CN102992900A - Pesticide-fertilizer composition containing nereistoxin and pyrethroid pesticides - Google Patents
Pesticide-fertilizer composition containing nereistoxin and pyrethroid pesticides Download PDFInfo
- Publication number
- CN102992900A CN102992900A CN2012104997782A CN201210499778A CN102992900A CN 102992900 A CN102992900 A CN 102992900A CN 2012104997782 A CN2012104997782 A CN 2012104997782A CN 201210499778 A CN201210499778 A CN 201210499778A CN 102992900 A CN102992900 A CN 102992900A
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- CN
- China
- Prior art keywords
- fertilizer composition
- fertilizer
- medicine fertilizer
- pesticide
- nereistoxin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 38
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 241000576429 Forsythia suspensa Species 0.000 description 1
- 229930191978 Gibberellin Natural products 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 240000000233 Melia azedarach Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 240000003889 Piper guineense Species 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 235000006753 Platycodon grandiflorum Nutrition 0.000 description 1
- 240000003582 Platycodon grandiflorus Species 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 241000405414 Rehmannia Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 239000000877 Sex Attractant Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 241001671204 Stemona Species 0.000 description 1
- UMVBXBACMIOFDO-UHFFFAOYSA-N [N].[Si] Chemical compound [N].[Si] UMVBXBACMIOFDO-UHFFFAOYSA-N 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical group C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003448 gibberellin Substances 0.000 description 1
- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical class C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 239000003621 irrigation water Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229960001952 metrifonate Drugs 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000011278 mitosis Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 239000006012 monoammonium phosphate Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000003375 plant hormone Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000001243 protein synthesis Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229940126589 solid medicine Drugs 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000014616 translation Effects 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- UOXSXMSTSYWNMH-UHFFFAOYSA-L zinc;2-aminoacetate Chemical compound [Zn+2].NCC([O-])=O.NCC([O-])=O UOXSXMSTSYWNMH-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide-fertilizer composition containing nereistoxin and pyrethroid pesticides. The pesticide-fertilizer composition comprises active ingredients, efficiency enhancing ingredients and fertilizer ingredients, wherein the active ingredients consist of nereistoxin pesticides and pyrethroid pesticides, the efficiency enhancing ingredients consist of fulvic acid and silicon abundance ring, and the fertilizer ingredients comprise any one or more than one of humic acid, amino acid, ammonium sulfate, potassium sulphate, urea, ammonium nitrate, ammonium bicarbonate, potassium chloride, monopotassium phosphate, calcium superphosphate and calcium-magnesia phosphate fertilizer. By application of the drug fertilizer composition, the yield of crops can be improved, the prevention effect on injurious insects can be improved, and the pesticide residue can be reduced. The weight ratio of the nereistoxin pesticides to the pyrethroid pesticide is 10-50: 1-5.
Description
Technical field
The invention belongs to agrochemical field, relate to the medicine fertilizer composition that is formed by sterilant, synergistic component and plant nutrient substance, relate to particularly a kind of medicine fertilizer composition, purposes and preparation thereof of comprising ethiprole of preventing and treating the crop subterranean pest-insect and nutrition being provided.Relate more specifically to a kind of medicine fertilizer composition that comprises ethiprole.
Background technology
At present sterilant medicine fertilizer more and more is subject to peasant's welcome, and it can desinsection on the one hand, can provide the crop alimentary material on the other hand, and the applied once medicine is fertile, solves except insect pest and somatotrophic problem simultaneously.The fertile Patents of disclosed medicine is a lot of at present, for example following patent application:
Number of patent application 02131126 discloses a kind of Aju water dispersion granule and production method thereof, technical scheme is with Avrmectin and efficient cypermethrin compounded pesticide composition, take chemical fertilizer as carrier, be added with auxiliary agent and emulsifying agent, make it the water dispersible granules that granulating and forming is combination of pesticide and fertilizer.
Number of patent application 201110282407 discloses a kind of Insecticidal fertilizer, its technical scheme Insecticidal fertilizer comprises: anion surfactant 10-30%, carboxy methyl cellulose 1-2%, polynary emulsifying agent 1-3%, sodium sulfate 16-25%, stablizer 0.5-2%, tripoly phosphate sodium STPP 3-10%, microemulsion 1-5%, urea 20-40%, monoammonium phosphate or/and diammonium phosphate 1-5%, Repone K or/and vitriolate of tartar 1-5%, described microemulsion is at least a in fenvalerate emulsion, 45% imidacloprid emulsion.
It is fertile that number of patent application 201210085799 discloses a kind of multifunctional bio medicine, its technical scheme is that multifunctional bio medicine fertilizer is by urea 10-20 part, Repone K 10-15 part, zinc sulfate 0.2-0.7 part, manganous sulfate 0.3-0.8 part, ferrous sulfate 0.4-0.9 part, borax 0.8-2.0 part, naphthylacetic acid 0-0.03 part, Plant hormones regulators,gibberellins 0.01-0.04 part, ammonium sulfate 6-12 part, diammonium phosphate 5-9 part, organic raw material 30-40 part, sterilant 0.04-0.08 part, sterilant 0.03-0.05 part, additive 5-9 part, peat soil 9-11 part, Chinese cabbage slag 10-13 part, dregs of a decoction 15-20 part forms; Described sterilant is Volaton or Trichlorphon; Described sterilant is derosal or m-tetrachlorophthalodinitrile; Described additive is one or more of zinc-amino acid chelate, manganese, iron, copper, molybdenum, boron; Described organic raw material is comprised of the raw material of following weight proportion: chinaberry fruit 4-7 part, Pepper stalk 15-19 part, the cow dung that fully becomes thoroughly decomposed or hog manure 30-40 part, yeast 0.06-0.15 part; The described dregs of a decoction comprise by weight: Radix Codonopsis 3.1-4.5 part, tuber of stemona 2.1-3.2 part, rhizoma Gastrodiae 0.6-1.5 part, capsule of weeping forsythia 0.8-1.3 part, glutinous rehmannia 2.3-2.8 part, balloonflower root 0.5-1.3 part.
Number of patent application 201010534319 discloses a kind of nuisance-free medicinal fertilizer of can insect-killing trapping, again can promoting growth of plants and preparation method thereof, nuisance-free medicinal fertilizer comprises organic fertilizer 10-90%, sex attractant 0.2-40%, sterilant 2-40%, organic 5-40%, auxiliary agent 0.1-30%.
Number of patent application 200810028884 discloses a kind of fertilizer granules, and fertilizer granules is by Chlorpyrifos 94, macroelement N, P, K, trace element zinc, boron, sustained release dosage, attractive substance, dispersing auxiliary, media assemblage; Wherein: Chlorpyrifos 94 content 0.1%-30%; Macroelement N content 5%-45%, P content 1%-15%, K content 1%-20% in the fertilizer composition, trace element zinc content 0.1%-5%, boron content 0.1%-5% in the fertilizer composition; Sustained release dosage content 0.1%-5%, attractive substance content 0.1%-10%, dispersing auxiliary content 0.5%-5%, all the other are filler.
The disclosed medicine fertilizer of above-mentioned document is realized the fertile mixing of medicine although realized medicine and fertilizer with certain physical aspect in the process of using, in the process of using, can not realize influencing each other of medicine and fertilizer, and effect is general.And do not solve the problem of dispenser process Pesticide Residues.
Summary of the invention
For solving the problems of the technologies described above, the invention provides a kind of medicine fertilizer composition that comprises neires toxin and pyrethroid insecticides, this medicine fertilizer composition comprises activeconstituents, synergistic component and fertilizer component, activeconstituents is comprised of neires toxin and pyrethroid insecticides, synergistic component is comprised of xanthohumic acid and silicon Feng Huan, fertilizer component comprises humic acids, amino acid, ammonium sulfate, vitriolate of tartar, urea, ammonium nitrate, bicarbonate of ammonia, any one in Repone K, potassium primary phosphate, calcium superphosphate and the fused(calcium magnesium)phosphate or multiple.This medicine fertilizer composition can improve the output of crop, improves the preventive effect of insect and reduces pesticide residue.Wherein the weight ratio of neires toxin and pyrethroid insecticides is 10-50: 1-5.
In the above-mentioned medicine fertilizer composition, the weight ratio of xanthohumic acid and silicon Feng Huan is 10-30: 1-5.
In the above-mentioned medicine fertilizer composition, the weight ratio of activeconstituents, synergistic component and fertilizer component is 0.1-2: 10-50: 100-1000.
In the above-mentioned medicine fertilizer composition, pyrethroid insecticides is selected from Deltamethrin, fenvalerate, Fenvalerate, bifenthrin, Cypermethrin, lambda-cyhalothrin, tralomethrin, flucythrinate, permethrin, one or more in acrinathrin and the brofluthrinate.
In the above-mentioned medicine fertilizer composition, sandworm toxin insecticide is selected from one or more in cartap, desinsection peace, disosultap, monosultap ammonium, thiocyclam, desinsection list, bensultap, the polythiane.
The present invention also provides and has used above-mentioned medicine fertilizer composition raising crop yield and improve the purposes of killing the insect effect, and wherein said crop is any in eggplant, tomato, potato, sweet potato, radish, jowar, tobacco, wheat, paddy rice, corn, cucumber, peanut, coconut, balsam pear, soybean, tea tree, rubber, sugarcane, pea, wax gourd, pears, banana, pawpaw, green soy bean, mango, watermelon, oranges and tangerines, orange, Kiwifruit, strawberry, pineapple, capsicum, apple, jujube, persimmon, grape, cherry, lichee, peach and the cotton; Described insect is one or more in the snout moth's larva of rice, aphid, mite class, leafhopper, plant hopper, thrips, Cnaphalocrocis medinali(rice leaf roller), rice plant skipper, phyllocnistis citrella stainton, cabbage caterpillar, small cabbage moth, tea geometrid, the thin moth of tea, smaller green leaf hopper, Pyrausta nubilalis (Hubern)., sugarcane borer, eating-core bean worm, melon trypetid, bollworm, the weevil etc.
Above-mentioned medicine fertilizer composition can be prepared into liquid medicine fertilizer, also can be prepared into solid medicine fertilizer.
The application process of above-mentioned medicine fertilizer composition if the pest damage phase of fertilizer application period and crop is more approaching, preferably can be coordinated fertilization time with the application process of compound manure, strives for reaching the dual function of volume increase and desinsection.
The method of fertilising can be applied fertilizer by the root solid, or dissolves fertilizer in the irrigation water, and best mode is again row irrigation after the fertilising of root solid.
Introduced in the present invention xanthohumic acid and silicon Feng Huan as reinforcing aids, increased the effect of crop yield when realizing effectively killing crop pest, and can reduce the insecticide residues of executing on the crop.
Fulvic acid substance is to the extensive production-increasing function of farm crop, and the multiple product for agriculture such as foliage fertilizer that contain xanthohumic acid all have the effect that strengthens crop anti-adversity and improve output.The used xanthohumic acid of the present invention is the xanthohumic acid that extracts in the alcohol slops of sugarcane deep processing alcohol.
Silicon Feng Huan is a kind of silicoorganic compound with outstanding molecular structure and notable biological activity.Can improve plant cell mitosis, strengthen photosynthesis, promote protein synthesis, thereby improve the ability of plant Absorbing Nutrients, promote the formation of crop kernel, increase the protein content of fruit, reach and make crop precocious, increase the effect of thousand seed weight, crop yield is increased considerably.Can improve the anti-adversity abilities such as plant is disease-resistant, cold-resistant, resistant to lodging, be applicable to one and cut plant.Have the advantages such as wide spectrum, efficient, low toxicity, noresidue, chemical name is the chloromethyl hetero nitrogen silicon tricyclic, and this medicine can be bought from market and obtain.
The present invention so that medicine fertilizer composition of the present invention can improve the output of crop, improves the preventive effect to insect through with xanthohumic acid and the silicon Feng Huan builder as sterilant, can also effectively reduce the pesticide residue of sterilant in crop simultaneously.
Embodiment
In order to understand the present invention, the below further specifies the present invention with embodiment, but does not limit the present invention.
The material of using among the following embodiment is market and buys, and all can buy from market to obtain.If use mineral manure in the medicine fertilizer composition, then the prilling process of medicine fertilizer can adopt the conventional prilling process of composite fertilizer, also can adopt following preparation method's granulation:
The batching of raw material: will live in generating and divide, synergistic component and fertilizer are prepared according to weight;
Mix and blend: the raw material stirring for preparing is evenly improved the even fertilizer efficiency content of fertiliser granulates integral body, adopt horizontal mixer or pan mixer to carry out mix and blend;
Caking is pulverized: with the pulverizing such as raw material bulk caking of mixing and stirring, be convenient to subsequent granulation processing, mainly adopt chain type pulverizer etc.;
The material granulation: the material after will stirring, crushing is sent into tablets press by rotary conveyor and is carried out granulation;
The one-level screening: tentatively sieve the particle work in-process, underproof particle returns the reprocessing of mix and blend link, generally uses cylinder round sifter;
The particle oven dry: particle that tablets press is made and the screening of process one-level is sent into dryer, and the moisture oven dry with particle includes increases granule strength;
The particle cooling: the fertiliser granulates excess Temperature after the oven dry, easily caking through cooled, be convenient to pack and preserved, and transportation, adopts cooler to cool off;
The classification of particle secondary: will cool off gradation later, underproof particle sieves qualified product out through pulverizing again granulation, can sieve with the two stage cylinder sieve apparatus;
Finished particle coating: qualified product is coated with brightness and the roundness degree that the clothing coating increases particle, carries out coating with coating machine;
The finished particle quantitative package: the particle that wrapped film namely finished particle is sent into feed bin by rotary conveyor and is temporarily stored, and the automatic quantitative packing envelopes such as connecting electronic ration package scale, sack closer are placed the ventilation and preserved again.
The xanthohumic acid of xanthohumic acid for from the alcohol slops of sugarcane deep processing alcohol, extracting, the preparation method is as follows:
1kg alcohol slops decompression heating evaporation is concentrated, control pressure, vaporization temperature is 40 ℃ ± 3 ℃, the stopped heating when weight percent of dry-matter reaches 60% in the measurement concentrated solution obtains concentrated solution; Stirred liq at the uniform velocity in the heat-processed.Then in concentrated solution, add the vitriol oil, make that the mass concentration of sulfuric acid reaches 30% in the concentrated solution, 60 ± 2 ℃ of lower ageings 20 hours, get ageing liquid;
With the sodium hydroxide solution alkalization of ageing liquid with 0.5%wt, stir the lower sodium hydroxide solution that adds, measure the pH of solution, regulate the add-on of sodium hydroxide solution, when being 8, pH stops to add sodium hydroxide solution, occur precipitation in the solution, will precipitate part by removing by filter, obtain solution I;
With the hydrochloric acid soln acidifying with 8%wt of the solution I of above-mentioned acquisition, stir when adding hydrochloric acid soln and measure pH, when being 1, pH value stops to add hydrochloric acid soln, and precipitation appears in the solution, will precipitate partly by removing by filter the acquisition solution II;
In solution II, add acetone, the volume of the acetone of adding be solution II volume 10%.The solution that has added acetone is fully stirred, and the acetone soln part is collected in then centrifugal layering;
Partly input acetone soln in the still kettle, the decompression heating maintains the temperature at 45 ℃ ± 2 ℃ lower concentrated acetone solns, with recover acetone, and remaining material, maintain the temperature at 45 ℃ ± 2 ℃ lower dryings through the decompression heating, obtain solid phase prod xanthohumic acid 21.78g after the drying.
Embodiment 1:
Get raw material Deltamethrin 0.02kg, desinsection peace 0.4kg, xanthohumic acid 20kg, the former medicine 2kg of silicon Feng Huan, urea 220kg, fused(calcium magnesium)phosphate 210kg, vitriolate of tartar 248kg is prepared into granule according to the preparation technology of composite fertilizer.
Embodiment 2:
Get raw material tralomethrin 0.02kg, desinsection list 0.4kg, xanthohumic acid 15kg, the former medicine 5kg of silicon Feng Huan, ammonium sulfate 420kg, fused(calcium magnesium)phosphate 210kg, Repone K 150kg is prepared into granule according to the preparation technology of composite fertilizer.
Embodiment 3:
Get raw material lambda-cyhalothrin 0.02kg, thiocyclam 0.4kg, xanthohumic acid 25kg, the former medicine 5kg of silicon Feng Huan, ammonium nitrate 285kg, calcium superphosphate 335kg, Repone K 150kg is prepared into granule according to the preparation technology of composite fertilizer.
The comparative example 1:
Get raw material Deltamethrin 0.02kg, desinsection peace 0.4kg, urea 220kg, fused(calcium magnesium)phosphate 232kg, vitriolate of tartar 248kg is prepared into granule according to the preparation technology of composite fertilizer.
The comparative example 2:
Get raw material tralomethrin 0.02kg, desinsection list 0.4kg, ammonium sulfate 420kg, fused(calcium magnesium)phosphate 210kg, Repone K 170kg is prepared into granule according to the preparation technology of composite fertilizer.
The comparative example 3:
Get raw material lambda-cyhalothrin 0.02kg, thiocyclam 0.4kg, ammonium nitrate 285kg, calcium superphosphate 365kg, Repone K 150kg is prepared into granule according to the preparation technology of composite fertilizer.
Effect embodiment:
The medicine fertilizer of Application Example 1-3 and comparative example 1-3 is at paddy field application by throwing them, the preventive effect that detected insect on the paddy rice on the 5th day after the dispenser, the insecticidal total residual quantity that detected in the rice plant at the 15th day.Residual quantity detects according to ratio method, directly compares as the 100% insecticidal total residual quantity that compares different sterilant medicine fertilizer with pesticide total residue in the rice plant of comparative example 1-3 dispenser.The output situation is added up when harvesting.
As can be seen from the above, when medicine fertilizer composition of the present invention is applicable to Control Insect Pests In Rice Field, not only improve output, and has preferably preventive effect in the control of rice grub, basically reach the preventive effect more than 90%, and reduced pesticide residue number, pesticide residue reduces.
From interpretation of result, the adding of xanthohumic acid and silicon Feng Huan is so that the drug effect raising of sterilant, these two kinds of auxiliary agents add simultaneously can also further reduce pesticide residue, improve output, both are combined with, improve output on the one hand, increased the preventive effect to rice grub, reduced on the other hand pesticide residue.
Claims (7)
1. medicine fertilizer composition that comprises neires toxin and pyrethroid insecticides, this medicine fertilizer composition comprises activeconstituents, synergistic component and fertilizer component, activeconstituents is comprised of neires toxin and pyrethroid insecticides, synergistic component is comprised of xanthohumic acid and silicon Feng Huan, fertilizer component comprises humic acids, amino acid, ammonium sulfate, vitriolate of tartar, urea, ammonium nitrate, bicarbonate of ammonia, Repone K, potassium primary phosphate, in calcium superphosphate and the fused(calcium magnesium)phosphate any one or multiple, wherein the weight ratio of neires toxin and pyrethroid insecticides is 10-50: 1-5.
2. medicine fertilizer composition according to claim 1, wherein the weight ratio of xanthohumic acid and silicon Feng Huan is 10-30: 1-5.
3. medicine fertilizer composition according to claim 1 and 2, wherein the weight ratio of activeconstituents, synergistic component and fertilizer component is 0.1-2: 10-50: 100-1000.
4. each described medicine fertilizer composition according to claim 1-3, wherein pyrethroid insecticides is selected from Deltamethrin, fenvalerate, Fenvalerate, bifenthrin, Cypermethrin, lambda-cyhalothrin, tralomethrin, flucythrinate, permethrin, one or more in acrinathrin and the brofluthrinate.
5. each described medicine fertilizer composition according to claim 1-4, wherein sandworm toxin insecticide is selected from one or more in cartap, desinsection peace, disosultap, monosultap ammonium, thiocyclam, desinsection list, bensultap, the polythiane.
6. application rights requires each described medicine fertilizer composition of 1-5 to improve crop yield and improve the purposes of killing the insect effect, and wherein said crop is any in eggplant, tomato, potato, sweet potato, radish, jowar, tobacco, wheat, paddy rice, corn, cucumber, peanut, coconut, balsam pear, soybean, tea tree, rubber, sugarcane, pea, wax gourd, pears, banana, pawpaw, green soy bean, mango, watermelon, oranges and tangerines, orange, Kiwifruit, strawberry, pineapple, capsicum, apple, jujube, persimmon, grape, cherry, lichee, peach and the cotton; Described insect is one or more in the snout moth's larva of rice, aphid, mite class, leafhopper, plant hopper, thrips, Cnaphalocrocis medinali(rice leaf roller), rice plant skipper, phyllocnistis citrella stainton, cabbage caterpillar, small cabbage moth, tea geometrid, the thin moth of tea, smaller green leaf hopper, Pyrausta nubilalis (Hubern)., sugarcane borer, eating-core bean worm, melon trypetid, bollworm, the weevil etc.
7. the application process of each described medicine fertilizer composition of claim 1-5, the method is with the application process of compound manure, if the pest damage phase of fertilizer application period and crop is more approaching, preferably can coordinate fertilization time, strive for reaching the dual function of volume increase and desinsection.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210499778.2A CN102992900B (en) | 2012-11-29 | 2012-11-29 | Pesticide-fertilizer composition containing nereistoxin and pyrethroid pesticides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210499778.2A CN102992900B (en) | 2012-11-29 | 2012-11-29 | Pesticide-fertilizer composition containing nereistoxin and pyrethroid pesticides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102992900A true CN102992900A (en) | 2013-03-27 |
| CN102992900B CN102992900B (en) | 2014-11-26 |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651517A (en) * | 2013-12-12 | 2014-03-26 | 济南凯因生物科技有限公司 | Monosultap contained EW (emulsion in water) and application |
| CN103651515A (en) * | 2013-12-12 | 2014-03-26 | 济南凯因生物科技有限公司 | Thiocyclam-containing emulsion in water and application |
| CN103651528A (en) * | 2013-12-10 | 2014-03-26 | 济南凯因生物科技有限公司 | Composition containing thiocyclam and application of composition |
| CN103651531A (en) * | 2013-12-10 | 2014-03-26 | 济南凯因生物科技有限公司 | Water dispersible granules containing cartap and application of water dispersible granules |
| CN103651518A (en) * | 2013-12-12 | 2014-03-26 | 济南凯因生物科技有限公司 | Cartap contained EW (emulsion in water) and application |
| CN103772067A (en) * | 2014-01-07 | 2014-05-07 | 叶长东 | Humic acid-type organic-inorganic insecticide-fertilizer composition containing tea saponin and prepared by using waste of sugar refineries and alcohol plants |
| CN103772068B (en) * | 2014-01-07 | 2016-01-20 | 叶长东 | A kind of Humic acid type organic-inorganic medicine fertilizer composition comprising neires toxin and nicotinic insecticide utilizing sugar refinery, grain distillery's waste |
| CN105272619A (en) * | 2015-10-30 | 2016-01-27 | 广西金神农生态农业科技开发有限公司 | Foliar fertilizer for hybrid oranges |
| CN107827624A (en) * | 2017-12-20 | 2018-03-23 | 青岛住商中农肥料有限公司 | A kind of Synergistic slow release urea and its preparation technology |
| CN107853307A (en) * | 2017-11-30 | 2018-03-30 | 惠州市支持网知识产权运营有限公司 | A kind of insecticide fertilizer composition |
| CN109232078A (en) * | 2018-09-17 | 2019-01-18 | 上海必增生物科技有限公司 | A kind of organosilicon biological composition and its application method |
| CN112314620A (en) * | 2020-11-16 | 2021-02-05 | 辽宁山水益农科技有限公司 | Multi-effect insecticidal composition containing organic silicon plant growth regulator |
| WO2024014946A1 (en) * | 2022-07-15 | 2024-01-18 | Учреждение "Международный Казахско-Турецкий Университет Имени Ходжи Ахмеда Ясави" | Complex insecticide and fertilizer for melon fly control |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101560126A (en) * | 2009-05-31 | 2009-10-21 | 刘庆丰 | Water-application quick floating oil pesticide and application method thereof |
| CN102775246A (en) * | 2012-08-16 | 2012-11-14 | 叶长东 | Fipronil-containing pesticide fertilizer composition |
| CN102775245A (en) * | 2012-08-16 | 2012-11-14 | 叶长东 | Pesticide-fertilizer composition containing Fipronil and pyrethroid pesticides |
-
2012
- 2012-11-29 CN CN201210499778.2A patent/CN102992900B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101560126A (en) * | 2009-05-31 | 2009-10-21 | 刘庆丰 | Water-application quick floating oil pesticide and application method thereof |
| CN102775246A (en) * | 2012-08-16 | 2012-11-14 | 叶长东 | Fipronil-containing pesticide fertilizer composition |
| CN102775245A (en) * | 2012-08-16 | 2012-11-14 | 叶长东 | Pesticide-fertilizer composition containing Fipronil and pyrethroid pesticides |
Non-Patent Citations (2)
| Title |
|---|
| 吴海花等: "《杀虫剂毒理学》", 31 May 2010, 中国农业科学技术出版社 * |
| 苏建坤等: "杀虫剂触杀联合毒力的研究", 《安徽农业科学》 * |
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| CN103651528A (en) * | 2013-12-10 | 2014-03-26 | 济南凯因生物科技有限公司 | Composition containing thiocyclam and application of composition |
| CN103651531A (en) * | 2013-12-10 | 2014-03-26 | 济南凯因生物科技有限公司 | Water dispersible granules containing cartap and application of water dispersible granules |
| CN103651515B (en) * | 2013-12-12 | 2015-06-10 | 徐茂航 | Thiocyclam-containing emulsion in water and application |
| CN103651515A (en) * | 2013-12-12 | 2014-03-26 | 济南凯因生物科技有限公司 | Thiocyclam-containing emulsion in water and application |
| CN103651518A (en) * | 2013-12-12 | 2014-03-26 | 济南凯因生物科技有限公司 | Cartap contained EW (emulsion in water) and application |
| CN103651517A (en) * | 2013-12-12 | 2014-03-26 | 济南凯因生物科技有限公司 | Monosultap contained EW (emulsion in water) and application |
| CN103772067A (en) * | 2014-01-07 | 2014-05-07 | 叶长东 | Humic acid-type organic-inorganic insecticide-fertilizer composition containing tea saponin and prepared by using waste of sugar refineries and alcohol plants |
| CN103772068B (en) * | 2014-01-07 | 2016-01-20 | 叶长东 | A kind of Humic acid type organic-inorganic medicine fertilizer composition comprising neires toxin and nicotinic insecticide utilizing sugar refinery, grain distillery's waste |
| CN103772067B (en) * | 2014-01-07 | 2016-01-20 | 叶长东 | A kind of Humic acid type organic-inorganic medicine fertilizer composition comprising tea saponin utilizing sugar refinery, grain distillery's waste |
| CN105272619A (en) * | 2015-10-30 | 2016-01-27 | 广西金神农生态农业科技开发有限公司 | Foliar fertilizer for hybrid oranges |
| CN107853307A (en) * | 2017-11-30 | 2018-03-30 | 惠州市支持网知识产权运营有限公司 | A kind of insecticide fertilizer composition |
| CN107827624A (en) * | 2017-12-20 | 2018-03-23 | 青岛住商中农肥料有限公司 | A kind of Synergistic slow release urea and its preparation technology |
| CN109232078A (en) * | 2018-09-17 | 2019-01-18 | 上海必增生物科技有限公司 | A kind of organosilicon biological composition and its application method |
| CN112314620A (en) * | 2020-11-16 | 2021-02-05 | 辽宁山水益农科技有限公司 | Multi-effect insecticidal composition containing organic silicon plant growth regulator |
| WO2024014946A1 (en) * | 2022-07-15 | 2024-01-18 | Учреждение "Международный Казахско-Турецкий Университет Имени Ходжи Ахмеда Ясави" | Complex insecticide and fertilizer for melon fly control |
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Denomination of invention: The invention relates to a medicine fertilizer composition containing Nereis toxin and pyrethroid insecticide Effective date of registration: 20200923 Granted publication date: 20141126 Pledgee: Bank of Communications Ltd. the Guangxi Zhuang Autonomous Region branch Pledgor: Ye Changdong Registration number: Y2020450000039 |
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