CN103013274A - Surface skid-resistant coating composition - Google Patents
Surface skid-resistant coating composition Download PDFInfo
- Publication number
- CN103013274A CN103013274A CN2012104953661A CN201210495366A CN103013274A CN 103013274 A CN103013274 A CN 103013274A CN 2012104953661 A CN2012104953661 A CN 2012104953661A CN 201210495366 A CN201210495366 A CN 201210495366A CN 103013274 A CN103013274 A CN 103013274A
- Authority
- CN
- China
- Prior art keywords
- weight parts
- described composition
- amine
- epoxy
- resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 239000011347 resin Substances 0.000 claims abstract description 22
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 14
- 239000003822 epoxy resin Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 40
- 150000001412 amines Chemical class 0.000 claims description 26
- -1 polyoxyethylene Polymers 0.000 claims description 24
- 229920002050 silicone resin Polymers 0.000 claims description 18
- 239000004593 Epoxy Substances 0.000 claims description 17
- 239000011236 particulate material Substances 0.000 claims description 15
- 229920002943 EPDM rubber Polymers 0.000 claims description 10
- 239000004743 Polypropylene Substances 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 4
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004902 Softening Agent Substances 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 229920003986 novolac Polymers 0.000 claims description 2
- 238000005457 optimization Methods 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- 125000002943 quinolinyl group Chemical class N1=C(C=CC2=CC=CC=C12)* 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 24
- 239000011248 coating agent Substances 0.000 abstract description 23
- 239000000463 material Substances 0.000 abstract description 15
- 239000002245 particle Substances 0.000 abstract description 11
- 239000011521 glass Substances 0.000 abstract description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract description 2
- 239000010703 silicon Substances 0.000 abstract description 2
- 229910052710 silicon Inorganic materials 0.000 abstract description 2
- 238000005299 abrasion Methods 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 239000004576 sand Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 10
- 229920002994 synthetic fiber Polymers 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004844 aliphatic epoxy resin Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 125000005375 organosiloxane group Chemical group 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 2
- WGRZHLPEQDVPET-UHFFFAOYSA-N 2-methoxyethoxysilane Chemical compound COCCO[SiH3] WGRZHLPEQDVPET-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920006222 acrylic ester polymer Polymers 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000004842 bisphenol F epoxy resin Substances 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- RSKGMYDENCAJEN-UHFFFAOYSA-N hexadecyl(trimethoxy)silane Chemical compound CCCCCCCCCCCCCCCC[Si](OC)(OC)OC RSKGMYDENCAJEN-UHFFFAOYSA-N 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to a surface skid-resistant coating composition which comprises the following components in parts by weight: 12-75 parts of epoxy resin and organic silicon resin, 30-60 parts of a synthetic particle material and 2-13 parts of an amine function curing agent. The surface skid-resistant coating composition also comprises a surfactant and a conventional additive. The synthetic particle material is used for replacing traditional glass beads, quarts sand and the like, thus the surface skid-resistant coating composition is better in hand feel of a coating film, has skid resistance of the existing product, and has high scratch resistance, abrasion resistance, and resistivity to outside chemical materials.
Description
Technical field
The present invention relates to a kind of surface anti-skidding coating composition.
Background technology
Anti-skid is the essential characteristic of skid-resistant coating, is a kind of property of filming and having.Skid-resistant coating mainly contains the materials such as anti-skidding pellet, film-forming resin, and anti-skidding pellet is in order to improve the additive of paint film non-skid property, to give the paint film skid resistance, the personnel's of preventing tumble injury of slipping; Film-forming resin has the effect of fixing anti-skidding pellet, protects simultaneously ground not to be damaged.
The existing history for many years of the development and use of skid-resistant coating.Abroad, base-material is selected common Synolac, chlorinated rubber, resol or modified epoxy usually, the weathering resistance of these resins, good mechanical property.Mix in the resin with hard and large particle, such as quartz sand or the analogue of cheapness, these weighting material grains protrude from the surface greatly, produce larger friction resistance, thereby reach anti-skidding purpose.
UK Patent Application 2156672 also discloses a kind of such preparation.A kind of coating composition that rough coatings is provided for sanitary product has been described in this patent application.Visit composition and comprise a kind of polymkeric substance, particularly a kind of polymethylmethacrylate, a kind of filler, a kind of particulate material and a kind of solidifying agent, preferably benzoyl peroxide.Particulate material is that 200 to 800 microns granulated glass sphere forms by size preferably.For example can aforementioned coating composition be coated in the mode of brush at such as bathtub, shower floor the end, thereby provide nonskidcoating for it.
A shortcoming of the coating of UK Patent Application 2156672 is, coatingsurface has relatively large polarity, this is because this coating is comprised of polymethyl acrylate and granulated glass sphere, thereby makes water be easy to rest between the granulated glass sphere of coating, and it is unfavorable for the non-skid property of coating.Because the existence of water, bacterium and mould also are easy to be grown in wherein, and this is not only harmful to HUMAN HEALTH, bring detrimental action also can for simultaneously the non-skid property of coating.
CN 1459479A relates to a kind of preparation at the surface coated non-skid finish.Said preparation comprises water base paint compositions, particulate material and water base solidifying agent, and this particulate material is by synthetic granulometric composition.This invention also relates to a kind of method and the method for using said preparation coating non-skid finish for preparing said preparation, has the product of non-skid finish and comprise the preparation that synthesizes particle non-skid finish is being coated surperficial application.
Summary of the invention
The object of the invention is to the problem for prior art, a kind of colour-fast, firm, scratch resistance and wear-resisting non-skid finish are provided, and outstanding weather resistance is arranged when outdoor application, chemical substance is had good resistivity.
The present invention easily uses, and has acceptable machinery and protective value when solidifying at ambient temperature, and is being exposed to later acceptable machinery and protective value under the high heat condition.
For reaching this purpose, the present invention by the following technical solutions:
A kind of surface anti-skidding coating composition is characterized in that, described composition comprises:
(A) Resins, epoxy of 12 ~ 75 weight parts and silicone resin;
(B) the synthetic particulate material of 30 ~ 60 weight parts; And
(C) the amine official of 2 ~ 13 weight parts can solidifying agent.
Resins, epoxy of the present invention is selected from the mixture of a kind of in dihydroxyphenyl propane, Bisphenol F, novolak, cyclic aliphatic, aliphatic series, polyoxyethylene glycol, the polyglycidyl ether basic ring epoxy resins or derivatives thereof or at least two kinds, bisphenol A epoxide resin for example, aliphatic epoxy resin, bisphenol F epoxy resin and polyglycidyl ether basic ring epoxy resins etc.
The parts by weight of Resins, epoxy of the present invention and silicone resin can select 12.5 ~ 74,28 ~ 63, and 40 ~ 50,42 etc., both weight ratios are 1 ~ 6, for example 1.02 ~ 5.8,1.8 ~ 5,2.6 ~ 4.6,3.2 ~ 4 etc., further preferred 2 ~ 5, most preferably 3.
Synthetic particulate material of the present invention is made by the homopolymer of homopolymer, ethene and the unsaturated olefin of polypropylene, polyethylene, polystyrene, ethene and vinyl acetate between to for plastic or the mixtures a kind of or two kinds in the EPDM rubber at least, further optimization polypropylene and/or EPDM rubber.Its parts by weight can select 30.2 ~ 58.5,38 ~ 51,43 ~ 47,46 etc.
Described synthetic particle is by the non-polar material manufacturing.The multipolymer of polypropylene, polyethylene, polystyrene, ethene and vinyl acetate between to for plastic for example, ethene and unsaturated olefin are such as multipolymer and the EPDM rubber of propylene, 1-butylene, 1-hexene and 1-octene.By using the synthetic particle of nonpolar synthetic materials, so that preparation according to the present invention was applied to the surface when upper, the coating polarity that obtains is lower, therefore, does not have or only have water seldom can be retained between the particle of coating.In addition, described synthetic materials can to unite use also very important with described water base paint compositions.According to the present invention, the synthetic materials of use is preferably polypropylene and EPDM rubber, particularly preferably EPDM rubber grain.
The hardness of synthetic materials is depended in the selection of suitable synthetic particle especially, uses as far as possible softer synthetic materials, for example uses HDPE, LDPE, perhaps even poly 1-butene.According to the present invention, the Shore hardness of the synthetic particle of use is at least 65, preferably is at least 85.Synthetic particle can be all size, and the purposes of coating is depended in the selection of size.For example, if coating is for coating bathtub or bathing base, the size of the synthetic particle of then selecting will make the coating of acquisition touch up comfortable.
Synthetic particulate material of the present invention mean sizes be 15 ~ 360 microns, for example 15.3 ~ 359 microns, 30 ~ 312 microns, 55 ~ 280 microns, 100 ~ 233 microns, 165 ~ 200 microns etc., further preferred 36 ~ 200 microns, most preferably 150 microns.The size of particulate material is relevant with its range of application.
Amine official of the present invention can solidifying agent be selected from the mixture of a kind of in aliphatic amine, cycloaliphatic amine, poly-phthalein amine, modified amine, polyoxyalkylene polyamines, polyamide base amine or the polyimidazole quinoline class or at least two kinds.Described solidifying agent is when coating is coated substrate surface, and coating composition can be crosslinked, thereby produces non-skid finish.Can use widely solidifying agent of existing known use as amine curing agent, need only the kind according to resin, suitably selection can be reacted with it and the amine curing agent of its sclerosis is got final product.
According to the present invention, well adhere from the teeth outwards in order to make preparation, preferably also contain a kind of tensio-active agent in the preparation.This tensio-active agent is preferably polysiloxane, for example propyl-triethoxysilicane, hexadecyl Trimethoxy silane, vinyl three (2-methoxy ethoxy) silane, 3-azido-propyl-triethoxysilicane, 3-thiocyano propyl triethoxy silicane, APTES and two (3-triethoxysilylpropyltetrasulfide) amine.Especially, tensio-active agent is APTES and/or two (3-triethoxysilylpropyltetrasulfide) amine of technical grade.
Described composition also comprises flow agent, defoamer, softening agent, fire retardant, dispersion agent or its mixture as auxiliary agent.
Dispersion agent among the present invention can be salt or polymeric carboxylic salt or the undersaturated poly carboxylic acid of polymer of long-chain polyamino acid amides and polymeric carboxylic ester.
Flow agent can be acrylate or inorganic modified acrylate or organo-siloxane or polyethers or polyester resin change properties of organic silicon oxygen alkane or mineral oil.
Defoamer can be organo-siloxane or acrylic ester polymer.
As the preferred technical solution of the present invention, described composition comprises:
(A) Resins, epoxy of 23 ~ 45 weight parts and silicone resin;
(B) the synthetic particulate material of 42 ~ 55 weight parts; And
(C) the amine official of 5 ~ 10 weight parts can solidifying agent.
As the most preferred technical scheme of the present invention, described composition comprises:
(A) Resins, epoxy of 30 weight parts and silicone resin;
(B) the synthetic particulate material of 52 weight parts;
(C) the amine official of 8 weight parts energy solidifying agent;
(D) polysiloxane of 7 weight parts, and
(E) auxiliary agent of 3 weight parts.
" comprising " of the present invention, mean it except described component, can also comprise other components, these other components give described coating composition different characteristics.In addition, " comprising " of the present invention, can also replace with enclosed " being " or " by ... form ".
Coating composition of the present invention can pass through the method coating of brush, roll-in, injection, blade coating or japanning.
The present invention is suitable for the surface of various materials coating nonskidcoating, such as brick, cement, wood, stone, synthetic materials, steel, iron, enamel material, bed course ethene etc.Surface to be coated can be plane, convex surface or concave surface.For example, tile work ground, shower floor and bathtub.
The present invention in use, the substrate surface that need apply with clean-out system and adhesion promotor pre-treatment first is applied to coating of the present invention on this surface again.With clean-out system and the pretreated purpose of adhesion promotor be for obtain coating with the surface good adhesive property.
If the surface is to contain silicon face, such as stone or cement, so at first clean with clean-out system, then clean with polysiloxane, according to the present invention, polysiloxane wherein is preferably the mixture of APTES and two (the silica-based propyl group of the 3-triethoxy first) amine of technical grade.
If the surface is the surface that contains synthetic materials, then preferred the processing with clean-out system first in this surface use the adhesion promotor that is comprised of polar polymer liquid to process.
The clean-out system that the present invention uses preferably comprises the organic liquid of one or more polar organic compounds.
The product that can use non-skid finish has, and for example bathtub, shower floor and tile work ground are such as the tile work ground in hospital, hotel and the natatorium.
Compare with the prior art scheme, the present invention has following beneficial effect:
It is wetting, anticorrosive that the present invention has excellent base material, the character of scratch resistance and ventilation property aspect.
The present invention has easy construction, and paint film property is good, strong adhesion, and physical strength is high, and water-fast, oil resistant, wear resistance are very high, and weathering resistance is good, and non-skid property waits well good characteristic, in producing storing, is not easy to produce layering, precipitation, good stability.
Below the present invention is described in more detail.But following example only is simple and easy example of the present invention, does not represent or limit the scope of the present invention, and interest field of the present invention is as the criterion with claims.
Embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, typical but non-limiting embodiment of the present invention is as follows:
Embodiment 1
A kind of surface anti-skidding coating composition, described composition comprises by weight:
(A) bisphenol A type epoxy resin of 75 weight parts and silicone resin; The weight ratio of described Resins, epoxy and silicone resin is 5;
(B) the polypropylene GRANULES material of 30 weight parts, its mean sizes is 200 microns; And
(C) the amine official of 13 weight parts can solidifying agent.
Embodiment 2
A kind of surface anti-skidding coating composition, described composition comprises by weight:
(A) bisphenol f type epoxy resin of 12 weight parts and silicone resin; The weight ratio of described Resins, epoxy and silicone resin is 1;
(B) the EPDM rubber grain material of 60 weight parts, its mean sizes is 36 microns; And
(C) the amine official of 2 weight parts can solidifying agent.
Embodiment 3
A kind of surface anti-skidding coating composition, described composition comprises by weight:
(A) aliphatic epoxy resin of 23 weight parts and silicone resin; The weight ratio of described Resins, epoxy and silicone resin is 2;
(B) the polypropylene GRANULES material of 55 weight parts, its mean sizes is 360 microns; And
(C) the amine official of 5 weight parts can solidifying agent.
Embodiment 4
A kind of surface anti-skidding coating composition, described composition comprises by weight:
(A) polyglycol type epoxy resins of 45 weight parts and silicone resin; The weight ratio of described Resins, epoxy and silicone resin is 6;
(B) the EPDM rubber grain material of 42 weight parts, its mean sizes is 15 microns; And
(C) the amine official of 10 weight parts can solidifying agent.
Embodiment 5
A kind of surface anti-skidding coating composition, described composition comprises by weight:
(A) Resins, epoxy of 30 weight parts and silicone resin; The weight ratio of described Resins, epoxy and silicone resin is 3;
(B) the granules of polystyrene material of 52 weight parts; Its mean sizes is 150 microns;
(C) the amine official of 8 weight parts energy solidifying agent;
(D) polysiloxane of 7 weight parts, and
(E) auxiliary agent of 3 weight parts.
The comparative example
With disclosed technical scheme among the CN 1459479A as comparative example of the present invention:
A kind of composition of water-base preparation:
A. aliphatic polyester-urethane
B. hexamethylene diisocyanate (NCO content: 23% weight)
C. water, dimethylethanolamine and acetic acid ethoxycarbonyl propyl ester or acetic acid methoxyl group propyl diester mixture
40% solution; PH=7.0-8.5; The polypropylene GRANULES or the EPDM rubber grain that add 6% (weight) in hydroxyl value (according to solid matter)=3.1-3.6 mixture.
On product of the present invention and the coating of Comparative Examples product and floor, measure its frictional coefficient such as following table:
| Embodiment | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative Examples |
| Slip ratio | 0.58 | 0.62 | 0.60 | 0.65 | 0.663 | 0.53 |
As can be seen from the above table, the frictional coefficient of product of the present invention is apparently higher than Comparative Examples, and therefore, the non-skid property excellence is in Comparative Examples.
Applicant's statement, the person of ordinary skill in the field is on the basis of above-described embodiment, concrete content point value with above-described embodiment component, combined with the technical scheme of summary of the invention part, thereby the new numerical range that produces, also be one of record scope of the present invention, the application is no longer enumerated these numerical ranges for making specification sheets simple and clear.
Claims (10)
1. a surface anti-skidding coating composition is characterized in that, described composition comprises by weight:
(A) Resins, epoxy of 12 ~ 75 weight parts and silicone resin;
(B) the synthetic particulate material of 30 ~ 60 weight parts; And
(C) the amine official of 2 ~ 13 weight parts can solidifying agent.
2. composition according to claim 1, it is characterized in that, described Resins, epoxy is selected from the mixture of a kind of in dihydroxyphenyl propane, Bisphenol F, novolak, cyclic aliphatic, aliphatic series, polyoxyethylene glycol, the polyglycidyl ether basic ring epoxy resins or derivatives thereof or at least two kinds.
3. composition according to claim 1 and 2 is characterized in that, the weight ratio of described Resins, epoxy and silicone resin is 1 ~ 6, and is further preferred 2 ~ 5, most preferably 3.
4. described composition one of according to claim 1-3, it is characterized in that, described synthetic particulate material is made by the homopolymer of homopolymer, ethene and the unsaturated olefin of polypropylene, polyethylene, polystyrene, ethene and vinyl acetate between to for plastic or the mixtures a kind of or two kinds in the EPDM rubber at least, further optimization polypropylene and/or EPDM rubber.
5. one of according to claim 1-4 described composition is characterized in that, the mean sizes of described synthetic particulate material is 15 ~ 360 microns, further preferred 36 ~ 200 microns, and most preferably 150 microns.
6. described composition one of according to claim 1-5, it is characterized in that, described amine official can solidifying agent be selected from the mixture of a kind of in aliphatic amine, cycloaliphatic amine, poly-phthalein amine, modified amine, polyoxyalkylene polyamines, polyamide base amine or the polyimidazole quinoline class or at least two kinds.
7. one of according to claim 1-6 described composition is characterized in that, described composition also contains polysiloxane as tensio-active agent.
8. one of according to claim 1-7 described composition is characterized in that, described composition also comprises flow agent, defoamer, softening agent, fire retardant, dispersion agent or its mixture as auxiliary agent.
9. one of according to claim 1-8 described composition is characterized in that, described composition comprises by weight:
(A) Resins, epoxy of 23 ~ 45 weight parts and silicone resin;
(B) the synthetic particulate material of 42 ~ 55 weight parts; And
(C) the amine official of 5 ~ 10 weight parts can solidifying agent.
10. one of according to claim 1-9 described composition is characterized in that, described composition comprises by weight:
(A) Resins, epoxy of 30 weight parts and silicone resin;
(B) the synthetic particulate material of 52 weight parts;
(C) the amine official of 8 weight parts energy solidifying agent;
(D) polysiloxane of 7 weight parts, and
(E) auxiliary agent of 3 weight parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210495366.1A CN103013274B (en) | 2012-11-28 | 2012-11-28 | A kind of surface anti-skidding coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210495366.1A CN103013274B (en) | 2012-11-28 | 2012-11-28 | A kind of surface anti-skidding coating composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103013274A true CN103013274A (en) | 2013-04-03 |
| CN103013274B CN103013274B (en) | 2016-03-09 |
Family
ID=47962403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210495366.1A Active CN103013274B (en) | 2012-11-28 | 2012-11-28 | A kind of surface anti-skidding coating composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103013274B (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265849A (en) * | 2013-05-24 | 2013-08-28 | 苏州市德莱尔建材科技有限公司 | Ethylene propylene diene monomer wear-resistant paint for wood floor |
| CN103382349A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Skid-resistant crack-resistant floor paint |
| CN103525213A (en) * | 2013-09-03 | 2014-01-22 | 吴江市冰心文教用品有限公司 | Anti-skid abrasion-resistant coating |
| CN104261204A (en) * | 2014-09-05 | 2015-01-07 | 常熟市方园纺织器材厂 | Anti-sliding abrasion-resisting yarn disc |
| CN104878378A (en) * | 2015-04-27 | 2015-09-02 | 苏州统明机械有限公司 | High temperature-resistant coating for metal surfaces and preparation method of coating |
| CN105670462A (en) * | 2016-04-21 | 2016-06-15 | 苏州群力防滑材料有限公司 | Antiskid composition coating stadium |
| CN105670461A (en) * | 2016-04-21 | 2016-06-15 | 苏州群力防滑材料有限公司 | Non-slip composition coating pedestrian overpass |
| CN106803927A (en) * | 2016-12-30 | 2017-06-06 | 国家电网公司 | A kind of 500kV converting station electric powers equipment live exploration observation device |
| CN108395676A (en) * | 2018-04-09 | 2018-08-14 | 合肥市闵葵电力工程有限公司 | A kind of high-temperature and wear-proof of bearing surface and preparation method thereof |
| CN108948944A (en) * | 2018-05-25 | 2018-12-07 | 袁杰 | A kind of preparation method of permanent seal cooling non-skid coating |
| CN110527360A (en) * | 2019-09-16 | 2019-12-03 | 深圳市刚塑科技有限公司 | A kind of surface of polymer material hardening anti-scratch coating and preparation method thereof |
| CN111393071A (en) * | 2020-04-13 | 2020-07-10 | 上海砼仁环保技术发展有限公司 | Antiskid layer material composition for permeable pavement and preparation method thereof |
| CN112205900A (en) * | 2020-10-13 | 2021-01-12 | 海宁天三纸制品有限公司 | PP chopping board and manufacturing process thereof |
| CN112662355A (en) * | 2020-12-18 | 2021-04-16 | 广州市乐基智能科技有限公司 | Liquid thread locking sealant and preparation method thereof |
| CN116285663A (en) * | 2023-03-24 | 2023-06-23 | 西南林业大学 | Organic composite material for anti-skid coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4774278A (en) * | 1985-10-01 | 1988-09-27 | Shin-Etsu Chemical Co., Ltd. | Coating compositions |
| CN1459479A (en) * | 2002-05-20 | 2003-12-03 | 布格加德贝希尔公司 | Water base preparation and method for coating slide-proof layer and product containing his slide-proof layer |
| CN102325925A (en) * | 2009-02-27 | 2012-01-18 | 阿克佐诺贝尔国际涂料股份有限公司 | The high heat resistance nonskidcoating |
-
2012
- 2012-11-28 CN CN201210495366.1A patent/CN103013274B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4774278A (en) * | 1985-10-01 | 1988-09-27 | Shin-Etsu Chemical Co., Ltd. | Coating compositions |
| CN1459479A (en) * | 2002-05-20 | 2003-12-03 | 布格加德贝希尔公司 | Water base preparation and method for coating slide-proof layer and product containing his slide-proof layer |
| CN102325925A (en) * | 2009-02-27 | 2012-01-18 | 阿克佐诺贝尔国际涂料股份有限公司 | The high heat resistance nonskidcoating |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265849A (en) * | 2013-05-24 | 2013-08-28 | 苏州市德莱尔建材科技有限公司 | Ethylene propylene diene monomer wear-resistant paint for wood floor |
| CN103382349A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Skid-resistant crack-resistant floor paint |
| CN103382349B (en) * | 2013-07-08 | 2015-06-17 | 吴江华诚复合材料科技有限公司 | Skid-resistant crack-resistant floor paint |
| CN103525213A (en) * | 2013-09-03 | 2014-01-22 | 吴江市冰心文教用品有限公司 | Anti-skid abrasion-resistant coating |
| CN103525213B (en) * | 2013-09-03 | 2016-03-16 | 吴江市冰心文教用品有限公司 | A kind of anti-skid wearable coating |
| CN104261204A (en) * | 2014-09-05 | 2015-01-07 | 常熟市方园纺织器材厂 | Anti-sliding abrasion-resisting yarn disc |
| CN104878378A (en) * | 2015-04-27 | 2015-09-02 | 苏州统明机械有限公司 | High temperature-resistant coating for metal surfaces and preparation method of coating |
| CN105670461A (en) * | 2016-04-21 | 2016-06-15 | 苏州群力防滑材料有限公司 | Non-slip composition coating pedestrian overpass |
| CN105670462A (en) * | 2016-04-21 | 2016-06-15 | 苏州群力防滑材料有限公司 | Antiskid composition coating stadium |
| CN106803927A (en) * | 2016-12-30 | 2017-06-06 | 国家电网公司 | A kind of 500kV converting station electric powers equipment live exploration observation device |
| CN108395676A (en) * | 2018-04-09 | 2018-08-14 | 合肥市闵葵电力工程有限公司 | A kind of high-temperature and wear-proof of bearing surface and preparation method thereof |
| CN108948944A (en) * | 2018-05-25 | 2018-12-07 | 袁杰 | A kind of preparation method of permanent seal cooling non-skid coating |
| CN110527360A (en) * | 2019-09-16 | 2019-12-03 | 深圳市刚塑科技有限公司 | A kind of surface of polymer material hardening anti-scratch coating and preparation method thereof |
| CN111393071A (en) * | 2020-04-13 | 2020-07-10 | 上海砼仁环保技术发展有限公司 | Antiskid layer material composition for permeable pavement and preparation method thereof |
| CN112205900A (en) * | 2020-10-13 | 2021-01-12 | 海宁天三纸制品有限公司 | PP chopping board and manufacturing process thereof |
| CN112662355A (en) * | 2020-12-18 | 2021-04-16 | 广州市乐基智能科技有限公司 | Liquid thread locking sealant and preparation method thereof |
| CN116285663A (en) * | 2023-03-24 | 2023-06-23 | 西南林业大学 | Organic composite material for anti-skid coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103013274B (en) | 2016-03-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103013274B (en) | A kind of surface anti-skidding coating composition | |
| CN105176220B (en) | Synthetic emulsion diatom interiro wall latex paint and preparation method thereof | |
| TWI619781B (en) | Anti-slip coating and preparation, application method thereof | |
| CN102391767B (en) | High-solid-content interior and exterior crosslinked type water-in-water colorful granite paint and preparation method thereof | |
| AU2012244167A1 (en) | Peelable flexible coating, compositions and methods thereof | |
| CN102367354A (en) | Solvent-free epoxy primer for corrosion protection of 3 polypropylene (PP) at craters of steel pipelines | |
| CN105086794B (en) | Antiskid liquid, Non-slip material and preparation method thereof | |
| CN104513604A (en) | Double-component solvent-free polyurethane coating for preventing corrosion of outer wall of metal pipeline | |
| CN105440925A (en) | Waterborne woodware surface color modifier | |
| CN103409034A (en) | Skid-resistant coating and application thereof | |
| ES2151281T5 (en) | PREPARATION AND METHOD OF APPLICATION OF A NON-SLIP COAT ON A SURFACE AND PRODUCT PROVIDED WITH A NON-SLIP COAT. | |
| CN101613570B (en) | Colored gorgeous texture floor coating and construction method thereof | |
| CN105238201A (en) | Aerosol tile antiskid coating and preparation method thereof | |
| CN106010122A (en) | Hydrophobic corrosion-resistant ceramic paint and preparing method thereof | |
| CN107573856A (en) | A kind of anti-skidding Wax composition of water-based ceramic tile | |
| CN207469672U (en) | Anti-skidding antistatic floor lacquer coat | |
| CN108485498A (en) | A kind of super abrasive coating material | |
| US20170029678A1 (en) | Anti-slip flooring material, method for manufacturing anti-slip flooring material, and method for constructing floor by using anti-slip flooring material | |
| CN104926369B (en) | Non-slip material and preparation method thereof | |
| KR101250000B1 (en) | Composition for epoxy primer | |
| CN105711198B (en) | A kind of anti-skidding coiled material of automatically cleaning and preparation method thereof | |
| CN105238226A (en) | Solvent-free epoxy sand-surface non-slip terrace | |
| KR101623509B1 (en) | Flooring material composition for kitchen of high thermal resistance and high chemical resistance with high hygiene function, and treatment method of concrete surface using the same | |
| KR20160025921A (en) | Nonslip flooring material and method for constructing floor using the same | |
| US8772388B1 (en) | Intermediate resin blend for improved coatings |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 239351 Anhui city of Chuzhou province Tianchang Tianchang gold set Huangzhuang Industrial Park in Tianchang Kai Lin Chemical Co. Ltd. Applicant after: ANHUI KAILIN NEW MATERIAL Co.,Ltd. Address before: 239351 Anhui city of Chuzhou province Tianchang Tianchang gold set Huangzhuang Industrial Park in Tianchang Kai Lin Chemical Co. Ltd. Applicant before: TIANCHANG KAILIN CHEMICAL Co.,Ltd. |
|
| COR | Change of bibliographic data | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Surface antiskid coating composition Effective date of registration: 20220107 Granted publication date: 20160309 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI KAILIN NEW MATERIAL Co.,Ltd. Registration number: Y2022980000108 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230106 Granted publication date: 20160309 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI KAILIN NEW MATERIAL Co.,Ltd. Registration number: Y2022980000108 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A surface anti-skid coating composition Effective date of registration: 20230109 Granted publication date: 20160309 Pledgee: Tianchang Science and Technology Financing Guarantee Co.,Ltd. Pledgor: ANHUI KAILIN NEW MATERIAL Co.,Ltd. Registration number: Y2023980030581 |