CN102942904A - Paraffin-felt phase-changing composite heat storage material and heat storage device thereof - Google Patents

Paraffin-felt phase-changing composite heat storage material and heat storage device thereof Download PDF

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Publication number
CN102942904A
CN102942904A CN2012104679949A CN201210467994A CN102942904A CN 102942904 A CN102942904 A CN 102942904A CN 2012104679949 A CN2012104679949 A CN 2012104679949A CN 201210467994 A CN201210467994 A CN 201210467994A CN 102942904 A CN102942904 A CN 102942904A
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paraffin
felt
storage material
energy storage
thermal energy
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CN102942904B (en
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冯志标
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

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Abstract

The invention discloses a paraffin-felt phase-changing composite heat storage material, which mainly comprises paraffin and a felt. The felt is placed in melted paraffin for immersion, and after the felt is fully saturated, the felt is taken out and congealed to prepare the material. According to the paraffin-felt phase-changing composite heat storage material, paraffin is adopted as a phase-changing material, the felt is used as an absorption and support structure to prepare the material, thus the defects of flowing paraffin in a liquid phase and rapid radiation are overcome, and the prepared paraffin-felt phase-changing composite heat storage material has the advantages of a light proportion, fundamental non-flowing, a stable shape, zero corrosion and better and unexpected effects on heat storage and heat preservation.

Description

A kind of paraffin-felt phase transformation thermal energy storage material and heat-storing device thereof
Technical field
The present invention relates to paraffin-felt phase transformation thermal energy storage material and utilize the heat-storing device that paraffin-felt phase transformation thermal energy storage material is prepared from.
Background technology
In the winter time when cold weather, people's custom is with the electric hot-water bag heating, and electric hot-water bag becomes the indispensable article for keeping out cold of people.But electric hot-water bag adopts water as heat-storage medium, and the flowability of water is strong, can scald the people when the electric hot-water bag leakage, and causes easily water bag expansion blast, can cause very large potential safety hazard to people.
Paraffin has the advantages such as physicochemical property long-term stability, heat accumulation rate height, wide material sources, cheap, pollution-free, non-corrosiveness, is a kind of comparatively desirable phase-change heat-storage material, and people attempt using it to replace water as heat accumulating.But single paraffin has liquid phase flow, the shortcomings such as slow and rapid heat dissipation of conducting heat.Although the research of wax phase change matrix material is also arranged at present, such as phase change composite materials such as paraffin-graphite, paraffin-perlite, paraffin-vermiculites etc., the heat insulation effect of these phase change composite materials, soaking time etc. are all undesirable.
Felt has that adsorptive power is strong, stable molding, the characteristics such as heat insulation, but it there is no heat storage function, and thermal conductivity is little, felt can be burnt the very fast disappearance of heat behind the stopped heating during heating.
Summary of the invention
The object of the invention is to overcome above-mentioned shortcoming, a kind of paraffin-felt phase transformation thermal energy storage material is provided, and utilize the heat-storing device that paraffin-felt phase transformation thermal energy storage material is prepared from, utilize paraffin to be phase change material, take felt as absorption and supporting structure be prepared from, have than single paraffin and the beyond thought better heat-storage heat-preserving effect of water.
For addressing the above problem, the present invention is achieved through the following technical solutions:
Paraffin of the present invention-felt phase transformation thermal energy storage material, it mainly is comprised of paraffin and felt, floods by felt being placed the paraffin of fusing, after felt absorption is full, takes out cooled and solidified and is prepared from.
In described paraffin, add by weight 10% PE wax.
Described paraffin is fusing point 58-60 ℃ refined wax or SEMI-REFINED PARAFFIN WAX.
The invention still further relates to a kind of heat-storing device that described paraffin-felt phase transformation thermal energy storage material is prepared from that utilizes, it coats encapsulation in paraffin-felt phase transformation thermal energy storage material outside with aluminium-foil paper or high-temperature resistant membrane commonly used (such as nylon film etc.).
Comprise two-layer at least paraffin-felt phase transformation thermal energy storage material in the described heat-storing device.
Position between described paraffin-felt phase transformation thermal energy storage material is two-layer arranges fever tablet and temperature control electronic package.
Paraffin of the present invention-felt phase transformation thermal energy storage material, utilize paraffin to be phase change material, take felt as absorption and supporting structure be prepared from, overcome the shortcoming of paraffin liquid phase flow and rapid heat dissipation, prepared paraffin-felt phase transformation thermal energy storage material light specific gravity, substantially flow, dimensionally stable, non-corrosiveness, and have better beyond thought heat-storage heat-preserving effect.Add PE wax (stablizer), more be difficult for trickling after paraffin is melted.Use refined wax or the SEMI-REFINED PARAFFIN WAX of 58-60 ℃ of fusing point, can make the heat-storage heat-preserving better effects if of paraffin of the present invention-felt phase transformation thermal energy storage material.
Take the paraffin for preparing-felt phase transformation thermal energy storage material as the basis, coat encapsulation in paraffin-felt phase transformation thermal energy storage material outside with aluminium-foil paper or high-temperature resistant membrane commonly used (such as nylon film etc.), can be so that the flowability of paraffin reduces.Comprise two-layer at least paraffin-felt phase transformation thermal energy storage material in the heat-storing device, and the position between paraffin-felt phase transformation thermal energy storage material is two-layer arranges fever tablet and temperature control electronic package, this mode has increased the contact area of paraffin and heating element, better solved the slow shortcoming of paraffin heat transfer, it is relatively even that paraffin is heated, increase the quantity of heat storage of paraffin, more the power and energy saving.The temperature control electronic package mainly is made of thermostat and overtemperature prote safety fuse, can make the temperature control of heat-storing device safer.
A kind of paraffin of the present invention-felt phase transformation thermal energy storage material, and utilize the heat-storing device that paraffin-felt phase transformation thermal energy storage material is prepared from can be used for the fields such as electric heating bag, warming shoe, incubation canteen, heat accumulation floor.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail.
Embodiment 1:
Heating becomes liquid (being solid-liquid phase change) with melted paraffin wax, become the felt piece of desired shape and size to place the paraffin of fusing to flood stamping-out, after the absorption of felt piece is full, takes out cooling and solidify, namely make paraffin of the present invention-felt phase transformation thermal energy storage material.During scale operation, can be with whole felt by stamping-out on request again after the condensation of e Foerderanlage Adsorption Paraffin.
Embodiment 2:
Heating becomes liquid (being solid-liquid phase change) with melted paraffin wax, add by weight 10% PE wax (polyethylene wax (PE-WAX)), become the felt piece of desired shape and size to place the paraffin of fusing to flood stamping-out, after the absorption of felt piece is full, take out cooling and solidify, namely make paraffin of the present invention-felt phase transformation thermal energy storage material.During scale operation, can be with whole felt by stamping-out on request again after the condensation of e Foerderanlage Adsorption Paraffin.
Embodiment 3:
Heating is fused into liquid (being solid-liquid phase change) with fusing point 58-60 ℃ refined wax or SEMI-REFINED PARAFFIN WAX, become the felt piece of desired shape and size to place the paraffin of fusing to flood stamping-out, after the absorption of felt piece is full, take out cooling and solidify, namely make paraffin of the present invention-felt phase transformation thermal energy storage material.During scale operation, can be with whole felt by stamping-out on request again after the condensation of e Foerderanlage Adsorption Paraffin.
Embodiment 4:
Heating is fused into liquid (being solid-liquid phase change) with fusing point 58-60 ℃ refined wax or SEMI-REFINED PARAFFIN WAX, add by weight 10% PE wax (polyethylene wax (PE-WAX)), become the felt piece of desired shape and size to place the paraffin of fusing to flood stamping-out, after the absorption of felt piece is full, take out cooling and solidify, namely make paraffin of the present invention-felt phase transformation thermal energy storage material.During scale operation, can be with whole felt by stamping-out on request again after the condensation of e Foerderanlage Adsorption Paraffin.
The paraffin for preparing by the present invention-felt phase transformation thermal energy storage material (representing with this material in the form) and traditional heat-storage medium-water and single paraffin phase ratio have the following advantages:
Project This material Water Paraffin
Light specific gravity 0.69 1 0.9
Soaking time is long 4 hours 2.5 hour 1.3 hour
Mobile Substantially do not flow Mobile strong More liquid
Felt has that adsorptive power is strong, stable molding, the characteristics such as heat insulation, but it there is no heat storage function, and thermal conductivity is little, felt can be burnt the very fast disappearance of heat behind the stopped heating during heating.
Embodiment 5:
At first the method according to embodiment 1-4 makes required paraffin-felt phase transformation thermal energy storage material, then coat encapsulation in paraffin-felt phase transformation thermal energy storage material outside with aluminium-foil paper or high-temperature resistant membrane commonly used (such as nylon film etc.), be prepared into heat-storing device; Comprise two-layer at least paraffin-felt phase transformation thermal energy storage material in the heat-storing device, and the position between paraffin-felt phase transformation thermal energy storage material is two-layer arranges fever tablet and temperature control electronic package.
Put the cloth bag that is designed on request different shape in the outside of heat-storing device, sponge etc. strengthens feel on the cloth bag back boxing, just makes Waterless electric heating bag.Heat-storing device is installed at the large end of shoes, just becomes heat-storage warm-keeping shoes.Heat-storing device is installed in the incubation canteen, just can greatly prolongs soaking time.Heat-storing device is installed in the floor, just can makes the significant heat accumulation of power saving floor.The present invention can also develop the warming product innovation of more heat accumulation, is a kind of very promising heat accumulation novel material.
In sum, be preferred embodiment of the present invention only, be not the present invention is done any pro forma restriction; The those of ordinary skill of all industry all can be implemented by the above the present invention swimmingly; But all those skilled in the art can utilize the disclosed above technology contents and a little change of making within not breaking away from the technical solution of the present invention scope, modify and the equivalent variations that develops, and are equivalent embodiment of the present invention; Simultaneously, the change of any equivalent variations that all foundations essence technology of the present invention is done above embodiment, modify and differentiation, all still belong within the protection domain of technical scheme of the present invention.

Claims (6)

1. paraffin-felt phase transformation thermal energy storage material is characterized in that:
It mainly is comprised of paraffin and felt, floods by felt being placed the paraffin of fusing, after felt absorption is full, takes out cooled and solidified and is prepared from.
2. paraffin according to claim 1-felt phase transformation thermal energy storage material is characterized in that:
In described paraffin, add by weight 10% PE wax.
3. paraffin according to claim 1-felt phase transformation thermal energy storage material is characterized in that:
Described paraffin is fusing point 58-60 ℃ refined wax or SEMI-REFINED PARAFFIN WAX.
4. one kind is utilized the claim 1-3 heat-storing device that each described paraffin-felt phase transformation thermal energy storage material is prepared from, and it is characterized in that:
Coat encapsulation in paraffin-felt phase transformation thermal energy storage material outside with aluminium-foil paper or high-temperature resistant membrane.
5. according to claim 4ly utilize the heat-storing device that paraffin-felt phase transformation thermal energy storage material is prepared from, it is characterized in that:
Comprise two-layer at least paraffin-felt phase transformation thermal energy storage material in the described heat-storing device.
6. according to claim 5ly utilize the heat-storing device that paraffin-felt phase transformation thermal energy storage material is prepared from, it is characterized in that:
Position between described paraffin-felt phase transformation thermal energy storage material is two-layer arranges fever tablet and temperature control electronic package.
CN201210467994.9A 2012-11-19 2012-11-19 Paraffin-felt phase-changing composite heat storage material and heat storage device thereof Active CN102942904B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103409113A (en) * 2013-07-23 2013-11-27 苏州天脉导热科技有限公司 A heat storage material
CN105694824A (en) * 2016-04-12 2016-06-22 段传璞 Method for preparing phase-change composite materials applied to hot-water bags
CN106820524A (en) * 2015-12-03 2017-06-13 哈尔滨市三和佳美科技发展有限公司 Heat storage type incubation canteen
CN113388240A (en) * 2021-06-15 2021-09-14 威驰腾(福建)汽车有限公司 Graphite felt composite material and forming method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102282302A (en) * 2008-12-19 2011-12-14 Iq泰克斯专利管理有限责任公司 Super absorber polymer felt and method for the production thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102282302A (en) * 2008-12-19 2011-12-14 Iq泰克斯专利管理有限责任公司 Super absorber polymer felt and method for the production thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103409113A (en) * 2013-07-23 2013-11-27 苏州天脉导热科技有限公司 A heat storage material
CN106820524A (en) * 2015-12-03 2017-06-13 哈尔滨市三和佳美科技发展有限公司 Heat storage type incubation canteen
CN105694824A (en) * 2016-04-12 2016-06-22 段传璞 Method for preparing phase-change composite materials applied to hot-water bags
CN113388240A (en) * 2021-06-15 2021-09-14 威驰腾(福建)汽车有限公司 Graphite felt composite material and forming method thereof

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Denomination of invention: Paraffin-felt phase-changing composite heat storage material and heat storage device thereof

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