CN102936649A - Method for recovering nickel, cobalt, manganese and iron by roasting and leaching nickel oxide ore - Google Patents
Method for recovering nickel, cobalt, manganese and iron by roasting and leaching nickel oxide ore Download PDFInfo
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Abstract
The invention relates to a method for recovering nickel, cobalt, manganese and iron by roasting and leaching nickel oxide ore. The method includes: ball milling the nickel oxide ore to obtain mineral powder; then adding mineral powder additives into the mineral powder; balling, roasting and conducting leaching processing on roasted mineral materials through water or diluted hydrochloric acid to obtain leaching agent of the nickel oxide ore; adding oxidant into the leaching agent, processing to obtain sediment of cobalt oxide and manganite, adding calcium oxide or sodium hydroxide into filtrate to conduct processing to obtain mixture sediment containing nickel and iron. The method is reasonable in process design and good in operability and can use mineral resource effectively and achieve large-scale industrial production; achieves recycling of four elements of nickel, cobalt, manganese and iron in leaching agent of the nickel oxide; and saves production cost.
Description
Technical field
The present invention relates to a kind of metallurgical method, particularly a kind of nickel oxide ore Roasting And Leaching reclaims the method for nickel cobalt ferromanganese.
Background technology
Nickel oxide ore is a kind of mineral association that contains various metals unit rope.It contains iron, nickel, cobalt, manganese, aluminium and magnesium etc.In order to recycle these true valency metallic elements, people have adopted the methods such as pyrometallurgy and hydrometallurgy.Traditional nickel oxide ore pyrometallurgy treatment technology has the thick reduction of rotary kiln drying-electric furnace reduction melting to produce ferronickel; Sintering-blast furnace sulfiding smelting is produced low nickel matte; And the nickel pig iron is produced in sintering-blast furnace retailoring.The melting of rotary kiln drying prereduction electric furnace reduction is the classical technique of processing nickel oxide ore, technological process is as follows: moisture approximately 30% nickel oxide ore through rotary kiln after 800 ~ 900 ℃ of lower drying and dehydratings and thick reduction are processed, send into again ore-smelting furnace, the retailoring output is nickeliferous under about 1550～1600 ℃ high temperature〉10% ferronickel, be enriched to more than 25% through the further refining of converter again and sell, for producing stainless steel.The method has that Technological adaptability is strong, flow process is brief, the nickel recovery high.
The blast furnace sulfiding smelting be with nickel oxide ore after allocating an amount of calcium oxide and silicon-dioxide into, approximately sintering piece (or push agglomerating, naturally dry) under 1100 ℃ into, allocate again 10～20% pyrite and about 20～30% coke into, 1300 ℃ of lower meltings in blast furnace, the low nickel matte product of output nickeliferous 8～15%.Because every kind of valuable metal constituent content is relatively less in nickel oxide ore, so the energy consumption that adopts pyrometallurgy to smelt is higher, this is the main drawback of nickel oxide ore pyrometallurgical smelting.So people adopt the method for hydrometallurgy, optionally extract valuable metal wherein.In recent years, nickel oxide ore sulfuric acid wet process extractive technique obtains to develop rapidly.
Nickel minerals sulfuric acid wet process extractive technique commonly used has: sulfuric acid pressure leaching, the leaching of sulfuric acid normal pressure, sulfuric acid dump leaching and reduction roasting-ammonia leaching etc.The sulfuric acid pressure leaching is processed nickel oxide ore, is to leach under 230 ~ 260 ℃ of high temperature and 4-5Mpa high pressure, and nickel, cobalt leaching yield can reach about 95%.Reducing roasting ammonia soaking technology has reagent N H
3Can be recycled, consumption is little, can comprehensive recovery nickel, the advantages such as brill, iron, and nickel, the cobalt leaching yield is on the low side is its main drawback.The sulfuric acid normal pressure leaches nickel oxide ore, is that the mineral composition according to handled nickel oxide ore prepares leach liquor under normal pressure, and usually giving up in the resulting leach liquor has the iron of 10～30g/L, the nickel of 3～5g/L, the cobalt of 0.1～0.3g/L, the magnesium of 30～40g/L.Usually adopt calcium oxide or calcium hydroxide to neutralize in advance the iron in the deposition removal leach liquor and aluminium; And then neutralization precipitation nickel and cobalt or with carbonate deposition nickel and cobalt or with sulfide precipitation nickel and brill; Again with calcium oxide neutralization precipitate magnesium thereafter.The emphasis of above-mentioned technique is nickel and the cobalt of recycling in the solution, and all processes valuable element iron, magnesium etc. discarded as impurity unit rope.In addition, in the first step of this technique, namely remove in iron and the aluminium process neutralizing in advance with calcium oxide or oxygen calcium oxide since with the adsorption coprecipitation of iron and aluminium, and local basicity is too high, often causes valuable nickel and cobalt to lose in a large number.
Summary of the invention
Technical problem to be solved by this invention is for the deficiencies in the prior art, and the nickel oxide ore Roasting And Leaching that provides a kind of technological design more rationally, effectively to reclaim multiple element, the raising rate of recovery and product purity in the nickel oxide ore reclaims the method for nickel cobalt ferromanganese.
Technical problem to be solved by this invention is to realize by following technical scheme.The present invention is the method that a kind of nickel oxide ore Roasting And Leaching reclaims nickel cobalt ferromanganese, is characterized in, its step is as follows:
(1) ball milling: nickel oxide ore is carried out ball milling in wet-type ball mill, account for more than 60% for-100 orders to ore powder granularity, get breeze;
(2) mix: the additive that adds powdered ore quality 5～30% in the breeze; Described additive is that the first component of 1:4～20 and second component mix and form by mass ratio, and the first component is selected from least a in sodium-chlor, magnesium chloride or the calcium chloride, and second component is selected from least a in coke powder, coke, coal or the carbon; Get the breeze mixture;
(3) balling-up: in the breeze mixture, add an amount of water, make it form the ore deposit ball;
(4) roasting: the ore deposit ball is dropped in the roasting kiln, at 800～1300 ℃ of lower roasting 1～36h; Cool off to get the roasting mineral aggregate;
(5) leach: it is to leach processing in 1～34% the dilute hydrochloric acid that the roasting mineral aggregate is dropped into water or mass concentration, obtains the leach liquor of nickel oxide ore; The temperature that leaches when processing is 20～100 ℃, and the time is 30～180min, and it is 90～120:1 that the add-on of water or dilute hydrochloric acid accounts for the breeze weight ratio;
(6) enriching and recovering cobalt and manganese: add at least a in sodium chlorate, hypochlorous acid, hypochlorite, chlorine, black nickel or the potassium permanganate in the leach liquor and process as oxygenant, the oxygenant usage quantity is precipitate cobalt and the required theoretical amount of manganese 1～5 times, under the condition of 30～100 ℃ of temperature, stir during processing, the stirring linear velocity is 3～6m/s, reaction times 30n～120min, filter the co-precipitation that obtains cobalt/cobalt oxide and Mn oxide, filtrate for later use;
(7) in and co-precipitation nickel and iron: add calcium oxide in the filtrate that makes to step (6) or sodium hydroxide is processed, the usage quantity of described calcium oxide or sodium hydroxide is 1～3 times of the required theoretical amount of iron nickel aluminium in the filtrate; Under the condition of 30～100 ℃ of temperature, stir, reaction times 30～120min, the mixture precipitation that obtains nickeliferous and iron is filtered in terminal point pH=7～9.
Nickel oxide ore Roasting And Leaching of the present invention reclaims in the method and technology scheme of nickel cobalt ferromanganese, and further preferred technical scheme is as follows:
1. in the step (2): the additive that adds powdered ore quality 15～20% in the breeze; Described additive is that the first component of 1:10～15 and second component mix and form by mass ratio.
2. in the step (5): the temperature that leaches when processing is 20～45 ℃, and the time is 60～120min, and the hydrochloric acid add-on accounts for 50～100% of breeze weight.
3. in the step (6): the oxygenant usage quantity is precipitate cobalt and the required theoretical amount of manganese 2～3 times, stirs under the condition of 50～70 ℃ of temperature during processing, and the stirring linear velocity is 4～5m/s, reaction times 60～90min,
4. in the step (7): the usage quantity of described calcium oxide or sodium hydroxide is 2 times of the required theoretical amount of iron nickel aluminium in the filtrate.
5. in the step (7): under the condition of 40 ℃～60 ℃ of temperature, stir reaction times 60～90min, terminal point pH=8.
6. in the step (5): it is 105:1 that the add-on of water or dilute hydrochloric acid accounts for the breeze weight ratio.
In the inventive method, the chemical composition of raw ore nickel oxide ore is generally be weight %: Ni0.5～5, Co0.05～0.15, Fe10～30, Mn0.5～5, MgO 5～30, SiO
25～45, Al
2O
33～15, CaO 0.1～5.
Compared with prior art, the technique effect of the inventive method is as follows:
1. the inventive method has realized nickel, cobalt, manganese and the iron recycling of totally 4 kinds of elements in the nickel oxide ore leach liquor;
2. the inventive method has been produced the mixture of the mixture that contains cobalt/cobalt oxide and Mn oxide, nickeliferous and iron, and multi-products has possessed various industrial uses;
3. the inventive method has been used roasting method, for later process is provided convenience, water or dilute hydrochloric acid is leached, and except low cost, production environment is friendly;
4. the inventive method can improve the rate of recovery and the purity of the mix product of nickeliferous, manganese, cobalt and iron; Saved production cost;
5. the inventive method technological design is reasonable, and is workable, can effectively utilize Mineral resources, can realize extensive workerization production.
Embodiment
Below further describe concrete technical scheme of the present invention, so that those skilled in the art understands the present invention further, and do not consist of its Copyright law.
Embodiment 1, and a kind of nickel oxide ore Roasting And Leaching reclaims the method for nickel cobalt ferromanganese, and its step is as follows:
(1) ball milling: nickel oxide ore is carried out ball milling in wet-type ball mill, account for more than 60% for-100 orders to ore powder granularity, get breeze;
(2) mix: the additive that adds powdered ore quality 5% in the breeze; Described additive is that the first component of 1:4 and second component mix and form by mass ratio, and the first component is selected from least a in sodium-chlor, magnesium chloride or the calcium chloride, and second component is selected from least a in coke powder, coke, coal or the carbon; Get the breeze mixture;
(3) balling-up: in the breeze mixture, add an amount of water, make it form the ore deposit ball;
(4) roasting: the ore deposit ball is dropped in the roasting kiln, at 800 ℃ of lower roasting 1h; Cool off to get the roasting mineral aggregate;
(5) leach: it is to leach processing in 1% the dilute hydrochloric acid that the roasting mineral aggregate is dropped into water or mass concentration, obtains the leach liquor of nickel oxide ore; The temperature that leaches when processing is 20 ℃, and the time is 30min, and it is 90:1 that the add-on of water or dilute hydrochloric acid accounts for the breeze weight ratio;
(6) enriching and recovering cobalt and manganese: add at least a in sodium chlorate, hypochlorous acid, hypochlorite, chlorine, black nickel or the potassium permanganate in the leach liquor and process as oxygenant, the oxygenant usage quantity is precipitate cobalt and the required theoretical amount of manganese 1 times, under the condition of 30 ℃ of temperature, stir during processing, the stirring linear velocity is 3m/s, reaction times 30min, filter the co-precipitation that obtains cobalt/cobalt oxide and Mn oxide, filtrate for later use;
(7) in and co-precipitation nickel and iron: add calcium oxide in the filtrate that makes to step (6) or sodium hydroxide is processed, the usage quantity of described calcium oxide or sodium hydroxide is 1 times of the required theoretical amount of iron nickel aluminium in the filtrate; Under the condition of 30～100 ℃ of temperature, stir, reaction times 30min, terminal point pH=7 filters the mixture precipitation that obtains nickeliferous and iron.
Embodiment 2, and a kind of nickel oxide ore Roasting And Leaching reclaims the method for nickel cobalt ferromanganese, and its step is as follows:
(1) ball milling: nickel oxide ore is carried out ball milling in wet-type ball mill, account for more than 60% for-100 orders to ore powder granularity, get breeze;
(2) mix: the additive that adds powdered ore quality 30% in the breeze; Described additive is that the first component of 1:20 and second component mix and form by mass ratio, and the first component is selected from least a in sodium-chlor, magnesium chloride or the calcium chloride, and second component is selected from least a in coke powder, coke, coal or the carbon; Get the breeze mixture;
(3) balling-up: in the breeze mixture, add an amount of water, make it form the ore deposit ball;
(4) roasting: the ore deposit ball is dropped in the roasting kiln, at 1300 ℃ of lower roasting 36h; Cool off to get the roasting mineral aggregate;
(5) leach: it is to leach processing in 34% the dilute hydrochloric acid that the roasting mineral aggregate is dropped into water or mass concentration, obtains the leach liquor of nickel oxide ore; The temperature that leaches when processing is 100 ℃, and the time is 180min, and it is 120:1 that the add-on of water or dilute hydrochloric acid accounts for the breeze weight ratio;
(6) enriching and recovering cobalt and manganese: add at least a in sodium chlorate, hypochlorous acid, hypochlorite, chlorine, black nickel or the potassium permanganate in the leach liquor and process as oxygenant, the oxygenant usage quantity is precipitate cobalt and the required theoretical amount of manganese 5 times, under the condition of 100 ℃ of temperature, stir during processing, the stirring linear velocity is 6m/s, reaction times 120min, filter the co-precipitation that obtains cobalt/cobalt oxide and Mn oxide, filtrate for later use;
(7) in and co-precipitation nickel and iron: add calcium oxide in the filtrate that makes to step (6) or sodium hydroxide is processed, the usage quantity of described calcium oxide or sodium hydroxide is 3 times of the required theoretical amount of iron nickel aluminium in the filtrate; Under the condition of 100 ℃ of temperature, stir, reaction times 120min, terminal point pH=9 filters the mixture precipitation that obtains nickeliferous and iron.
Embodiment 3, and a kind of nickel oxide ore Roasting And Leaching reclaims the method for nickel cobalt ferromanganese, and its step is as follows:
(1) ball milling: nickel oxide ore is carried out ball milling in wet-type ball mill, account for more than 60% for-100 orders to ore powder granularity, get breeze;
(2) mix: the additive that adds powdered ore quality 15% in the breeze; Described additive is that the first component of 1:100 and second component mix and form by mass ratio, and the first component is selected from least a in sodium-chlor, magnesium chloride or the calcium chloride, and second component is selected from least a in coke powder, coke, coal or the carbon; Get the breeze mixture;
(3) balling-up: in the breeze mixture, add an amount of water, make it form the ore deposit ball;
(4) roasting: the ore deposit ball is dropped in the roasting kiln, at 1100 ℃ of lower roasting 24h; Cool off to get the roasting mineral aggregate;
(5) leach: it is to leach processing in 15% the dilute hydrochloric acid that the roasting mineral aggregate is dropped into water or mass concentration, obtains the leach liquor of nickel oxide ore; The temperature that leaches when processing is 30 ℃, and the time is 120min, and it is 105:1 that the add-on of water or dilute hydrochloric acid accounts for the breeze weight ratio;
(6) enriching and recovering cobalt and manganese: add at least a in sodium chlorate, hypochlorous acid, hypochlorite, chlorine, black nickel or the potassium permanganate in the leach liquor and process as oxygenant, the oxygenant usage quantity is precipitate cobalt and the required theoretical amount of manganese 3 times, under the condition of temperature 60 C, stir during processing, the stirring linear velocity is 4m/s, reaction times 60min, filter the co-precipitation that obtains cobalt/cobalt oxide and Mn oxide, filtrate for later use;
(7) in and co-precipitation nickel and iron: add calcium oxide in the filtrate that makes to step (6) or sodium hydroxide is processed, the usage quantity of described calcium oxide or sodium hydroxide is 2 times of the required theoretical amount of iron nickel aluminium in the filtrate; Under the condition of temperature 50 C, stir, reaction times 60min, terminal point pH=8 filters the mixture precipitation that obtains nickeliferous and iron.
Embodiment 4, and a kind of nickel oxide ore Roasting And Leaching reclaims the methods experiment one of nickel cobalt ferromanganese:
Used nickel oxide ore consists of (% by weight): Ni 1.4, Fe 14, Co 0.08, MgO18.5, SiO
235.7, Mn 1.2, CaO0.3, Al
2O
36.08, Cr1.02.
Additive add-on (% by weight): 20%; The magnesium chloride of 1:5 and coke powder;
Add an amount of water in the breeze mixture, the ore deposit ball is dropped in the roasting kiln, at 900 ℃ of lower roasting 10h after making it form ore deposit ball; Cool off to get the roasting mineral aggregate; It is to leach processing in 1～34% the dilute hydrochloric acid that the roasting mineral aggregate is dropped into water or mass concentration;
Leaching condition: raw meal particle size-74 μ m accounts for 70%, to account for the breeze weight ratio be 100:1 to the add-on of water or dilute hydrochloric acid; 85 ℃ of extraction temperatures, extraction time 60min, stirring linear velocity 4.5m/s.Leaching yield: nickel 99%, cobalt 94%, iron 99%, manganese 85%.
Nickel oxide ore leach liquor principal element content following (g/L): Fe 25, Ni 4.5, Co 0.25, Mg 35, Mn 3, Al 1.5, pH=1.
Cobalt manganese oxidation and coprecipitation processing condition: add oxidation precipitation cobalt+sodium chlorate of 2 times of manganese theoretical amount, oxidation precipitation temperature 60 C, oxidation precipitation time 60min.Deposition rate: cobalt 82%, manganese 96%.The cobalt manganese mixture weight percentage composition that obtains is: Fe 3%, Ni 0.3%, Co 2.2%, Mn 32%.
In the ferronickel and the coprecipitation technology condition: the neutralization precipitation temperature 60 C, add calcium hydroxide slurry, control terminal point pH=8.5, iron deposition rate 99.9%, nickel deposition rate 99.5%.The weight percentage of ferronickel enriched substance is: nickel 7%, iron 50 %, MgO 4%.
Embodiment 5, and a kind of nickel oxide ore Roasting And Leaching reclaims the methods experiment two of nickel cobalt ferromanganese:
Used nickel oxide ore forms (% by weight): Ni 1.6, Fe 16 Co 0.07, MgO15.8, SiO
241.2, Mn1.1, CaO0.2, Al
2O
35.28, Cr0.92.
Additive add-on (% by weight): 28%; The sodium-chlor of 1:15 and coke;
Add an amount of water in the breeze mixture, the ore deposit ball is dropped in the roasting kiln, at 1000 ℃ of lower roasting 18h after making it form ore deposit ball; Cool off to get the roasting mineral aggregate; It is to leach processing in 1～34% the dilute hydrochloric acid that the roasting mineral aggregate is dropped into water or mass concentration;
Leaching condition: raw meal particle size-74 μ m accounts for 70%, to account for the breeze weight ratio be 95:1 to the add-on of water or dilute hydrochloric acid; 88 ℃ of extraction temperatures, extraction time 60min, stirring linear velocity 5m/s.Leaching yield: nickel 99%, cobalt 96%, iron 99%.
Nickel oxide ore leach liquor principal element content following (g/L): Fe 28, Ni 5.2, Co 0.22, Mg 30, Mn 2.93, Al 1, pH=0.5.
Cobalt manganese oxidation and coprecipitation processing condition: add oxidation precipitation cobalt+manganese theoretical amount 3 times of De Guo ?nickel, oxidation precipitation temperature 50 C, oxidation precipitation time 90min.Deposition rate: cobalt 88%, manganese 98%.The cobalt manganese mixture weight percentage composition that obtains is: Fe 4%, Ni 0.35%, Co 2.6%, Mn 38%.
In the ferronickel and the coprecipitation technology condition: the neutralization precipitation temperature 60 C, add calcium hydroxide slurry, control terminal point pH=9, iron deposition rate 99.9%, nickel deposition rate 99.5%.The weight percentage of ferronickel enriched substance is: nickel 8.5%, iron 55%, MgO5%.
Embodiment 6, and a kind of nickel oxide ore Roasting And Leaching reclaims the methods experiment three of nickel cobalt ferromanganese:
Used nickel oxide ore forms (% by weight): Ni 1.8, Fe 13, Co 0.08, MgO16.5, SiO
238.2, Mn1.8, CaO0.32, Al
2O
34.57, Cr1.15.
Additive add-on (% by weight): 18%; The calcium chloride of 1:8 and coal;
Add an amount of water in the breeze mixture, the ore deposit ball is dropped in the roasting kiln, at 1200 ℃ of lower roasting 30h after making it form ore deposit ball; Cool off to get the roasting mineral aggregate; It is to leach processing in 1～34% the dilute hydrochloric acid that the roasting mineral aggregate is dropped into water or mass concentration;
Leaching condition: raw meal particle size-74 μ m accounts for 60%, to account for the breeze weight ratio be 102:1 to the add-on of water or dilute hydrochloric acid; 90 ℃ of extraction temperatures, extraction time 60min, stirring linear velocity 5m/s.Leaching yield: nickel 99.5%, cobalt 99.5%, iron 99%.
Nickel oxide ore leach liquor principal element content following (g/L): Fe 24, Ni 5.9, Co 0.26, Mg 31.5, Mn 4, Al 1.2, pH=0.6.
Cobalt manganese oxidation and coprecipitation processing condition: add oxidation precipitation cobalt+clorox of 3 times of manganese theoretical amount, 40 ℃ of oxidation precipitation temperature, oxidation precipitation time 60min.Deposition rate: cobalt 80%, manganese 92%.The cobalt manganese mixture weight percentage composition that obtains is: Fe 3%, Ni 0.15%, Co 1.6%, Mn 28%.
In the ferronickel and the coprecipitation technology condition: 40 ℃ of neutralization precipitation temperature, add sodium hydroxide slurry, control terminal point pH=9, iron deposition rate 99.9%, nickel deposition rate 99.5%.The weight percentage of ferronickel enriched substance is: nickel 12%, iron 60%, MgO3%.
Claims (7)
1. the method for a nickel oxide ore Roasting And Leaching recovery nickel cobalt ferromanganese is characterized in that, its step is as follows:
(1) ball milling: nickel oxide ore is carried out ball milling in wet-type ball mill, account for more than 60% for-100 orders to ore powder granularity, get breeze;
(2) mix: the additive that adds powdered ore quality 5～30% in the breeze; Described additive is that the first component of 1:4～20 and second component mix and form by mass ratio, and the first component is selected from least a in sodium-chlor, magnesium chloride or the calcium chloride, and second component is selected from least a in coke powder, coke, coal or the carbon; Get the breeze mixture;
(3) balling-up: in the breeze mixture, add an amount of water, make it form the ore deposit ball;
(4) roasting: the ore deposit ball is dropped in the roasting kiln, at 800～1300 ℃ of lower roasting 1～36h; Cool off to get the roasting mineral aggregate;
(5) leach: it is to leach processing in 1～34% the dilute hydrochloric acid that the roasting mineral aggregate is dropped into water or mass concentration, obtains the leach liquor of nickel oxide ore; The temperature that leaches when processing is 20～100 ℃, and the time is 30～180min, and it is 90～120:1 that the add-on of water or dilute hydrochloric acid accounts for the breeze weight ratio;
(6) enriching and recovering cobalt and manganese: add at least a in sodium chlorate, hypochlorous acid, hypochlorite, chlorine, black nickel or the potassium permanganate in the leach liquor and process as oxygenant, the oxygenant usage quantity is precipitate cobalt and the required theoretical amount of manganese 1～5 times, under the condition of 30～100 ℃ of temperature, stir during processing, the stirring linear velocity is 3～6m/s, reaction times 30n～120min, filter the co-precipitation that obtains cobalt/cobalt oxide and Mn oxide, filtrate for later use;
(7) in and co-precipitation nickel and iron: add calcium oxide in the filtrate that makes to step (6) or sodium hydroxide is processed, the usage quantity of described calcium oxide or sodium hydroxide is 1～3 times of the required theoretical amount of iron nickel aluminium in the filtrate; Under the condition of 30～100 ℃ of temperature, stir, reaction times 30～120min, the mixture precipitation that obtains nickeliferous and iron is filtered in terminal point pH=7～9.
2. nickel oxide ore Roasting And Leaching according to claim 1 reclaims the method for nickel cobalt ferromanganese, it is characterized in that, in the step (2): the additive that adds powdered ore quality 15～20% in the breeze; Described additive is that the first component of 1:10～15 and second component mix and form by mass ratio.
3. nickel oxide ore Roasting And Leaching according to claim 1 reclaims the method for nickel cobalt ferromanganese, it is characterized in that, in the step (5): the temperature that leaches when processing is 20～45 ℃, and the time is 60～120min, and the hydrochloric acid add-on accounts for 50～100% of breeze weight.
4. nickel oxide ore Roasting And Leaching according to claim 1 reclaims the method for nickel cobalt ferromanganese, it is characterized in that, in the step (6): the oxygenant usage quantity is precipitate cobalt and the required theoretical amount of manganese 2～3 times, under the condition of 50～70 ℃ of temperature, stir during processing, the stirring linear velocity is 4～5m/s, reaction times 60～90min.
5. nickel oxide ore Roasting And Leaching according to claim 1 reclaims the method for nickel cobalt ferromanganese, it is characterized in that, in the step (7): the usage quantity of described calcium oxide or sodium hydroxide is 2 times of the required theoretical amount of iron nickel aluminium in the filtrate.
6. nickel oxide ore Roasting And Leaching according to claim 1 reclaims the method for nickel cobalt ferromanganese, it is characterized in that, in the step (7): stir reaction times 60～90min, terminal point pH=8 under the condition of 40 ℃～60 ℃ of temperature.
7. nickel oxide ore Roasting And Leaching according to claim 1 reclaims the method for nickel cobalt ferromanganese, it is characterized in that, in the step (5): it is 105:1 that the add-on of water or dilute hydrochloric acid accounts for the breeze weight ratio.
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| CN104263909A (en) * | 2014-09-28 | 2015-01-07 | 毛黎生 | Process for recovering nickel, cobalt and iron from nickel oxide ores by virtue of roasting and water leaching |
| CN105648238A (en) * | 2014-12-08 | 2016-06-08 | 张家彦 | Preparation method for obtaining nickel-based materials |
| CN107419089A (en) * | 2017-04-18 | 2017-12-01 | 彭海洋 | The method of low-grade high impurity ore magnetizing roast removal of impurities |
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| CN101798633A (en) * | 2010-03-24 | 2010-08-11 | 东北大学 | Method for treating limonite type oxidized nickel ore by roasting and leaching |
| CN101914691A (en) * | 2010-08-31 | 2010-12-15 | 中南大学 | Method for extracting nickel and cobalt by processing poor nickel laterite |
| CN102041381A (en) * | 2011-01-17 | 2011-05-04 | 河南永通镍业有限公司 | Method for recovering nickel, cobalt, iron, manganese and magnesium from oxidized nickel ore |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104263909A (en) * | 2014-09-28 | 2015-01-07 | 毛黎生 | Process for recovering nickel, cobalt and iron from nickel oxide ores by virtue of roasting and water leaching |
| CN105648238A (en) * | 2014-12-08 | 2016-06-08 | 张家彦 | Preparation method for obtaining nickel-based materials |
| CN105648238B (en) * | 2014-12-08 | 2018-07-13 | 张家彦 | A kind of preparation method obtaining nickel base material |
| CN107419089A (en) * | 2017-04-18 | 2017-12-01 | 彭海洋 | The method of low-grade high impurity ore magnetizing roast removal of impurities |
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