3 on fabric, is characterized in that: described reaction monomers is maleic anhydride, R
2cOOC (R
1) CH
2, CH
2c (R
4) COOR
5in one or more, wherein R
2cOOC (R
1) CH
2middle R
1for H or CH
3, R
2for C
1~ C
10alkyl, hydroxyl C
1~ C
10alkyl in one or more; CH
2c (R
4) COOR
5middle R
4for H or CH
3, R
5for C
1~ C
10alkyl, hydroxyl C
1~ C
10alkyl in one or more.
5. the colouring method of a kind of natural minerals dyestuff according to claim 3 on fabric, is characterized in that: described solvent is methyl alcohol, ethanol, acetone, butanone, ethyl acetate, dimethyl sulfoxide (DMSO) or carbon tetrachloride; Initator is: azoic compound initiator or organic peroxide evocating agent; The poor solvent of copolymer is: acetone, chloroform, carrene, methyl alcohol or benzinum, and the poor solvent of copolymer depends on the solvent that reaction system is used and reaction monomers.
6. the colouring method of a kind of natural minerals dyestuff according to claim 5 on fabric; it is characterized in that: described azoic compound initiator is azodiisobutyronitrile or 2,2'-Azobis(2,4-dimethylvaleronitrile), organic peroxide evocating agent is benzoyl peroxide, cumyl peroxide, dilauroyl peroxide or di-isopropyl peroxydicarbonate.
7. the colouring method of a kind of natural minerals dyestuff according to claim 1 on fabric, is characterized in that: the mineral dye in described step (2) is green ore, brown ore, blue ore, red ore or yellow ore.
8. the colouring method of a kind of natural minerals dyestuff according to claim 1 on fabric, is characterized in that: in described step (2), the particle diameter of nano-mineral dyestuff is 90 ~ 300nm.
9. the colouring method of a kind of natural minerals dyestuff according to claim 1 on fabric, it is characterized in that: in described step (2), bake out temperature is 80 ~ 100 DEG C, drying time is 1 ~ 3min, and baking temperature is 130 ~ 150 DEG C, and the time of baking is 3min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210552968.6A CN103015224B (en) | 2012-12-18 | 2012-12-18 | Method for dyeing fabric with natural mineral dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210552968.6A CN103015224B (en) | 2012-12-18 | 2012-12-18 | Method for dyeing fabric with natural mineral dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103015224A CN103015224A (en) | 2013-04-03 |
| CN103015224B true CN103015224B (en) | 2015-04-22 |
Family
ID=47964289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210552968.6A Expired - Fee Related CN103015224B (en) | 2012-12-18 | 2012-12-18 | Method for dyeing fabric with natural mineral dye |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103015224B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103938386B (en) * | 2014-04-25 | 2016-11-16 | 何炽斌 | Utilize the production method of pure natural dye juice dyed cloth |
| CN106367999A (en) * | 2016-08-27 | 2017-02-01 | 新马（安徽）制衣有限公司 | Dyeing method for superfine textile fiber fabrics |
| CN106367997A (en) * | 2016-08-27 | 2017-02-01 | 新马（安徽）制衣有限公司 | Dye for superfine polyester fiber |
| CN106245375B (en) * | 2016-09-21 | 2018-06-01 | 佛山市南海德耀翔胜纺织有限公司 | A kind of dyestuff and its preparation and colouring method based on cellulose base aeroge |
| CN109252402A (en) * | 2018-07-10 | 2019-01-22 | 长兴金发纺织有限公司 | A kind of low pollution dark color bedclothes fabric colouring method |
| CN111118924B (en) * | 2019-12-30 | 2021-12-14 | 邢台恒进纺织有限公司 | Method for continuously dyeing denim |
| CN111138910B (en) * | 2020-01-10 | 2022-02-11 | 常州大学 | Mineral water red paste, preparation method thereof and application thereof in textile |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1944786A (en) * | 2006-09-22 | 2007-04-11 | 大连轻工业学院 | Yellow (red) native mordant agent of natural plant dye and its using method |
| CN101983991A (en) * | 2010-07-26 | 2011-03-09 | 杭州集美印染有限公司 | Preparation method and dyeing method of sapelli wood natural dye |
| CN102535194A (en) * | 2012-02-24 | 2012-07-04 | 台州东海塑料品制造有限公司 | Method of dyeing fabric by using dye |
-
2012
- 2012-12-18 CN CN201210552968.6A patent/CN103015224B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1944786A (en) * | 2006-09-22 | 2007-04-11 | 大连轻工业学院 | Yellow (red) native mordant agent of natural plant dye and its using method |
| CN101983991A (en) * | 2010-07-26 | 2011-03-09 | 杭州集美印染有限公司 | Preparation method and dyeing method of sapelli wood natural dye |
| CN102535194A (en) * | 2012-02-24 | 2012-07-04 | 台州东海塑料品制造有限公司 | Method of dyeing fabric by using dye |
Non-Patent Citations (2)
| Title |
|---|
| 中国传统矿物颜料、染色方法及应用前景初探;龚建培;《南京艺术学院学报》;20031125(第4期);80-84 * |
| 天然染料及其开发应用;王雪梅;《浙江纺织服装职业技术学院学报》;20100915(第3期);19-24 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103015224A (en) | 2013-04-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103015224B (en) | Method for dyeing fabric with natural mineral dye | |
| CN100432319C (en) | Fabric coating dyeing process | |
| CN101418523B (en) | Method for producing energy-saving and environment-friendly type soft resin-bonded pigment printing nap cloth | |
| CN104213349B (en) | The production method of the destarch of TR cloth, refining and dispersion dyeing one-bath process | |
| CN101348618B (en) | Preparation of nano black carbon and use of nano black carbon in fabric dyeing | |
| CN106637902B (en) | A kind of dyeing method of the polyester cotton mixed machine fabric natural elasticity fabric of resistance to industrial washing | |
| CN104213398A (en) | Production method for polyester cotton oxygen bleaching and disperse dyestuff dyeing one bath process | |
| CN106638036A (en) | Method for cation modification and salt-free dyeing of cellulose fabric through one bath | |
| CN106223003A (en) | A kind of dyeing and finishing technology of polyester cotton blending fabric | |
| CN106283723B (en) | Modified Gardenia Yellow and its method that cation-modified cellulose base fiber fabric is dyed | |
| CN110230216A (en) | A kind of Lyocell fibers fabric of natural dye dying and preparation method thereof | |
| CN102587153A (en) | Method for dyeing silk broadcloth by using plant dye solution extracted from lily | |
| CN106149425A (en) | A kind of dyeing and finishing processing method of cotton-polyester blend fabric | |
| CN108252130A (en) | The pad dyeing colouring method of alginate fibre/polyester fiber blended fabric | |
| CN101824761A (en) | Dyeing method | |
| CN102493228B (en) | Method for dyeing wool fabric by using bacterial dye of prodigiosin | |
| CN102174747A (en) | Environment-friendly textile printing pearlescent adhesive cement and preparation method and application thereof | |
| CN102605652A (en) | Method for dyeing pure silk by regarding rare earth material as mordant | |
| CN106592224A (en) | Wear-resisting ironing-free finishing liquid of shirt and finishing method of wear-resisting ironing-free finishing liquid | |
| CN106087219A (en) | The preparation method of Semen Phaseoli floss far-infrared magnetic performance shell fabric with health care function | |
| CN102433772B (en) | Natural dye dyeing method based on non-damaging modification of real silk fabrics | |
| CN103243573B (en) | A kind of dyeing and printing process for imitation memory fabric | |
| CN102767077B (en) | Dyeing method for soybean fibres and blended fabric of soybean fibres | |
| CN108193517A (en) | Terylen cotton knitting cloth directly/dispersion single bath process short route dyeing and finishing technology | |
| CN107574683A (en) | A kind of method that bafta gloss and wrinkle resistance are improved with decatize decoration method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150422 Termination date: 20171218 |