CN102943258B - Environment-friendly rust-removing anti-rust agent - Google Patents

Environment-friendly rust-removing anti-rust agent Download PDF

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Publication number
CN102943258B
CN102943258B CN201210348121.6A CN201210348121A CN102943258B CN 102943258 B CN102943258 B CN 102943258B CN 201210348121 A CN201210348121 A CN 201210348121A CN 102943258 B CN102943258 B CN 102943258B
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Prior art keywords
rust
environment
friendly
agent
removing anti
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CN201210348121.6A
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CN102943258A (en
Inventor
张乃庆
吴启东
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Daqing Baofeng Science & Technology Co., Ltd.
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Shanghai Jinzhao Energy Saving Technology Co Ltd
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Abstract

The invention provides an environment-friendly rust-removing anti-rust agent. The agent consists of the following raw materials, by weight: 5%-20% of diethylene glycol monobutyl ether, 10-15% of KOH, 5-10% of oxalic acid, 5-10% of gluconic acid, 5-10% of phosphate, 2-5% of potassium tetraborate and the balance of deionized water. The environment-friendly rust-removing anti-rust agent provided by the invention has good rust-removing and anti-rust performance, and is healthful and environment-friendly. The environment-friendly rust-removing anti-rust agent can be diluted with 0-50 times of water and used for rust removal and rust prevention under different processing processes and different conditions.

Description

Environment-friendly type rust-removing and-preventing agent
Technical field
The invention belongs to metal rust preventing technical field, be specifically related to a kind of environment-friendly type rust-removing and-preventing agent.
Background technology
Mechanicals will be used metallic substance mostly, in manufacturing processed, to removing unavoidably corrosion product, carries out rust prevention during manufacture; After product is made, in delivery, stock, use procedure, all may be subject to oxygen in environment or the erosion of acid-alkali medium, carry out antirust, to the corrosion having occurred, also will eliminating rust, it is antirust to carry out again, traditional water-based antirust agent generally uses nitrate, nitrite and dichromate etc. to have the composition of carcinogenic teratogenesis to carry out antirust processing, and the health to workman and the pollution of environment have very large negative impact.
Summary of the invention
The object of the invention is to: overcome the deficiencies in the prior art, a kind of environment-friendly type rust-removing and-preventing agent is provided, to replace original traditional rust-preventive agent take nitrate, nitrite and dichromate as main component.
For achieving the above object, the present invention has adopted following technical scheme:
A kind of environment-friendly type rust-removing and-preventing agent, is prepared from by the raw material mixed dissolution of following weight percent:
The preparation method of above-mentioned environment-friendly type rust-removing and-preventing agent: take raw material by described weight percent, taken diethylene glycol monobutyl ether, potassium hydroxide, oxalic acid, gluconic acid, phosphoric acid, potassium tetraborate, add successively and in the deionized water taking, be heated to 50-60 ℃ and be stirred to all the components and dissolve completely, till container bottom sediment-free, cooling rear packing.
Beneficial effect of the present invention:
The present invention compared with prior art, has the following advantages:
Environment-friendly type rust-removing and-preventing agent of the present invention has good derusting rust-proofing performance, and health environment-friendly.
Diethylene glycol monobutyl ether is good tensio-active agent, can well remove the greasy dirt of metallic surface etc., convenient rust cleaning and antirust;
Oxalic acid, gluconic acid and potassium hydroxide reaction, the oxalate of generation and grape acid group can with the complexing of metal ion such as iron, copper, easily remove the corrosion of metallic surface;
Phosphate radical, hydrogen phosphate, dihydrogen phosphate that phosphoric acid and potassium hydroxide reaction generate can generate phosphoric acid molysite with iron ion reaction, are attached to metallic surface, effectively prevent that metal from continuing corrosion;
Potassium tetraborate can form in metallic surface the special protective layer of one deck, effectively prevents metallic corrosion;
Deionized water Main Function, for increasing solvability, makes the concentrated solution of preparation more stable, often contains the metal ion such as calcium, magnesium in non-deionized water, can affect the solvability of above composition.
Environment-friendly type rust-removing and-preventing agent of the present invention can with after 0-50 water dilution doubly for the derusting rust-proofing under different complete processings and different condition.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment 1:
Take 15kg diethylene glycol monobutyl ether, 13kg potassium hydroxide, 10kg oxalic acid, 5kg gluconic acid, 5kg phosphoric acid, 2kg potassium tetraborate, add successively and in the 50kg deionized water taking, be heated to 50-60 ℃ and be stirred to all the components and dissolve completely, till container bottom sediment-free, cooling rear packing.
Embodiment 2:
Take 16kg diethylene glycol monobutyl ether, 12kg potassium hydroxide, 6kg oxalic acid, 6kg gluconic acid, 6kg phosphoric acid, 3kg potassium tetraborate, add successively and in the 51kg deionized water taking, be heated to 50-60 ℃ and be stirred to all the components and dissolve completely, till container bottom sediment-free, cooling rear packing.
Embodiment 3:
Take 17kg diethylene glycol monobutyl ether, 13kg potassium hydroxide, 7kg oxalic acid, 10kg gluconic acid, 5kg phosphoric acid, 2kg potassium tetraborate, add successively and in the 46kg deionized water taking, be heated to 50-60 ℃ and be stirred to all the components and dissolve completely, till container bottom sediment-free, cooling rear packing.
Embodiment 4:
Take 18kg diethylene glycol monobutyl ether, 10kg potassium hydroxide, 8kg oxalic acid, 8kg gluconic acid, 8kg phosphoric acid, 4kg potassium tetraborate, add successively and in the 44kg deionized water taking, be heated to 50-60 ℃ and be stirred to all the components and dissolve completely, till container bottom sediment-free, cooling rear packing.
Embodiment 5:
Take 19kg diethylene glycol monobutyl ether, 11kg potassium hydroxide, 9kg oxalic acid, 8kg gluconic acid, 10kg phosphoric acid, 5kg potassium tetraborate, add successively and in the 38kg deionized water taking, be heated to 50-60 ℃ and be stirred to all the components and dissolve completely, till container bottom sediment-free, cooling rear packing.
Embodiment 6:
Take 20kg diethylene glycol monobutyl ether, 15kg potassium hydroxide, 5kg oxalic acid, 5kg gluconic acid, 5kg phosphoric acid, 5kg potassium tetraborate, add successively and in the 45kg deionized water taking, be heated to 50-60 ℃ and be stirred to all the components and dissolve completely, till container bottom sediment-free, cooling rear packing.

Claims (1)

1. an environment-friendly type rust-removing and-preventing agent, is characterized in that, is prepared from by the raw material mixed dissolution of following weight percent:
CN201210348121.6A 2012-09-18 2012-09-18 Environment-friendly rust-removing anti-rust agent Active CN102943258B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210348121.6A CN102943258B (en) 2012-09-18 2012-09-18 Environment-friendly rust-removing anti-rust agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210348121.6A CN102943258B (en) 2012-09-18 2012-09-18 Environment-friendly rust-removing anti-rust agent

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CN102943258A CN102943258A (en) 2013-02-27
CN102943258B true CN102943258B (en) 2014-06-25

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104451727B (en) * 2014-12-02 2017-05-03 佛山市海明威生态科技有限公司 Anti-rusting agent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1417385A (en) * 2002-11-29 2003-05-14 广西大学 Surface scale eliminating method for anode guide rod in aluminium electrolysis
CN1498286A (en) * 2001-02-26 2004-05-19 住友金属工业株式会社 Surface treated steel product, method for production thereof and chemical conversion treatment solution
CN1846015A (en) * 2003-08-29 2006-10-11 日本巴卡莱近沽株式会社 Alkali cleaning fluid for aluminum or aluminum alloys and method of cleaning
CN101368274A (en) * 2007-08-15 2009-02-18 江苏海迅实业集团股份有限公司 Steel antirust agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1498286A (en) * 2001-02-26 2004-05-19 住友金属工业株式会社 Surface treated steel product, method for production thereof and chemical conversion treatment solution
CN1417385A (en) * 2002-11-29 2003-05-14 广西大学 Surface scale eliminating method for anode guide rod in aluminium electrolysis
CN1846015A (en) * 2003-08-29 2006-10-11 日本巴卡莱近沽株式会社 Alkali cleaning fluid for aluminum or aluminum alloys and method of cleaning
CN101368274A (en) * 2007-08-15 2009-02-18 江苏海迅实业集团股份有限公司 Steel antirust agent

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Effective date of registration: 20191227

Address after: 163000 incubator 2, building three, Grand Park, hi tech Zone, Heilongjiang, Daqing

Patentee after: Daqing Baofeng Science & Technology Co., Ltd.

Address before: 200062, room second, building 1006, 414 Jinsha River Road, Shanghai, Putuo District

Patentee before: Shanghai Jinzhao Conservation of Energy Science & Technology Co., Ltd.