CN102964177A - Heavy-metal-resistant plant growth detoxification accelerant and method for using same - Google Patents
Heavy-metal-resistant plant growth detoxification accelerant and method for using same Download PDFInfo
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- CN102964177A CN102964177A CN 201210452414 CN201210452414A CN102964177A CN 102964177 A CN102964177 A CN 102964177A CN 201210452414 CN201210452414 CN 201210452414 CN 201210452414 A CN201210452414 A CN 201210452414A CN 102964177 A CN102964177 A CN 102964177A
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Abstract
The invention discloses a heavy-metal-resistant plant growth detoxification accelerant and a method for using the same. The accelerant is characterized by containing low dose of one of selenate or selenite, wherein an amino acid micro element fertilizer is also added, and the accelerant is sprayed onto the leaves for a plurality of times during a period of 7-40 days before crops are harvested. A method for preparing and the method for using are simple and practicable and are convenient to popularize. By the accelerant, the contents of heavy metals of cadmium, antimonium and the like in the crops can be effectively reduced, the crop yield and quality are improved, and the problem that most people in China insufficiently intake selenium can be relieved through a method of reasonably increasing selenium contents in agricultural products, so that the production safety of the agricultural products in heavy metal pollution regions is effectively guaranteed.
Description
Technical field:
The invention belongs to agricultural technology field, be specifically related to a kind of plant detoxifcation growth stimulant and using method thereof that the heavy metals such as cadmium, antimony is had resistance.
Background technology:
Because Study on Soil Pollution Problems industrial, that agriculture production causes is on the rise, the pollution problem of especially ploughing has aggravated the contradiction that China has a large population and a few land at present.It is estimated, the whole nation is subjected to the grain of heavy metal contamination up to more than 1,000 ten thousand tons every year, nearly 20,000,000,000 yuan of the direct economic losses that causes, need reparation and the control of carrying out contaminated soil badly. compare other physics, biological renovation method, chemistry reparation has the characteristics such as but the instant effect original position is implemented, repairing effect is remarkable, more be applicable to the Pollution abatement of agricultural land soil, wherein, using chemical additive to polluted agricultural land is easy handling and method comparatively commonly used.
Aspect the selection of chemical additive, the stable fixing agent that the present heavy metal that is used for soil, settling and solid waste is stablized immobilization research is existing a lot, the natural organic matter class has peat, compost, bone black etc., and the natural mineral class has Wingdale, natural phosphate ore, calcite, kaolin, montmorillonite etc.; The synthetic class has synthetic nano level phosphoric acid molysite, synthetic zeolite, closes aluminide more, aluminium closes montmorillonite, phosphatic rock etc.; The waste class has flyash, blast furnace slag, red mud etc., and the chemical reagent class has calcium hydroxide, Secondary ammonium phosphate, calcium oxide etc.Above-mentioned materials utilizes mainly with the mode that directly adds soil, and life-time service can cause under soil compaction, the soil fertility and incite somebody to action, and finally causes unbalance, the crop failure of soil ecosystem.
Have in recent years report to show that selenium (Se) can suppress to plant (work) thing to the absorption of heavy metal element, an amount of selenium not only has anti-oxidant, function of detoxification in plant materials, can also promote photosynthesis of plant, improves tissue protein content, improves output.In addition, human body appropriate supplement Se can enhancing body immunizing power, its have delay senility, the cancer-resisting function.
Therefore, in agriculture production and heavy-metal composite pollution environmental improvement, development and use take selenium as main component, improve the chemical additive of Plant Tolerance heavy metal ability and Promoting plant growth, Heavy Metals Quantity of Crop in Wastewater not only can be reduced, the problem of the average daily Se intake of a lot of Area Inhabitants of China deficiency can also be alleviated by the mode that increases Selenium in Plants content.
Summary of the invention:
The present invention seeks to overcome the weak point that prior art exists, a kind of have the plant detoxifcation growth stimulant of the heavy metal resistances such as cadmium, antimony and the application process of said preparation are provided.
Plant detoxifcation growth stimulant of the present invention is that it is wherein a kind of to contain selenate or selenite, and adds the aqueous solution of Amino Acid Chelated Mineral Fertilizer.
The content of each component is in the described promotor, selenium 0.01-1mg/L, Amino Acid Chelated Mineral Fertilizer 500-3000mg/L.
The production method of described promotor is, according to above-mentioned formula rate, take by weighing each component, first with selenate or selenite wherein a kind of in preparing tank, be dissolved in water mix after, add again Amino Acid Chelated Mineral Fertilizer, continue to stir, leave standstill, get product, keep pH in the 6-7 scope in the whole production process, temperature remains on 10-35 ℃ of scope.
Described selenate or selenite wherein a kind of in preparing tank churning time be 5-20 minute, add that to continue churning time behind the Amino Acid Chelated Mineral Fertilizer be 30-60 minute, time of repose is 1 hour.
In calcium, magnesium, phosphorus, potassium, five kinds of elements of silicon one or more have been added in the described Amino Acid Chelated Mineral Fertilizer.
The present invention provides a kind of using method of above-mentioned plant detoxifcation growth stimulant simultaneously, before crop harvesting during 7 to 40 days in, be sprayed onto plant leaf 1-3 time in the foliage-spray mode.
Advantage of the present invention and positively effect:
Plant detoxifcation growth stimulant of the present invention can improve plant to the resistance of various heavy (cadmium, antimony etc.), the energy Promoting plant growth, increase crop yield, improve selenium content in the crop, for the guarantee of the grain-production safety in heavy metal contamination area provides technical guarantee.Its concrete function is as follows:
1, suppresses plant to the absorption of heavy metal
Selenium can alleviate the toxic action of heavy metal on plants, reduces plant to their absorption.Its mechanism comprises the oxidative stress that (1) alleviation heavy metal causes; (2) plant cell structures and the function under the remediating heavy metal stress conditions; (3) the plant photosynthesis under the recovery heavy metal stress condition; (4) reverse the heavy metal stress condition to the impact of plant essential nutrient element; (5) suppress plant to the absorption of heavy metal.
2, improve Selenium in Plants content
The Se of low dosage can not only lessening oxidative stress in the plant materials, can also strengthen the photosynthesis of crop, improves tissue protein content, improves output, strengthens anti-adversity ability.Plant can absorb selenium as main take Se4+, Se6+ and three kinds of forms of organic Se, and the plant detoxifcation growth stimulant of foliage-spray this patent invention can be made selenium content in the object by Effective Raise.Can also effectively alleviate the problem of China's most of population selenium intake deficiency by the mode of suitable raising selenium content of crops.
3, improve the heavy-metal contaminated soil fertility
Amino acid contained little fertilizer not only can improve nutrition content in the soil in this patent invention plant detoxifcation growth stimulant, can also effectively regulate soil ecosystem under life-time service, improves soil microbial activities, increases soil fertility.
Embodiment
Embodiment 1
Raw material is selenium 0.05mg/L, Amino Acid Chelated Mineral Fertilizer 1000mg/L by weight ratio.
Its processing step is, according to above-mentioned formula rate, take by weighing sodium selenate, Amino Acid Chelated Mineral Fertilizer, first sodium selenate is dissolved in water to stir after 5 minutes in batch tank and adds Amino Acid Chelated Mineral Fertilizer, continue to stir 30 minutes, left standstill 1 hour, get product, keep pH in the whole production process about 6.5, temperature remains on about 25 ℃.
Its use-pattern is, gets manual simulation's cadmium pollution soil (wherein cadmium concentration is about 50mg/kg) rice cultivation, respectively before rice harves 21,14 days the time, and foliage-spray 1 time.
Take the paddy rice that do not add any processing as control group.
After the rice harves in the seed heavy metal and selenium content shown in 1 table.
Table 1 (mg/kg)
Embodiment 2
Raw material is selenium 0.5mg/L, Amino Acid Chelated Mineral Fertilizer 800mg/L by weight ratio.
Its processing step is, according to above-mentioned formula rate, take by weighing sodium selenate, Amino Acid Chelated Mineral Fertilizer, first sodium selenate is dissolved in water in batch tank, to stir after 8 minutes and adds Amino Acid Chelated Mineral Fertilizer, continue to stir 50 minutes, left standstill 1 hour, get product, keep pH in the whole production process about 6.5, temperature remains on about 15 ℃.
Its use-pattern is, gets manual simulation's antimony pollution soil (the about 50mg/kg of antimony concentration) sowing paddy rice, respectively before rice harves 30,20,10 days the time, and foliage-spray 1 time.
Take the paddy rice that do not add any processing as control group.
After the rice harves in the seed heavy metal and selenium content as shown in table 2.
Table 2 (mg/kg)
Process | Antimony content | Selenium content |
Embodiment 1 | 2.61±0.23 | 0.17±0.04 |
Contrast | 15.78±0.86 | 0.03±0.01 |
Embodiment 3
Raw material is selenium 1mg/L, Amino Acid Chelated Mineral Fertilizer 3000mg/L by weight ratio.
Its processing step is, according to above-mentioned formula rate, take by weighing sodium selenate, Amino Acid Chelated Mineral Fertilizer, first sodium selenate is dissolved in water in batch tank, to stir after 20 minutes and adds Amino Acid Chelated Mineral Fertilizer, continue to stir 60 minutes, left standstill 1 hour, get product, keep pH in the whole production process about 6.5, temperature remains on about 30 ℃.
Its use-pattern is, gets manual simulation's cadmium, antimony combined contamination soil (the about 25mg/kg of cadmium concentration, the about 25mg/kg of antimony concentration) sowing paddy rice, in rice harves in the time of front 15 days, and foliage-spray 1 time.Take the paddy rice that do not add any processing as control group.
After the rice harves in the seed heavy metal and selenium content as shown in table 3.
Table 3 (mg/kg)
Process | Cadmium content | Antimony content | Selenium content |
Embodiment 1 | 0.13±0.02 | 3.77±0.75 | 0.13±0.06 |
Contrast | 0.66±0.31 | 14.81±1.31 | 0.02±0.01 |
Claims (5)
1. the plant of preventing from heavy metal detoxifcation growth stimulant is characterized in that it is the aqueous solution that comprises following component: selenium 0.01-1mg/L, Amino Acid Chelated Mineral Fertilizer 500-3000mg/L.
2. the plant of preventing from heavy metal as claimed in claim 1 detoxifcation growth stimulant is characterized in that selenium described in the claim 1 derives from sodium selenate or Sodium Selenite is wherein a kind of.
3. the plant of preventing from heavy metal as claimed in claim 1 detoxifcation growth stimulant is characterized in that having added in the Amino Acid Chelated Mineral Fertilizer described in the claim 1 in calcium, magnesium, phosphorus, potassium, five kinds of elements of silicon one or more.
4. the plant of preventing from heavy metal as claimed in claim 1 detoxifcation growth stimulant, it is characterized in that preparing in the following manner, take by weighing each component according to ratio described in the claim 1, with selenate or selenite is wherein a kind of is dissolved in water, add again Amino Acid Chelated Mineral Fertilizer first in preparing tank, continue to stir, leave standstill, get product, keep aqueous solution pH in the 6-7 scope in the whole production process, temperature remains on 10-35 ℃ of scope.
5. the plant of preventing from heavy metal as claimed in claim 1 detoxifcation growth stimulant is characterized in that using in the following manner, before crop harvesting during 7 to 40 days in, be sprayed onto plant leaf surface 1-3 time in the foliage-spray mode.
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CN103936495A (en) * | 2014-02-19 | 2014-07-23 | 浙江大学 | Preparation used for reducing accumulation of cadmium in tobacco, and application method thereof |
CN103980030A (en) * | 2014-02-19 | 2014-08-13 | 浙江大学 | Preparation for reducing accumulation of cadmium in crops and application method thereof |
CN104082341A (en) * | 2014-07-19 | 2014-10-08 | 柏连阳 | Leaf surface spraying agent for soil heavy metal treatment and preparation method for leaf surface spraying agent |
CN104496632A (en) * | 2014-11-17 | 2015-04-08 | 浙江大学 | Method for ensuring safe output of paddy planted in lead mild-moderate polluted soil and used preparation |
CN105612848A (en) * | 2016-01-25 | 2016-06-01 | 农业部环境保护科研监测所 | Method for reducing content of cadmium and arsenic of rice |
CN105613578A (en) * | 2016-02-04 | 2016-06-01 | 太原科技大学 | Composition, preparation and method for lowering cadmium accumulation in cucumber |
CN106045665A (en) * | 2016-05-26 | 2016-10-26 | 上海泽耀环保科技有限公司 | Selenium-rich leaf fertilizer inhibiting absorption of heavy metals and preparation method and application thereof |
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CN107008746A (en) * | 2017-05-09 | 2017-08-04 | 绵阳荣耀科技有限公司 | A kind of multiple-effect heavy metal pollution of soil passivator |
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CN103936495A (en) * | 2014-02-19 | 2014-07-23 | 浙江大学 | Preparation used for reducing accumulation of cadmium in tobacco, and application method thereof |
CN103980030A (en) * | 2014-02-19 | 2014-08-13 | 浙江大学 | Preparation for reducing accumulation of cadmium in crops and application method thereof |
CN103936495B (en) * | 2014-02-19 | 2015-10-28 | 浙江大学 | A kind ofly reduce the preparation and using method thereof that cadmium accumulates in tobacco |
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CN104496632A (en) * | 2014-11-17 | 2015-04-08 | 浙江大学 | Method for ensuring safe output of paddy planted in lead mild-moderate polluted soil and used preparation |
CN106977243A (en) * | 2016-01-17 | 2017-07-25 | 廖鹏 | Plant heavy metal efficiently repairs nutritional agents and preparation method thereof |
CN106977348A (en) * | 2016-01-17 | 2017-07-25 | 廖鹏 | Efficient renovation agent of heavy metal-polluted soil and preparation method thereof |
CN105612848A (en) * | 2016-01-25 | 2016-06-01 | 农业部环境保护科研监测所 | Method for reducing content of cadmium and arsenic of rice |
CN105613578A (en) * | 2016-02-04 | 2016-06-01 | 太原科技大学 | Composition, preparation and method for lowering cadmium accumulation in cucumber |
CN106045665A (en) * | 2016-05-26 | 2016-10-26 | 上海泽耀环保科技有限公司 | Selenium-rich leaf fertilizer inhibiting absorption of heavy metals and preparation method and application thereof |
CN107008746A (en) * | 2017-05-09 | 2017-08-04 | 绵阳荣耀科技有限公司 | A kind of multiple-effect heavy metal pollution of soil passivator |
CN109913233A (en) * | 2019-04-28 | 2019-06-21 | 湖南省地球物理地球化学勘查院 | A kind of water paddy soil heavy metal passivation modifying agent |
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CN110149869A (en) * | 2019-05-28 | 2019-08-23 | 农业农村部环境保护科研监测所 | Inhibit the preparation and method of cadmium enrichment in rice |
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Application publication date: 20130313 |